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By Frank M. Vodoklys

This is the final report on Contract H0220049 covering the period from 27 April 1972 to 30 April 1974. The objective of the contract was to develop and evaluate materials and methods to achieve post explosion identification of explosives reliably and economically through the use of phosphor coded grains incorporated into the explosive during its manufacture. A coding system of two spotting phosphors and seven coding phosphors was successfully developed during the execution of the contract. The ability of the coded grains to survive detonation in many different types of explosives was demonstrated and the complete code was extracted from a single 100 micron post-explosion fragment. A method was established for testing grain strength to correlate with field test results and an optical system was designed for extracting the code from the grains. Also in fulfillment of the contract requirements a laboratory method for manufacturing the coded grains was established and ten one-pound samples, each with a different code, were fabricated. Finally, a method was developed for applying a coating of polyethylene to the grains to prevent sensitization of the tagged explosives and the ten one-pound samples were coated and delivered to the Bureau of Mines.

Jan 1, 1974

By Pedro Lilienfeld

This report presents a design and cost investigation for several alternative versions of a field-worthy mining machine-mounted respirable dust monitor. Three main design variations are considered: (a) light scattering sensing, (b) Beta-filter tape sensing, and (c) a combination of the two preceeding methods. Eventual instrument production coats as a function of design complexity are tabulated. Cost estimates for the development and field testing of field-worthy prototypes are also presented. A general discussion on the technical aspects of these design alternatives is included following a modular-hierarchical approach of progressive complexity. The technical background to this report has been provided by the experience and results derived from the work performed under U.S. Bureau of Mines Contracts Nos. H0166097 and H0377092.

Jan 1, 1980

By Kim B. Shedd

The U.S. Bureau of Mines Particulate Mineralogy Unit examined the habits of six zeolite minerals commonly occurring in domestic zeolite deposits. Mineral habit is of interest because current theory on the potential for sarcoma production in test animals emphasizes the size and shape of mineral particles, without regard to composition or structure. A scanning electron microscopic study revealed that, of these six minerals, only mordenite and erionite crystallized in acicular to fibrous habits, The fibrous varieties of these two minerals were characterized by size and shape on the transmission electron microscope, and their dimensions were compared with those of asbestos and amphibole cleavage fragments. When comminuted, these two minerals possess "fibrosity indices" similar to those of amphibole cleavage fragments. One sample, a rare woolly erionite, has uniform widths, large aspect ratios, and a "fibrosity index" similar to those of asbestos.

Jan 1, 1982

By A. L. Foote

This is the final report of work accomplished during 1973-75 under U. S. Bureau of Mines Contract No. H0242015, "System for Handling Underground Mine Supplies and Materials." The purpose of the contract was to develop a mechanical device which could safely perform handling tasks that are normally done manually in underground bituminous coal mines. The report discusses studies leading to construct-ion of a battery-operated, three-wheel vehicle with a six-degree-of-freedom manipulator. Supportive design studies included collection and analysis of production, manual functions, and injury data on the underground bituminous coal mining industry. Transfer tasks in section storage and working places were the prime candidates for mechanical handling. Functional specifications were developed for two handling devices (one to handle existing unit loads and one to handle repackaged unit loads) and for a vehicle to mount the handling device. Design concepts for nine different handling devices were developed and a cost/benefit evaluation made for each. Detail design, capital and operating costs, and method improvement savings data were developed for two battery-operated vehicles and for two different manipulators. The three-wheel vehicle with anthropomorphic manipulator was chosen for development.

Jan 1, 1978

By Ross W. Smith

Microflotation and surface chemical studies were conducted on a chromite from the Stillwater Complex in Montana and on some of the minerals usually found to be associated with such chromites. Considering the chromite it was found that aging the ground mineral in air or heating it markedly affected its flotation behavior. Much of the observed effects could be attributed to oxidation reactions involving surface chromium and iron species. Strongly acid pretreating the mineral appeared to reverse such effects. Thus, it can be concluded that the manner in which the mineral (or the ore) is pretreated is of utmost importance in its flotation. Work carried out on associated gangue minerals determined how they are likely to behave in a flotation environment and how certain foreign ions derived from a chromite ore itself can affect their surface characteristics and, thus, presumably also their behavior in a flotation circuit.

Jan 1, 1981

By Walter L. Finlay

The Bureau of Mines has developed prototype instruments promising to improve the ability to warn of imminent roof falls. An unusually good opportunity to test these comparatively under natural caving conditions was afforded by the forecasted caving in August 1977 of a mined-out region of the White Pine Mine. The latter's rock strata closely resemble those in many coal mines. The anticipated cave was of the competent-roof/weak-pillar type. It occurred as, and when, predicted. Automated convergence and bed separation gages agreed well with the standard manual convergence gage measurements. A micro seismic gage was found to be insensitive to the fall and may require different test conditions for effectiveness. A roof resistivity unit was tested under a separate Bureau of Mines contract. (No. H02720J7). An unplanned addition showed interesting potential.

Jan 1, 1978

By John C. Edwards, Gene F. Friel

A series of liquid fuel fire experiments evaluated the comparative responses of five types of commercially available smoke detectors and a diffusion-mode carbon monoxide (CO) detector under normal and reduced airflow conditions based upon the alarm times of the detectors. These experiments were conducted in the Safety Research Coal Mine at the U.S. Bureau of Mines Pittsburgh Research Center. Two of the smoke detectors had manufacturer set alarms. For the other three smoke detectors, an alarm point was defined in terms of their background analog signal and the detector's electrical output noise under ambient conditions. A correlation was developed of the travel time of 5 ppm CO between pairs of CO detectors with the travel time calculated from entry and crosscut volumes and measured airflow. Based upon the relative performance of smoke detectors in this limited study, smoke detectors can be as effective as CO detectors for mine fire detection once identifiable alarm values are defined. Implementation of smoke detectors as part of an atmospheric mine monitoring system will improve mine safety.

Jan 1, 1996

By R. O. Dannenberg

The Bureau of Mines conducted laboratory batch and small-scale continuous tests to remove traces of dissolved molybdenum from water simulating waste discharged from a molybdenum concentrator, Molybdenum concentrations, initially ranging from 2 to 10 ppm, were decreased to 0.5 ppm or less by coprecipitation of the molybdenum with freshly precipitated ferric hydroxide" The precipitate was separated as a froth by dissolved-air flotation for subsequent disposal. Although the treated water met current environmental standards for contained molybdenum, contained particulate iron might have to be removed by filtration for the water to be acceptable. Estimated costs for treating concentrator effluent water were 55 cents, 57 cents, and 64 cents per 1,000 gal at initial molybdenum concentrations of 2, 4, and 10 ppm, respectively.

Jan 1, 1982

By James N. Bayne

An examination and analysis of Landsat digital data in the monitoring of surface mines in selected counties of South Carolina.

Jan 1, 1979

By Fred Leighton

The Bureau of Mines has developed rock noise source location techniques that may be used to obtain precise and practical source locations from micro-seismic field data. These techniques enable one to monitor all or any part of a rock structure and map progressive stress buildup or rock movement. Thus, the microseismic method of determining instability in rock structures is becoming an invaluable engineering tool for the mining or civil engineer engaged in rock excavation and construction.

Jan 1, 1970

By John E. Kelley

A method for measuring the spark-shower radiance of metals when abraded on a grinding wheel was developed by the Bureau of Mines for evaluating the sparking tendency of metals. The radiance was measured in units of emissive power per solid angle per area of the detector. Over 100 metals were tested and rated relative to commercially pure iron. The metals tested included elemental metals, iron binary and ternary alloys, iron-carbon ternary alloys, commercial steels, nonferrous alloys, and a few hard-metal compounds. Some alloys were synthesized; others were obtained commercially. Alloys that possessed good strength properties were emphasized for selection. The results indicate that the spark-shower radiance of plain carbon steels and carbon alloy steels was greater than that of pure iron. Certain elements, particularly vanadium and chromium, reduced the sparking tendency of iron. Stainless steels and particularly nickel alloys displayed low spark-shower radiance. Some metallic elements had much lower radiance than iron; others, much greater. Plain carbon steels, heat treated to a variety of hardnesses, gave radiance values that generally increased with increasing hardness. The effect on sparking tendency of an increase in hardness of an alloy steel was studied. The sparking tendency increased with an increase in hardness to a maximum, then decreased with a further increase in hardness.

Jan 1, 1974

By M. C. Irani

The Bureau of Mines, in cooperation with the Mine Safety Appliances Co., has developed a continuous-recording methanometer utilizing a catalytic combustion detector. The methanometer, which is presently operating at 22 exhaust fans at 14 mines in the Eastern coalfields, is reliable and simple to install, operate, and maintain. The instrument and the details of its installation and calibration are described. Analytical data obtained by infrared spectrophotometer and gas chromatograph are presented to substantiate its re liability.

Jan 1, 1974

By R. W. Stahl

The use of continuous mining machines has greatly minimized the necessity for blasting in coal mines, even during pillar recovery; however, explosives are still used to blast stumps. The use of improper blasting materials, improper procedures, or both has caused mine explosions and fires, with loss of life and property damage. Researchers and manufacturers are continuously improving explosives and blasting accessories; use of the more recently developed materials will make the blasting operation safer. Extreme caution is mandatory when blasting stumps, as the ignition of methane or coal dust may trigger an explosion or cause a fire. Since the blasting of stumps will no doubt continue, although often unnecessarily, this paper summarizes recent findings published by the Bureau of Mines and recommends safer methods.

Jan 1, 1962

By R. S. Dean

[During the past fiscal year the Metallurgical Division has made important contributions along the lines dictated by the Bureau policy of conservation of domestic mineral resources through Its investigations include determining of fundamental data of metallurgically important materials improvement of standard ore-treatment method to eliminate waste and improve the grade or recovery of the products; and development o new metallurgical processes.]

Jan 1, 1940

By G. Hakes

A data bank on bolter technology was assembled which included state-of-the-art industrial equipment as well as new equipment currently under development for the U.S. Bureau of Mines. This information was augmented by field visits to selected USBM contractors, mine operators and others for the purpose of obtaining a thorough understanding of present coal mine roof bolting safety and productivity problems. These direct contacts provided valuable insight regarding requirements for new bolting equipment necessary to assure wide user acceptance. Using this background material and information, a series of roof bolter concepts was developed offering improved operator safety with minimum impact on productivity. The concepts developed utilize existing componentry and technology wherever possible. All of the concepts feature a fully protected operator station located 6' to 10' outby the active bolt line and the hazardous rotating machinery.

Jan 1, 1978

By Derek Ellis

Volume II of this two-part series on Submarine Tailings Disposal (STD) as a tailings management option for coastal and island mines contains descriptions of lesser known case histories. The Misima gold mine (Papua New Guinea) and the Black Angel lead-zinc mine (Greenland) are described in some detail as the best documented cases. Atlas copper mine (The Philippines) is less fully described due to relative lack of documentation. The Misima and Atlas STD systems are working to their design criteria. At Black Angel the system adopted did not prevent contamination for a number of reasons, which are now understood. Two cases are described where STD is being developed. They are the Cayeli Bakir copper mine Turkey), and the Toquepala and Cuajone mines (Peru). There is excellent documentation available for both cases. Three case histories are described where tailings have reached the sea either through beach or river discharge. In one case the STD option has been explored (Marcopper Mine, The Philippines). In the others we explore in hindsight whether STD might have been a viable alternative using the Screening Criteria that this Volume develops - see below. The mines are Bougainville Copper Mine in Papua New Guinea, and Jordan River Mine (Canada). There is potential for STD at all three sites. Finally, the Volume presents Screening Criteria for appraising STD, based on the experience in design, operation and environmental impact reviewed in the case histories.

Jan 1, 1994

By L. C. IlsLey

Many accidents rightly classifiable as electrically caused are not so classified for the reason that in numerous accidents the part that electricity played in causing the fatality is only suspected. For instance, a workman might receive a shock that would cause him to lose his balance and fall beneath a trip of cars; if no one saw the first part of the accident, the cause undoubtedly would be charged to "haulage." This paper covers a brief study of fatal and nonfatal electrical accidents. The first usually result from direct contact with the electrical circuit or electrical apparatus; the second more often are the result of arcing or flashing due to handling defective apparatus or making repairs on "live" equipment or circuits. It is hoped that helpful suggestions may be offered for minimizing accidents of these two classes.

Jan 1, 1938

By PW Meisel

An hydraulic-powered reel system to minimize peak tension transients in shuttle car trailing cables has been theoretically designed and analyzed using a computer. A single spring-loaded take-up sheave stores or gives up cable to maintain tension within specified limits. Controls have been incorporated to shut down the vehicle before all cable is removed from the reel and to de-energize the cable in the event of a reel/cable jam. Full-scale hardware configuration drawings sufficient for manufacture of a test system have been completed.

Jan 1, 1983

By Rudolf E. Greuer

This study concerns itself with two topics of the mine ventilation - mine fire interface which, when the work for this study began, did not seem to receive sufficient attention. Section 1: Comments on Spontaneous Combustion of Coal in Mines It is attempted to describe heat generation, heat and oxygen transport, in such a way that existing experimental data for U.S. coals can be used to assess conditions inducive to spontaneous heatings quantitatively. Investigated are, in particular, critical air velocities, minimum sizes of coal accumulations, moisture contents and the influence of mining factors. An extensive, practice oriented literature survey is included. Section 2: The Early Detection of Mine Fires by Assessment. of Mine Gases The suitability of the major constituents of combustion products for an early detection of fires is discussed. The same is done for gas concentration ratios. Since it was felt (at least at the time when this report section was written) that the value of the carbon monoxide/oxygen deficiency ratio was overestimated, the usefulness of monitoring this ratio as compared to monitoring CO concentrations was critically investigated. The state of art concerning instrumentation and organization of fire detection systems is reviewed also.

Jan 1, 2011

By John G. Palmer

Continued development of an especially impregnated silica gel capable of reversible chemical detection of carbon monoxide (CO) was reported. The affects of changes in mine-related ambient conditions on the detection catalyst's response were explored. Temperature, humidity, and several interfering gases were found to affect the detection catalyst. The interferents include hydrogen sulfide, nitrogen dioxide, acetylene (and methylacetylene), and ammonia. High humidity decreased the detection catalyst's sensitivity to carbon monoxide for some formulations. Increasing temperature generally decreased the reaction time of the detection catalyst with carbon monoxide. Badges and carriers for the visual presentation of the detection catalyst were constructed. Several variations of these devices included provisions for absorbants and filtering agents which help protect the detection catalyst from gaseous interferents. A variety of catalyst support agents were tested in an effort to find the most suitable. Included were alumina, magnesium oxide, magnesium silicate, and several forms of silica gel. In addi tion to free-flowing forms of these sorbents, thin layer chromatography plates coated with cellulose, alumina, and silica gel and newly developed PTFE entrained silica gels were examined. A limited physical, chemical, and mechanistic characterization of the detection catalyst and the materials used to prepare it has been carried out. Metal component ratio studies, spectral, analytical, pH, and rate measurements were done.

Jan 1, 1982