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By M. E. Austin

Many numerical models for the tubular solid oxide fuel cell (SOFC) exist, with various degrees of sophistication. However, the question of what physics must be modelled, and what can be neglected has not been resolved. A parametric model is proposed and analyzed to quantify the influence of thermal phenomena such as reaction heat generation, cathode channel convective cooling, and thermal radiation with participating media. Currently, a three-dimensional model is used to simulate the conditions of an anode supported cell in the centre of a tube bundle. The interconnect and nickel foam spacers that bridge adjacent cells in series and parallel, respectively, are neglected thus enabling a domain consisting of a 45o azimuthal section of the tube. The conservation equations for mass, energy, and species transport are solved using commercial computational fluid dynamics software, and radiation heat transfer is also modelled using a Discrete Ordinates method. Finally, temperature-dependent material properties and reaction rates are used. The model predicts lower overall temperatures than models that do not include radiative heat exchange and more moderate temperature gradients than those that ignore participating media radiation. Further, different regimes are identified, from convection dominated heat transfer to radiation dominated heat transfer. The results can be used to aid in the selection of appropriate models for a given fuel cell operating regime.

Jan 1, 2005

By G. W. Diehl, G. A. Griffiths

"Gentlemen, one week ago, I attended the University of Minnesota's Annual Symposium on Mining, in Duluth. A good part of this symposium was dedicated to mill linings of rubber.At this symposium, three mining companies published results from long time full scale tests with rubber linings in mills at four different mines. These were the Republic and Empire Mines of Cleveland Cliffs Iron Company, the Groveland Mine of Hanna Mining Company and the Eagle Mountain Mine of Kaiser Steel Corporation. These papers will be printed in due time and I will not endeavour to relate their full contents, let me only say that in three of the plants, the linings were found to be very economical compared wi.th steel, and that these three are converting over completely to rubber linings, while the fourth, Empire Mine, reported no economical results as far as the shell lining goes, whereas the grates showed promise of becoming economical. The authors of the Cleveland Cliff's paper, however, stated that design improvements in the rubber lining possibly could result in an economical lining also for Empire Mine.That rubber linings in mills, in most cases, show better wear life than steel linings, is known by most of the audience. But, one thing that has not before been disclosed by the endusers is the effect of rubber linings on the grinding economy. All three papers mentioned above reported no change in capacity or grind and two of them reported a decrease in power consumption per ton ground. Hanna Mining reported an average decrease over a three year period for one mill of over 10%. This, of course, puts the economy of a rubber lining in a completely new light. Finally, a point of interest at this meeting was that all three papers emphasized the design aspect, Thus the industry has acknowledged what I believe to be a very important fact - the design of a lining is often more important than the material it is made of."

Jan 1, 1970

By B. Van den Bogaert, K. Binnemans, T. Van Gerven

Europium is one of the most critical rare-earth elements due to the limited supply of this element combined with a high demand for red lamp phosphors. Therefore, the recycling of europium from end-oflife lamp phosphors has become increasingly important. Photochemical reduction of europium(III) to europium(II) and subsequent removal from rare-earth mixtures by precipitation as EuSO4 is a very selective and efficient method to recover europium from binary europium/yttrium solutions. It is shown that full separation of europium and yttrium is feasible from laboratory prepared non-equimolar Eu/Y mixtures up to a ratio of 1/20, which reflect the composition of red lamp phosphors. Optimal conditions were determined at pH 4 with isopropanol as a radical scavenger, which is a less harmful and toxic compound than the commonly used formic acid scavenger. Europium removal efficiencies of more than 95% were achieved, with a purity of 98.5% of the EuSO4 precipitate. The irradiance of the used light source, expressed in mW/cm2, has a large impact on the illumination time needed to remove europium from the solution. It is observed that higher irradiance results in a shorter induction time, i.e. a period during which virtually no europium is removed, and a faster removal rate once the induction time has passed. The photochemical separation technique was applied to recover europium from leached industrial red lamp phosphor (YOX) powder, with a Eu/Y ratio of 1/30. Europium recovery of 50% was reached with a purity of 96%, proving the feasibility of this method for the recycling of europium from end-of-life lamp phosphors.

Jan 1, 2016

By Andre Vien, D. H. Hendriks, D. Willet, B. C. Flintoff

"For many years the training of mill operators was an informal process which involved senior operators training junior operators on an as-needed basis. Recognizing the needs and benefits of better training some companies, and even some provinces through legislation, have moved to ensure that a formalized training program exists in the plants. These programs tend to focus on basic safety and operations. Much remains to be done. With the more rapid incorporation of new processing and information technologies, and the goal to keep labour costs to a minimum by doing more with less, operator training has become a critical issue. This paper briefly examines the evolution of training programs, provides some measure of their effectiveness, and explores some recent developments which could have a very significant impact on the industry.PreambleOne can draw an analogy between operator training and the mechanical support of production equipment. When we buy a piece of process equipment it is critical that the mechanical installation be done properly to ensure that the device will operate at peak performance on start-up. Once the equipment is running, some form of preventive maintenance is required to ensure continued efficient operation. The operators and the equipment are both elements of the processing system, yet the former do not seem to get the same ""start-up"" or ""operating"" support. Are they not seen as critical to efficient operation? Why is this so? What impact does it have? How can we improve?These are all very logical and important questions, although the answers are not nearly so obvious. In the mineral processing industry, progress in operator training over the past thirty years has been limited and quite variable. To address the perceived need for a more coherent and consistent approach, some provinces have moved to incorporate basic training requirements in their legislation. Some plants have gone a few steps further by building integrated training programs into their operating culture. One conclusion which can be easily reached is that there are no standards, and that the range of training activity is great. In other words, a flotation operator is not a flotation operator is not a flotation operator. Their knowledge and skills are very much a function of training and experience, which are clearly corporate and site specific."

Jan 1, 1994

By E. Wusaty

"Fording Coal is a wholly owned subsidiary of Canadian Pacific Limited. The company was founded in 1968 to mine metallurgical coalfor export at the Fording River operations in southeast British Columbia.Today, Fording Coal Limited also operates the Whitewood mine under contract to TransAlta Utilities and the Genesee mine under a joint venture arrangement with Edmonton Power. Both these operations are located just west of Edmonton and produce subbituminous low-sulphur coal which is used for power generation. Fording also owns and operates two industrial mineral mines in the United States and is mining overburden under a lo-year contract with Syncrude Canada at Fort McMurray.As of December 1992, Fording Coal Limited owns and operates the Greenhills mine which was closed due to bankruptcy. This papers deals with the innovations and changes which have been made and those which are currently being implemented to make this operation competitive in the world export coal market. IntroductionOn December 4, 1992, following a tendering process, Fording Coal was awarded 80% controlling interest in the Greenhills mine by Trustee Arthur Andersen Inc. Assets acquired included 100010 of the land and coal leases and 80% of the major joint venture assets including all structures. The remaining 20% is owned by Pohang Steel Canada Ltd., a wholly owned subsidiary of Pohang Iron Steel Co. of Korea. The Greenhills mine had been in continuous operation since 1983 and was finally closed due to bankruptcy of its majority owner on October 31, 1992.A permit to operate the Greenhills mine was issued by the British Columbia government on January 29, 1993, and Fording Coal Limited started mining operations in late February 1993.To return the Greenhills mine to profitability significant changes were required in workforce productivity, mining methods and equipment selection. These mine plan changes are designed to make the Greenhills operation competitive in world markets, provide longterm employment for the company's workforce and ensure that a secure supply of coal is available."

Jan 1, 1994

By Bordeaux Sciences Agro-INRA UMR 1065 SAVE, S. Piutti, E. Benizri, S. Lopez

Ultramafic soils display high concentrations of nickel (Ni) and a number of nutrient deficiencies (e.g. N, K, P). Ni-hyperaccumulator plants have evolved on such environments, developed specific metal homeostasis showing concentrations of Ni sometimes above 1% in their aerial biomass (Baker & Brooks 1989). Alyssum murale, a Ni-hyperaccumulator, is commonly found around the Mediterranean but can grow on non-ultramafic soils as well, with an altitudinal extension ranging from sea level to 2000 m.a.s.l. Rhizosphere bacterial communities associated with Ni-hyperaccumulator plants can differ from those of non-accumulating plants growing at the same site. Among edaphic factors that could influence the phylogenetic structure of the bacterial communities, altitude and metal-bioavailability and in particular nickel could be significant. However, most studies have focused on analyzing soils with techniques that provide little detail about the phylogenetic structure of these bacterial communities present in ultramafic soils. The objectives of this study were to understand the specific changes in the structure of A. murale rhizosphere bacterial community that occur across two gradients: 1°) elevation and 2°) Ni geochemistry, using pyrosequencing technique (454-pyrosequencing of 16S rRNA gene). It was found that the higher the soil chemically-available Ni contents, the higher the relative abundance of Proteobacteria and Actinobacteria. On the contrary, the abundance of TM7 decreased with increasing levels of available Ni. Moreover, Chloroflexi was present with 53 to 77% of relative abundance. These results demonstrate that soil chemically-available Ni drives the bacterial community diversity in the rhizosphere of Alyssum murale regardless the elevation gradient and other different soil physicochemical parameters. These results should now be confirmed in different ultramafic edaphic environments worldwide (e.g. ultramafic lateritic covers) and in the rhizosphere of different hyperaccumulator taxa.

Jan 1, 2016

By Li Qihou, Liu Zhihong, Liu Zhiyong, Yao Wei

Black copper sludge, which mainly contains copper, arsenic and a little antimony, bismuth, selenium, tellurium, is an important recyclable secondary resource. In this paper, selective removal of arsenic from black copper sludge by alkaline oxidative pressure leaching was studied. The influences of alkali concentration, leaching time, leaching temperature, oxygen pressure, liquid-solid ratio and other variables on the leaching rate of arsenic, copper and tellurium were investigated. The results were as follows: when the leaching process was conducted at initial alkali concentration of 1mol/L, liquid-solid ratio of 10, stirring rate of 500r/min, leaching temperature of 140°C for 5 h and oxygen pressure of 2.5MPa, the leaching rates of arsenic and tellurium were 85.43% and 59.7% respectively, and copper, antimony, bismuth were not leached. Hence, arsenic has been removed effectively from black copper sludge, while the valuable metals such as copper, antimony and bismuth remained in the residue that can be further recovered easily. INTRODUCTION Black copper sludge is a byproduct in the purification process of copper electrolyte. Arsenic, antimony and bismuth are major harmful impurities in copper electrolytic refining system. The accumulation of these impurities will cause adverse effects, such as the increase of electrolyte resistance and power consumption and deterioration of cathode copper quality (Wang, Liu, & Zhang, 2001). Hence, electrolyte purification is an essential part of the electrolysis process (Liang, Chen, & Guo, 2009). Electrolyte purification methods include electrowinning (Davenport, King, Schlesinger, & Biswas, 2002), solvent extraction (Navarro, Simpson, & Alguacil, 1999), ion exchange (Arroyo et al., 2017), coprecipitation (Wang et al., 2003, 2018; Xiao et al., 2007; Xiao, Cao, Mao, Shen, & Ren, 2014), activated carbon adsorption (Navarro & Alguacil, 2002), electrodialysis (Cifuentes et al., 2015), redox process (Zhou, Peng, Zheng, Ma, & Cui, 2011; Peng, Zheng, Zhou, & Chen, 2012; Zheng, Peng, Ke, & Chen, 2013), among which the electrowinning method is simple in operation and effective in impurities removal, making it the main process for current electrolyte purification. Some copper ions can react with harmful impurities to form complex black copper sludge by controlling the operation conditions of electrowinning process. Based on the estimated data provide by Davenport et al. (2002), an annual output of 400,000 tons cathode copper could produce 432-2168 tons of black copper sludge by electrowinning method. Black copper sludge contains 30~50% copper, 15~30% arsenic and a small amount of rare elements such as selenium and tellurium. Thus, recovery of valuable metals can bring huge economic interests. Moreover, arsenic in these sludges could cause significant environmental pollution. Therefore, effective removal of arsenic from these sludges is urgent and significant.

Jan 1, 2019

By S. Eckert, M. Reuter, O. Keplinger, D. Obiso, N. Shevchenko, M. Akashi

We report on laboratory experiments focusing on bubbling phenomena arising from gas injection through a top submerged lance (TSL) in a liquid metal layer. The objective of this study is to reveal the characteristics of the formation and behaviour of the particular bubbles at different gas flow rates and submergence depths of lance. Visualization was performed in the eutectic alloy GaInSn using X-ray radiography. Argon bubbles were injected through the injection positions at three different submergence depths. Essential parameters such as the bubble size, bubble shape, detachment frequency and the two- dimensional gas distribution in the flat vessel were obtained by image processing. The results show that the deep position of the submerged lance causes an asymmetric large-scale circulation inside the fluid vessel. Bubble detachment frequencies were calculated by Fast Fourier Transformation from fluctuations of the image intensity in the vicinity of the nozzle injection point. This frequency does not show strong variations with respect to changes of the gas flow rate and the submergence depth of the nozzle. An increasing gas flow rate results in an increasing two-dimensional projected bubble area and the occurrence of a significant number of small bubbles being trapped by the strong fluid flow in the liquid metal layer. INTRODUCTION The Top Submerged Lance (TSL) process has been an essential component of the metallurgical industry since the emergence of first concepts about 50 years ago (Floyd, 2005). The process, which is characterized by blowing reactive gas through the submerged lance into a liquid bath, was developed mainly for improving the tin smelting process and has been applied for waste treatment or the production of several metals such as copper, lead, nickel and zinc. The productivity of the reactor is determined mainly by the efficiency of the chemical reaction between the gas or solid particles and the liquid. To achieve a high efficiency requires good exchange between the gas-liquid phase and therefore a large interface area. The efficiency changes greatly with the number and size of bubbles injected from the nozzle and the extent of splashing on the free surface. The degree of turbulence in the bath plays a decisive role here. For the reason, the design of an efficient TSL process requires a profound knowledge of the fluid dynamics especially for complex multiphase flows.

Jan 1, 2019

By Xuanxue Mo, Zengqian Hou

"Yidun Island Arc in Sanjiang Region is one of the important Kuroko-type volcanogenic massive sulfide deposits (VMS) districts in southwestern China. Tectonically, the region is situated in the eastern portion of the Tethys orogenic belt, and is a late Triassic extensional island-arc. The island-arc underwent earlier arc construction, intra-arc rifting, later arc construction and backarc spreading during its evolution and formed a complete trench-are-basin system, i.e., the Ganzilitang suture zone, forearc basin, outer are, intra-arc rifting zone, inner arc and back-arc basin from east to west across the island-arc.Kuroko-type VMS deposits and occurrences discovered so far are limited to within the intra-arc rifting zone of the Yidun Island Arc and tend to occur in groups or clusters distributed in separate faultbound basins; e.g., Zengke, Gacun and Xiangcheng basins, in which submarine volcanic rocks, especially bimodal volcanic suites, were extensively developed. The VMS deposits formed in the waning stages of volcanic eruption in the late Triassic and are hosted in the uppermost section of acidic volcanic rocks (rhyolitic-dacitic) within a bimodal suite. The orebodies are associated with these host rocks: rhyolitic-dacitic pyroclastic rocks and exhalites and chemical sedimentary rocks.All VMS deposits in Sanjiang are of the Zn-Pb-Cu type. The architecture of the deposits is twofold, consisting of concordant lenses and layers of massive sulfides and an underlying discordant stockwork. All deposits show metal zoning. The hydrothermal alteration related to mineralization is strong and asymmetrical, and is found dominantly within the stockwork zone and host rocks surrounding the ores. There are two alteration patterns: (1) chloritization - sericitization - silicification from outer sides to core of the alteration pipe; and (2) silicification + sericitization - silicification + carbonate from the lower to upper part of the alteration pipe.The mineralization temperatures of ore-forming fluids vary in the range 200°C to 335°C. Thermal evolution of the fluids displays temperature profiles that first increase and then decrease with progression of mineralization processes. The majority of black-ore minerals (Groups I and informed during intensifying stages of hydrothermal activity, and the majority of semi-yellow-ore minerals (Group III) formed during a thermal maximum. There followed the formation of fine-grained black-ore minerals (Group IV), which interacted with barite layers during decreasing temperature phases.Oxygen and hydrogen isotope studies show that the sources of ore-forming fluids for the Kurokotype VMS deposits are two-fold: seawater and magmatic hydrothermal solutions, represented by the Kuroko deposits in Japan and Kuroko-type VMS deposits in Sanjiang, respectively. In the latter case the hydrothermal solutions reacted with host rocks and mixed with cold seawater percolating downward, and circulated through volcanic rocks resulting in development of alteration zones and formation of ore minerals in Kuroko-type VMS deposits."

Jan 1, 1993

By Antonio Laguna

During the past few years, synthetic efforts have been addressed to the synthesis of polymeric materials with optical or semiconducting properties or even with capabilities to act as sensors for volatile organic compounds (1). The most recent studies have been concerned with the synthesis of heterometallic systems with short metal-metal interactions and the determination of their optical properties. These complexes are undoubtly interesting from a theoretical viewpoint and include an emerging class of luminescent materials, in which the observed luminescence results mainly from the interactions among the different metal centers, as well as the environments of these atoms. The understanding of the photophysics and photochemistry of these products could permit the design of complexes with appropriate metals and ligands chosen for individual applications. Following a synthetic strategy consisting on reactions between acid heterometal complexes and basic gold precursors we have succeded in synthesizing supramolecular assemblies formed via acid-base stacking, which display tunable luminescence or selective and reversible sensitivity to Vapour Organic Compounds (VOC?s) (2-5). In this sense, in accord with previous Mössbauer studies carried out in the gold precursor complex [AuR2]- (R = C6F5), the basic properties of this and related materials have been employed as building blocks of supramolecular assemblies in their reactions with complexes in wich the metallic centers act as lewis acids as, for instance, Tl(I) or Ag(I) (6). For instance, in the case of silver, by reacting equimolecular quantities of [NBu4][Au(C6F5)2] with AgClO4, in acetone, a solid of stoichiometry [Au2Ag2(C6F5)4(OCMe2)2]n is obtained. The polymeric nature of this material in solid state is confirmed through X-ray analyses (figure 1). It consists of polymeric chains formed by repetition of Au2Ag2 moieties linked through short gold-gold interactions. Nevertheless, in solution, the nature of this polymeric materials was still a matter of controversy and, in this case, the optical properties have been shown as useful tools in order to obtain information. Thus, while dilute acetone solutions of this complex give a emission coming from pentafluorphenyl localized ??* excited states, in accord with the presence of isolated tetranuclear Au2Ag2 units, when the measurements are done at different and higher concentrations, a band that does not obey the Lambert-Beer law appears. This deviation is consistent with molecular aggregation in solution of these units through gold-gold interactions, and a clear correlation between the emssion wavelength and the structure in the solid state and in solution is shown (figure 2). DFT calculations accord with the observed experimental behaviour and show the nature of the orbitals involved in each transition.

Oct 1, 2003

By Chen Bang, Xia Xiao’ou, Zhang Feng

"Ores with compressive strength lower than 150 MPa are usually easy to be crushed by conventional jaw crushers and cone crushers. However, for hard ores with compressive strength exceeding 150 MPa and 200 MPa and even up to 250 MPa, such as andesite, hard basalt and olivine, it is difficult to reach satisfactory crushing size and yield or difficult to meet service life and stability use requirements of quick-wear parts by using conventional crushers. As continued increase in ore mining depth and constant generation of new type materials, equipment demand for crushing hard ores becomes increasing high. A new type inertia vibrating crusher is designed. It is powered by a high-speed rotating vibration exciter and can obtain required crushing force by adjusting eccentric mass, eccentricity and rotating speed so as to crush various ores with high hardness. This paper introduces the design process of its structure and working principle, discusses the design calculation methods of vibration excitation system, vibration damping and energy storage system and other key mechanism and provides technical references for this type of vibrating crusher.DESIGN PHILOSOPHYThe conventional jaw crusher mainly acquires extrusion force from crank motion to realize crushing. The motor drives the eccentric shaft via the transmission device to bring the moving jaw to swing relative to the stationary jaw. When the moving jaw moves close to the stationary jaw, ores between them are crushed by extrusion; when the moving jaw moves away from the stationary jaw, crushed ores are discharged from the discharge gate at the lower end between the moving jaw and the stationary jaw.The conventional spring cone crusher and the hydraulic cone crusher mainly acquire extrusion force from cranking motion to realize crushing. The motor drives the eccentric sleeve via the transmission device, the moving cone shaft generates an eccentric distance to make cranking motion under the action of the eccentric sleeve. When the moving cone moves close to the stationary cone, ores between them are crushed by extrusion. When the moving cone moves away from the stationary jaw, crushed ores are discharged from the discharge gate at the lower end between the moving cone and the stationary cone under the action of dead weight."

Jan 1, 2016

By C. Bazin

"Discrete transfer functions which use the grinding circuit feed tonnage to predict mass flowrates at reagent addition points in the flotation circuit were calibrated using a dynamic grinding/flotation simulator. Predicted values are multiplied by g/t ratios to calibrate reagent flow. The transfer functions are currently integrated into the distributed control system at Les Mines Selbaie.INTRODUCTIONThe development of adequate tools for the control of flotation processes is a continuous challenge. Since the early 1970's there have been numerous publications dealing with practical applications of flotation process control. A review of that literature shows that basic feedback and feedforward controls are the two preferred strategies for flotation processes. Some advanced control schemes started to emerge (e.g. Zaragoza and Herbst, 1988). Feedforward and feedback aim at reducing the effect of the following flotation process disturbances (e.g. McKee, 1991):0 Changes in throughput;0 Changes in feed grade;0 Changes in particle floatability (size, liberation, surface oxidation ... );0 Deliberate changes of set-point;Feedforward strategy acts on manipulated variables, mainly reagent addition, to attenuate the effect of disturbances such as changes of feed rate and grade. The feedforward strategy is driven by measurements of disturbances. Feedback control acts to compensate unmeasured disturbances, such as ore floatability, and to bring process variables to targeted set-points of concentrate or tails grades. The feedback control action is driven by set-point error, caused by either a deliberate change of set-point or unaccounted disturbances.This paper proposes a way to improve feedforward control schemes by addition of a simple model of solids transportation. The feedforward strategy considered in this paper is of ratio type, i.e. the manipulated variable is changed according to a predefined ratio between this variable and the measured disturbances. A typical example is the ratioed reagent addition to mass flow of ore."

Jan 1, 1993

By P. J. van Staden

Several differences exist between the columns used for laboratory simulations of heap leaching and commercial heaps. Column walls support part of the weight of the ore and restrict the particle packing arrangements. Columns are typically of a diameter that is smaller than the dripper spacing to be used on the commercial heaps. The stacking practices that cause segregation and stratification on heaps are absent from columns. Intuitively, these physical differences would be expected to be the reasons behind the observed differences between column and heap leaching performance. But how can they be quantified, and what is the magnitude of the differences? Could some of these differences be built into column leaching experiments in order to better simulate commercial-scale heap leaching performance to ease the scale-up calculations from column leaching data? Alternatively, could heap construction practices be improved so that the ideal performance obtained in columns could be emulated on heaps? Data from a few heap leaching cases studies that permit direct comparisons between column and heap leaching performance is analysed, to reveal the extent of the differences in resistance to mass transfer. Discussion is provided on the implications for column and heap leaching practice, and for scale-up design procedures. INTRODUCTION Differences have been known to exist between leaching performance observed in laboratory columns and that of commercial-scale heaps. Both the heap leaching kinetics and finally achievable extent of extraction are generally found to be inferior in heaps compared to that achieved in columns. Heap leaching design engineers extrapolate the anticipated heap leaching performance by multiplying the time-axis of a column-leaching curve by a factor of about 2 and the extraction-axis by a factor of about 0.8, as explained by Jansen and Taylor (2002), Scheffel (2002), John (2011) and Scheffel, Guzmán, and Dreier (2016). The procedure is illustrated in Figure 1 by means of a hypothetical example. The solid line represents the leaching performance observed in a laboratory column, and the dashed line represents the anticipated leaching performance of a heap, extrapolated from the column leaching data using these empirical scale-up factors.

Jan 1, 2019

By D. A. Brown, C. Lowe

"Abstract -A multi-sensor (electromagnetics, magnetics, gamma-ray spectrometry, and VLF) geophysical survey was recently conducted in the Purcell Basin of southeastern British Columbia in an area encompassing the world-class Sullivan Sedex deposit. The purpose of the survey was to geophysically characterize the known mineral occurrences and to develop strategies to enhance future mineral exploration in the basin. Follow-up investigations of geology and measurements of rock physical properties helped constrain interpretations of the geophysical data sets.Despite extraction of more than 90% of the ore from the Sullivan deposit, it is clear that the mineralization there, as well as at other Sedex occurrences surveyed, is characterized by high conductivity values, strong bedrock conductors, and elevated magnetic anomaly values. The albite-sericite alteration which accompanies this mineralization yields high potassium and low thorium-potassium ratio values. Associated Moyie gabbro is characterized by low electrical conductivity and radioelement concentrations and by high magnetic anomaly values. The study has also aided exploration for other mineral deposit types including stratabound Cu-Ag, placer gold, vein and disseminated basemetal deposits. In addition, the geophysical data have helped constrain geological interpretations of the basin."

Jan 1, 1998

By Laxman M. Amaratunga, David N. Yaschyshyn

"In the mining industry several types of fills are used for backfill operations. They are broadly categorized into three basic types: rock fill, hydraulic/slurry fill, and paste fill. Recently, paste fill has become the popular alternative for backfilling because of its many environmental and operational advantages including its ability to use total tailings, both fine and coarse fractions.Amaratunga and Annor (1989) first presented the concept of agglomeration of fine tailings, which are otherwise excluded from backfilling, for utilization in backfill as a readily available supplementary fill material. Previous experimental work investigated the use of agglomerated fine gold mill tailings in low density slurry fills (60 -70% pulp density), consisting of varying agglomerate and tailings compositions.This paper presents the ongoing research into utilizing these agglomerates in a high density paste fill (70 -85% pulp density). Various binder dosages, curing period and combinations of pellet to tailings ratios were studied. Slump of the raw fill and compressive strength of the cured fill were examined. Results from the above study indicate that agglomerated tailings paste fill (ATPF) has superior strength characteristics when compared to total tailings paste fills.IntroductionThe Canadian mining industry produces more than 500 million tonnes of tailings and waste rock annually. These tailings consist of a coarse fraction and a fine fraction and can be either reactive (acid generating) or non-reactive. Most mining operations utilize the coarse fraction for backfilling while the fines have been traditionally disposed of in surface tailings ponds. Recently, paste fill has been developed which uses a fraction of the fine tailings (10 - 30% w/w of >45 µ,m) in the fill. This development allows a mining company to use a portion of the fines for backfill, but still requires surface impoundment of the unused portion of fine tailings. Reactive tailings have the added problem of generating acid after being oxidized in the presence of air and water. Treating acid mine drainage (AMD) seepage from these ponds has proven to be a costly environmental problem and long term liabilty.One practical method to reduce the environmental impacts associated with the tailings pond and to modify the physical and chemical properties of the fine mill tailings so that they can be utilized and disposed of in an environmentally safe manner through surface or underground applications is through agglomeration using the Cold-Bond Tailings Agglomeration technology (CBTA). Amaratunga and Annor (1989) first presented the concept of agglomeration of fine tailings for use as coarse aggregates for underground backfill, gravel or surface covering material. CBT A reduces the necessity of impounding tailings on surface while providing a suitable coarse aggregate resource material for practical use. Although the CBT A technology has been mainly limited to pelletization agglomeration alone, other forms of agglomeration like pressure agglomeration which include the techniques of briquetting and extrusion have also proven successful (Amaratunga, 1995)."

Jan 1, 1996

By Jan E. Nesset, L. Paul Staples

"High Gradient Magnetic Separation (HGMS) technology, although developed over 2 decades ago, has not been widely applied to the separation of sulphide minerals. Under conditions of strong magnetic field gradients, weakly magnetic minerals such as chalcopyrite (CuFeS2) and marmatite (Zn(Fe)S, sphalerite with iron in solid solution) behave paramagnetically and can be effectively separated from diamagnetic minerals such as galena (PbS). The application of this technology to the separation of Cu-Pb and Zn-Pb bearing streams in the treatment of fine grained complex sulphides may in some cases be more effective than separation by flotation. A 2 TPH Sala HGMS pilot plant was operated at Brunswick for a nine month period, ending in March 1995. The testing demonstrated the mechanical reliability of the technology, the consistency of operating results and the scale up from laboratory testing. HGMS is seen as a complimentary technology to flotation, best suited to performing those separations of galena (and other diamagnetics) which flotation does not do as well.IntroductionBackgroundSince the turn of the century, the magnetic character or magnetic susceptibilities of minerals have been determined with increasing precision and accuracy. Figure 1 illustrates specific magnetic susceptibilities of some common minerals. As long as susceptibility ranges do not overlap, separation is possible.In 1937, the principle of using a magnetizable matrix material in a magnetic field to increase both magnetic flux density gradients and number of capture sites for susceptible minerals was first applied (Frantz). It was not until the 1970's, however, that the genuine development of wet high gradient magnetic separation began with the introduction of very fine matrix materials to the magnetized volume of large solenoid magnets. Today, dozens of HGMS units purify, filter and separate minerals, primarily for the removal of iron stained minerals from clays used in the paper coating and china clay industries and for the recovery of fine titanium and iron oxides in the iron ore industry. Only the Garpenburg mill in Sweden is currently applying a continuous HGMS machine to separate complex sulphide minerals; upgrading a lead concentrate since 1988."

Jan 1, 1996

By Adriana Ramirez, Bradford C. Wesstrom, Blanca Olave

The Freeport McMoRan El Paso Copper Refinery optimizes electrolyte quality using a number of systems. The facility controls copper, arsenic, antimony and bismuth using electro-winning cells within the Tank House and Nickel Carbonate Plant Liberator Circuit (NCP). The NCP manages sulfuric acid content utilizing recycled electrolyte in the slimes autoclave as well as operation of the Acid Purification Unit, APU. The El Paso Refinery removes common sulfates using metal hydrolysis with sodium carbonate. Finally, a Mechanical Vapor Recompression, (MVR), at the water recovery plant removes sodium sulfate generated by the NCP. This paper will provide a summary of these operations. INTRODUCTION In the mid 1920’s Nichols Copper Company, in Laurel Hill, New York, recognized the need for a modern copper refining facility in the southwest. Because of the many railroad heads, affordable power and abundant labor supply, and the close proximity to regional copper smelters in Mexico, Arizona, and New Mexico, El Paso became the ideal location. In December 1928, ground was broken for the joint venture refinery between the Nichols Copper Company, Phelps Dodge, and the Calumet and Arizona Mining Company. In September 1930, Nichols Copper Company became a part of Phelps Dodge Corporation after a stock exchange. In July 1938, Nichols Division officially became Phelps Dodge Refining Corporation. In March 2007, Freeport McMoRan Copper & Gold acquired Phelps Dodge. Water is a precious commodity in the desert southwest, making conservation of this natural resource an important goal for the El Paso Operations. In the 1980’s, work on the treatment of slimes was improved through the use of pressure leaching of the refinery slimes using an autoclave. Due to the high tellurium content in the leached slimes solution, it was crucial to implement a method for its removal before the solution returns to the tank house electrolyte. A copper telluride cementation operation was installed for tellurium recovery and the ability for the recycle of the leachate and wash water to the refinery electrolyte. In October of 1997, ground was broken for the construction of the water recovery plant using an MVR to reuse process water, reducing water consumption by 25%. In 2002, electrolyte purification was further improved with the installation of an Acid Purification Unit, (APU) (Sheedy, Pajunen, & Wesstrom, 2007). The APU recycles 90% of the acids (both sulfuric and arsenic acids) back to the tank house electrolyte. The solution that passes through the APU is treated with soda ash to precipitate metals out of solution as carbonates and generates a sodium sulfate solution. This sodium sulfate solution is easily processed in the new water recovery plant, where the majority of the water recycles back into the plant as pure condensate. In 2012, the power plant at the refinery upgraded its Reverse Osmosis System to provide RO water to the tankhouse. This insured that the refinery would not have to bleed electrolyte for metals contained in well water such as: calcium, magnesium, iron and sodium chloride.

Jan 1, 2019

By Szilvia Szabo, Jozsef Paulovics, Ljudmilla Bokanyi

"Waste recycling is one of the most important challenges of the XXI century. The recycling of wastes is closely related to and bases on the mineral processing. Many mineral processing techniques and equipment are applied in this field. The principles of the characterisation of wastes and design of technologies is rather similar to the classic mineral processing. Nevertheless, the diversity of the wastes and their complex composition and properties, as well as their environmental impact requires a special approach.Solar elements have sandwich structure of glass substrate and cover, as well as a very thin semiconductor layer. CdTe semi-conductor can be recycled by flotation. Within the RESOLVED (LIFE European Framework) R&D project on the recycling of solar elements the surface properties of pure CdTe semiconductor and pure glass were investigated by the measurements of zeta-potential using Zeta PALS Brookhaven instrument at University of Miskolc. Applied surfactants were: potassium ethyl xanthate; the anionic oxhydryl Aero Promoter 825 or Flotinor SM 35; the cationic Armoflote 43 or Armoflote 64, as well as Hostaflot LET (dithiophosphoric acid diethyl ester) and Hostaflot M91 (mercaptobenothiazole). The tested electrolyte was sodium-silicate. Zeta-measurements were carried out in full pH-range. Interfacial interactions were detected and interpreted. The basic results were verified by the flotation kinetic tests.Finally, the flotation technological experiments were carried out at a semi-technical scale using the real obsolete solar elements. The particle size at the liberation degree of 98% was as fine as below 5 µm. A special flotation cell providing the generation and distribution of very fine air bubbles was built. The pre-concentrate for the manufacturing of the test solar module was performed and transported to the BAM Institute (Berlin), the principal co-ordinator of the Project, and then further to the First Solar (USA) where a new panel was manufactured using recycled semi-conductor."

Jan 1, 2016

By Dirk Claessens

The term ?cost? is too small when describing the destructive power of safety incidents for mining companies. Breaches in employee or environmental safety are felt way beyond the bottom-line: human life can be taken; ecosystems tarnished; the ire of peoples, media and government inflamed; significant halting of production; and high levels of legal and financial challenges. According to a recent survey of Mining executivesi, ?ensuring workforce safety? was the most important issues identified above any other, with a plurality of 31 percent, reigning above capital projects, product efficiency, and equipment reliability. We accept that safety is a most paramount issue, yet for many reasons we keep approaching the problem the same way we have in the past. We need to stop doing the same things decade over decade and try something new. New innovations are significantly changing the fundamentals of how mining companies explore, excavate, produce, refine and distribute their valuable commodities. Technologies such as visualization, analytics, location awareness, and gaming simulation are making these enterprises smarter. Now, attention turns to an area we?ve long held as integral to our business: safety. By using the same breakthrough technologies that are changing our business, we can now boldly imagine ? and credibly strive for ? a world of zero incidents.

Aug 1, 2013

"In 1989, improved milling and recoveries resulted in a record production of 7 722 200 Ib Nb2P5 at the Niobec Mine. At the beginning of 1990, proven and probable reserves stood at 11 952 000 tons grading 0.65% Nb205. This year, the world steel market has slowed and as a result, niobium consumption is down. Consequently, production at the mine dropped 14% for the second quarter.IntroductionThe Niobec Mine is located approximately nine miles northwest of Chicoutimi, Quebec, (Fig. I). After ten years of production, the Niobec Mine is the only operating niobium mine in North America and the second largest producer of niobium in the world after Brazil.The Niobec Mine is a joint venture held equally by Teck Corporation and Carnbior. Teck Corporation operates the mine while Cambior is responsible for marketing and selling the niobium pentoxide concentrate (Nb2P5).The deposit was discovered in 1964 following an airborne radiometric survey in search of uranium. However, mining of the deposit did not begin until 1976. The initial production capacity of 1500 tons per day was increased several times to the present capacity of 2450 tons . The deposit is considered as an ample source of pyrochlore concentrate for at least 15 years at the present production rate.Niobium, also known as columbium, is a greyish-white metal used primarily as an alloy in various steels and other metals. The use of niobium in alloys heightens tensile strength and improves corrosion resistance while at the same time reducing the weight of the alloy. Niobium is also used in the fabrication of steel for the aerospace, automobile, and oil and gas pipeline industries. Although substitutes for niobium exist, their use often results in diminished performance and net cost increases."

Jan 1, 1990