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By Zhang. L.

Ordered intermetallic PtSb had been synthesized by arc-melted and then sintering treatment. The electro-oxidation of formic acid on PtSb was investigated at room temperature by cyclic voltammetry and chronoamperometry. The results are compared to those at a polycrystalline platinum electrode surface. It was found that PtSb intermetallic was catalytically more active than pure platinum according to the onset potential and current density. XRD and XPS technologies had been used to investigate the crystal structure and electron effect. We think formic acid decomposition on PtSb favors the reactive intermediate route and is not very much affected by the CO intermediate as compared to Pt.

Jan 1, 2005

By A. A. Burgoyne

"The McDame chrysotile asbestos deposit located near Cassiar in northern British Columbia isfound at depth and on trend to the southeast of the currently mined open-pit Cassiar asbestos deposit. The ultramafic rock hosting the McDame is serpentinized peridotite of the Upper Paleozoic Sylvester Group contained in an ophiolitic sequence preserved within a lower thrust sheet of the Sylvester Allochthon. The Sylvester stratigraphic package is a series of thrust slices composed of argillite, tuff and volcanic flows, diorite and serpentinite. Contacts between units are often fault-controlled.The McDame asbestos-bearing ultramafite is considered to represent a separate interleaved fault-bounded slice of rock distinct from the Cassiar asbestos deposit.Asbestos mineralization of the McDame deposit was discovered in /978. Exploration during /980 and /98/ focused on extensive underground drilling of the deposit and in /983 on geological mapping, airborne and ground magnetic surveys. In /984 a 622.5 m borehole was drilled with a 242 m intersection of McDame ultramafite of which the lower 15/ metres contain potentially economic chrysotile asbestos. The McDame deposit averages 90 m thick, trends north-south, dips easterly and plunges southeasterly. The deposit is estimated to contain geological reserves in the order of 62 million tonnes containing asbestos fibre similar in value to the Cassiar deposit.The McDame is considered a major world-class asbestos deposit. A decision to develop and mine the deposit will require further substantial underground exploration and evaluation. A + 1200 m exploration adit driven to the hanging wall of the deposit was undertaken in 1985 in anticipation of bulk sampling and diamond drilling in 1986."

Jan 1, 1986

By S. I. Vobnout, J. Wm. White, J. P. Olson

"Mine management now recognizes the value of computer-based truck-shovel dispatching in open pit mines. The key tangible benefits are substantial productivity increases with a given fleet of equipment or, alternately, significant reductions in equipment required to meet production quotas. In this paper, the authors review the literature, report on efficient, optimal algorithms for haul truck dispatching in real-time, and briefly discuss methods used by various mines to evaluate productivity improvements over manual methods. Actual results obtained at thirteen mining operations around the world are also presented.IntroductionModular Mining Systems manufactures, installs, and supports its computer-based DISPATCH system at mines worldwide. DISPATCH is a large scale, computer-based mine management system which controls the dispatching of all haul trucks in any open pit mine (Fig. 1). When increased production is important, DISPATCH gets the needed production increase with fewer new or recommissioned trucks. DISPATCH also helps operations meet its blending objectives while minimizing rehandle and maintaining production. Furthermore, DISPATCH includes a powerful, eventdriven simulation subsystem. With the simulator mine management can pose ""what if' situations and see the predicted effect on production"

Jan 1, 1993

By Y. Wang

Phosphates and fluorides are used as regulators for the removal of silicates from diasporic-bauxite both in direct and reverse flotation. While using dodecylamine chloride as a collector, micro-flotation studies showed that sodium hexametaphosphate has stronger depressing power on diaspore than on silicate minerals with increasing sodium hexametaphosphate concentration at pH 6.5, but sodium fluorosilicate shows poor depression on diaspore with increasing sodium fluorosilicate concentration at the same pH. Zeta potentials of diaspore and silicate minerals become more negative both in the presence of sodium hexametaphosphate and sodium fluorosilicate. Adsorption density studies indicated that the adsorption density of sodium hexametaphosphate on diaspore is much higher than that on silicate minerals at the concentration of 75 mg/L. FTIR spectroscopy studies show that sodium hexametaphosphate interacted with the Al atoms exposed on the diaspore and silicate minerals surfaces to form P?O?Al bonds through the P02 groups. It is possible that sodium fluorosilicate interacted through F- or [SiF6]2- with silicate minerals surfaces based on the analysis by AES.

Jan 1, 2006

By Trevor McGiddy

"Australia's prosperity relies significantly on income generated from exports of resources and agricultural products. In 1989-1990, coal was Australia's most valuable export commodity, contributing. A $5.7 billion or 14% of all export income.The abundance and quality of its coal resources and the proximity of Australia to the rapidly developing economies of Southeast Asia were significant factors that encouraged export-oriented growth and investment and will continue to do so. On the other hand, the 1980shighlighted the sensitivity of the industry to international changes in supply and demand, currency and socio-political forces.Following many years of disappointing returns for investors, mainly as a result of falling Australian dollar coal prices, resolve will be necessary to maintain competitiveness with resource-rich nations. In recent years, operators, unions and governments have begun to embark on a long overdue rationalization of domestic issues in a bid to increase productivity and reduce costs.The nature of mining operations is also changing; deeper surface mines and the growth of longwall mining will require the development of new technology and skills. Other challenges emerging from the international environmental debate will require that Australia responds appropriately to demands for cleaner fuels, energy efficiency and environmental responsibility.The future development of the Australian coal industry will therefore be influenced by its own ability to become more efficient and mature in the production of quality coal products and through rational international response to environmental questions."

Jan 1, 1992

By H. W. King

"Cryogenic engineering is concerned with components and machines which operate for long periods of time at temperatures within a few degrees of absolute zero. The absence of a ductile-brittle transition is thus the prime component of the specification for a suitable low-temperature alloy. The word "" cryo"" means ""frost-forming"" , and this leads to the second component of the alloy specification, which is resistance to corrosion in humid atmospheres. Further, although most early applications of low-temperature alloys were limited to the storage or transportation of liquified gases, an increasing proportion of alternative energy storage and conversion technologies are being based on the availability of high-field superconducting solenoids. The third basic component of the specification for a low-temperature alloy is thus the absence of a low-temperature ferromagnetic transition.Although the firs t two of these components of the specification can be met by using austenitic stainless steels, many of these supposedly "" non-magnetic"" alloys have been found to undergo martensitic transformations to ferromagnetic phases at very low temperatures. In addition, steels which remain structurally stable may still exhibit other magnetic transitions, e.g. to antiferromagnetic or superparamagnetic states. The successful application of these alloys in cryogenic engineering has thus required an initial basic study of the types of magnetic transition that can occur in such concentrated solid solutions, followed by a more applied study directed at an alloy formulation which will induce beneficial magnetic states at low temperatures."

Jan 1, 1981

By Mohammadreza Jalali

Alberta contains over 400 billion barrels of viscous crude oil in fractured carbonates but there is no viable extraction technology as yet. Petroleum geomechanics has become a vital part of the assessment of such hydrocarbon reserves, especially for naturally fractured cases, which are particularly challenging in terms of accurate recovery prediction because of joint fabric complexity and lithological heterogeneity. As a result of interconnected fractures, transport properties of fractures (mostly permeability issues rather than thermal effects) are affected by production and injection activities that change the pore pressures, temperatures, saturations, and effective stresses. Enhanced oil recovery methods involving massive amounts of fluid injection (hot or cold) at high pressure (pinj) may be used to mobilize and produce the oil; therefore, deeper understanding of the fractured systems is desirable. Pressure and temperature variations in a fractured reservoir change the in situ stresses in the reservoir and surrounding rocks; this affects fracture apertures, radically changing the bulk flow properties because flux rate is highly sensitive to aperture. Hence, coupled pressure, temperature and effective stress changes must be considered for fractured reservoirs under a thermo-hydro-mechanical (THM) coupling approach.A hybrid FDM/DDM coupled method is presented to couple pore pressure and stress around a fracture in an impermeable matrix block. Deformation and stresses are calculated in each time step and then fracture permeability, which is the most sensitive petrophysical parameter in fractured reservoirs, is updated based on the fracture aperture variation. This model is then verified with UDEC (Universal Distinct Element Code) which uses a discrete approach to cope with fractured rock mass behavior.

Jun 1, 2012

By H. Alzraiee

Traditional planning methods such as CPM and PERT have been useful tools to manage construction projects. However, the underlying model of these traditional methods often seems to fail to represent real projects as they tend to assume no interrelationship between project components. In reality, project components have complex dynamic feedback process that requires modeling of inherent uncertainty in the execution of these projects. Nevertheless, this dynamic nature and uncertainty have not been explicitly addressed by traditional planning methods. Project failure can be attributed to poor representation of the inner and outer aspects of operations that are responsible for project dynamics. Uncontrollable external forces are often cited but the real cause may be internal such as the feedback process among components of the project. An alternative perspective is offered in this paper through system dynamics (SD) that accounts for the feedback process and discrete event simulation (DES) for modeling the uncertainty. The proposed method utilizes SD method for modeling project dynamics and DES method coupled with CPM network for operational details and uncertainty, respectively. A case study that involves preparing engineering drawings in a design office is used to demonstrate the use of the developed method and to highlight its capabilities. Modeling the dynamic dimension is expected to enhance planning and scheduling of construction operations and to provide a better understanding of the impact of various internal and external factors on project schedule and productivity performance.

Aug 1, 2013

By I. Pérez-Rey, J. Arzúa, L. R. Alejano

"The decrease in strength with increasing rock specimen size is usually associated to the increase in the number of defects inside the specimens at small scale (centimeters) but also to the role of the rock mass structure at the rock mass scale (meters to decimeters).This matter of concern was particularly focused when determining the size of pillars in underground mines. Some formulae regarding strength of pillars have been proposed but they usually consider only the size and shape of the pillars and the strength of the intact rock. The structure tends to be overlooked or hidden behind the scale, but it is probably very relevant. For standard tunnel design, the approach by Hoek and Brown (1997), taking the structure into account in terms of the GSI, is commonly used. However, this approach does not specifically consider the size of the tunnel. Thus, a size larger than the so-called representative elementary volume is implicitly contemplated.The authors have recently performed a lab study on the effect of the structure in the strength, deformability and post-failure characteristics of granite at lab scale (NX size) extended here. This experimental program included intact and artificially jointed rock specimens. Obtained results permit to observe the changes in strength, deformability and post-failure behavior of this “small scale rock masses”, associating the role of the structure to the observed complete stress-strain response of the specimen, which can improve our understanding of the actual complete mechanical response of rock masses."

Jan 1, 2015

By V. Bruned, K. Mohamed, A. Michaut

Orano Mining Somaïr uranium treatment plant (Niger) uses a pugging-curing process to leach uranium. Sulfuric acid, nitrates and water are added to the finely grinded ore in a rotary drum to leach uranium bearing minerals and solubilize uranyl sulfate ions. Reagents, sulfuric acid and nitrates, are the main OpEx of this process step. The economical optimization of their addition requires a thorough knowledge of the ore behavior in solution with these reagents. Orano Mining technical direction and Somaïr laboratories developed a model to predict the curing process uranium recovery surface with a limited number of parameters. Experimental laboratory work to fit the model needs to be done for each type of ore which can require a lot of metallurgical tests and would be time consuming. In order to optimize the required number of tests, an innovative experience plan was designed in parallel to the development of this model reducing the required number of tests to only eight. Once the parameters of the models are correctly fit, the comparison between the estimated values and the actual values for the uranium recovery is excellent (less than 0.5% error in average). Associated with an updated cost model of the curing process, this new recovery model helps the plant operator find the best set of reagents to maximize curing process profitability in the Somaïr plant day after day.

Jan 1, 2020

By B. Hewitt

Murrin Murrin Operations has not had a successful beginning. Numerous reliability and operability issues many of which are the result of design decisions have been addressed through mechanical and operational changes and the CCD circuit is no exception. The decision to install, the installation and the results of the CCD1 rake-lift mechanism and feedw ell dilution system are discussed in this paper. The installation was justified on improved operational robustness and an increase in the in the underflow density of 1% (per cent w/w). At approximately the same time process modifications in the solution neutralisation circuit were implemented and these changes altered the rheology of the slurry reporting to CCD1. Since the modifications to CCD1 and the solution neutralisation circuit, the CCD circuit has averaged a 2% improvement in the circuit underflow density. The CCD1 modification was completed on time and mechanically has performed well. From a risk point of view, the central rake-lift and Turbodil® dilution system add a degree of freedom and robustness to CCD1 operation that has extended the range of operational confidence. In this respect, the modification has been a success and is complementary to solution neutralisation improvements.

Jan 1, 2004

By Z. Zhao, B. Li

"Fractures are the key channels for fluid flow and mass transport in fractured rocks of low/negligible matrix permeability. In single rock fractures, surface roughness causes fluid flow in tortuous paths, and reduces the overall fracture conductance. A number of empirical models have been proposed to relate the reduced hydraulic aperture to the mechanical aperture due to surface roughness, which were revisited and compared. Using two of those relationships between hydraulic apertures and mechanical apertures, we studied the influences of local surface roughness of fractures on fluid flow and solute transport processes at the macroscopic scales of fracture networks. The results show that fracture roughness can affect the flow rates and residence time to varying extent, mainly depending on the empirical models between hydraulic apertures and mechanical apertures. However, fracture roughness has negligible influences on the general patterns of fluid flow (channeling) and solute migration (e.g., travel paths and shape of breakthrough curves). This is because the connectivity of a fracture network is mainly determined by other geometrical parameters (fracture positions, orientations, and lengths), rather than roughness or apertures. INTRODUCTIONIn fractured crystalline rocks of low or negligible matrix permeability, fluid flow and contaminant migration mainly occur within the connected fractures. An understanding of fluid flow and contaminant migration in fractured rocks is a crucial issue in many deep underground projects, e.g. underground repositories for radioactive waste, CO2 sequestration, enhanced geothermal systems, oil and gas production, etc. Rock fractures are typically rough-walled, and surface roughness appears to have first order control on the mechanical and hydraulic behavior of single rock fractures (Boutt et al., 2006).It is well known that the mechanical aperture of a rock fracture is usually larger than its hydraulic aperture, due to fracture surface roughness (Tsang and Witherspoon, 1983). However, for naturally fractured rocks including numerous discontinuities, the effects of this reduced hydraulic aperture in local fractures on macroscopic fluid flow and solute transport in complex fracture systems still remain unclear. Many previous studies assumed identical hydraulic and mechanical apertures in discrete fracture network models for simplicity (Min et al., 2004; Zhao et al., 2011). Therefore, the main objective of this study is to evaluate the influences of local surface roughness of fractures on fluid flow and solute transport processes at the macroscopic scales of fracture networks, by employing the empirical models that relate the hydraulic aperture to the mechanical aperture."

Jan 1, 2015

By A. Kobzhanov, S. Saparova, S. Brochot, D. A. Mango

KATCO (an ORANO Mining and Kazatomprom joint venture) is the largest in-situ leach uranium mining operation in the world, exploiting the Muyunkum and Tortkuduk uranium deposits in southern Kazakhstan. After extraction from the deposits, uranium is then transported via a hydraulic network to be purified in three processing plants located near these deposits. Within KATCO, with the support of ORANO Mining and CASPEO, in 2018 and 2019, a large project that had as its main objective to improve the uranium accounting system was implemented. The objective of this paper is to describe this project and all the changes that it entailed. At KATCO plants, a black-box approach was previously used for uranium accounting. However, it is recommended to use all the available measurements and to deploy a data reconciliation model (between well-fields and plant) as the reconciliation uncertainty is overall lower and it provides a more accurate uranium balance. During the deployment of this project, the rules and algorithms to generate the uranium accounting report, the associated flow diagrams (for uranium accounting), the streams, units of operation, stocks, reporting and Key Performance Indicators calculation rules were re-defined.

Jan 1, 2020

By D. A. Garland, A. D. Jackson

"Alanx ceramic/metal composites are proprietary products developed by Lanxide Corporation who joined with Alcan to form Alanx Products L.P. in 1988. Alanx ceramic/metal composites are composed of silicon carbide in a combined alumina and metallic aluminum matrix. In laboratory slurry wear tests conducted by Alanx ceramic/metal composites have shown to perform well against other wear resistant materials. At the Kidd Creek Concentrator Alanx CG896 ceramic/metal composite was tested in two pumping applications, the primary cyclone feed pumps and the filter feed pumps. In both instances the wear rates of the parts made of Alanx CG896 were far less than the gum rubber parts traditionally used. As of year to date September 1992 the unit cost to repair primary cyclone pump parts has dropped 58% from 1991 figures. For the filter feed pumps the unit cost to maintain the pumps has dropped by 33% as compared to 1990 figures. The total savings represented by implementation of Alanx wear parts, based on projected year end unit costs for 1992, as compared to 1991 costs for primary cyclone feed pumps and 1990 figures for filter feed pumps, is $166,753. INTRODUCTIONAt the Kidd Creek Concentrator the cost to maintain the primary cyclone feed pumps and the filter feed pumps was a constant concern. Rubber wear part consumption was quite high and the manpower required was considerable. For 1991 the total cost to maintain five primary cyclone pumps was $244,062. The cost to maintain the filter feed pumps in 1990 was $72,076. A wear material was needed that would increase the time between repairs and that would increase the reliability of these pumps between scheduled shut downs."

Jan 1, 1993

By Mohamed Sassi, I. Kolo, R. L. Sousa, R. K. Abu Al-Rub, Manhal Sirat

"Fractures induced by folds are pivotal in hydrocarbon exploration, ground water transport and harnessing of geothermal energy. This is because of the need to predict and understand fracture propagation in reservoirs which have folded rock formations. Despite its prominence, there is a lack of reliable numerical models for simulating fractures resulting from rock folding. This is partially due to the difficulty involved in fracture modelling. As a contribution to fold-fracture modelling, this work applies a coupled plasticity-damage model to rock fracturing and anticlinal folds. Parametric studies on a single folded layer give insight into the fold formation and behaviour. The anisotropic continuum damage model which considers both tension and compression is formulated using the power damage evolution law. For ease in formulation, strain equivalence hypothesis is adopted whereby the strain is the same for both damaged and undamaged configurations. Lubliner plasticity yield criterion is adopted for plastic deformation. The model is coded in Abaqus user subroutine UMAT and is applicable to quasi-brittle materials.INTRODUCTIONThe understanding of fractures in the earth’s crust helps in the prediction, evaluation and characterization of fractured reservoirs, whether they are petroleum, geothermal or underground water reservoirs. This is partly because reservoir permeability and stability are dependent on fracture properties (Nelson, 2001). To achieve this, various approaches have been developed to analyze reservoir rock fractures. These could be grouped into (a) discrete approaches – where the rock mass is represented by a finite number of well-defined components and (b) continuum approaches – where the mathematical assumption of an infinitesimal element is made (Jing, 2003). Ivanova (Ivanova, 1998) comprehensively studied fracture systems in nature and highlighted folds as one of the major geologic settings that produce fractures. Naturally occurring folds in reservoirs sometimes compound fracture analysis. It might not be clear whether the fractures formed before, during or after rock folding. Fractures formed during the folding process are expected to show stress orientations related to folding and are thus of primary concern in rock folding simulation. It could be argued that there are no numerical models that as"

Jan 1, 2015

By J. F. Wang, Y. Jin, Z. L. Wang

Smelting reduction as an ironmaking technology for the 21st century has been challenging the traditional blast furnace. The process has many attractive advantages over the blast furnace, however, the massive by-produced coal gas mainly containing CO, H2 and CO2 requires further treatment. From a chemical engineering view, coal gas is a valuable chemical stock and can be transformed into hydrogen-rich synthesis gas. Hydrogen can be directly used as clean fuel and synthesis gas can be used for the production of some important chemicals such as methanol, ammonia and dimethyl ether. Among those chemicals, dimethyl ether as an alternative clean fuel for diesel engine and liquefied petroleum gas has been drawing more attention. It has excellent environmentally-benign behaviours not only in compression ignition combustion, but also in the much lower emission of SOx and NOx. In this work, a combined technology of smelt reduction ironmaking and direct synthesis of dimethyl ether, which will strongly promote the energy efficiency, environmental protection and resource recovery, is proposed and described in detail.

Jan 1, 2004

By O. Kodym

The paper has focused on possibilities of interconnecting information sources concerning monitoring & control of mining industry technical processes (TP), and the related safety hazards. The key issue is the comprehensiveness of the information presented to users. Information can be presented by virtual reality means, when the seemingly true presentation of the production process scene along with user friendly presentation of related information is available. The user in its role of a process supervisor is not only a mere scene observer but, thanks to the interactive functions of virtual environment, he participates in the scene of his control. As such his control and management abilities increase because he can absorb, more easily understand and asses the information provided.

Aug 1, 2013

By T. R. Heflin

The paper provides a comprehensive discussion of pump selection for the hydrometallurgical industry. Material suitability, in addition to proper size and design, will provide extended life for pumps in erosion /corrosion service.

Jan 1, 1979

By B. A. Watters, G. A. Parslow, F. H. Mcdougall

Carbonate-rich rocks occur at several localities within the Flin Flon volcanic sequence of the eastern Amisk Lake area. The rocks occur in two areas: as a group of small occurrences on islands within Amisk Lake and as two much larger linear belts running parallel to the regional structure east of Amisk Lake. Mineralogically, the rocks consist of talc and Ca-poor ankerite with occasional graphite. Segregation of these minerals and colour variation impart a well-defined planar fabric to the rocks and where the units are fairly continuous (e.g. Mosher Lake), their trend and attitude suggests a concordant relationship to the volcanics. Major and trace analysis of22 samples confirms the presence of two types, with one type being represented in each of the two areas. Most of the elements studied can be used to characterize the two groups, but three elements in particular give a clear separation: Mg, AI and Ni. Recalculation of the major element analyses, on a water and carbonate-f ree basis, indicates that one group (large concordant bodies with high MgO, high Ni and low AI20.J is altered ultrabasic material of peridotitic or dunitic composition. Because no relict igneous material is observed, and the contacts are apparently very sharp, it is possible that the hydration-carbonization process occurred simultaneously with intrusion, .in a closed system. The other group (small occurrences with relatively low MgO, low Ni and high AI203J represents alteration of basaltic rocks. AIthough some analyses suggest the introduction of calcium, as carbonate, along with the volatiles, the major oxides have remained remarkably stable during the alteration process(es).

Jan 1, 1981

By Ki-Bok Min, Bona Park

"In spite of the applications of DEM models to emulate the elastic modulus, Poisson’s ratio and strengths of isotropic rock in laboratory scale, extensions to anisotropic rock and larger engineering scale still have many challenges to overcome such as robust verification and validation against observed field case. In this study, a discrete element modeling was performed in order to represent a transversely isotropic rock such as shale, and the upscaled model was applied to foundation and borehole problems using PFC2D. The applicability of the upscaled rock mass model was verified by an analytical solution. The DEM modeling of stress redistribution induced by an applied surface line load compares well with Boussinesq’s isotropic solution and anisotropic solution given by Bray. The borehole model with a circular opening under biaxial stress was compared with both isotropic and anisotropic solutions resulting in good agreement. The abilities of DEM model to investigate the micromechanisms accounting for complex macroscopic behaviors and to predict the macroscopic behavior are discussed.The results demonstrate that DEM modeling has the potential to be applied to anisotropic rock mechanics problems on larger engineering scales such as wellbore stability problems especially in shale formations. Furthermore, the effect of anisotropy modeled through this study may be able to explain failure behavior of anisotropic rock encountered frequently in real cases.INTRODUCTIONAnisotropy is prevalent in various types of rocks, especially in shale that contain a set of parallel bedding planes. These weak planes in various forms are sources of large deformation and low shear strength and contribute significantly to the anisotropic behavior of rocks (Amadei, 1996; Cho et al., 2012; Kim et al., 2012). As elastic and strength behavior of anisotropic rock is substantially different from that of isotropic rock, proper consideration of anisotropy is of great importance. There is extensive of experimental evidence showing the anisotropy of shale. Niandou et al. (Niandou et al., 1997) analyzed the plastic deformation and failure mechanisms of Tournemire shale were highly dependent on the orientation of bedding planes. Cho et al. (Cho et al., 2012) presented various deformations and strengths of Boryeong shale obtained from laboratory experiments. Fjaer and Nes (Fjaer and Nes, 2013) performed uniaxial and triaxial compressive strength tests using Mancos shale, and they observed that the shear sliding along the planes of weakness before the occurrence of a major failure can reduce the strength of anisotropic rock. The recent research has demonstrated that the anisotropy of rock is an important consideration in rock engineering."

Jan 1, 2015