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By Z. Zhang, X. -G. Chen, F. Breton, A. Arici

"The microstructure of Al-10Si-0.3Mg-0.5Mn alloy with 0.27% Zr and 0.19% V addition was quantitatively analysed and compared to the base material. The addition of Zr and V in the AlSi10Mg alloy exhibit a beneficial effect on the Si modification, resulting in the reduction of the size of eutectic Si particles on both as-cast and T6 conditions. The quantitative image analysis results show that the Zr and V addition and T6 treatment can reduce the size of the intermetallic phases. In addition, the presence of Zr and V is favour to the partial dissolution of the intermetallic phases during the T6 treatment. Different heat treatment procedures were tested to optimize treatment parameters. The mechanical properties of the alloys were evaluated using hardness measurements and tensile tests. The results show that the addition of Zr and V can remarkably improve the mechanical properties on as-cast and T6-treated conditions. The correlation between the microstructure and mechanical properties of the alloys is discussed.INTRODUCTION Al-Si-Mg foundry alloys have been widely used in automotive and aerospace industries due to their high strength-to-weight ratio, heat-treatable capability and excellent castability. The alloying elements such as Cu, Mn, Fe are traditionally added into Al-Si-Mg alloys to improve their mechanical properties (Mohamed, Samuel, Samuel & Doty, 2009). In recent years, the attention has been paid to the effect of the transition elements such as Zr, V, Ti, etc, as minor alloying additives, on the properties of aluminum alloys (Elhadari, Patel, Chen, & Kasprzak, 2011; Kasprzak, Amirkhiz & Niewczas, 2014; Shaha, Czerwinski, Kasprzak, Friedman & Chen, 2015; Shaha, Czerwinski, Kasprzak & Chen, 2014; Mahmudi, Sepehrband, Ghasemi & 2006; Meng, Cui, Zhao & Zuo, 2013). Kasprzak et al., (2014) and Shaha et al., (2015) reported that additions of Zr, V, and Ti in Al-Si-Cu-Mg cast alloys can improve the alloy mechanical properties at high temperature by forming stable intermetallics and precipitates on as-cast and heat treatment conditions. On the other hand, the mechanical properties of near-eutectic and eutectic Al–Si cast alloys depend not only on the chemical composition but also, even more importantly, on microstructural features such as the morphology and size of eutectic silicon and intermetallic particles, which are present on both as-cast and heat treatment conditions (Mohamed et al., 2009). However, there is rather limited information on the effect of Zr and V on the microstructure features and mechanical properties of near-eutectic Al-Si-Mg cast alloys."

Jan 1, 2018

By Michael Klichowicz, Holger Lieberwirth

"For a detailed prognosis of mineral comminution processes, simulation tools like DEM still pose various challenges. Less realistic mineral structures can affect the results of simulation models such as bonded-particle models (BPM). Hence, in order to design mineral processes with these models as tools, representative mineral input data should be used. The article shows, how realistic 2D-structures can be modelled by taking advantage of the parameters identified by the Quantitative Mineralogical Analysis (QMA). Important quantitative parameters can be derived by analyzing three orthogonal thin or polished sections. For this reason point, line, and area analysis are applied. The mentioned parameters precisely describe the texture and structure of minerals. The newly developed software is able for the first time to semi-automatically analyze images of mineral structures using QMA. Moreover, statistically equivalent structures of minerals can be modelled using the QMA- parameters. Generating synthetic, but equivalent mineral structures opens the door for more reliable BPM based simulations. Within future research, the procedure will be adopted to generate 3D-structures. Therefore, QMA-based routines that already have been applied to generate 2D-models shall be utilized as basis. The aim of this procedure is to synthesize realistic microstructures based on certain statistical figures in order to improve comminution simulations.INTRODUCTION Due to its increasing capability, the use of computer technology is permanently intensifying in the design of mineral processes. The recent past has impressively shown that computer models can enhance the understanding of mineral processing. There is in fact a rising number of research activities, which are using simulation approaches to study various aspects of it. Weerasekara et al. (2013) give a comprehensive overview over the application of discrete element modelling (DEM) in the science of comminution.Nonetheless, using simulation tools such as DEM in general still poses a challenge. For a detailed simulation of a mineral comminution process with DEM, bonded particle models (BPM) appeared suitable in the past. The following issues, however, affect an appropriate prediction when modelling with BPM:• Simulations with high numbers of particles may need a lot of time for computation. • Internal modeling parameters like the spring and damper constants in DEM have to be adjusted by comparing its specific crushing behavior in the simulation to reality.• In order to use DEM for prediction of mineral processing, it is essential to validate the correctness of the models and assumptions, which is sometimes difficult. As Weerasekara et al. (2013) have stated it is crucial that the DEM method as well as the DEM code work properly.• It is challenging to implement the complex geometric structures of real minerals into the model."

Jan 1, 2016

By P. C. Holloway, M. J. Collins, K. R. Buban

Historically, there has been little incentive to process copper-arsenic concentrates by leaching, rather than via established smelting operations. However, with ever tightening environmental emission standards and more arseniferous concentrates being produced, increasingly sophisticated and upgraded off- gas handling facilities are required in smelting operations, generating greater quantities of challenging metallurgical dust. In this context, oxidative pressure leaching offers distinct advantages. The current state of pressure leach technology delivers high extractions from copper concentrates, while producing an environmentally stable process residue, without atmospheric emissions of sulphur dioxide or arsenic. However, as was shown in an earlier study, copper extractions and environmental leach residue stability are impacted negatively by arsenic levels above 2.5 to 3.0 wt%. In further studies on pressure leaching of copper concentrates, Sherritt has developed process conditions that allow even highly arseniferous (> 7 wt% As) feed materials to be converted into environmentally stable residues, with excellent copper extractions. At the same time, pressure leach residues can be generated that are amenable to silver recovery via direct cyanidation, without pre-treatment by lime boiling or hot curing. The results of pilot plant test work are discussed. INTRODUCTION As the production of copper has expanded over the years, resource exploitation has extended beyond relatively clean, high grade and easily accessible ores, and copper sulphide concentrates increasingly come with higher levels of contaminants, such as As, Hg, Sb and Bi, and lower copper and sulphide sulphur concentrations. However, as concerns on the impact of the emission of such contaminants into the natural environment have mounted, import/export restrictions have made the trading of copper concentrate more difficult, and, in particular, the export of concentrates with greater than 0.5 wt% As; under ever tightening environmental emission standards, these lower quality concentrates can be a significant strain on the off-gas handling facilities in smelting operations. The processing of arsenic bearing copper concentrates is, therefore, an increasing challenge as copper producers seek to exploit more complex mineralization and to extend the life of their operations. In this environment, processing arsenical copper concentrates with high temperature pressure leaching (>200°C) must be considered as an alternative to pyrometallurgical processing. Leaching kinetics for copper minerals at these temperatures are rapid and acid is generated for potential use in heap leach operations. Pressure leaching of copper concentrates eliminates gaseous emissions of arsenic and sulphur, while generating environmentally stable residues, as measured by the Toxicity Characteristic Leach Procedure (TCLP) (Kalanchey et al., 2007). Both medium and high temperature pressure leaching of copper concentrates have also proven themselves technically on an industrial scale (Marsden et al., 2004) with high copper recoveries.

Jan 1, 2019

By P. Hansman

"Place Dome Canada's Detour Lake Mine is a low-grade gold producer located in northeastern Ontario. Production is targeted for 2850 tonnes of ore per day. As reserves and mining areas continued to be found below and far to the west of the shaft (Fig. 1), it became necessary to review and upgrade the materials handling facilities. This paper deals with the selection, design and construction of an underground crusher and conveyor system capable of handling up to 450 tonnes per hour from the lowest existing level in the mine.BackgroundThe Detour Lake mine site is accessed via secondary Highway 652 which runs northeast out of Cochrane, Ontario. The road consists of 200 Ian of hard top followed by 100 Ian of well maintained gravel to the mine site. A 1500 m airstrip is maintained at the mine site for emergency use. Prior to 1991, the workforce was flown to and from the mine site. Crews were now bused to the site from Timmins. Remnants of a winter road exist to the southeast which at one time ended in La Sarre, Quebec. This was the route used to haul bulk items during the construction period and early production years.A town site has not been established at the site for the current operations. Instead, a rotational scheme is being utilized whereby most personnel will work seven days on site followed by seven days off site. For some employees, however, the work week is termed as a four/three schedule where they work 42 hours between Monday at 10:00 a.m. and Thursday at 4:00 p.m. with the following three days off. All surface employees and maintenance employees underground work 12-hour shifts. All underground employees work a lOV2-hour shift. Supervisors work a similar schedule as their crews, however, other staff may overlap their rotation during the week.A five-compartment shaft was sunk in 1984 from surface to the 610 m elevation. Shaft stations were established at the 120 m, 260 m, 360 m, 460 m, and 560 m levels. The cage compartment consists of a single deck, 4O-man cage in balance with a counterweight. The cage hoist is an Ingersoll-Rand 10H and is regulated to travel at 4.1 m/s. Two 9 t skips operate in balance at a travel speed of 7.1 mls. The skip hoist is a 3.05 m drum Nordberg. Both hoists are automated to function without a hoistman during normal skipping and cage service runs."

Jan 1, 1995

By Daniel Hodouin, Mélanie Proulx, Claude Bazin

"Collector and frother are commonly used to induce the floatability of valuable minerals in flotation plants. These reagents are usually distributed down a flotation bank or sometimes added in a single location at the top of the bank. A review of the literature and some experimental results obtained from laboratory and full scale trials indicate that the way flotation reagents are distributed down a flotation bank may influence the flotation response of coarse particles. The paper summarizes these observations which show that the distribution of reagents is a potential tuning variable for process optimization.IntroductionFlotation is in many cases the only way to concentrate sulphide and some oxide minerals. Flotation is a concentration process that uses particle surface composition to induce the selectivity by mean of hydrophobic reagents. The influence of particle size on flotation was firstly analyzed in the 50's1·2 and intensively investigated in the 70's, early 80's and 90's3-18. Most of the observed results show the existence of an optimum flotation size range9 whose recovery is not significantly influenced by a reduction of collector dosage""18. This result brought the idea of using a small portion of the total collector dosage at the top of a rougher bank and to distribute the remaining through the end of the bank to ensure sufficient collection of the coarse particles that need more hydrophobic coverage to attach to air bubbles and be lifted to the surface.This paper discusses the idea of using the distribution of reagents down a flotation bank to tune the operation of the process. Unlike the literature on the effect of reagents (collectors, frother...) dosage that is dense, little attention has been put on the distribution of reagents in a flotation bank. Although research on this subject has not been pushed very far, some operators have recognized the potential of a strategic addition of reagents down a flotation bank19. Except for a few exceptions, the proportions of the reagents to be distributed down a flotation bank are decided according to operator's experience instead of process analysis in relationships with particle size. This paper recalls observations made by different researchers that lead to the idea of using the distribution of reagents as a tuning variable for the flotation process. The paper does not present a detailed analysis or optimization scheme for tuning the distribution of reagents, but analyzes some plant and laboratory results with a view toward the development of a testing methodology and ultimately a validation or rejection of the idea."

Jan 1, 1998

By Changmiao Liu, Dong Dong

"Magnesite is a major mineral resource in China, whose output and export are massive and quite important to the world. Flotation performances of eight anionic collectors on magnesite were studied to find the proper ones. Micro-flotation results indicated that collectors of HOl, SDBS and AEP had outstanding flotation performances on magnesite, with the recovery ratio all reaching above 90% in a wide range of alkaline pulp. Solution chemistry calculation, Zeta potential and FTIR measurements were employed to reveal the interaction mechanism between anionic collectors and magnesite surfaces. Solution chemistry analysis indicated that the main active components of HOl, SDBS and AEP were anions and association complex anions in alkaline pulp. Magnesite surface was negatively charged in the alkaline pulp. The active sites on magnesite surface were mainly the components of MgOH-, Mg (OH)2, and MgCO3 when the pulp pH was over 8. Anionic components of HOl, SDBS and AEP reacted with Mg in magnesite surface to make the insoluble anionic salts. And the chemical adsorption was confirmed by the FTIR measurement evidences.INTRODUCTIONAs an important industrial mineral, magnesite has been widely applied in metallurgy, building materials, chemical industry, agro-pasturage and other fields (Hu et al., 2006). It is a major mineral resource in China with abundant reserves. Its output and export are massive and quite important to the world. Liaoning province is rich in magnesite, whose reserves and production both come first in China. So far the proven reserves have reached 2.91 billion tons, accounting for more than 90% of total reserves in China, and more than 25% in the world (Li et al., 2012).Magnesite ores in Liaoning province mainly contain crystalline magnesite, and the gangue minerals of quartz, dolomite, talc, tremolite, chlorite and carbonaceous materials. Some ores also contain a little pyrite, chalcopyrite, hematite and apatite. Most of the ores must be preprocessed to separate the useful parts from the large amount of gangue minerals, so that their value and industrial application can be enlarged and promoted.Flotation is commonly used to process the magnesite ores, and the conventional flotation methods include anionic and cationic flotation. In the former, gangue minerals of silicates were separated by using amine type cationic collectors. After the impurity minerals were removed, high qualified magnesite concentration could be gained. For the cationic flotation method, it had some drawbacks of lower recovery ratio and poor performance in the lower temperature pulp (Li et al., 1995)."

Jan 1, 2016

By S. Bantubani, I. Mc Dougall, S. Arjun, H. Joubert, R. Hansraj

The requirements determining the design of the Söderberg electrode columns used in base metal applications are different to those of other industries. There is a strong trend to position the contact shoes above the furnace roof in order to reduce the risk of water leakages directly onto the furnace bath. Tenova Pyromet has adapted its proven electrode column design for application on base metal electric furnaces based on these requirements. The design modifications implemented as well as considerations regarding the overall electrode-roof-furnace arrangement are discussed. Equally important is the management of the Söderberg electrodes to prevent over or under baking. Tenova Pyromet has developed the AutoFurn™ furnace controller to not only optimise furnace operations, but to improve electrode management. An overview of the electrode management control philosophy implemented by AutoFurn™ is provided, focusing on intelligent electrode regulation, slipping and baking. INTRODUCTION Tenova Pyromet has developed an electrode system for use in base metal furnaces, which builds on the experience that Tenova has gained during the past 30 years with electrodes in the ferroalloy and base metals industries. In base metals applications, an important safety consideration is the minimization of water within the furnace and on the furnace roof. In addition, direct contact between copper equipment such as contact shoes and pressure rings and the contents of the furnace is discouraged. In a 3 phase AC furnace, three electrode columns transfer the electrical energy to the furnace bath. Both Söderberg and prebaked carbon or UHP graphite electrodes are in use in base metal furnaces. In each column, the electrode is held in position by a hydraulic slipping and regulating device, a pressure ring and contact shoes. The electrodes can operate in a submerged-arc or brush-arc configuration, where the electrode is immersed in the slag or a short distance above the slag (Mc Dougall 2013). The electrode equipment is divided into an upper and a lower electrode assembly. The self-baking Söderberg electrode is made from lengths of steel casings that are added to the top of the electrode column and welded into place. Carbon electrode paste is added to the inside of these casings and is baked to form a solid tip in the region of the contact shoes. The working platform that surrounds the area where new electrode casings are added, is electrically isolated from the building and each electrode is isolated from the others to ensure the safety of the personnel who perform the electrode casing additions.

Jan 1, 2019

By C. W. Chao, M. Melashvili, F. Hilário

The processing of a bulk concentrate containing copper as chalcocite, enargite, bornite and chalcopyrite along with pyrite and precious metals of silver and gold was studied. A leaching study was undertaken to examine the application of the atmospheric acid leaching process to a bulk copper concentrate for copper recovery followed by cyanidation or thiosulfate leaching for gold and silver recovery. The extraction of copper exceeded 90% under some conditions and the recovery of gold and silver reached a maximum of 44 and 45%, respectively. A sample of bulk concentrate was roasted in air to oxidize the sulfides with release of sulfur dioxide followed by acid leaching of the roaster calcine and cyanidation of the acid leach solution. The copper extraction reached over 92% and the gold extraction exceeded 88%. The sulfur dioxide may be captured for acid production. INTRODUCTION The processing of a large primary copper deposit in Indonesia is under investigation. One of the possible routes for processing involves flotation of a bulk copper-gold concentrate followed by treatment by an atmospheric leach/SX-EW process for copper recovery. The atmospheric leach residue would then be leached for recovery of gold and silver. A second route involves roasting of the concentrate followed by acid leaching and SX-EW for copper recovery. The leach residue from the roaster calcine would then be leached for recovery of gold and silver. The roaster off-gases could be used for sulfuric acid manufacture, enabling the production of a valuable by-product. The Cobre Las Cruces (CLC) process (Munoz, Garcia, & Delgado, 2017) was designed to treat a resource of copper discovered close to Seville, Spain. The process was developed by Outotec with MK Gold (original project owner). INMET Mining subsequently purchased the deposit from MK Gold and built the copper processing facility. The CLC process is similar to the Mt. Gordon Copper process; except that OKTOP reactors have been installed instead of a low temperature, low pressure autoclave process. The plant was designed to treat 1.3 mtpa of ore at a grade of 6.2% Cu to produce 72,000 tpa of cathode copper over a 15 year project life. The main gangue mineral at Cobre Las Cruces was pyrite. The Cobre Las Cruces ore is therefore similar to a rougher flotation concentrate containing copper minerals and pyrite. The roasting of a rougher flotation concentrate can be designed to produce hematite, basic copper oxides and sulfur dioxide off gas. The acid leaching of the basic copper oxides may produce soluble copper for SX-EW recovery of copper. The sulfur dioxide off-gas may be used to make sulfuric acid.

Jan 1, 2019

By T. C. Chudy, C. C. Hamilton, G. R. Lane

The selection and provision of mineralogical services to assist in developing a GeoMetallurgical program for a Cu Porphyry Mine in South America is covered in this paper and presentation. The objectives of the study were to provide a rapid mineralogical scoping protocol to support and confirm results of sequential Cu leach data and to provide detailed mineralogical analysis of four composites and products on which locked cycle test-work were performed. Results showed good reconciliation was achieved between measured chalcopyrite and secondary Cu mineral contents with leach data using a linear intercept mineralogical procedure by TIMA (Tescan Integrated Mineral Analyser), as well as a generally positive correlation between pyrite and Cu-sulphide grain size. Size-by-size analysis of Composite feeds and test products was used to outline comparisons between feeds on a mineralogical basis and provide liberation and association data with which to diagnose and better explain performance. Identifying key mineralogical drivers to Cu recovery and concentrate grades using these results, a greater understanding of the role of chalcocite and pyrite on metallurgical performance was established. INTRODUCTION As a global supply of copper, porphyry copper deposits are typically very large, often in excess of a billion tons of ore (Keeney, Walters, & Kojovic, 2011; McMillan & Panteleyev, 1980) with grades typically between 0.2 and 1.2% Cu, and up to 2% Cu in places. They are also a source of gold. The complexity of copper porphyries arises from their classically zoned nature, the type of host rock, as well as whether or not they have been overprinted by oxidation, weathering and supergene enrichment (Sillitoe, 2011). Zones of alteration and other geological attributes give rise to varied mineralogy, ore mineral textures and material properties, all of which result in different processing characteristics. Due to the interdependencies of geological and processing characteristics, it is vital to study links between the geology at the macro-scale and mineralogical features down to millimeter and micrometer scale (mineral content and texture) and their influences on mineral processing behaviour (Cropp, Goodall, & Bradshaw, 2013). The growing field of GeoMetallurgy aims to provide an Orebody Knowledge framework by which to gather such information as it pertains to: (1) Understanding and predicting likely flotation response; (2) Guiding relevant test work to investigate and validate links, interdependencies, theories and data interpretation/evaluation; (3) Populate a block model with relevant information and; (4) Implement and refine the model for ongoing optimization and control. Specific questions addressed by using mineralogy often include flotation diagnostics as aids to interpretation, causes of dilution and losses to tailings, as well as guidance to sampling for test work (Cropp et al., 2013).

Jan 1, 2019

By W. Petruk

"D. Doyle How large is the beam to which you referred? Are we considering Watts, Griffis the probe of a 1 micron sized particle?& McOuatReply Yes. The beam would be about 1 micron. We could enlarge or reduce it depending on the current in-put.D. Doyle Then chemically bound material we might not see. If you are restricted to 1 micron then you would not be able to separate things smaller than this. Is this not so?Reply We won't be able to analyse it but we will see it as the scanning electron microscope has a resolution down to about 0.1 microns. We should be able to get the general composition of such a grain plus its surrounding grains. We feel we can then make a reasonable estimate if it were as small as 0.1 microns. An accurate analysis would be achieved with grains of 3 and 4 microns.D. Doyle Would this have an application in the hydrocarbon field?Reply The lowest atomic number would be sodium. We wouldn't be able to go below that atomic number. Anything with sodiumor a larger atomic number would enable us to analyse the carbon.M. Fairwether Do you have any policy relating to priorities. For instance areCominco companies going to be limited in the amout of samples permitted to give everyone a chance because quite frankly our company, and I'm sure all base metals companies can hardly wait for the installation of this equipment. I can forsee two years back-log of work in the first month.Reply Quite frankly, I haven't looked at this. At the present time the work is under the START program but I suppose we will have to look at possible changes. Anything under the START program has first line priority.B. Thorndycraft Will the briquetting of samples be automated as well? Pinson MiningReply No, not at this point. Our polish section laboratory is first-class and can turn out 18 polish sections a day which is more thar we can handle.B. Thorndycraft With the capability of this machine to operate in a hands-off manner perhaps it could start to look for the 5 micron gold particle in tailings?Reply I have such a program using a wave-length spectrometer rather than the energy dispersive. The wave-length spectometer is about 10 times as sensitive and would scan the section much faster. A one inch diameter polished section would be scanned in about 7 hours for anything 1 micron or larger."

Jan 1, 1984

By Louise Corriveau

Exploration strategies have traditionally considered felsic gneiss complexes of the Canadian Shield sterile. This paradigm is challenged with the discovery of extensive granulite-facies Cu-Au, Fe oxides-bearing hydrothermal systems in the 1.4 Ga Bondy and 1.5 Ga La Romaine volcano-plutonic complexes of the Grenville Province. Early identification of magnetite-rich units in association with meta-exhalite and pelite-like units was key to targeting the search for mineralization, protolith information and indicators of pre-metamorphic hydrothermal activity during regional surveys of these frontier terrains. Textural evidences for a volcano-plutonic setting were found. There remained, however, numerous impediments to the recognition that the ubiquitous magnetite-laden units and associated aluminous gneiss were hydrothermal in origin. Many metamorphic reactions form magnetite at the amphibolite to granulite facies transition, and hydrothermally-leached rocks resemble metapelite or migmatitic restite, while carbonate alteration zones may look like marble or calc-silicate rock. Non-typical metamorphic mineral assemblages, modes and colours arise when hydrothermally-derived rock types are metamorphosed. These effective markers served as tools for reliable field identification of hydrothermally-altered rocks. In our case-studies, we traced pre-metamorphic hydrothermally-driven Fe-oxide precipitation in association with sericitization, albitization, pyrophyllite alteration, chloritization, and B enrichment by mapping unusually high contents of (1) magnetite or hematite, (2) biotite, (3) albite, (4) sillimanite, (5) orthopyroxene or phlogopite with cordierite, and (6) tourmaline or kornerupine. The unveiled garnetite, tourmalinite, and aluminous gneiss had assemblages that vary according to metamorphic grade and composition. To assess if high mode of Fe-Mg-Al phases resulted from partial melting (restitic residue) or metamorphism of hydrothermal rocks, we compared leucosome mineral assemblages, shape and amount with that expected of in situ partial melting reactions. In both areas there is no compelling evidence for these units to be restites. In contrast, the presence of lapilli in garnet-cordierite-sillimanite gneiss, though extremely rare, constitutes conclusive evidence for extreme pre-metamorphic high-sulphidation alteration of a volcanic protolith, while Fe-oxides or sillimanite-bearing nodules and veins record a less pervasive alteration. Geochemical research on element mobility and mass balance calculations further testified of an hydrothermal origin for these gneisses. The magnetite-rich units, together with calc-silicate rocks, garnetite, hornblendite, albitite among amphibolite, provided effective guides to sites of fluid discharge and led to the discovery of Cu and Cu-Au showings. With the presence of highsulphidation alteration, these features suggest early Cu-Au VHMS-type alteration halos within a predominantly felsic composite volcano-plutonic arc setting for both case-studies. Evidences for subsequent F-driven orthomagmatic fluid activity are also present.

May 1, 2003

By Candido Bariáin

A new vapochromic material of formula [Au2Ag2(C6F5)4(bipy)2]n (bipy = 2,2´ bipyridine) has been developed and used for the detection of some volatile organic compounds as acetone either in vapour or in water solution. The material is presented in the form of powders which colour changes with acetone vapours turning from bright yellow in the absence of vapour to white in the presence of vapour. By using the sol-gel technique, the powder ? dispersed in tetraethyl orthosilicate- was easily deposited on optical fibres. In order to study experimentally the behaviour of this material for construction practical optical fibre sensors, a sol-gel material doped with the vapochromic material is deposited onto an extreme of a monomode fibre connected to a coupler. The behaviour of the material was studied for different wavelengths and concentrations of acetone vapours and acetone/water solutions. Changes up to 4dB in the reflected optical power were detected. Optical fibre sensors have many advantages over conventional ones, such as electromagnetic interference immunity, passivity behaviour, possibility of using multiplexation techniques, low weigh and little size, etc. Actually, there is an increasing interest in developing optical fibre sensor for vapour detection in the chemical industry and in fact many sensor had been developed [1]. Some are based on the deposition of a sol-gel-based material either over the core of an optical fibre [1] or onto the thinner zone of a biconically tapered optical fibre [2]. Others are based on Fabry-Perot interferometers [3]. Also there are sensors based on the reflection of the light on films, on the fluorescence of dye-doped polymer cladding in fibre, on colorimetric reagents in the core of a silica fibre or on surface plasmon [4]. The possible materials for the construction of such sensor should be colorimetric reagents able to change the colour or refractive index in the presence of same organic vapours. There are not many metallic complexes with these properties, although same interesting examples have been reported in the chemistry of palladium and platinum as [Pt(p-R-C6H4NC)4][Pd(CN)4] described by Nagel [5] and Mann [6], which reported the construction of some LEDs. We recently reported the preparation of a novel vapochromic material (Fig 1) [7] which can be used for the construction of optical fibre tapered environmental sensors [8,9] of vapour organic compounds (VOC´s). Also we reported other nickel and palladium derivatives which present this type of behaviour [10]

Oct 1, 2003

By M. Cai

"It is well known that Peak Particle Velocity (PPV) plays a critical role in triggering rockburst damage in burst-prone underground mines. To estimate the PPV distribution around excavations, advanced numerical modeling can be used. In wave propagation numerical modeling, velocity field is often assumed to be uniform around an excavation. However, it is observed that wave velocities near mine openings are not constant, but rather non-uniform. Wave velocity in a rock mass depends on many factors such as rock quality and confinement. In particular, confinement has a large influence on wave velocity. The confinement around an excavation is low at the wall boundary and increases gradually and reaches a constant value far away from the excavation boundary. Hence, stress redistribution due to excavation will have a profound influence on wave propagation in underground mines. A better understanding of the influence of excavation effect on wave propagation helps to interpret the field observation of rockburst damage and improve mine safety. For this purpose, a non-uniform velocity model need to be constructed and the influence excavation effect should be taken into account in numerical wave propagation modeling.In the present study, a non-linear velocity model is developed firstly by considering the influence of confinement on wave velocity. This model links wave velocity to confinement explicitly. A coupled numerical method is then developed and used to study the seismic wave pattern around excavations in underground mines. Two codes, FLAC and SPECFEM2D, are coupled in the analysis. The motivation of developing the FLAC/SPECFEM2D coupled approach is to take merit of each code, such as the stress analysis capability in FLAC and the powerful wave propagation analysis capability in SPECFEM2D. The coupling process is realized through three steps: (1) static stress redistribution around an excavation is analyzed in FLAC; (2) data for coupling analysis, such as non-uniform velocity field (based on the new developed velocity model), mesh, absorbing boundaries, etc., are generated by FISH functions in FLAC and passed to SPECFEM2D; and (3) wave propagation modeling is performed in the SPECFEM2D considering a fault-slip seismic source. Because stress redistribution around the excavation is considered, non-uniform velocity field for the SPECFEM2D model can be obtained and this is a notable feature of this study. Very large difference in the S-wave response in these two modeling approaches with uniform and non-uniform velocity fields can be seen from the modeling results.Using the FLAC/SPECFEM2D coupled modeling approach, accurate velocity models can be constructed and this in turn will help to produce accurate PPV distribution around the excavations. Accurate PPV contours can be used to identify high rockburst risk zones for improved dynamic ground support strategy."

Jan 1, 2015

By M. Mahdi Aboutalebi, Roderick I. L. Guthrie, Mihaiela Isac

"A preliminary computational fluid flow model has been developed to simulate the flow field of liquid steel in the mold region of billet mold casting. This study reports the effect of different Submerged Entry Nozzles (SEN) on the fluid flow in round and square billet, curved mold, casters. In this study, ANSYS Fluent 14.5 software was used to model the 3-D turbulent flow of liquid steel. The standard k-0 model was used to simulate turbulence in the mold region. Similarly, the species transport equations were discretized to simulate the dye injection test into the mold cavity. The behavior of flow in the mold region was validated against previous experimental work. Predicted results showed that different nozzle types plus the slight curvatures in the molds can significantly influence the flow patterns generated within the mold region, and thereby affect the finished quality of the billet products.INTRODUCTIONConventional Continuous Casting (C.C) processes are presently used to solidify more than 95% of the 1.5 billion tons of steel now produced in the world annually (World Steel in Figure, 2014). This overwhelming contribution of C.C processes for steel production is the prime motivation for this study, in order to understand and optimize the casting processes and thereby reduce internal defects and minimize energy consumption. The primary objective of all C.C processes is to maintain liquid metal purity during the casting process and to create a uniform flow within the caster so as to avoid internal and external defects. In this regard, studying fluid flows in the mold region of continuous caster has attracted many research groups, in both academia and industry, in recent years. The mold region is one of the most critical parts of the C.C. process, in which the transport phenomena associated with this region can significantly affect the quality of the final products. Thus, proper control of fluid flows within this region can be expected to greatly decrease both internal and surface defects such as Oscillation Marks (OM), inclusion entrapment, and Mold Powder Entrapment (MPE). In the casting process, the fluid flow in the mold region can be affected by a number of variables, such as; the flow control system (stopper rod or slide gate), nozzle geometry, SEN (Submerged Entry Nozzle) depth, casting speed, mold dimensions, gas injection, and the application of electromagnetic fields. One of the most influential and easily-changed fluid flows are the jets of steel issuing from the SEN. Nozzle geometries are variable, consisting of a number of exit ports, different port angles, and/or port sizes, the bottom shape of the nozzle, and the SEN immersion depth (Thomas, 2001). The SEN characteristics can markedly affect meniscus surface velocities, surface level profiles, and turbulence levels that can vary in terms of the frequency and the magnitude of their fluctuations."

Jan 1, 2016

By R. J. McLeod

"A new backfill plant was constructed in 1966 adjacent to the mill of Giant Yellowknife Mines. The reasons for the addition were to increase the storage capacity for sand fill, provide facilities for mixing cement with the fill for mine stope floors and provide a system for pumping fill to B -3 raise, a horizontal distance of 4700 feet from the mill. At the same time it was hoped to increase the density of the fill pumped underground.The plant consists of two only steel storage tanks of approximately 400 tons capacity of sand fill each. They are 17 feet in diameter and have conical bottoms. The cylindrical section is 28 feet high and the conical section 14 feet high. Each tank is fitted with water nozzles around the conical sections to remove solids at the required density. The water pressure on the nozzles is 150 lbs per square inch. The cyclones used to produce the sand back fill are located on top of the storage tanks. Five model Dl0B Kreb cyclones are used for this purpose. The vortex finders are 2 1/ 4 inch and the apex 1 1/4 inch. The cement silo or storage tank is located in the same building. It is a steel tank 17 feet diameter by 41 feet high with a conical bottom. The silo holds 250 tons of bulk cement, which is unloaded by air from a bulk highway carrier using 12 to 15 lbs air pressure. The cement is conveyed to the top of the silo, a distance of 70 feet from the ground by 450 lbs. of air.The mixing tank is a rubber lined steel tank 14 feet in diameter by 14 feet high. It is equipped with a Lightning Mixer supplied by Greey Mixing Equipment Ltd. The mechanism is driven by a 40 HP motor. The lower shaft is unsupported and is equipped with two 36 inch diameter axial flow turbine type rubber covered impellers. The backfill is discharged from the storage tank into the mixing tank by a 5"" x 4"" SRL-C pump powered by a 20 HP motor. A level control in the mixing tank regulates the rate of discharge of this pump through a Grinnell-Saunders automatic control valve. The cement silo is situated at such a height above the mixing tank to allow for a Rota-Lock, a small hopper and a cement feeder. The feeder is an Omega gravimetric belt type dry feeder with a Sensogram controller. The capacity of the cement feeder is 20 tons of cement per hour. The cement and backfill are mixed in the mixing tank at whatever ratio is required for the mine stope floors."

Jan 1, 1968

By Avi Nanda, Robert Brandt, Alex Piatkiewicz, David M. Jones

In 2010 the United States Environmental Protection Agency (UESPA) revised the National Ambient Air Quality Standards (NAAQS) by lowering the permissible value to a 1-hour average SO2 concentration of 75 ppb. In 2012, the USEPA designated the Miami area as non-attaining for the new SO2 NAAQS. A number of options were studied to assist in bringing the Miami smelter into attainment with the new standard. The chosen solution included: Installation of a large tertiary hooding system over the converter aisle; Hooding of the anode vessels and treatment of the anode gas in a baghouse; Installation of a large 2,325,212 Nm3/hr caustic scrubber to treat the captured converter fugitives and anode off-gases; Installation of a secondary ESP for the tapping fugitive off-gas treatment system; and the continuous scrubbing of all acid plant tail stack gases. The modifications have reduced smelter SO2 emissions by 85%, achieving a world class SO2 stack emissions rate of 0.45 kg of SO2/tonne Cu. INTRODUCTION The Freeport McMoRan Miami smelter has been previously described in literature (Steinborn, Pasca, Sallee, Binegar, Bhappu). For the sake of brevity a brief description is given here. The Miami smelter is located 129 km east of Phoenix, Arizona near the town of Miami, Arizona. The smelter was established in 1915 and has undergone a number of process upgrades and modernizations over the years. The present smelter consists of an Isasmelt furnace, an electric settling furnace, four Hoboken converters, two anode refining vessels & one casting wheel; and one double contact sulfuric acid plant. Concentrates are railed & trucked to Miami from four Freeport McMoRan mines located in Arizona & New Mexico. The wet concentrates, typically containing 10% H2O with a Cu/S ratio of 0.85, are smelted in an Isasmelt furnace to a matte grade of 58%. The entire output from the Isasmelt is laundered into an Elkem electric furnace (originally installed in 1972 as the primary smelting furnace) for separation into matte and slag. Slag containing 0.85% Cu is skimmed from the electric furnace and discarded. Molten matte, containing 60% Cu, is tapped from the electric furnace and processed in one of four Hoboken converters to produce blister copper. Two anode refining vessels further refine the blister copper before the final product is cast on a single, 30 mold, casting wheel. All of the anodes produced at Miami are shipped to the Freeport McMoRan electrolytic refinery in El Paso Texas for refining into cathode copper. Smelter off-gases from the Isasmelt, electric furnace and Hoboken converters are combined and treated in a double contact acid plant to produce sulfuric acid. Acid produced at Miami is internally consumed at Freeport McMoRan mines in the region.

Jan 1, 2019

"Industry Guide 7 contains the Securities and Exchange Commission’s basic mining disclosure policy. It provides guidance for Registrants on various matters including the definition and disclosure of proven and probable reserves and the definitions of exploration, development and production stages. The definitions and disclosure instructions contained in this Guide apply to all public mining entities and their public disclosures. As NI 43-101 is law in Canada, the SEC allows mineral resources and mineral reserves prepared under CIM Definition Standards for issuers that are reporting in Canada but are also registered with the SEC. The SEC places conditions on the disclosure of these estimates. US shareholders are cautioned that the requirements under NI 43-101 and the CIM Definition Standards differ significantly from those of Industry Guide 7.Note: this Guide contains the Commission's basic mining disclosure policy. The definitions and disclosure instructions contained in this Guide apply to all public mining entities and their public disclosures pursuant to the rules of Regulation S-K. Questions regarding the application of these definitions and rules to specific situations should be asked of the Commission's mining engineers or geologists at either the Office of Engineering, Division of Corporation Finance, 202-272-3252, or the Branch of Geology, Central Regional Office, 303-844-1000.(a) Definitions. The following definitions apply to registrants engaged or to be engaged in significant mining operations:(1) Reserve. That part of a mineral deposit which could be economically and legally extracted or produced at the time of the reserve determination.Note: Reserves are customarily stated in terms of DoreD when dealing with metalliferous minerals; when other materials such as coal, oil shale, tar, sands, limestone, etc. are involved, an appropriate term such as Drecoverable coalD may be substituted.(2) Proven (Measured) Reserves. Reserves for which (a) quantity is computed from dimensions revealed in outcrops, trenches, workings or drill holes, grade and/or quality are computed from the results of detailed sampling and (b) the sites for inspection, sampling and measurement are spaced so closely and the geologic character is so well defined that size, shape, depth and mineral content of reserves are well- established.(3) Probable (Indicated) Reserves. Reserves for which quantity and grade and/or quality are computed from information similar to that used for proven (measured) reserves, but the sites for inspection, sampling, and measurement are farther apart or are otherwise less adequately spaced. The degree of assurance, although lower than that for proven (measured) reserves, is high enough to assume continuity between points of observation.(4)(i) Exploration StageDincludes all issuers engaged in the search for mineral deposit (reserves) which are not in either the development or production stage."

Jan 1, 2003

By T. I. . I. Sibbald, D. E. Jiricka

The Goldfields area on the north shore of Lake Athabasca , was active in the thirties and early fortie . In 1934, Tom Box discovered gold mineralization in quartz veins in pyritized 'granite' at the ite of what wa to become the Box Mine of the Consolidated Mining and Smelting Company of Canada Ltd . In the rush of activity that followed numerou other gold occurrences were found. the most significant of the e being the Athona and Frontier prospects which underwent underground development bur did not reach production. Probable reserve identified to date in the Box and Athona deposits amount to some 3.5 million ton grading an average 0.ITT oz gold/ton . Some 10 to 15 million tons of lower grade, po ible reserve are also reported at the Box. From 1939 to 1942, the mine produced, from underground , 64,066 ounces of gold from ore grading 0.0452 oz gold/ton at a cost of between $1.5 and $2.0 a ton. The Goldfield area is underlain by upracrustal rock intruded by mafic bodies and invaded by ·granite'. The upracru tal . thought to be of Lower Proterozoic age are characterized by a helf-type ucce ion metamorpho ed under lowermiddle amphibolire facie conditions into quartzites, quartz-mica chi ts. dolomitic marbles, diop idic calc-silicates and cordierite-anthophyllite-biotite schi t . Amphibolites of presumed igneou origin form concordant to subconcordant units up to a few ten of metre thick in the upracrustals and occur as le regular masses in the 'g ranite·. Compositionally they vary from gabbroic to granodioritic. with the more mafic varieties being most common. Granitic rocks exhibiting a variety of textural , structural and compositional characteristics underlie most of the area. Four main units are recognized: foliated (older) 'granite', 'leucogranite', feldspar augen 'granite· and pyritic mine 'granite', however, in geological mapping the e are somewhat arbitrarily differentiated due to transitional relationships and admixture of types. Although there is no unambiguous age data available for the e 'granite ' adjacent northshore 'granite' of geologically similar age yield Rb-Sr isochron dates around 2000 Ma. The area is characterized by two major deformation events of which the earliest gave rise to the dominant regional foliation and to rare minor and outcrop scale folds. This foliation which in general parallels compositional layering is folded into the major Goldfields syncline, whose axis plunges weakly to moderately outh. Related open minor folds have subvertical axial surfaces which are locally paralleled by a weakly defined schistosity. Most rock display a pronounced rodding fabric, coaxial with second fold axes and apparently the product of this deformation event. However, a note of caution is introduced into this interpretation, as the rodding fabric is also parallel to first fold axe .

Jan 1, 1986

By Jeremy D. Glennon

A number of exciting challenges, opportunities and unanswered questions remain concerning the chemistry, geochemistry, medical, industrial and analytical applications of gold and its compounds.1 Among the challenges presented is the need for extraction methods for gold, at process and indeed analytical scales, that avoid the use of organic solvents or hazardous reagents. Extensive environmental contamination has occurred in the Brazilian Amazon from the mercury-gold amalgamation process. Major problems with the cyanidation process are the relatively slow dissolution kinetics and the health and environmental problems associated with it. With innovation and technical changes, a cleaner way for solubilising and extracting this versatile precious metal can be found. This cleaner future may lie in supercritical fluid science. Interestingly, geochemical studies of gold solubility and speciation in hydrothermal solutions have highlighted the importance of supercritical conditions and sulphur species in the deposition of gold in natural environments. Gold solubility in supercritical brines is far higher than previously supposed while interest in the high content of carbon dioxide in the mineralizing fluids is growing. 2,3 In recent years, also, there has been a tremendous amount of attention paid in analytical chemistry and in industry, to the area of supercritical fluid extraction (SFE) of organic and metallic species. 4 This interest has been fuelled by the introduction of more stringent environmental control and the subsequent need for cleaner solvents and processes to replace established ones. Carbon dioxide is the substance of choice for SFE because of its moderate critical parameters (Tc = 31oC, Pc = 73atm), inertness and availability in pure form. It is an excellent extraction medium for non-polar and moderately polar species, and with careful ligand design, it can be used for analytical and process scale metal extraction from solution and solid phases. In general, the dissolution of a metal in supercritical CO2 (sc-CO2) requires that the charge on the metal ion be neutralised on complexation by the ligand or through a form of ion pairing (analogous to the situation where metal ions are extracted into organic solvents, such as methyl isobutyl ketone or toluene). In this way, then, many chelating agents such as dithiocarbamates and hydroxamic acids have been utilised to extract metal ions such as Cu and Fe into sc- CO2, the process greatly enhanced by the use of fluorinated ligand derivatives. 5-7 In this review paper, we show that supercritical conditions and complexation with sulphur donor atoms, important in the natural deposition of gold, can form the basis of a clean, eco-friendly chemistry for gold extraction. Analytical scale extractions of gold from a variety of matrices can be conveniently used to assess the efficiency of any new proposed ligand.

Oct 1, 2003

By Z. Zhong, Y. J. Hu, D. Elsworth

"A standard triaxial apparatus was set up to perform sliding tests. Slide-hold-slide (SHS) tests, with hold times from 10 to 3000s and at invariant effective confining pressures of 1MPa, incremented to 3MPa and then 5MPa, were conducted on both dry and wet split limestone samples to study the evolution of fracture friction under holding and sliding processes. Limestone fracture shows time-dependent behaviors in SHS tests, friction drops (creep) gradually during hold periods, and recovers (healing) after re-slide. Frictional healing and creep increment are proportional with hold times, while are inversely proportional with effective confining pressures. Moreover, the wet sample displays heavier healing than the dry one, whereas creep increment of the wet sample is lighter than the dry one. We conclude that the evolution of limestone fracture friction is significantly controlled by mechanisms of fluid-rock interactions.INTRODUCTIONThe evolution of the mechanical properties of fractures and faults exerts a critical influence on the behavior of fault zones and on the earthquake cycle. In addition to natural processes, this behavior has broad implications in induced seismicity and influences oil and gas production, the sequestration of carbon dioxide and the disposal of nuclear wastes.Fault friction is typically measured by slide-hold-slide experiments, where fault gouge is deformed at low velocities (<0.1 mms-1) and over small shear offsets (<30 mm) (Dieterich, 1979, 1981; Mair et al., 1999; Marone, 1998, 2004) or alternatively with rotary-shear devices, that enable higher slip velocities over very large shear offsets (Hirose & Shimamoto, 2005; Mizoguchi et al., 2006). Typical experiments (Dieterich, 1972; Marone, 1998; Olsen et al., 1998; Bos & Spiers, 2002; Tenthorey et al., 2003) show significant creep during the holding period and frictional healing (strength gain) upon reloading. Fault creep and healing are often time-dependent with longer hold times typically resulting in greater magnitudes of creep and in strength gains (Tenthorey et al., 2003; Yasuhara et al., 2005; Carpenter et al., 2012). Frictional healing may arise from growth of grain contacts (potentially induced by pressure solution) (Rabinowicz, 1951; Dieterich & Kilgore, 1994; Yasuhara et al., 2005), strengthening of the contacts (correlates with cementation) (Hickman & Evans, 1992; Beeler et al., 1994; Karner et al., 1997; Olsen et al., 1998; Muhuri et al., 2003; Tenthorey et al., 2003; Li et al., 2011) or via other changes in state including changes in porosity and rearrangement of force chains. Experimental evidence (Dieterich, 1979, 1981; Johnson, 1981; Marone & Scholz, 1988; Marone, 1998; Saffer & Marone, 2003; Moore & Lockner, 2007; Ikari et al., 2007; Ikari et al., 2011; Carpenter et al., 2012) quantifies both the mode and magnitude of second-order changes in the velocity-dependent (including velocity- strengthening and weakening) evolution of frictional strength."

Jan 1, 2015