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By Stanislaw Trenczek

Natural hazards such as rock bumps, methane, coal dust explosions, airborne respirable dust, outbursts of gas and rocks, water, radiation caused by natural radioactive materials, spontaneous fires, and climatic hazards, occurring in the Polish hard coal mines, should be controlled. These hazards are characterized by different scale levels numbered from 2?5. To recognize the amount and levels of hazards, research works were carried out in 109 mining districts of mines belonging to Jastrzebska Spólka Weglowa, Katowicki Holding Weglowy and Kompania Weglowa. These are 86 % of all mines and could be regarded as representative of the majority of Polish mining. The hazards have been classified as regards the frequency of their occurrence as: commonly occurring ? with a frequency of 100 % (like airborne respirable dust and fire hazards), high occurrence frequency ? frequency from 60 to below 100 % (methane hazard ? 83.5 %, coal dust explosion hazard ? 92.0 %, and water hazard ? 99.1 %), medium occurrence frequency ? from 30 to below 60 % (rock-bump hazard ? 52.3 % and climatic hazards ? 51.4 %), and episodic occurrence frequency ? below 30 % (outburst of gas and rocks and radioactive hazards). The dynamics of effects of growth in hazard levels to their intolerable values is diverse. Some of them are passive in nature, which allows for longer observation of changes and appropriate early response (as for climatic and spontaneous fire hazards). However the majority of them take on the character of disasters, like methane or coal dust explosions and damage of the excavation structure ? as occurs after a rock-bump or rock outburst; and creation of an atmosphere unfit for breathing ? during open or spontaneous fires, or after gas outbursts containing methane. There are also latent hazards whose effects do not influence indeed a process of production; however they are detrimental to health when a worker is exposed for a long time to airborne respirable dust and radiation. For other types of hazards a level of danger may be only estimated. Since the systems monitoring allows a wider range of control, therefore, aside from rock-bump and methane hazards, there are monitored also fire hazards including measurements of other air parameters (velocity, pressure, humidity, temperature, O2, CO2 concentration). A few types of monitoring systems are used in Polish mines, like the monitoring systems for environmental parameters such as SMP-NT, SMP-NT/A, the telemetric systems CST-40, CST/A, including the computer-aided system for methanometry control officer SWµP, the computer-aided measuring systems KSP-1, KSP-2, KSP-2C, or the production and safety control system VENTURON. The underground part of the systems monitoring of natural hazards contains measuring devices and equipment for automatic control (power-off) of machines and electric devices in case of increased methane hazard. The surface part of the monitoring system allows the measuring data to be visualized and pre-alarm (warning) and alarm states to be displayed. Furthermore it makes it possible to archive and report the data and to control the underground supply and signalling devices. The EMAG Institute developed monitoring methods to extend a measuring range of monitored parameters (such as methane and fire hazards) as well as to monitor so far unmonitored hazards like dust hazards (by continuous monitoring of dust levels in mine air) and climatic hazards (by online monitoring climatic parameters of mine air).

Aug 1, 2013

By E. Brzychczy

Artificial intelligence techniques are ever more frequently implemented in the modern world. One of their numerous uses is supporting enterprise management. Intelligent techniques and intelligent information technology (IT) systems can be implemented in mining-related issues as well. The author of this article concentrates on supporting the process of planning mining operations by intelligent systems and techniques. The author also underlines the importance of knowledge accumulation in a mining enterprise (especially tacit knowledge) as well as its efficient storing and using. Additionally, the author provides a short description of characteristics of intelligent IT systems and indicates their capabilities in planning mining operations. She presents two solutions, namely: an advisory system which supports the process of planning preliminary works and exploitation works in hard coal mines, and a method of modeling and optimizing mining operations. Finally, the author indicates a few possible future development trends of intelligent systems - the intelligent systems of decision support.

Aug 1, 2013

By J. Manchisi

This study has investigated the use of blast furnace slag as functional adsorbent for metal ions in acid mine drainage treatment. This opportunity has not yet been developed into a practical process partly because of limited understanding of rates and mechanisms of adsorption process and inconsistency in interpretations of adsorption data. The overall objectives were to determine the efficiency and mechanisms of sorption process of metal ions in a multiadsorbate system. We employed standard materials characterisation techniques to analyse composition, structure and surface morphology of the slag. Batch adsorption experiments were then conducted to study the mechanisms, kinetics and efficiency of metal sorption as a function of pH, phase ratio, mixing time, mass and particle sizes of slag. Both XRF and adsorption data suggested the slag to possess acid neutralising capacity. This slag is non-crystalline based on XRD pattern, has adequate porosity and pore volume comparable to similar commercial adsorbents but it has inferior pore structure, pore size distribution and BET surface area to be effective under wide applications. Metal sorption increased with decrease in slag particle diameter, decrease in initial metal concentration and increase in the mass of slag. Although slags have demonstrated to efficiently treat low concentrations of single and multiadsorbate effluents using fine particle sizes, they have limited capacity to treat multiadsorbate systems for some metal ions. This is probably due to low affinity, competitive adsorption or limitation in material?s adsorptive properties. Sorption mechanisms probably involve precipitation and ion exchange on the basis of alkaline pH and exchangeable slag surface ions. Sorption preference is proposed as Fe2+>Cu2+>>Cd2+>Co2+>Mn2+. Despite these limitations, deeper understanding of sorption behaviour of metal ions by slags for application in dilute and large volumes of effluents is necessary where precipitation and other standard techniques are either inefficient or uneconomic. Thus, this study has established that sorption capacity of slag to remove metal ions from acidic effluents is selective, limited to certain metal ions and for other ions only at low concentrations. Further adsorption studies in multiple solutes under various experimental conditions or those that can propose an economic slag activation process are needed that improves or widens adsorption window.

Aug 1, 2013

By William Winsor, Harold L. Snyder

"AbstractShould oil and gas be proven in commercial quantities on the Labrador Shelf, current technology is not adequate for production operations in this severe environment, which includes yearly invasion of pack ice and icebergs. The fishery of this section of the North Atlantic is a vital resource to which a major oil spill or blow-out would impose an intolerable burden, This means that production systems must be designed and built to be fail-safe.The experiences of mining in Bell Island and Cape Breton have shown that it is possible to operate beneath the ocean floor, and this technology may hold the key for safe, reliable and economic production, This paper attempts to define particular problems and outline possible solutions.IntroductionOUR DISCUSSION is subject to the assumption that large hydrocarbon reservoirs will be discovered in the sedimentary basin of the Labrador continental margin. The petroleum industry has not attempted to operate in a harsher area. The Labrador coastline is exposed to North Atlantic storms and icebergs year’round, Arctic pack ice occurs up to six months of each year. However, there is no doubt that, if sufficient hydrocarbon potential is outlined, development will proceed."

Jan 1, 1977

By B. W. Steele

"Dofasco began operations in 1912 as a steel foundry located in Hamilton, Ontario. Today, Dofasco is a fully integrated mill that manufactures hot rolled, cold rolled, galvanized and tinplate steels. Customers include the automotive, construction, tubular, manufacturing, appliance, packaging and steel ser-vice centre industries. Raw steel production and purchased semi-finished steel processed in1994 was 3.5 million net tonnes. Dofasco employs 7300 people at its Hamilton facility.Environmental management at Dofasco is guided by its environment policy and associated commitments. This paper discusses Dofasco’s responsibility for its products as it relates to these commitments. Dofasco is com-mitted to:n the principles of sustainable development that require that activities be conducted in a manner that provides for the present without compromising the ability of future generations to meet their needs. These principles will be integrated into product design, manufacturing and business planning;n managing renewable and non-renewable resources through the responsible application of reduce, reuse, and recycle principles;n minimizing any potential impact of its operations and products on the environment, employees, customers and the community;n continuous improvement of the effectiveness and integrity of our environmental management systems;n developing understanding among all employees about their responsibilities, and assigning the necessary authority; andn meeting the standards set by relevant legislation and international agreements through participation with governments and the diligent application of economically feasible and scientifically sound methods and technologies."

Jan 1, 1996

By Wm. L. Giachino

"Over the last 10 years, C-1-L has played a significant role in the major advances that have taken place in blasting technology, among them the following: development and introduction of capsensitive slurries; development of bulk slurry systems both for underground and open-pit operations; development of the TOE-DET and ANODET systems of delay blasting;introduction of the NONEL system of initiation;development of the Vertical Crater Retreat (VCR) system of mining.This paper identifies areasin which we foresee further developments in blasting technology over the next 10 years and outlines how and to what extent C-1-L will become involved."

Jan 1, 1980

By Duanyou Li, Qing Xiao, Zhiwang Wang, Xiaoqing Gan

"Seepage is a major cause of earth-rockfill dam failure. Numerical simulation of infiltration process, distribution of drift, flow velocity and direction after the impoundment can guide seepage control and evaluate its effects. A double field coupling model is established based on soil consolidation theory and the interaction between the seepage field and the temperature field. The simulation is implemented under the situation of core wall setted, core wall not setted, and core wall setted with concentrated leakage. The results indicated that the saturation line height was significantly reduced due to impervious core wall, and the temperature distribution is uniform above the saturation line. If concentrated leakage occurs, temperature distribution of dam was significantly changed, which is consistent with theoretical inference.INTRODUCTIONEngineering seepage field distribution must be calculated in seepage control design, optimization, and correction of new engineering construction of earth dams, as well as in seepage monitoring and evaluation of existing earth-rockfill dams. The aim of calculation is to identify the important parameters in seepage field, such as the coefficient of permeability, seepage flow, pressure, head, and allowable seepage slope, for effectively implementing seepage control design, correction, safety assessment, and anti-seepage reinforcement. These seepage parameters usually can be obtained by in-situ test and back-analysis based on reliable monitoring data.In order to obtain reliable monitoring data and reflect the earth-rockfill dam seepage state and change process, appropriate monitoring technology and monitoring method is necessary. The traditional seepage monitoring method is through site inspection and sensors (e.g., osmometer, piezometric tube and measuring weir) that buried in the structure and its foundation. However, there are still some disadvantages:"

Jan 1, 2015

By W. W. Cummings

The Mineral King Mine, owned and operated by Sheep Creek Mines is located in the Purcell mountain range of southeastern British Columbia. Production of lead and zinc concentrates commenced in 1954 some 60 years after the initial discovery. Low cost mining methods have been employed to extract 16,0C'O tons of ore monthly from large ore bodies formed by replacement in limestone. Extensive areas in the limestone are yet to be explored and success in the search for new ore bodies is anticipated.

Jan 1, 1960

By D. A. Riva

"The Line Creek Project is located in southeastern British Columbia, approximately 25 kilometres north of Sparwood. The design is to produce a total of2.7 million tonnes of coal annually. This is made up of1.4million tonnes of thermal coal and 1.3 million tonnes of metallurgical coal.Construction commenced in the spring of 1980 and mining operations began in July 1981. The thermal processing plant, maintenance and dry facilities, as well as extensive road and bridge construction, were completed in early 1982. A collective agreement was signed with the International Union of Operating Engineers, Local 115, in June 1981.The first unit train left Line Creek on February 18, 1982 with a load of thermal coal bound for the Ssangyong Corporation in Southern Korea. It was the start of a ten-year contract to supply 350,000 tonnes annually to fire their cement kilns. Additional contracts for 750,000 tonnes will fuel the boilers of Korea Electric Company's San Chon Po and Go-Jeong power stations. Metallurgical coal shipments are scheduled to leave the Roberts Bank port in Vancouver in April 1983.Tracking an introductory presentation given at the 1981 CIM Annual General Meeting in Calgary, this paper highlights the salient developments by which ""The Line Creek Project"" has progressed during the past year to the"" Line Creek Operation"". Line Creek has com e on stream as scheduled and will meet all contractual commitments pertaining to timing, volumes and quality for thermal coal. The first train load left the plant in mid-February, and the first boat load to Korea departed Roberts Bank in mid-April. Metallurgical coal deliveries will commence in April 1983."

Jan 1, 1982

By L. Vu, V. Popov, J. Beland, R. Darling

"The Ferderber gold deposit is of Archean age. It consists of a series of gold-bearing quartz lenses within a shear zone that crosscuts the central part of the quartz dioritic Bourlamaque batholith. On average, this zone strikes N70E and dips 65SE. The Ferderber shear zone, which hosts the ore lenses, has been affected by a succession of tectonic events. A possible early period of brittle shear, accompanied by the formation of quartz lenses, resulted from strike slip movement along the zone. These early quartz veins were subsequently folded and boudinaged during reverse movement that accompanied a prolonged period of ductile shear. More quartz veins were emplaced in the shear zone at this time; these were also deformed by the thrusting. The latest tectonic event to affect the shear zone was a period of brittle fracture.Early dextral strike-slip movement on the shear zone is suggested by the local occurrence of Riedel shears, the preferred association of ore with east-northeast oriented segments of the zone, and by the apparent en echelon arrangement of some ore lenses. The most important event, a reverse movement, is indicatedby the attitudesoffoliation, folds, boudins, COS tectonites and slip planes. The late brittle fracturing formed narrow gouge filled faults, locally flanked by brecciazones, whichrun generally within and parallel to the shear zone, and also conjugate fractures that crosscut the zone.The Ferderber and six other adjacent gold deposits were formed in a structural regime dominated by a generally horizontal north-south regional compression. The Y axis of the strain ellipsoid is east-west and varies from horizontal to a plunge of 25 0 w."

Jan 1, 1987

By V. A. Chanturiya, T. N. Matveeva, N. K. Gromova, T. A. Ivanova

"The research is aimed at solving the problem of increasing the extraction of gold from refractory ores, which are the main source of growth in gold production in the next decades. The purpose of the research is the development and scientific substantiation of the reagent modes for flotation extracting of gold from refractory ores using eco-friendly low-cost herbal modifiers (HM), providing increase in gold recovery and quality of gold concentrates. In the course of research laboratory techniques for the preparation of experimental samples of HM were developed, which included the sequence of operations of grinding Heraclium leaves and stems grinding, 2-stages extraction at a temperature of 50-60 °C, short-term ultrasonic treatment, filtration and subsequent unification of extracts. According to the developed method, the experimental samples of HM and conducted research were tested to analyze their sorption and flotation activity related to the extraction of gold from refractory gold ores.New data on adsorption and flotation properties of Heraclium stems and leaves extracts (HSE) in selective flotation of Au-sulfide minerals were obtained using UV-spectroscopy, scanning electronic and laser microscopy and atomic force microscopy. The dimensions and shapes of adsorbed hydrophilic films of herbal reagents were identified and mechanism of formation of stable insoluble compounds on the surface of minerals in flotation was explained.Research flotation tests carried out on samples of refractory gold ore of one of Russia deposits showed the possibility of effective use of herbal modifiers to improve qualitative and quantitative indicators of enrichment compared with the standard reagent regime. New reagent modes, using herbal modifiers in an amount of 5 to 10 ml of the extract (300 - 600 g / t, respectively) improves the quality of the concentrate: gold content attains 14.7 g / t, 1.34 times higher than in the baseline experiment and provides a gain of 3.13% extraction.The developed reagent regime with herbal modifiers is the author's original design, patented (patent of the Russian Federation) and have no analogues in the world of mineral processing. (Application number 2015116125 from 04.28.2015, ""The method of flotation separation of sulfide minerals using herbal modifier"", Russia). Actual application of new plant extracts as modifiers in flotation of sulfide minerals is the possibility of replacing of highly toxic chemical compounds by environmentally safe substances of plant origin. Implementation of the developed methods of extracting gold from refractory minerals with herbal modifiers will help to improve gold recovery at 3-5% and the quality concentrate of not less than 1.2 times, leading to higher productivity and a reduction of the negative man-made effects on the environment ."

Jan 1, 2016

By N. Kubo

Sumitomo Toyo Copper Smelter and Refinery was commenced in 1971, and its production capacity of sulfuric acid was 550tpd at the beginning. In 2001 Toyo Copper Smelter and Refinery projected to expand its copper production capacity to 450,000tpy, and now the project is still in progress. To achieve this expansion project, 4,000tpd of sulfuric acid production capacity is necessary to the acid plant. So as a part of this project, the construction of the new converting and absorbing line and the improvement of the existing converting and absorbing line were carried out from 2001 until 2005. Then the production capacity of these 2 lines has already reached the target, 4,000tpd of sulfuric acid. Moreover, at the design of the new line, we adopted several latest technologies and materials in order to construct the world's leading acid plant. Basing on the operation performance of the new line, we have improved the existing line in 2005. Both of these 2 converting and absorbing lines are working quite well and contribute to big energy saving and excellently stable operation. Cu2007

Jan 1, 2007

By T. Grammatikopoulos, A. Jordens, C. Gunning

"Exploration activity for rare earth element (REE) deposits (i.e., alkaline complexes, carbonatites) has increased significantly in the last decade. A number of deposits have been evaluated around the globe. However, new mines have not been commenced in the last few years with the exception of Mount Weld (Lynas) and Mountain Pass (Molycorp).Resource estimation of REE can follow similar guidelines to other metal projects. However, the inherent mineralogical characteristics of the REE deposits, despite their complex nature, have been generally overlooked by many exploration companies. These include variability of the ore, liberation and association of the REE minerals, and grain size, all of which can affect the processing of the ore. Each deposit appears to be different in terms of matrix and REM (rare earth minerals). Light REE bearing minerals such as allanite, monazite, bastnaesite, synchysite, and HREE bearing minerals such as fergusonite and xenotime can vary widely in composition, grain size and association (e.g., carbonates or hard silicates). On the other hand, although not really REM, zircon, Zr-silicates, titanite, fluorite, apatite, and in some cases many other common silicate minerals can carry trace to significant concentrations of REE.The evaluation of REE deposits should include an appropriate mineralogical characterization in order to quantify the REM, distribution, liberation and association by quantitative mineralogical techniques (i.e., QEMSCAN, MLA, TIMA and others); chemistry of the REM by electron probe micro analysis (EPMA), Laser Ablation ICP-MS or ToF SIMS.These techniques provide valuable data for geological purposes such as: defining quantitatively, the variability and distribution of the REM; differentiating between LREE and HREE zones to delineate ore; and metallurgical purposes to predict minerals/REE behaviour during processing. The lack of a comprehensive mineralogical characterization often leads to the wrong processing path and ultimately affects the elemental/mineral recovery."

Jan 1, 2016

By M. Walmsley, D. Maynard

"This paper describes the use of terrain and soil information in the planning of mine developments, particularly in satisfying many of the existing provincial regulatory requirements. It is also noted that, if properly used, this will provide a solid data base for cost-efficient and environmentally acceptable land use.IntroductionIn planning the development or expansion of a new or existing mine, engineering alternatives are judged on many factors, one of which is the environmental influence. Ecological investigations, ensuring consideration of a rational approach to managing land use and environmental impacts, should be carried out prior to a final decision being made on mine development. The Pit Slope Manual (CANMET, 1976) suggests that both baseline aquatic and terrestrial data be collected and interpreted in such pre-mining surveys. In British Columbia, planning procedures now exist which incorporate biophysical studies to help identify, assess and manage major environmental impacts associated with mine development.Methods outlined in the Guidelines for Coal Development (E.L.U.C., 1976) have been successfully applied in recent years. Following this example, the Inspection and Engineering Division of the B.C. Mineral Resources Branch prepared guidelines to help expedite the development of new base metal mines (Procedures for Obtaining Approval for Metal Mine Development; Ministry of Energy, Mines and PetroleumResources, 1979).The metal-mine guidelines require the proponent of a new mine development project to prepare a two-stage assessment proposal which systematically moves from a preliminary feasibility study (Stage I) to a final project design (Stage II), including application for regulatory approvals. One purpose of the Stage I report is to provide a description of the existing environmental conditions that could be affected by the proposed development. A preliminary environmental impact assessment should also be reported. The Stage II report will contain detailed assessment and management of environmental impacts."

Jan 1, 1981

By R. L. Bruening, R. M. Izatt, N. E. Izatt, K. E. Krakowiak, S. R. Izatt

The need for selective metal separations has increased as the mining industry encounters more complex ore bodies and the demand for higher performance end products expands. Molecular Recognition Technology (MRT) is a green chemistry process that involves use of SuperLig® resins to selectively remove desired metals from a variety of solutions in mining and metals processing industries. Recoverable metal concentrations can range from multiple g/L to mg/L or less. The MRT separation process is based on green chemistry principles and can efficiently produce high purity metal products with minimal waste generation and energy usage. In this paper, applications of MRT to metal recovery and purification in the minor and specialty metals industry will be presented and discussed. Examples will be described involving cobalt, nickel, zinc, rhenium, iridium, indium, germanium, bismuth, and cadmium, as well as removal of lead and iron from process streams.

Jan 1, 2015

By T. Wajima

"A novel carbonaceous adsorbent for recovery of nickel from nickel plating waste solution was prepared from rice straw using sulfur impregnation. The rice straws were cut to 1 cm pieces, and then immersed in 0.01 - 3 M K2S solution to prepare sulfur-immersed materials. The immersed-materials were heated at 100-700 ºC in nitrogen gas to produce the sulfur-impregnated carbonaceous adsorbent by pyrolysis. The contents of carbon and sulfur in the adsorbent and abilities of adsorbent to recovery nickel from aqueous solution were examined. The contents of carbon and sulfur in sulfur-immersed materials are almost same as those in raw material. In pyrolysis, with increasing the heating temperature to 200 ºC, the contents of carbon and sulfur are almost constant, and then above 300 ºC those increase. The recovery for nickel using raw material, sulfur-immersed material and the product pyrolyzed at 100 - 200 ºC are almost same, and with increasing the heating temperature to 400 ºC, that of the product increases, and above 500 ºC that of the product decreases. In immerse step, with increasing K2S concentration, the carbon content of the product at 400 ºC gradually decreases, the sulfur content of the product increases, and the recovery for nickel using the product gradually increases and then above 1 M K2S decrease. The product prepared from material immersed in 1 M K2S solution at 400 ºC indicates a maximum recovery for nickel ion. The product can adsorb nickel ion in nickel plating waste solution coexisting with phosphate ion, and adsorbed nickel ion in the product was deposited as nickel metal after heating at 1000 ºC under N2 atmosphere.INTRODUCTIONRice is the second world’s largest cereal crop after wheat, but produces large amount of straw residues, of about 330 million metric tonnes. Rice is a widely grown crop in Asia, and rice straw is produced as a by-product of rice production. In most parts of rice fields, open-field burning of rice straw is commonly practiced in the region when there is limited time to prepare a field for the next crop. However, open-field burning of crop residues is an uncontrolled combustion process during which air pollutants are emitted into atmosphere. These air pollutants have significant toxicological properties and are potential carcinogens (Gadede et al., 2009). Although wildfires are prohibited in cultivation fields of most countries, farmers usually keep on burning their crop by-products. Biomass burning is an important source of aerosol particles which may affect local and regional air quality (Gao et al., 2011), and also contribute to global climate changes."

Jan 1, 2016

Forward-Looking Statements Information set forth in this presentation may involve forward-looking statements under applicable securities laws. Forward looking statements are statements that relate to future, not past, events. In this context, forward-looking statements often address expected future business and financial performance, and often contain words such as "anticipate", "believe", "plan", "estimate", "expect", and "intend", statements that an action or event "may", "might", "could", "should", or "will" be taken or occur, or other similar expressions. Forward-looking statements or information relate to, among other things expected iron ore demand, timing for a production decision, expected share price drivers, potential railway options, timing, grade and quantity of potential resource estimates, employment and economic benefits, taxation estimates and timing of key project milestones. By their nature, forward-looking statements involve known and unknown risks, uncertainties and other factors which may cause our actual results, performance or achievements, or other future events, to be materially different from any future results, performance or achievements expressed or implied by such forward-looking statements. Such factors include, among others, the following risks: the risks associated with the need for additional financing; operational risks associated with exploration; fluctuations in commodity prices; title matters; environmental liability claims and insurance; reliance on key personnel and other risks and uncertainties discussed in the management discussion and analysis section of our interim and most recent annual financial statement or other reports and filings with the TSX Venture Exchange and applicable Canadian securities regulations. Forward-looking statements are made based on management's beliefs, estimates and opinions on the date that statements are made and the Company undertakes no obligation to update forward-looking statements if these beliefs, estimates and opinions or other circumstances should change, except as required by law. Investors are cautioned against attributing undue certainty to forward-looking statements. NI 43-101 Qualified Person Alderon?s exploration work on the Kami Project is supervised by Edward Lyons, P.Geo., the Chief Geologist for Alderon and a Qualified Person as defined byNational Instrument 43-101. Mr. Lyons has reviewed and is responsible for the technical information contained in this presentation. Mr. Lyons is a member in good standing of the Association of Professional Engineers and Geoscientists of British Columbia (APEGBC) and the Professional Engineers & Geoscientists Newfoundland & Labrador (PEGNL) as a registered Professional Geoscientist (P.Geo.).

May 1, 2011

By M. Abumiya, N. Onodera

"The synthesis of large scorodite particles in non-ferrous metallurgical industries usually requires a high-cost operation involving heating and high-pressure autoclaving. To overcome these obstacles, an atmospheric-pressure process for scorodite synthesis (DMSP®) was developed, in which ferrous ions were oxidized by oxygen gas in the presence of pentavalent arsenic ions. This process gives scorodite of good crystallinity with particle sizes as large as 15-20 µm. The solutions used for scorodite synthesis in the DMSP® are prepared from various residues containing arsenic from non-ferrous smelters. The solutions may be contaminated with Cu, Sb, and Bi, for example, and therefore the effects of such impurities on the formation of crystalline scorodite need to be investigated. In this study, the effects of Cu, Sb, and Bi contaminants on the formation behaviors of scorodite particles in the DMSP® were investigated systematically.INTRODUCTIONThe synthesis of crystalline scorodite (FeAsO4·2H2O) is a suitable method for arsenic (As) stabilization and storage of As-containing by-products such as flue gas dusts in non-ferrous smelters. It is expected that the formation of large, highly-crystalline scorodite particles would be an ideal method for avoiding the release of arsenic to the environment. Generally, autoclave methods under pressurized oxidation conditions at temperatures above 100°C have been used for the formation of arsenic minerals such as scorodite. However, the autoclave method requires sealed vessels that are resistant to high pressure, heat and acids. This process is also unfavorable on account of the high construction expenses, and high running costs as a result of vapor heat loss. Processes for synthesizing scorodite under atmospheric conditions at temperatures below 100°C which do not need an autoclave have therefore been extensively investigated (Demopoulos, Droppert, & VanWeert, 1994; Demopoulos, 1996; Demopoulos, Lagno, Wang, & Singhania, 2003; Droppert, Demopoulos, & Harris, 1996; Filippou & Demopoulos, 1997).Recently, Fujita et al. (Fujita, Taguchi, Abumiya, Matsumoto, Shibata, & Nakamura, 2008a, 2008b, 2009; Fujita, Taguchi, Kubo, Shibata, & Nakamura, 2009; Fujita, Taguchi, Shibata, & Nakamura, 2009) developed a new method for producing large scorodite crystalline particles with improved filtration and washability properties at normal atmospheric pressure and temperatures below 100°C. In the new method, oxygen gas (O2) is blown into solutions containing a high concentration of arsenic ions (As(V)) and ferrous ions (Fe(II)). The Fe(II) ions were subsequently oxidized to ferric ions (Fe(III)), resulting in the formation of large scorodite particles. High supersaturation of solutes such as Fe(III) will result in excessive nucleation, and the formation of poorly crystalline phases. The scorodite formation must therefore be conducted in a manner that avoids the critical supersaturation level being exceeded. It is supposed that the oxidation of Fe(II) to Fe(III) by O2 gas in the new method suppressed the supersaturation of Fe(III) during scorodite formation. The low Fe(III) supersaturation resulted in formations of highly crystalline scorodite particles of size of around 20 µm. In June 2008, based on the developed process described above, DOWA began experiments to verify the industrial capability of a plant with a capacity of 30 MT/month of As. It was successfully proven that it is possible to produce crystalline scorodite industrially on a commercial scale. This process was named and trademarked as DMSP® (Kubo, Abumiya, & Matsumoto, 2010)."

Jan 1, 2012

By S. P. Cashin, D. Kashuba, W. Esplin

Barrick has had 6 autoclaves in operation at the Goldstrike Mine, North of Carlin Nevada, since 1993. The 6 autoclaves operate in parallel, processing slurry of gold ore. The gold in the ore is predominantly associated with, and encapsulated by, sulphide minerals. It is necessary to oxidize at least 90% of the sulphide mineral before the gold can be concentrated using a cyanide/carbon-in-leach (CIL) circuit. Sulphide oxidation chemical reactions occurring in the autoclaves are exothermic; however, the sulphide content in the ore is not high enough to operate the autoclaves in an auto-thermal mode. Heat from steam is added to the first 2 of 5 autoclave compartments to initiate the sulphide oxidation reactions. The steam used to heat the autoclaves is supplied by three boilers, which are fuelled with propane gas. The completion of a few operations and maintenance projects in the last 2 years has resulted in a 50% reduction in propane energy requirements. The autoclave operating temperatures were minimized. Excess oxygen addition was held as low as possible. The material of construction for the compartment walls inside the autoclaves was changed from brick to Titanium metal. And, the speed of the autoclave slurry agitators was increased. All of these activities had an impact on the propane energy requirements of the autoclaves. Presented below is a description of the autoclave systems, and a discussion of how the energy needs were reduced, resulting in significant operating cost savings.

Jan 1, 2004

By P. V. Amosov, V. A. Masloboev, D. V. Makarov, S. G. Seleznev, A. A. Baklanov

"The development of industry and intensive use of natural resources leads to a significant decrease in the share of reserves of rich ores, deposits of which have nearly all been exploited. Large amounts of displaced rock mass are accumulated, significant emissions of gas and dust from mining, dust from dumps and tailing pits, ingress of chemicals and toxic elements in surface and groundwater all can have negative effects on existing ecosystems and human health. Especially dangerous is the impact in Arctic regions with extreme climate conditions. The maintenance of overburden dumps and tailings dams requires significant capital and material costs. In this paper, some mining enterprises of the Murmansk region, in the Russian Federation, consider the environmental problems of the industry and propose some solutions.INTRODUCTIONThe safety of environment during the extraction and processing of minerals is a very acute problem throughout the whole world. The problem acquires a specific character in the Russian Federation. There, rather poor minerals, often existing in unconventional forms and including several mineral components are processed. The Russian mineral base has a specific geographical location; most of the deposits under operation are located in the Subarctic or Arctic regions, as well as in Siberia and in the Far East. Vast amounts of rock waste and tailings pose serious economic and ecological problems in mining regions. The operation of overburden heaps and tailings requires considerable capital and material costs. The dumps withdraw vast lands from potential commercial use. Large amounts of mined rock disturb the existing geological balance; emissions of gas and dust which accompany the mining operations, dusting of waste heaps and tailings, emissions of reagents and heavy metals into natural surface and ground waters all can produce negative effects on existing ecosystems and human health."

Jan 1, 2016