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By R. Argane

In this work we assessed the geochemical behavior of concentrator tailings deposited at the abandoned mines of Zeida and Mibladen (Upper Moulouya, Morocco), using physico-chemical analyses, mineralogical characterization, acid base accounting and weathering cell tests. The aim of the study was to evaluate mine drainage quality and to assess metal mobility from these concentrator tailings. Chemical analyses show that the Upper-Moulouya abandoned tailings contain relatively high quantities of lead (0.261 to 0.594 % wt). Mineralogical analyses reveal the abundance of neutralizing minerals (calcite, dolomite, ankerite, and aluminosilicates) which influence mine drainage and metal mobility in mine tailings. Leachate analyses from weathering cell tests show alkaline conditions, small conductivity values, and low solubility of Pb-mineral phases. According to these results, abandoned mine tailings in the Upper-Moulouya district have very low potential for generation of contaminated mine drainage and for leaching of heavy metals. However, the inhalation of tailings exposed to winds generate dust problem facing the local population and may cause health consequences.

Aug 1, 2013

By J. E. Quinn, S. Wolstencrof, K. H. Soldenhoff

Ion Exchange (IX) using Strong Base Anion Exchange (SBA) resins is conventionally used to purify uranium from sulfuric acid pregnant leach solutions (PLS), particularly when uranium grades are relatively low. However, the presence of chloride in the PLS interferes negatively with conventional SBA based IX processes, by reducing the uranium loading on the resin. Chloride can be present in the PLS due to the use of saline bore or seawater in leaching, or chloride containing leach/IX reagents. ANSTO has been examining strategies to combat this problem for several years. ANSTO previously reported that a recently developed high-capacity SBA resin was capable of extracting uranium efficiently from saline leach liquors produced at Boss Resources’ Honeymoon in-situ recovery mine in South Australia. The resin was tested successfully in a 2017 Field Leach Trial carried out onsite in the existing wellfield area. While the piloting was extremely promising, the elution was more challenging, with eluate tenors limited to 2 g/L U3O8 using NaCl. This is due to the resin’s strong affinity for the uranium complex, which makes it difficult to elute efficiently by standard methods. In this paper, we describe a novel elution process developed for strong base resins that significantly improves upon conventional methods. The process, developed by ANSTO, is based upon conversion of the extracted uranyl sulfate species to uranyl carbonate, followed by elution with sodium chloride. The loading and elution process was demonstrated in continuous locked-cycle piloting conducted at ANSTO in 2019. The results were excellent, with eluate tenors of 8–9 g/L U3O8 achieved from Honeymoon PLS containing 50 mg/L U3O8, with very little transfer of impurities. In subsequent test work, the eluate was shown to be amenable to uranium peroxide precipitation. The results represent a huge step forward for the purification of uranium from saline leach liquors.

Jan 1, 2020

By S. Esfahani, M. Barati

Heat recovery from blast furnace slags is often contradicted by another requirement, to generate amorphous slag for its use in cement production. As both the rate and extent of heat recovery and slag structure are determined by its cooling rate, a relation between the crystallization kinetics and the cooling conditions is highly desired. In this study, slags with different basicities were studied during non-isothermal cooling. Their continuous cooling transformation (CCT) diagram were plotted and compared with each other. Then, a mathematical model was developed that predicts the amount of crystallization during cooling. The results were validated by experiments performed by Single Hot Thermocouple Technique and image analysis. A second mathematical model that calculates temperature history of slag during its cooling was coupled with the above model, to allow optimizing the slag/air ratio for both heat recovery and slag glass content.

Jan 1, 2015

By S Sokhanvaran

Electrodeposition of silicon from a cryolite based electrolyte at a relatively low temperature (1000°C) is a promising approach to generate high purity silicon. In order to obtain fundamental data pertaining to electrowinning of silicon from Cryolite?SiO2 melts, density and electrical conductivity measurements were made. A range of temperatures and SiO2 contents was studied for each property. It was found that while density has an inverse relationship with temperature, the dependence for electrical conductivity is direct. Increasing silica content up to the saturation limit (~ 5 wt%) increases the density whereas further increase in SiO2, lowers the melt density. On the other hand, the conductivity is lower for the melts with greater SiO2 content, at any temperature.

Jan 1, 2011

By W. L. Brown

"The Normetal mine is about 7 miles east of the Ontario-Quebec boundary, and 13 miles north of the town of Dupuy on the Canadian National railway. The mine workings are largely on lots 44 and 45 in the south half of range 10, Desmeloizes township.The surface outcrop is reported to have been discovered by a trapper previous to 1925, but the details are obscure. The property was originally owned by the Canadian Exploration Company of Amos, Quebec, and was later transferred to Abana Mines, Limited. The latter Company carried out underground work from two shafts down to the 550-foot level. The property was acquired by Normetal Mining Corporation in 1931 and was reopened in 1933, when development work was carried down to the 800-foot level. The mine was closed down in 1935 because metal prices did not justify production at that time. It was reopened early in 1937 and milling commenced in September of that year. To the end of 1945, a total of 1,497,- 169 tons of ore was milled from which was produced 184,533 tons of copper concentrates containing 84,738,368 lb. copper, 2,744,100 oz. silver, 26,230 oz. gold, and 153,524 tons of zinc concentrates containing 163,752,433 lb . zinc."

Jan 1, 1954

By Gyeonghye Moon, Inhyeok Choi, Jyothi Rajesh Kumar, Jin-Young Lee

"This paper deals with the recovery of the tungsten and vanadium from spent SCR catalyst leach liquors by different hydrometallurgical methods. The first part consists of pressure leaching of spent SCR catalyst using caustic soda followed by metal recovery by liquid-liquid extraction. In a leaching process, the following experimental parameters were tested and optimized: NaOH, particle size of feedstock, temperature, and solid to liquid ratio. The optimum condition for leaching of tungsten and vanadium was under the following conditions: NaOH 3 mol/L, temperature 250°C, particle size <300 µm, and solid to liquid ratio 0.4. From these optimum conditions in this experiment, the dissolution efficiency of vanadium and tungsten was 91.5and 87%, respectively. Liquid-liquid extraction following commercial extractants were tested: TBP, Cyanex 272, D2EHPA, Aliquat 336, Primeme JM-T, Alamine 308, Alamine 304-1, and methyl-tri-octyl-ammonium chloride. The conditions for both valuable metal recoveries were optimized.INTRODUCTIONSelective Catalytic Reduction (SCR) catalyst has become the most effective to reduce nitrogen oxide (NOx) emissions from stationary segments such as power plants and waste incinerations around the world due to the reinforcing regulatory trend and emerging environmental issues (Forzatti, 2001; Spivey, 2002; Li et al., 2011).Currently, the most widely used SCR catalyst is V2O5-WO3/TiO2 system due to its great catalytic properties (Li et al., 2011; Marshneva et al., 1995; Marbergeret al., 2015). In general, the composition of the SCR catalyst used in the stationary application is 0.5 to 1 wt% of V2O5and 7 to 10 wt% of WO3(Marberger et al., 2015; Chen &Yang, 1992, Vuurman et al., 1991; Alemany et al., 1991). Currently spent SCR catalysts are treated as waste and disposed of in landfills. This causes a lot of waste of secondary resources of vanadium and tungsten. In terms of industrial value of vanadium and tungsten (Gupta &Mukherjee, 1990; Moskalyk &Alfantazi, 2003) and reduction of pollutant emissions, it should not be disregarded for their recovery for their material recycling from spent SCR catalyst. However, investigations for recovery of metal values from spent SCR catalyst has been rarely carried out."

Jan 1, 2017

By R. M. BUCHANAN

The segment of Canadian industry based on smelting of alum in um and manufacture of consumer products is based entirely on imported alumina and bauxite. In the absence of Canadian bauxite deposits, consideration of anorthosite, a less desirable aluminous rock, is being undertaken as one alternative in maintaining assurance of supply. Anorthosites in Canada cover many thousands of square kilometres of the Precambrian Shield. Although compositions vary widely among Canadian anorthosites, many appear to exceed the specified minimum of 25% A I 20 3 in bodies containing more than the required JOO million tonnes. A lthough most Canadian anorthosites are of Precambrian age, one located in British Columbia has been identified as being Middle _Cretaceous.

Jan 1, 1984

By G. M. Furnival

A PROGRAMME of structure drilling was commenced in the Southern Alberta Plains in June, 1943, for the purpose of determining the geological structure of the underlying sediments. More than 270 holes have been drilled throughout an area of some 1,800 square miles or 1,000,000 acres (see Figure 1). The Southern Plains of Alberta are covered by a mantle of glacial drift,&apos; at places exceeding 200 feet in thickness. Only where this mantle has been dissected by deep drainage channels is bed-rock exposed to any great extent. Along such channels, surface geological mapping can be conducted to ad- vantage. Accordingly, geological mapping was commenced _in 1942 and continued each season to the present. To supplement this information, a survey of the water wells was carried on in conjunction with the mapping. However, to obtain more positive and evenly distributed structural control throughout the area as a whole and to define more adequately structural trends indicated by the preliminary mapping, it was necessary to resort to the use of drills to penetrate the glacial mantle. Various types of light drills are commonly used for this purpose and provide geological information in the form of drill cuttings, cores, drilling time rates, etc. Correlation of information is generally obtained through comparison of cored sections, drill cuttings, micro-fossils, and drilling time rates. However, in this case the holes were electrologged and correlations were made chiefly by comparison of such logs. The data so obtained is plotted and portrayed in the form of structure contour maps on recognizable stratigraphic horizons and in the form of isopach maps of the recognizable stratigraphic intervals penetrated in the holes. This method had not been widely used in Alberta previously and the technique employed was necessarily developed after the project began.

Jan 1, 1945

By S. Dominguez, E. Gebrehiwot, S. Richardson, S. Sandoval

Copper electrowinning/electrorefining (EW/ER) is powered by direct current (DC) rectifiers that typically generate 30,000 to 70,000 amps and a bus-bus voltage of 200 to 500 volts DC. Tankhouses are designed so that DC current flows through “cell lines” which contain individual EW/ER cells electrically connected in series. Electrolyte composed of copper sulfate and sulfuric acid in water forms the “liquid conductor” that connects the metallic conductors in this circuit. In this setting, stray current is a DC current that strays from and therefore bypasses the tankhouse circuit by finding a path to ground, often through the electrolyte in pipelines that feed into and discharge from the cells, or through dried electrolyte (i.e. sulfate), which is also electrically conductive. Tankhouse workers can be exposed to shock hazards if they become part of a stray current path to ground. This presentation details examples of stray current shock hazards in electrolytic tankhouses and provides voltage and amperage measurements associated with stray current in these examples. A review of critical safety controls in EW/ER tankhouses that will mitigate the risk of employee shock from stray current is also provided. INTRODUCTION Electrolytic tankhouses are designed to deliver relatively large amperages of DC current to a series of electrolytic cells in which copper is plated out of solution using the classic anode-cathode pair geometry within each cell. Electrolyte is the “liquid conductor” that transfers current in between the metallic conductors of the cell. The metallic conductors include inter-cell copper bus bars and the anodes and cathodes themselves. It is sometimes forgotten that electrolyte as a conductor is capable of delivering DC current outside the designed circuit of a tankhouse. Stray current is a DC current that strays from the tankhouse electrical circuit by finding a path to follow other than the designed path. Safety becomes a concern when there is a risk of an employee becoming part of an accidental stray current path, thereby suffering an electrical shock. In 2016, Freeport-McMoRan (FMI) suffered a fatality at one of its copper electrowinning tankhouses. The forensic analysis concluded that stray current from the tankhouse rectifier contributed to the fatality. An employee accidentally fell into contact with a metal flange at the end of an HDPE pipe that was collecting cell overflow electrolyte from the tankhouse. DC current passed through the employee to ground, creating a shock that was judged to contribute to his death. The situation was exasperated because the employee was unconscious, and therefore was exposed to the stray current for several minutes before being found. In addition, the employee’s clothing was saturated with liquid, and the employee was found kneeling in puddled liquid on the ground. FMI immediately began an investigation into the root cause of the stray current that was measured at the scene. Sufficient electrolyte had accumulated in the HDPE pipe such that a continuous path was formed between it and electrolyte that was continuously overflowing from energized electrowinning cells. The metal flange on the pipe was the metallic conductor that carried the current to the employee from the electrolyte inside the pipe. Current then flowed through the employee to ground. Because of this incident, FMI undertook an extensive review of the hazards of stray current in EW/ER. FMI’s tankhouse workforce received a Tankhouse Electrical Safety training course developed in- house to insure worker understanding of stray current hazards. Tankhouse design changes were implemented to better insulate workers from stray current. Personal protective equipment (PPE) standards were also reviewed and changes made.

Jan 1, 2019

By Marcio Luis S. Godoy

The Salobo Project will be the first Vale operation to use an HPGR mill to process copper-gold ore. The mine is located in Para state, southeast of the Amazon region in Brazil. The circuit was designed to treat 12 million metric tons per year of finely disseminated sulphide ore with high hardness. The comminution circuit comprises a gyratory primary crusher, secondary crushing utilizing two cone crushers, two 2 x 1.5 m HPGR operating in closed configuration with 6 mm screens, followed by two 26 x 40 ft ball mills. The concentration circuit consists of two rougher flotation stages using mechanical cells, regrinding with vertical mills, three cleaner stages with columns and one cleaner scavenger stage in mechanical cells. The concentrate is dewatered, filtered and transported by trucks and train to the port, to be exported. The circuit was designed on the basis of data obtained from a comprehensive laboratory and pilot plant campaign. The ore variability was assessed through simulation using data from a drilling core characterization program. The start-up of the industrial plant is planned for 2011. This paper describes the main aspects of circuit design, as well as information related to the beginning of the project construction.

May 1, 2010

By G. A. Pinsky, Pickard M. K

"IntroductionTWO METHODS of mucking have been used in sinking C shaft, the five-compartment production shaft of the Yellowknife property of Giant Yellowknife Gold Mines, Limited:(a) Band mucking during the original sinking in 1949 and 1950 (l); and(b) Mechanical mucking with the Cryderman shaft mucker during the recent deepening in 1954.This paper briefly describes the recent deepening and compares the performance figures of the two sinking operations.PlanningProduction planning in 1952 showed that it would be advisable to deepen C shaft in 1954 to provide for three new production levels and the installation of an underground crusher. To complete the required shaft work it would be necessary for a shaft crew to deepen the shaft about 500 feet, to partly excavate three level stations and a crusher station, and to cut a station for the loading pocket. Figure 1, a vertical section of the lower part of the shaft, shows the details of the deepening programme.During the planning period, Giant had a rather small supervisory staff and at the same time was experiencing a heavy labour turnover. As it was obvious that production would suffer if the sinking crew were recruited at the mine, it was decided that the merits of contracting-the shaft sinking to an independent contractor should be investigated."

Jan 1, 1955

By G. W. Sparkes

The use of CR-39 plastic polymer as a solid state nuclear track detector in the textural analysis of radioactive minerals in geological samples was first described by I.R Basham in 1981. CR-39 autoradiographs provide a detailed, high-resolution image of the in situ distribution of the radioactive minerals within geological samples on both the macroscopic and microscopic scales. This technique is an inexpensive and effective means of obtaining detailed textural information that provides insight into the style of mineralization, its relationship to primary and secondary structures in the host rock, and its association with particular geological features or mineral phases. Although this technique does not provide any information on the identity of the minerals responsible for the radioactivity, the resultant autoradiographs can be used to select regions for further detailed analysis such as petrography, microprobe analysis, or SEM imaging. This paper summarizes the procedure and outlines the appropriate time and materials required for both the exposure and etching of the CR-39 with respect to the intensity of the radioactivity emitted by the geological samples.

Jan 1, 2013

By C. R. Julian

THE large pyrites ore-bodies, the underground mining of which is to be described, are situated at Rio Tinto in the Province of Huelva in Southern Spain. The situation of the different ore-bodies with relation to one another is shown in Figure 1. It will be seen on the plan that the strike of the ore-bodies is approximately east and west. The geology of the district has been very fully described by Dr. D. Williams (1), so that for the purposes of this paper it will be sufficient to give briefly the salient features o each of the two larger ore-bodies which are being mined by underground methods at the present time. (a) San Dionisio.-This ore-body is the largest single deposit in Rio Tinto, having on its upper levels a length of 3,500 ft. On the upper levels the average width is approximately 200ft. but in places on the lower levels there is a width of 900ft. of un broken pyrites. Diamond-drill holes, without running out of ore, show the ore-body to persist to a depth of at least 1,600 ft. The ore-body in the upper part lies between slate and porphyry walls, but in depth is enclosed in porphyry walls. (b) South Lode.-Faulting is considered to be responsible for the break in the solid ore between South Lode and San Dionisio. On the upper levels, the South Lode ore-body has an unbroken length of 4,000 ft. The massive pyrites has a maximum width of 300ft. and an average of about 100 ft. Ore has been proved to a depth of 1,000 ft., at which depth the ore-body is much reduced both in length and breadth. This ore-body, to the depth at which it has been proved, lies entirely between slate and porphyry walls. The South Lode and the San Dionisio ore-bodies are mined both by open-cast and by underground methods. There is evidence that these mines have been exploited intermittently during the last 3,000 years; but, as is to be expected, no records are available of the tonnage mined prior to the time of purchase by the present company.

Jan 1, 1940

By R. H. McCorkell

Radon emanation rates. J. and compositions of materials from the Canadian Certified Reference Materials Project (CCRMP) indicate that the fraction of the Rn produced that escapes, E, is usually 1% to 8% and the 238U decay chain is nearly in secular equilibrium. For some Chinese ore standards, E values are higher than f or the CCRMP materials. Standard ore tailings have 2/oPb concentrations higher than expected from their 226Ra concentrations and Rn escape rates (12 - 34%) . Biological materials have E ˜100%, their ash E ˜0%. Pelletizing ore powders at 20 000 lb/in2 reduces J by only 20 - 40% but only 2% of Rn escapes from pressed Li2B4O7 pellets and 0.01 - 0.04% from fused Na2B4O7 or Li2B4O7 discs. Large, difficult-to-explain random variations in J are observed in some situations but several highly reproducible ways of measuring emanation rates have been found.

Jan 1, 1986

By Xiao min Zhou, Yan Xu, Hongzhen Liang, Xiaonan He

"With the increase of shaft excavation depth, the thickness of the shaft lining increases sharply. It is difficult to reduce thickness of lining effectively by improving high-strength concrete performance. The concept of the New Austrian Tunneling Method (NATM) is that surrounding rock plays a certain role in tunnel support. The solution should be to find the correct relationship between shaft lining thickness and rock strength, which is related with the interaction between the surrounding rock and concrete lining. The plane strain mechanics model is introduced to calculate lining thickness. Shaft lining design of Cixi Colliery in China is completed with the mechanics-based method proposed in this study. The lining design is verified through numerical simulation and field monitoring. The simulation results show that the maximum mises stress is located at the inner edge of the shaft lining. The increase of lining thickness cannot effectively reduce concrete grade. The monitoring results indicate that a lining design thickness of 900mm with C60 concrete, is safe and reliable in the shaft over 1000metres.This analytical design method can well be referenced in similar deep shaft projects.INTRODUCTION The New Austrian Tunneling Method (NATM), thought to have helped revolutionize the modern tunneling method, is the most extensive design philosophy and construction principle in today's tunnel engineering. It began to attract attention in the 1960s based on the work of Ladislaus von Rabcewicz, Leopold Müller, and Franz Pacher in Austria[1]. NATM was originally developed for tunneling in depth and in high situ-stress conditions in the Alps. The history of sequential excavation was reviewed, which highlights the progress of tunnel design and construction in Europe after NATM[2]. Structural conditions were introduced into the equilibrium of tunnels in NATM, and the additional force was estimated to stabilize the excavation of the tunnel[3].From the perspective of applied mechanics, there was no accuracy theory to explain the interaction between the tunnel structure and the surrounding ground. Numerical calculation is an effective means to study the basic mechanism of tunnel excavation[4].Based on two-dimensional modeling approaches in the past, such as NATM and other derivatives, a three-dimensional model was studied to"

Jan 1, 2019

By G. De Gregoriis, G. E. da Mota, H. P. Dias, J. E. M. Blasques

In recent years, like many other smelters around the world, Albras has been increasing line current. The necessary adjustments to the work practices and process variables need to be made on all potlines, which in this case means on 960 cells at the same time. It was a challenging task to adjust the process parameters to the new amperage. In July 2003 potlines 2, 3 and 4 were running at 1 73 kA and the goal at that time was to reach 180 kA. Preliminary trials with 180 kA were performed on a group of 10 boosted cells on potline 3 in order to investigate possible operational problems. It was decided to increase the amperage in three steps accompanied by continual evaluation of the state of the process. In July 2004 the target of 180 kA was achieved with good operational results. This paper presents the overall results, the parameter adjustments made during the amperage increase in the booster group and how the increase was implemented on the other potlines.

Jan 1, 2006

By A. Anderko, R. D. Springer, R. D. Young

A thermodynamic model has been developed for calculating phase equilibria and other properties of multicomponent electrolyte systems. The model has been designed to reproduce the properties of both aqueous and mixed-solvent electrolyte systems ranging from infinite dilution to solid saturation or pure solute limit. The model incorporates formulations for the excess Gibbs energy and standard-state properties coupled with an algorithm for detailed speciation calculations. The excess Gibbs energy model consists of a long-range interaction contribution represented by the Pitzer-Debye-Hiickel expression, a second virial coefficient-type term for specific ionic interactions and a short-range interaction term expressed by the UNIQUAC equation. The accuracy of the model has been demonstrated for common acids and bases and for multicomponent systems containing aluminum species in various environments.

Jan 1, 2005

"The QEMSCAN system is the third generation of automated mineral analysis systems that began with the QEM*SEM at CSIRO 30 years ago (Butcher et al. 2000). It is now a successful commercial instrument with 39 instruments in operation around the world. Back Scattered Electrons (BSE) and Energy Dispersive (EDS) X-Ray spectra are used to create digital mineral images with mineral identification occurring online. Low-count EDS spectra are used preferentially to BSE brightness, allowing minerals to be accurately identified by chemical composition. Individual minerals or groups of similar compositions are identified by comparison to a comprehensive mineral database incorporated into the QEMSCAN software. Optical mineralogy and Scanning Electron Microscopy is a metallurgists’ tool for determining the ore process mineralogy and delivering a better flowsheet. These techniques have limitations, provide limited information and sometimes fail to provide representative information. In contrast, QEMSCAN provides information on the nature and occurrence of all mineral species present plus the liberation characteristics, looking at thousands of particles in the sample presented. Some of the data presented includes:• Particle and grain sizes• Dominant mineral species• Particle shape• Calculated metal content• Density• Deportment of elements of interest between the mineral phases• Quantitative mineralogy• Mineral associations, locking and liberation• Textural relationships (particle images)It can also be used on concentrates, polished sections or drill core. This is a significant improvement in ore characterisation providing lithology, mineralogy, liberation, ore grade and porosity from a sample. Theoretical grade-recovery curves can be created to be mineralogically limited from QEMSCAN analysis which, when compared with metallurgical results, are valuable in evaluating whether liberation or chemical selectivity is driving flotation performance. A number of case study examples are given where the QEMSCAN had a significant bearing on future project development at an early stage of exploration and mine development."

Jan 1, 2012

By W. Hawker, A. M. Ivana

"Pressure oxidation is used to liberate gold from refractory sulphide ore and concentrates with over fifteen autoclaves in operation. Despite the importance of pressure oxidation, the autoclave chemistry and chemical thermodynamics are not well established. For example, there is no consensus on aqueous iron speciation or stability of jarosite phases. Additionally, there remains questions about basic ferric sulphate formation and stability. In addition to a review of the current state of knowledge, a methodology to study the ferric precipitation reaction and relate the results to chemical thermodynamic predictions is presented which will be used to accurately define the phase boundaries of the iron precipitates in the future (hematite, jarosite and basic ferric sulphate).INTRODUCTION With declining availability of orebodies that respond to simple leaching conditions, pressure oxidation has become a prevalent technology to liberate gold locked in sulphide mineral matrices. Gold pressure oxidation was established 32 years ago, with McLaughlin being the first facility in 1985 (Thomas & Pearson, 2016). Pressure oxidation is carried out at elevated temperatures ranging from 180 to 240°C as shown in the summary of operations in Table 1 (Ruonala et al., 2016; Fleming, 2010).A considerable amount of research has been done to study iron solubility and precipitation under autoclave conditions (Tozawa & Sasaki, 1986; Umetsu et al., 1977; Sasaki et al., 1993; Fleuriault, 2016; Cheng & Demopoulos, 2004; Papangelakis et al., 1994; Yue et al., 2003). These reports provide a description of the process chemistry and iron behaviour in the autoclave. However, there remain questions about the type and stability of aqueous species and solid phases. This detailed information is required to build a robust chemical thermodynamic model of the system, allowing for equilibrium and kinetic reaction limitations to be discerned."

Jan 1, 2017

By A. G. Scobie

THE research laboratory of this Company was recently faced with the problem of determining trace amounts of tungsten in a series of classifier sands. A spectrographie survey revealed the feasibility of using this instrument in the final evaluation, but a check of the common methods in use for the isolation of tungsten (3, 4) showed these methods to give incomplete separation for trace amounts. An investigation into the possibility of modifying these procedures, or developing others, was thus indicated. ASSAY PROCEDURE Weigh 10 grams of 200-mesh ore or concentrate into a 400-ml. beaker, wet the sample well with about 20 ml. of water, and add 100 ml. of hydrochloric acid. Cover, digest at 60° to 70° C. for about 1 hour, and then boil down to approximately 25 ml. Cool, add 25 ml. of hydrochloric acid and 10 ml. of nitric acid, and again boil to former volume. Add 20-ml. portions of nitric acid with successive boiling clown until chemical action is complete. Then add 20-ml. portions of hydrochloric acid until all nitric acid is removed. Take nearly to dryness on a law-temperature hot plate, but do not bake. Take up in 10 ml. of hydrochloric acid and 20 ml. of water and heat on a law-temperature hot plate until all iron goes into solution. Dilute to 200 ml. and heat to just below boiling. Stir in pulp of about half of a No. 41 Whatman filter paper (12.5-cm.) and continue digestion on plate with occasional stirring for 15 to 20 minutes.

Jan 1, 1943