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By S. B. Lement

THE nature of the carbides that form during the tempering of martensite is a subject of continuing controversy. The only direct methods of identification available are X-ray and electron diffraction. These methods are subject to several difficulties. Only a relatively few diffraction lines of appreciable intensity emanate from carbide phases that are formed at low tempering temperatures. Furthermore, some overlapping of carbide and matrix lines occurs. There is also the problem that numerous lines in the patterns of possible carbide phases that may be present have about the same d-spacings. Increasing the number of carbide lines and eliminating the matrix lines can be accomplished by extraction techniques. However, there is always the possibility that a change in carbide structure will occur as a result of removal from the parent matrix. Therefore, such techniques as electrolytic extraction and making extraction replicas should be checked by other methods. For identifying small amounts of carbide in a tempered martensitic matrix, electron diffraction carried out in reflection is more advantageous than X-ray diffraction. To properly prepare a specimen for reflection electron diffraction, an etchant that will selectively attack the matrix and thereby cause the carbide particles to stand in relief should be used. With an electron beam directed at a grazing angle to the specimen surface, the major contribution

Jan 1, 1960

By H. O. Hofman

Discussion of the paper of H. O. HOFMAN and JOHN BLATCHFORD, presented at the New York meeting, February, 1916, and printed in Bulletin No. 109, January, 1915, pp. 91 to 97. ROBERT H. RICHARDS, Boston, Mass.-I should like to ask Professor Hofman whether he is able to roast his stibnite without any comparatively large amount of loss of antimony? H. O. HOFMAN, Boston, Mass.-Yes. The last statement I made was that the loss of antimony, during those tests, increased with the temperature, and that up to 372° C. there was no loss whatever in antimony, also that it increased to 4:2I per cent. with 545° C., the highest temperature that we obtained in our small furnace. ROBERT H. RICHARDS.-I should like to ask a second question, and that is, is it not true that stibnite can be roasted more completely than any other sulphide?

Jan 5, 1916

John M. Cairns, in an interesting letter dated June. 19, 1918, tells us of his experiences in Italy. He says, "It may interest you to know I came out to Italy after being on the Afghan frontier of Indian Baluchistan, in August last year, and for some time was posted at Turin as Railway Transport officer. At that time Turin was in the toils of the riots which were the forerunners and preliminaries which led up to the great Italian retreat (Capretto). Since then I have been all over Italy from (deleted by the censor) in Transportation intelligence, and now have just been transferred to the Directorate of Requisitions and Hirings, which now permits great opportunities of going nearly all over Italy (deleted by the censor). My address is L. of C. Branch, D. R. & H., A. P. 0. L/1, I. E. F.

Jan 9, 1918

MISSOURI SCHOOL OF MINES The Missouri Mining Association has enjoyed a very good year. Last October the society was reorganized and the following officers elected for the year: E. Ross HOUSHOLDER, President, ORE N. MANESS, Vice-president, WILLIAM REBER. Secretary, RUAL CHAVEZ, Treasurer. The head of our mining department, Prof. C. E. Forbes, is now serving as a Major in the United States. Army. We were fortunate in having. Prof. Chas. E. Locke, of Boston, with us for part of the winter to take charge of the senior mining work. During the autumn and winter months we had a number of informal smoker lectures in Norwood Hall. Among the speakers at these meetings were: H. A. Buehler, Missouri State Geologist; Chas. E. Locke, Boston, Mass.; V. H. Hughes, Tulsa, Okla.; Dorsey Lyon, Washington; D. C.; Prof. G. H. Cox, Professor of Geology, Rolla, Mo.; together with a number of returned alumni.

Jan 8, 1918

PICK AND SHOVEL CLUB, CASE SCHOOL OF APPLIED SCIENCE The last meeting of the year of the Pick and Shovel Club of Case School of Applied Science was held on May 20, 1919. The speaker, Dr. Zay Jeffries, gave a very instructive and interesting talk on the Metallography of Non-ferrous Metals. The club has had a very successful year in spite of the loss of a few months time through the S. A. T. C. Among the speakers for the year were Dr. F. R. Van Horn, Dr. C. H. Fulton, and Dr. W. R. Veazey of our school; Dr. E. S. Moore of Penn. State College; Dr. Ansel St. John, of the National Carbon Co.; and Mr. V. S. Bidle, of the W. S. Bidle Co. The graduating members wish the club the best of success for the coming year. BERTRAND R. WARMELING, Secretary.

Jan 7, 1919

The income of the Institute is derived from dues, subscriptions to MINING AND METALLURGY and sale of publications. These sources are fortunately supplemented by the interest from invested funds now amounting to over $500,000, a considerable portion constituting endowments for especial purposes. Aside from the medal funds the principal endowments are the James Douglas Fund for support of the Library, the Rocky Mountain Fund and the Seeley W. Mudd Memorial Fund. The income from the two last named is available for the support of research and a variety of other purposes. It is allocated by the Board of Directors upon recommendation of standing committees in each case. An active effort is being made to increase the endowments of the Institute, it being felt that unusual opportunities exist for research and public and professional service through the organization and at a minimum of expense.

Jan 1, 1932

By C. H. Mathewson

BeRyllium, magnesium, zinc and cadmium, together with mercury, constitute a coherent sub-group of the periodic system and these metals, excepting mercury, have been studied in sufficient detail by the new X-ray diffraction methods to prove their common adherence to the hexagonal close-packed type of crystal structure with a progressive increase in axial ratio as we pass through the group from beryllium to cadmium. The first four columns of Table 1 summarize the data on crystal structure of these metals reported in the International Critical Tables.' The last two columns are based on results obtained in the present investigation. Twinning has often been observed in zinc and cadmium. The general aspects of this twinning are abundantly illustrated by photomicrographs, diagrams, etc., in the papers by Romig, and Mathewson and Phillips reported to this Institute in 1927.2 A determination of the composition

By Ralph M. Barnett, Albert K. Smith

During the last few years, a great deal of interest has been aroused in the use of more refined blasting techniques. It has been the effort of many mining companies to reduce powder cost, obtain better rock breakage, reduce drilling costs and provide safer working places. With the advent of new types of powder and such techniques as cushion blasting, line blasting, smoothwall or soundwall blasting, and presplitting or preshearing, these goals are approaching reality. Smoothwall blasting and presplitting have re- ceived much attention at the Climax Molybdenum Co., Climax, Colo., mine because of the large cost factor involved. An experimental program was begun in 1961, and during 1964 to the present has been used in many working areas. Some spectacular results have been achieved by the operating personnel in hard ground, but the most beneficial results have been in areas where the ground has been soft and highly fractured.

Jan 7, 1965

By A. A. Dor

Of the numerous methods that have been tested or considered for the beneficiation of low-grade iron ores, this article deals only with proven flowsheets that are adopted in plants in operation or which have been reliably pilot-plant tested. Several recommended layouts are described and discussed. They illustrate recent trends and embody improvements and new features that have resulted from the experience acquired in the operation of the plants already in service. They have been developed, in the last few years, in the course of designing several iron ore beneficiation plants of various types and sizes. Some of the design features in the layouts which are submitted represent, in some respects, personal views and may not meet the full approval of others in this field. It is hoped that this presentation will provide an opportunity for constructive discussion of the problems involved and of suitable solutions.

Jan 6, 1962

By F. Brons, V. E. Marting

In the past, other authors.1, 2 have studied the influence of a skin effect on the productivity of a well. This skin effect, expressed by the skin factor S, is considered to be caused by a thin layer of impaired permeability immediately around the wellbore and extending vertically over the whole productive interval penetrated by the well. The skin factor S is defined as follows. Based on this, the impairment in productivity caused by a skin can be expressed by the fractional loss in productivity I, which is the loss in productivity divided by the total unimpaired productivity. For compressible flow in a stabilized well which drains a circular area of radius re, 1 is given by The present paper deals with a different kind of productivity impairment. Consider a well in which part of the productive formation is blocked off completely, either by incomplete penetration or by exclusion of parts of the productive zone by blank casing. In Fig. 1 (A, B and C), three examples are shown. Fig. 1(A) shows the situation where a well only partially penetrates the formation. This often is done to combat the actual or imagined danger of bottom-water coning. Fig. 1(B) shows a well producing from only the central portion of a productive interval. This type of completion is sometimes used where both water and gas coning are a problem. Although the case of a well producing through perforated casing cannot be treated in a manner similar to the previous two cases (where radial flow in the horizontal plane is assumed), Fig. 1(C) shows several intervals open to production and qualitatively describes this case (as will be discussed later). To study the loss in productivity in all these cases, two parameters are introduced which fully determine the impairment. The first is the penetration ratio "b," i.e., the total interval open to fluid entry divided by the total thickness of the productive zone. The second is the ratio hlrw. In this ratio, rw is the wellbore radius. The definition of h is more cumbersome. In Fig. 1(A), h is the thickness of the total productive interval. The streamline configuration for this case of partial penetration is basic to the other two cases considered (Views B and C of Fig. 1). It will be obvious from Fig. i (A) that the flow lines in the uppermost portion of the formation will be essentially horizontal, while those in the lower portion will curve upward toward the well. In Fig. 1(B), with only the middle portion of the zone open to production, the streamline configuration. of the upper half will be an exact mirror image of that in the lower half of the zone. Hence, for the case illustrated in Fig. 1(B), h is defined as one-half the total sand thickness. It follows, then, that in Fig. 1(C) h is one-half the distance between corresponding points in adjacent intervals. (In gun-perforated casing, h would be one-half the distance between perforations.) In a paper by Nisle4 and a paper given by the present authors5, the mathematical theory was developed for the cases under consideration. In the present publication, the emphasis is put on the results of these studies; consequently, the equations derived in Refs. 4 and 5 will be omitted, for the most part. The pressure drop p in a well producing from only a portion of the total formation thickness can, in analogy with Eq. 1, be expressed by Numerical solution of Eq. 5 by use of the IBM 650 leads to the following important conclusions. First, during a short period after starting production (usually on the order of a few minutes), the function p(b) is given by

By P. M. Aziz, I. Markson, C. S. Barrett

The abnormal after-effect in twisted wires that occurs when untwisting is interrupted by etching con be brought under control and used to study the mechanical properties of thin surface films and how they are effected by reagents and heat treatment. Results are given of studies of oxide films on high purity aluminum. IF a wire is subjected to plastic deformation by torsion and then released, it untwists in the normal after-effect, but under certain circumstances the untwisting is abruptly lessened or reversed by the application of an etchant to the wire.1,2 This abnormal after-effect may occur, for example, if there is a coherent oxide film on the surface of the wire which is removed by the etchant. Following a suggestion of A. H. Cottrell that predicted this effect, it is attributed to dislocations that had piled up beneath the oxide layer and represents the rapid release of residual stresses caused by these dislocations. When the layer is removed, the stress relief may be by escape of piled-up dislocations from the metal, or by an activation of latent sources of dislocations located at the surface, together with rebalancing of elastic stresses to compensate for the loss of stressed material, as in a residual stress analysis determination, these mechanisms acting singly or in combination.' The slower the attack of the reagent, the more gradual is the stress relief and the smaller the change in strain rate when the reagent is applied. A study has been made of the factors that influence the magnitude of the normal and abnormal after-effects with the object of developing techniques suitable for a quantitative investigation of the influence of various surface films on dislocations in wires, and of the rate and extent of the attack on the films by different reagents. It was found that reasonable sensitivity and reproducibility could be achieved if a suitable choice of variables was made and if these variables were held constant through a series of experiments. The method was then applied to a study of oxide films produced and treated in different ways on the surface of high purity aluminum wires, and to a study of the damage to these films caused by various reagents. Experimental Procedure The material used throughout this work was prepared from 99.9968 pct Al. This high purity aluminum was melted, cast into 1/2 in. diameter ingots, and then swaged and drawn without intermediate annealing to 0.040 in. diameter wire. A sketch of the apparatus employed for twisting is shown in Fig. 1. The test wires were mounted into the apparatus by cementing one end of the wire to the beaker and the other to the tube with laboratory wax of high melting point. The length of the wire between the waxed joints was 4.2 & 0.2 cm. Extreme care was taken during mounting to avoid cold-working the wire. The wire was twisted through 335" in 2 to 4 sec by rotating the pinion on the gear box until the vertical post on the rotating table, which was initially touching the horizontal stop, was arrested by the stop. All the tests were conducted with apparatus and reagents at the same temperature (about 25°C). In all tests, except those where the duration of the initial torque was investigated, the torque was applied for a period of 2 min. At the end of this time the table was rotated back a few degrees away from contact with the stop and the wire allowed to untwist. The after-effects were measured by reflecting a beam of light from the mirror shown on the apparatus. After the wire had untwisted for 6 min, a reagent was carefully poured into the beaker and thereby applied to the surface of the wire.. In some tests the liquid in the beaker was removed after a few minutes and replaced by an-

Jan 1, 1954

By Kenneth Seaver

(San Francisco Meeting, September, 1915) INTRODUCTION IT is rather gratifying that in the field of the manufacture 'of refractories, in which, as a whole, foreign practice has surpassed us, the United States stands pre-eminent in the making of silica brick. In some instances European manufacturers have refused point-blank to credit the possibility of making to such specifications as are common with us, until the actual 'completed shapes were shipped for inspection. But both the manufacturer and consumer in foreign lands are now frankly learning from us, and benefiting by our advanced practice in this field, as is evidenced by the orders placed here and the efforts put forth abroad to come up to the standard of American-made material. In no metallurgical operation has the employment of silica brick spread with. such leaps and bounds as in the building of plants for the carbonization of coal, particularly in the byproduct coke oven. Today, in practically all types of oven, the structure above the floor level (except the facings) is of silica, while in the recuperative and in some regenerative types, its use is extended to that portion of the oven below the floor as well. By reason of the fact that there are a number of classes of refractories of higher silica content than the usual so-called fire-clay brick, there is sometimes a misunderstanding as to the class of material referred to as "silica" brick. We here refer only to a brick having a silica content of 94 per cent. or more and made usually from quartzite rock with a small percentage of lime as a binder. The term "silica" brick is sometimes rather loosely applied to brick front highly siliceous clays, or to a quartzite refractory of mingled fire-clay and quartz rock; but such products are not considered in this discussion.

Jan 9, 1915

By W. B. Finkeldey, C. H. Mathewson, C. S. Trewin

This paper was prepared upon request as a contribution to a symposium covering the manufacture, properties, and uses of the important non-ferraus metals. In approaching a subject as broad as this, there is a natural desire to build up a comprehensive and finished production which shall constitute a dependable source of information on all questions properly belonging to this branch of metal technology. There are, however, a number of circumstances, apart from the mere routine of labor and thought involved, which operate rather effectively against the possibility of completing such .an ambitious program at the present time. First of all, as far as any public record of results is concerned, the commercial rolling, drawing, and forming of zinc with relation to changes of structure and properties—and this we consider to constitute the clement~ of metal technology—might as well be an unpractised art. We have never seen a published photomicrograph showing the structural characteristics of either hard or soft sheet or strip, although the structure of castings has been frequently described, and other coarse-grained structures resulting from hard-hammering and annealing have been reproduced. Thus, an author in this field must proceed to his task without much assistance from the literature, and the outcome can represent only a personal estimate of principles, facts, or findings, and not a summary or survey of progress in the entire field as determined by varied experience, practice, and settled opinion.

Jan 1, 1921

By F. F. McINTOSH

STEEL is a general name applied to the alloys of iron and carbon. These alloys always contain , other elements such as manganese, silicon, sulfur, and phosphorus. Manganese and silicon are usually considered to be alloying elements. Sulfur and phosphorus are regarded as impurities. Tradition has damned them both and, in addition to classifying them as impurities, has established the general impression that many of the ills of steels are the result of the presence of one or both of these elements. Metallurgists are inclined to question the soundness of this tradition. The fact that one blast-furnace plant is devoted entirely to the production of ferro-phosphorus which is used to rephosphorize basic open-hearth steel, and that sulfur is added to many heats of steel, indicates that these so- called impurities might also be classed as alloying elements, and that the tradition which damns them may not be altogether fair and well founded. A critical search through the technical literature on the effect of phosphorus on steel will disclose many references to its harmful effect. Most of these are general in character, but there has been a strong tendency to accept this traditional belief in the harmful effect of the element.

Jan 1, 1926

By W. J. Reagan

Mr. Caine, members and friends of the AIME Electric Furnace Conference, as Chairman of the Executive Committee it is my pleasure to welcome you to this our fifth annual conference. I can assure you that the conference chairman and his committee have prepared a program of unusual and timely interest. Mr. Caine has spoken of the educational session. This part of our program was of unusual interest last year and I am sure that the subject of this year's discussion will prove to be just as interesting. The wide variety of subjects cover both the basic and the acid electric furnace and are in keeping with the usual high quality maintained on our programs in past years. As the papers and discussions will be published in the PROCEEDINS, you will in a short time be able to add another volume to the present series.

Jan 1, 1947

One of our members, in Colombia, has written the following interesting account of his experience in trying to remit his dues to the Institute. "Last year I was away at the end of the year and on my return I was unable to obtain a draft in Honda until April, I believe. To avoid delay this year I remitted cash, early in January, to a friend in Bogota who I imagined could sell or procure for me various small drafts to cover my annual subscriptions. After many weeks' delay, I was informed that he could not get them for me and was remitting the cash to Honda where they were obtainable. After another long delay, I was informed that no one in Honda would sell drafts or checks for small amounts. Eventually I found a friend who was willing to oblige me in the matter and at once forwarded the amount."

Jan 8, 1919

The income of the Institute is derived from dues, subscriptions to MINING AND METALLURGY and sale of publications. These sources are fortunately supplemented by the interest from invested funds now amounting to over $500,000, a considerable portion constituting endowments for especial purposes. Aside from the medal funds the principal endowments are the James Douglas Fund for support of the Library, the Rocky Mountain Fund and the Seeley W. Mudd M.emoria1 Fund. The income from the two last named is available for the support of research and a variety of other purposes. It is allocated by the Board of Directors upon recommendation of standing committees in each case. An active effort is being made to increase the endowments of the Institute, it being felt that unusual opportunities exist for research and public and professional service through the organization and at a minimum of expense.

Jan 1, 1932

By Mason J. Christner

Geology has become increasingly quantitative in the last 20 years. This trend has been accelerated by computer capability in the manipulation of data. The mining industry has been relatively slow to harness computer power, but the larger companies have moved in this direction in the past few years. Among the leaders in this progression is the White Pine Copper Co., and the following is a brief description of their computer system for processing, managing, and utilizing geologic data. Geology The White Pine mine is in the Upper Peninsula of Michigan, 6 miles south of Lake Superior and 80 miles west of the Houghton-Hancock area, center of the famous Copper country. The ore body of chalcocite, native copper, and minor native silver, is a tabular body in the basal 25 ft of the flat lying Nonsuch Shale and the top part of the underlying Copper Harbor Conglomerate. Twelve or more

Jan 1, 1972

By Ernest P. Hall

At the SME Fall Meeting held in Phoenix, Ariz. last October, Ernest P. Hall, addressing an Air and Water Pollution session, noted that water pollution caused by acid drainage from bituminous coal measures had begun long before recorded history. "Until recently," he said, "man did not begin to understand the physical phenomena which took place to cause [it] and even today he does not know what can be done to prevent it." CAUSES "It is known from the reports of early explorers that drainage from bituminous coal measures was causing water pollution before coal mines were opened on this continent. They noted the nature of the polluted water in the runs and creeks and predicted the presence of substantial deposits of coal based on the appearance and character of the water. Even today, polluted water drains from virgin coal areas which have not been touched by mining machines," Mr. Hall said.

Jan 1, 1966

By D. E. Pickett, E. G. Joe

In accordance with good industrial practice, Canadian metallic-ore concentration plants have always recycled a high proportion of process water to save reagents, save power, conserve water resources, and to protect the community water supplies, to give only a few reasons. In the last few years there has been awakened public concern for the environment and, consequently, government regulations have been added as additional reasons. Present recycling practices are summarized as a basis for improved plant design and operating procedures and for further research. In addition, an attempt is made to determine why plants do not recycle water in certain situations. Although not all Canadian mills are covered, the many examples given indicate the problems and the effort being made to solve them. Wherever available, the chemical quality of the water and the process requirements are indicated as well as the other parameters affecting water recycling at each operation.

Jan 1, 1975