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By W. N. Marchant

The Bureau of Mines improved removal of selenium from zinc smelter acidic gas scrubber effluent by using zinc dust to precipitate soluble selenium prior to lime neutralization. Lime neutralization alone decreased selenium in the waste water from, typically, 6 parts per million to 2 parts per million, whereas the use of zinc dust precipitant gave an effluent containing less than 0.1 part per million of selenium. The waste treatment operation first was developed on a laboratory scale and later was successfully tested at a smelter site on a 1-gallon-per-minute basis. During the research a simple and rapid means was developed for determining selenium in waste water; the technique enabled visual semiquantitative selenium determinations that later were confirmed quantitatively by X-ray fluorescence.

Jan 1, 1978

By G. R. Hopkins

[Apparent progress in economy at petroleum refineries, as measured by the average amount of hest units required to refine a barrel or crude oil, received a set-back in 1938, when the average rose to 567,000 B. t. u., compared with 562,000 B. t. u. in 1937 (see fig. 1). The primary factor in the rise in average heat requirement's per barrel of crude oil refined in 1938 was the decline in total runs to Invariably the average requirement increases when crude inn to stills decline, and vice versa. In other words, annual gains in fuel efficiency at refineries are masked by the degree to which the capacity is utilized. Additional crude runs give lower average heat requirements in two grays first, because they are mane with the expenditure of cc-comparatively small amounts s of auxiliary heat, and, second, because additional runs generally represent simple topping operations. In 1938 crude runs to stills declined 1.6 percent (from 1,183,440,000 barrels in 1937 to 1,165,015,000 barrels in 1938), but the total heat consumption declined only 0.4 percent, or from. 663,866 billion B. t. u. in 1777 to 660, 56 billion in 1938.]

Jan 1, 1939

By E. L. Garton

The United Status Bureau of Mines has recently collected samples of crude petroleum from well] in the newly developed Joiner, Kilgore, and Longview fields of Rusk and Gregg Counties in the East Texas district, and from the Van field of the East Central district of Texas. East Texas Cruder The four samples of crude oil from the East Texas fields are all typical "intermediate base" crudes according to the classification given by Smith and Lane. 3 Sample 31,063 is from the discovery well in the Joiner field. This well came in on October 3, 1930, with an initial production of 400 barrels per day. Sample 31,062 was obtained from a well that was completed on February 1, 1931, with an initial production of 3,500 barrels per day. The 32 East Texas crudes are produced at an average depth of approximately 3,600 feet. which is the deepest Woodgine-sand production so far encountered in any of the Texas or Louisiana fields.

Jan 1, 1931

By Paul W. Jeran

Subsidence over a series of longwall panels undermining sloping terrain in southwestern Pennsylvania was monitored to verify the Bureau of Mines subsidence prediction model for the northern Appalachian coal region. Comparison of the field data to model output shows close agreement. Vertical movements over each panel ceased with the mining of the adjacent panel. Horizontal movements were significantly affected by topographic slope. The distribution of horizontal strains over each panel were similar, with a zone of compression occurring over the center of each panel. The zones of compression were flanked by zones of tension toward the rib. The magnitude of the tensions were affected by the slope. The strains developed at the completion of each panel were not significantly altered by the mining of subsequent panels.

Jan 1, 1988

By R. V. Ramani, A. S. C. Owili-eger

A mass balance equation can be written for the unit block of Figure 7 for changes within the volume during time At as: [ ] where x and y are the coordinates; q is the flow across any surface; p is the density of the fluid flowing through the medium; qvol is the volumetric flowrate; @ is the medium porosity; and Ax and Ay are the dimensions of the block. The subscripts t and (t+At) denote time levels and At is the change in time. Writing this equation in nota- tional form and on rearranging, the following expression is obtained:

Jan 1, 1974

By G. R. Hopkins

[Apparent progress in fuel economy at petroleum refineries, as measured by the average amount of .seat units required to refine a barrel of crude oil, received a set-back in 1935, when the average rose to 562,00 B. t. u., compared with 562,000 B.t.u. in 1937 (see fig. l). The primary factor in the rise in average heat requirement's per barrel of crude oil refined in 1938 wan the decline in total runs to Invariably the average requirement increases when crude ins to stills decline, and vice versa. In other words, annual gains in fuel efficiency at refineries arc masked by the degree to which the capacity is utilized. Additional crude runs give lower average e heat requirements in two ways - first, because they are mane with the c expenditure of comparatively small amounts of auxiliary heat, and, second, because the additional runs generally represent simple topping operations. In 1938 crude runs, to stills declined 1.6 percent (from 1,183,440,000 barrels in 1937 to 1,165,015,000 barrels in 1938), but the total heat consumption declined only 0.4 percent, or from 663,866 billion B. t. u. in 1777 to 660, 56 billion in 1938 .]

Jan 1, 1939

By C. J. Chindgren

Two air classification systems were built and tested as separatory devices for recovering the nonferrous metal values from shredded automotive nonmagnetic reject scrap. A horizontal air system with a capacity up to 16 tons per hour was used to obtain preliminary separations, and a smaller capacity vertical system was used as a cleaning device. Shredded automobile reject material containing aluminum, copper, and zinc values of about $55 per ton were air-classified in the horizontal elutriator. Ninety-six percent of the metal was recovered in a 74-percent metal concentrate. Tandem operation of both classifiers recovered 92 percent of the metal in an 80-percent concentrate while rejecting 87 percent of the nonmetallics. Heavy media separation of the air-classified concentrate produced an overall recovery of 91 percent of the metal in the form of a 99-percent metal concentrate.

Jan 1, 1971

By Th. G. Sahama

This paper contains some new heat-of-solution measurements of geikielite (MgTiO3), limonite (FeTiO3), fayalite (Fe2SiO4), and a natural forsterite in mixed acid (HF +HCl) and gives the results of a thermodynamic attack on the problem of stability of geikielite in rocks.

Jan 1, 1949

By R. C. Buehl

An experimental iron blast furnace of 3-foot-diameter hearth, producing about 12 tons of metal per day, was operated for 2 weeks with various proportions of anthracite replacing a corresponding amount of coke. The furnace operated well with anthracite in amounts up to 40 percent of the total fuel and produced metal of uniformly low sulfur and normal silicon contents. An increase to 50 percent anthracite during two attempts resulted in poor operation and the charge hung in the s haft of the furnace. INTRODUCTION Anthracite production in Pennsylvania decreased from 84,400,000 net tons in 1926 to 40,600,000 net tons in 1952, and there was a further decline in 1953 to 30,900,000 net tons. Employment in the anthracite industry dropped from 165,000 men working an average of 244 days per year in 1926 to 57,900 working an average of 163 days per year in 1953,3/ which has naturally resulted in considerable unemployment in the region. The industry is actively engaged in promoting new uses for anthracite to increase the demand and thus improve economic conditions in the region. One possibility is the use of anthracite to replace part of the coke for smelting iron ore in blast furnaces. The tests in this report were made to determine whether this use of anthracite would be feasible.

Jan 1, 1955

By W. A. Dunkley

During the past year and a half the Western United Corporation of Aurora , Illinois , has been distributing carburetted water ges from its Lockport , Ill . , plant , to an extensive territory , under an initial pressure ranging up to 90 lb.. per sq. in . The most distant distributing point on the system is at Harvard , Ill . , about 35 miles from the plant.. The territory supplied is approximately 85 miles long and 35 miles wide , the total mileage of rains being 1223 , or approximately 24 per cent of all the gas trains in Illinois outside the city of Chicago .

Feb 1, 1923

By J. R. White, S. W. Lambert, C. M. McCulloch

Examination of several coalbeds in Walker County, Ala., Cambria, Greene, and Fayette Counties, Pa., and Raleigh and Wyoming Counties, W. Va., indicates that cleat orientations are similar throughout a vertical sequence of strata. Studies of cleat orientation were carried out in underground mines that are operating in separate coalbeds vertically above one another. The data show that over a vertical separation of 100 to 400 feet, the average difference in coal cleat orientation between mines is 04° for the face and 08" for the butt cleat. Variations of coal cleat direction between coalbeds examined in strip-mined areas show similar values. Cleat orientations measured at outcrops agree well with the directions measured underground, suggesting that the amount of vertical separation between coalbeds has little effect on the resulting differences in cleat directions. The largest variation of cleat directions between adjacent coalbeds occurs where a large horizontal distance separates two sample locations. Cleat orientations for deeper coalbeds are most reliable where the data are taken from directly above.

Jan 1, 1976

By J. O. Lewis

"The significant facts in the problem of the relation between the production of crude petroleum, and the ever-increasing demand for petroleum products are that in spite of continually increasing production, improvements in methods of refining and utilization, and heavy increases in imports, demands grow still more rapidly and we seem always faced with a shortage at hand or lust ahead. On the other hand, our foremost authorities warn um of entirely inadequate domestic reserves. Looking abroad we find some large fields and many of speculative promise, 'tut the situation is complicated by international relations and demands by other countries which promise to be even more insistent than oars. This is the situation, then. We can not rely upon our own Crude Petroleum to meet the Ever Increasing Demand for Petroleum Products.I wish to follow this somewhat alarming statement by saying at once that the Bureau of Mines is not pessimistic in facing this situation. To my mind those who discuss the oil situation may be placed in three categories; the pessimists, the optimists, and the super-optimists. The pessimists I call those who see darkly and will concede no possibility of solution. According to them a few years will see the automobiles piled in windrows of 'dilapidated junk, I have no sympathy with this point of view and deem it vicious and entirely unwarranted.The optimists I term those who believe that there is a solution and that we shall be able to meet all of our reasonable requirements for as far into the future as can be foreseen, yet who recognizes that this desired end can not be attained without prevision and energetic effort.The super-optimists are those who will say to you, ""There is nothing to this talk of shortage, whenever we have needed oil we have always found it and always will."" To these gentlemen the possibility of an inadequate supply of oil is as incomprehensible as the possibility of the extinction of the passenger pigeon was to the early settlers who saw flocks that hid the sun for days during their passage. The passenger pigeon disappeared within two generations thereafter, and I deem this point of view as being perhaps more vicious than that of the extreme pessimist. It seems to me it is nothing less than improvidence lulling us into a false sense of security. There is an old proverb to the effect that ""The Lord helps him who helps himself."" I believe that we shall solve the oil problem, but I do not think it will be solved by vague optimism. It is going to call for our most energetic efforts and I believe we shall have to do a lot of ""helping ourselves."""

Oct 1, 1920

By E. J. Lintner

This paper is one of a series being prepared by the United States Bureau of Mines describing clay mining, crushing and grinding methods, and costs at various clay-mining operations throughout the United States. These papers are designed to disseminate technical information regarding methods used. The cost tabulations represent local operating expenditures only and not total production costs. Although the publication of total production costs might not be advisable in some instances, yet a knowledge of operating costs is essential to the technical discussion and study of the methods employed. The attention of the reader is specifically called to-this distinction between total and operating costs in order that no misunderstanding of the cost tabulations shall ensue. The following report deals specifically with the methods employed by the Dennison Sewer Pipe Co., Dennison, Tuscarawas County, Ohio.

Jan 1, 1936

By James W. Ballard

The facts are generally accepted that an atmosphere containing large quantities of any dust is objectionable to breathe and that some dusts are more dangerous than others. Therefore, knowledge of the com-position of dusts is important in evaluating the hazard entailed on exposure. At present, free silica, of which quartz is the most abundant form, is considered one of the most significant dusts, from the standpoint of pneumoconiosis, and one State5/ has established permissible limits of air dustiness on the basis of the free-silica content of rock. The amount 06 free silica in materials used for rock dusting also has been limited.6/ Determination of free silica or quartz, therefore, is important.

Jan 1, 1940

By H. B. Humphrey, J. J. Forbes

"In accident prevention, a study of statistical data is necessary to determine primary causes of accidents to devise means to eliminate causes at the original sources. Explosions in coal mines of the United States during the 10 years ending December 31, 1931, ranked third in the causes of fatal accidents; they constituted 16.2 per cent of all fatal accidents in bituminous mines and 8.4 per cent of all fatal accidents in anthracite mines. A study of coal-mine explosions in Pennsylvania, with approximately 160,000 men employed in anthracite mines and about 145,000 in bituminous mines or about 205,000 out of -the approximately 525,000 men employed in all coal mines of the United States, should give information of value to all persons endeavoring to reduce or eliminate coal-mine explosions. This circular reviews explosions of gas or dust or of both in the coal mines of Pennsylvania to show the hazard of gas and dust, to point out the influence of certain factors in causing explosions, and to emphasize the efficacy of explosion-preventive measures.The data published annually by the State Department of Mines and of the United States Bureau of Mines were used in compiling the tables of explosions. Through the cooperation of W. H. Glasgow, secretary, Department of Mines of Pennsylvania, and his assistants, many doubtful cases were clarified, so that as far as recorded the history is comparatively complete. Figures used in compiling some of the tables were furnished by W. W. Adams, chief statistician, demographical division, United States Bureau of Mines.Anthracite in the Wyoming Basin of Pennsylvania was used locally by gunsmiths in 1755, by blacksmiths in 1769, and as domestic fuel in 1808.Mining and shipments developed slowly between 1806 and 1812, but more rapidly after that.Early mining along the outcrops gave essentially no trouble from gas, but by 1870, when State inspection was established, explosions were frequent; ventilation was crude and accumulations of gas were generally ""brushed"" or burned out.Table 1 lists 1,232 ignitions and explosions of gas in anthracite mines from 1870 to 1932, inclusive, every one of which was accompanied by loss of life. Some details are given of 110 representative cases in which five or more lives were lost or in which it appeared that some violence was present.During the period 1870 to 1932, inclusive, gas explosions caused 2,213 fatalities, or an average of about two deaths for each ignition or explosion. Records are not available as to the number injured in these and in other explosions where no deaths occurred, but from a study of explosion reports it appears probable that the number injured exceeds the number killed. In the 110 cases described, 599 were killed and 294 were injured. As shown in Table 2, fatalities from gas explosions averaged 8.3 percent of the total fatalities in Pennsylvania anthracite mines from 1870 to 1931, varying from 6.0 percent in 1931 to 13.1 percent in 1927."

May 1, 1933

By Roy E. Peterson

The Bureau of Mines conducted an investigation to produce metallized pellets from domestic iron ore superconcentrates using lignite and subbituminous coal as reductants. Feed materials for the metallizing process consisted of commercially indurated iron oxide pellets and green pellets prepared from upgraded domestic concentrates with graphite or limestone as internal additives. Durability of the green pellets during metallization was investigated in tests conducted in a 7-inch-ID rotating drum furnace. Test results indicated that the major cause of pellet disintegration with the concentrates used was the tumbling action during reduction rather than forces generated within the pellets. In larger scale tests made in a 34-inch-ID by 35-foot-long kiln, the previously indurated pellets were metallized with lignite at 1,030° C with little disintegration. A 96-percent level of metallization was obtained in pellets having an average compressive strength of 420 lb. In subsequent, similar tests using green pellets containing graphite or limestone, pellet disintegration was more severe, with 10 to 40 percent of the feed being lost as dust. The surviving pellets had metallizations ranging from 88.3 to 94.4 percent and compressive strengths ranging from 60 to 68 lb.

Jan 1, 1976

By John J. Sammarco

Illumination plays a critical role in an underground miner?s safety because miners depend most heavily on visual cues to recognize hazards. Mobile mining machinery, located in the miner?s peripheral field-of-view (±10° to about ±60° off-axis), may pose potential pinning and striking hazards. The main objective of this research was to determine if there were peripheral visual performance improvements for the detection of moving objects when using cool-white light-emitting diode (LED) cap lamps as compared to incandescent (INC) light bulbs commonly used in miner cap lamps. The cap lamp variable of interest is the spectral power distribution (SPD); the illuminances were normalized by a diffusion filter. The second objective was to determine if age is a factor for peripheral visual performance. This is important because the workforce is aging ? the average miner age is about 43 years old. Thirty subjects participated in the study; ten subjects each in the age groups of younger (18 to 25 years), middle (40 to 50 years), and older (50+ years). Visual performance was quantified by the subjects? speed and accuracy of response to detect the rotation of high-contrast (white) circular targets located 3.83 meters (m) away at -20°, 40°, and 50° off-axis. The speed of detection and the number of missed target rotations (accuracy) were measured. The prototype LED cap lamp results were best with a 11% to 15% improvement compared to the INC and LED cap lamps respectively. Age does appear to be a significant factor. For the middle and older age groups?, target movement detection time increased 75% and 60% and the number of missed targets increased 500% and 450% respectively in comparison to the youngest age group. The results also suggest that target location is a significant factor. The subjects? target movement detection time for the 40° and 50° target movements increased 16% and 69% respectively as compared to the -20° target.

Jan 1, 2008

By Will H. Coghill

[The supply of gravel spar and of acid spar is not well balanced. Gravel spar -- 85 per cent flourspar, 5 per cent silica -- gluts the market, whereas acid spar -- 98 per cent fluorspar, 1 per cent silica -- is somewhat scarce. Hence it is desirable to convert some of the gravel spar into acid spar. Knowledge of this condition prompted the Franklin. Fluorsrar Co. at Paducah. Ky., to enter into cooperation with the U. S. Bureau of Mines and the Missouri School of Mines and Metallurgy to improve the methods of fluorspar, milling so that morn acid spar would be available. The fluorspar company detailed Mr. Omar Greeman for the work. During the course of the investigation, while Mr. Greeman was also doing work for a master's degree in the School of Mines? an extensive study was made of gravity concentration of fluorspar ores. Decrepitation by heat treatment was also given a laboratory try-out. A part of tie time was spent on flotation; these notes relate only to the flotation. The results of one of the flotation runs is appended. The test was made in a 500-gram mechanical-agitation machine. The sample was ground to 100-mesh in a pebble mill.]

Jan 1, 1928

By P. L. Sibrell

Electrorefining of Ti in nonaqueous solvents has been studied by the U.S. Bureau of mines as a method for recycling impure scrap Ti. Electrochemical behavior of Ti species was investigated using cyclic voltammetry. Research results showed that Ti metal can be dissolved in polar solvents such as dimethylformamide or dimethyl sulfoxide. However, deposition of Ti from these solvents was not successful. Several solvent systems were investigated for electrodeposition of Ti but no deposits were obtained. Reduction of Ti4+ complexes to Ti3+ proved to be straightforward, but reduction to lower oxidation states could not be confirmed. In dimethylformamide solutions, cyclic voltammetry results demonstrated the reduction of Ti to an oxidation state of less than three, but no Ti metal was identified. In dimethyl sulfoxide solutions containing LiCl, it was possible to deposit Li metal. After adding Ti salts to the solution, electrolysis quickly passivated the electrode. Deposition of Ti was also investigated in solutions of dimethoxyethane and propylene carbonate but, again, no reduction of Ti to oxidation states of less than three occurred. Therefore, the prospects for a nonaqueous electrorefining system for Ti metal do not appear promising.

Jan 1, 2010

By J. T. McCartney

In an effort to correlate the size of pyrite particles in coal and coal-particle association with the removal of pyrite before burning, the Bureau of Mines conducted a study of 61 coals presently being used for electric power production. The results were obtained by visual microscopic studies of polished briquets of minus l4-mesh samples. Mean pyrite particle sizes ranged from 20 to 400 microns and proportions of pyrite contained in coal particles to an extent greater than 50 percent by volume (estimated) ranged from 20 to 95 percent. These parameters were correlated with reductions in pyrite accomplished by float-sink tests at 1.60 sp gr on 14-mesh, 3/8-inch, and 1-1/2-inch samples. The correlation coefficients between pyrite removal and mean pyrite particle size were 0.89, 0.84, and 0.79, respectively, for these samples. Correlation coefficients between pyrite removal and coal-pyrite association parameter were 0.92, 0090, and 0.85, respectively. It is apparent that extent of pyrite removal can be fairly well predicted from microscopic analysis.

Jan 1, 1969