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By B. J. Scheiner

Electrooxidation of cinnabar mercury ores (HgS) was investigated as a means of providing an effective and economical hydrometallurgical technique for extraction of mercury from its ores, particularly those too low in grade to allow economical metal recovery by retorting or furnacing techniques. Oxidation was accomplished by electrolysis of ere slurried with brine. Cinnabar was dissolved by oxidation of the insoluble sulfide to soluble mercuric salts. The mercury ion in a brine solution forms a stable tetrachloro complex. Typical laboratory experiments required I to 7 hours of electrolysis at 35-percent pulp density in a brine solution that contained 4 to 20 weight-percent sodium chloride (NaCl). Power consumption ranged from 10 to 50 kwhr/ton of dry ore. Mercury extraction values between 90 and 99 percent were obtained with all of the ores investigated. Subsequent mercury recovery from leach solutions was readily accomplished by precipitation on zinc. Pilot mill experiments in a 100- to 200-lb/hr extraction plant are in progress to quantify power and reagent requirements, and extraction and recovery data obtained to date closely parallel those obtained in the laboratory.

Jan 1, 1970

By J. H. McClain

In the last 3 years' operation of the zirconium-production plant, zirconium metal has been employed to good advantage in many applications. The most frequent use has been in situations requiring resistance to attack by hydrochloric acid. In this service, it has been shown to be a serious competitor to Hastelloy. Zirconium also has excellent resistance to most other corrosives end could be considered for use as an all purpose metal. For example, this report cites 18 applications in hydrochloric acid, 4 applications in sulfuric acid, 5 applications in phthalic-hydrochloric acid, 3 applications in wet hydrogen chloride-chlorine atmospheres, and 2 applications in fused caustic.

Jan 1, 1954

By Thomas C. Atchison, Joseph M. Pugliese

Six explosives were compared by measuring their strain- producing abilities in limestone . Peak strain , e , varied with scaled distance , R/Ro , according to the following equation : € = Kc (R /R 。)- ". The distance exponent , n , was a constant of the rock and did not depend upon explosive . The strain intercept , Ke , increased with increasing detonation pressure of the explosive . The strain intercept also depended upon the explosive- to - rock impedance ratio . For impedance ratios from 0.53 to 1.38 , the strain intercept was approximately proportional to the medium stress , Pn , as calculated from the explosive detonation pressure , P , and the explosive - torock impedence ratio , Z , by the simple elastic theory relation : P = 2P / ( 1 + Z ) . PD However , the data indicated that , at lower values of impedance ratio , the strain intercept is relatively larger than would be expected from the simple elastic theory . The results presented provide a simple method for predicting the relative effectiveness of different explosives in breaking limestone from the detonation pressures and characteristic impedances of the explosives .

Jan 1, 1964

By W. B. Berwald, T. W. Johnson

"The United States Bureau of Mines, in cooperation with the Natural Gas Department of the American Gas Association, has been studying actively for the past several years the flow of natural as through high-pressure pipe lines. 4 This report deals with that part of the study involving the design of pipe-line systems consisting of lines laid parallel to each other. The lines are referred to as the original line and the parallel line. The paralleling lire may or may not extend the entire length &f the original line; however, the parallel line is connected at its two ends to the original line.As a result of the large expansion of the natural-gas industry almost all markets within economic distance, from the developed as fields have at least one pipe line supplying them with natural gas. Small increases in the consumers' demand for natural-gas can be met usually by increasing operating pressures, but any marked increase in demand necessitates paralleling sections of the existing systems. It is believed that to a large extent future expansion in the natural—gas industry will consist of paralleling the present lines. The several formulas given in this report have been developed to aid in the design of such systems. Curves and tables were prepared from these formulas to simplify the calculations materially and to facilitate determination of the sizes of pine to be used in paralleling various diameter lines to give the most economical design. The formulas are presented without detailed derivations, as a complete report on the flow of natural gas through pipe lines is being prepared which will contain the derivations of these formulas. Examples included here show the detail of application of the several formulas to problems of design of parallel lines."

Jun 1, 1934

By Otis E. Perkins

This paper is one of a series being prepared for the United States Bureau of Mines to disseminate technical information retarding the methods used in mining nonmetallic minerals. The cost tabulations represent operating expenditures only and not total costs. It is recognized that publication of total costs might in many instances cause embarrassment to individual operators as well as to the industry as a whole. On the other hand, operating costs are essential to the technical discussion and study of the methods employed. The attention of the reader is specifically called to this differentiation in order that no misunderstanding of the scope of the cost tabulations shall ensue. This paper deals particularly with methods and costs of dredging, classifying materials, and transportation at the plant of the Ross Island Sand & Gravel Co. of Portland, Ore. ACKNOWLEDGMENTS The author wishes to acknowledge the assistance of Harold Blake, general manager of the company, and of A. V. Kramer, cashier in charge of the plant office.

Jan 1, 1933

By Henry E. Blake

The Bureau of Mines has been engaged in a continuing research effort to develop processes for increasing the recovery and utilization of fluorine from low-grade resources. This current research has shown that over 98 percent of the fluorine in phosphate rock is extracted when the ore is treated with excess phosphoric acid in the presence of water vapor at 150° to 180° C. More than 80 percent of the fluorine can be recovered as fluosilicic acid, which can then be converted to commercially useful hydrogen fluoride or fluorspar by previously developed Bureau processes. Extraction of P205 from the ore was about 98 percent in batch tests and 90 percent in semicyclic tests.

Jan 1, 1974

By Carlton E. Brown

This report contains information on the relation between and precision or reproducibility of counts (light-and dark-field) of the dust in liquid from simultaneous impinger, midget-impinger, electric-precipitator, and filter-paper samples. The impinger was the main sampler used from about 1922 to 1939 by industrial hygienists in the United States for collecting samples of unhygienic dust from the atmospheric environment of workers. The midget-impinger, a small modification of the preceding impinger described in 1937, has been the sampler used most since about 1939. Electric precipitators5/6/ have been used to a limited extent, mainly by the Bureau of Mines in the laboratory, for obtaining results comparable to impinger results. A filter-paper sampler for obtaining results comparable to impinger results has been described by Brown. All these samplers have a high collecting efficiency for particles larger than 1 micron in diameter revealed by the usual light-field counting procedure. However, their collecting efficiencies are quite variable for the smaller particles revealed by the dark-field counting procedure used in this study. Published information on the relation between the results of these samplers is limited and scattered. Summaries of some of this information are given in this report along with some previously unpublished information.

Jan 1, 1949

By Andrew W. Berg

The Bureau of Mines Mineral Industry Location System (MILS) is part of the computerized Minerals Availability System (MAS), a comprehensive data base of known mineral deposits. MILS, the location subsystem of MAS, has become widely used by the minerals industry and organizations with land-use planning and land management responsibilities. Information on more than 135,000 mineral locations and processing plants in the United States is contained in the data base. This information includes the name, location, mineral commodity, type of operation, bibliography, and cross-references for each property or prospect. Computer-drawn map overlays at various scales showing clustered MILS locations and computer printouts keyed to those overlays are available for inspection and reproduction at the Bureau's Field Operations Centers at Juneau, Alaska, Denver, Colo., Pittsburgh, Pa., and Spokane, Wash.

Jan 1, 1979

By C. S. ROBINSON, T. M. Romslo

This investigation was conducted jointly by the Bureau of Mines and the Geological Survey to obtain further information on the source and economic possibilities of the copper mineralization exposed on the Copper Giant group of claims, Ajo mining district, Pima County, Ariz. The Copper Giant group of claims was first brought to the attention of the Bureau of Mines by Joseph Hunter (deceased), Phoenix, Ariz., part owner of the claims. In December 1942 these claims, and an adjoining group, were investigated by T. C. Denton, mining engineer, formerly with the Bureau of Mines, and Nels P. Peterson, geologist, Federal Geological Survey. It was concluded the area could not be considered as a source of copper for immed- iate emergency needs and that further investigation of the area, at the time, was not warranted. In the spring of 1948 the lessee, J. H. Greenway Albert, requested Bureau of Mines assistance in developing the property. J. H. Hedges, former chief, Tucson Branch, Mining Division, and Lincoln A. Stewart, mining engineer, Bureau of Mines, made a cursory examination of the property and noted that at numerous places, low-grade copper mineralization appeared on fractures and bedding of the Locomotive fanglomerate and Ajo volcanics, which are thought to be of Tertiary age. During the period of May 11 through 14, 1949, Bureau of Mines engineers3 mapped and sampled two areas of mineral- ization. On June 2 and 3, 1949, the areas selected by the Bureau and three other nearby mineralized areas were investigated by C. A. Anderson and R. S. Cannon, Jr., of the Federal Geological Survey. As a result of these examina- tions, further investigation of certain areas was believed to be merited. The Copper Giant area was selected as the most favorable in which to carry out exploratory and development work. The field work on the project was started in October 1949 and completed in December 1949. It consisted of road building, trenching, sampling, topo- graphic and geologic mapping, diamond drilling, and logging of core. Samples taken on the project and during preliminary examinations totaled 64, of which 63 were surface samples. Diamond drilling, started October 10 and completed December 7, consisted of two holes for a total depth of 1,542 feet.

Mar 1, 1952

By Emery Chilton, Charles Taylor, Mark Senk, Linda McWilliams

Three-axis ultrasonic anemometers are used to study airflow in the NIOSH ventilation gallery where ventilation in an underground mine is simulated. In this study, performance characteristics of this anemometer are evaluated and the effects of sensor orientation and sampler location on flow readings are examined. The study results provide guidelines for more effective use of the ultrasonic anemometers in the ventilation gallery.

By Ann Hubbs, Vincent Castranova, Jane Y. C. Ma, De-Hwa Chao, Joseph K. H. Ma

AN OVERVIEW OF THE ACTION OF TETRANDRINE ON SILICOSISBecause of the persistent presence of silica dust in the lungs silicosis is a progressive and irreversible disease. At present, there is no proven effective therapy for silicosis. Limited choices of therapeutic intervention with corticosteroids and other immunosuppressive regimens 1,2 have been accepted for some forms of pulmonary fibrosis. These treatments are only minimally effective, and the results provide little understanding of the disease state due to the lack of correlation between drug activity and the mechanism of fibrosis. Thus, continuing effort must be made in the search for effective antifibrotic agents, which may be used to provide a sequential analysis of the fibrotic process and to open the door for further research and clinical development. Tetrandrine is one of hundreds of drugs screened for antifibrotic activity by Chinese scientists. It has been used in China as a treatment for silicosis in open clinical trials3 and in laboratory animals. The action of tetrandrine on pulmonary fibrosis has been attributed to its ability to inhibit particle stimulation of alveolar macrophages, a key cell type central to the fibrotic process, to release oxygen radicals and inflammatory cytokines. Alveolar macrophages (AM) residing on the alveolar wall, are the predominant phagocytic cells of the lungs responsible for pulmonary defense against inhaled microorganisms and other particles and thus play an important role in maintaining the homeostasis of the lungs. 7 Ample evidence suggests that cells of the monocyte-macrophage series play an important role in the immunopathogenesis of pulmonary fibrosis. When upregulated by silica, alveolar macrophages generate reactive oxygen metabolites8·9 which can damage lung parenchyma and release fibrogenic growth factors and cytokines, 10,11 such as interleukin 1 (IL-1), which can induce fibroblast proliferation and collagen synthesis. The cytokine-mediated fibroblast proliferation and collagen synthesis are key steps in the development and progression of pulmonary fibrosis .11 Previous studies by our group have shown that tetrandrine exhibits strong binding affinity to AM and inhibits particle-stimulated respiratory burst activity (oxygen consumption, superoxide anion release, and hydrogen peroxide secretion) in these cells. 13 In addition, studies by Kang et al. 14 have reported that tetrandrine inhibits silica-induced release of fibrogenic factors such as IL-1 which are capable of inducing fibroblast proliferation and collagen synthesis. Reist et al. 15 further suggested that the antifibrotic action of tetrandrine may be mediated in part by the direct effect of this drug on the ability of fibroblasts to respond to proliferative agents. These results indicate that the mechanism of silicosis involves activation of AM and fibroblasts by silica, resulting in abnormal collagen production due to miscommunications between the cell types. Tetrandrine may interrupt this process by direct interaction with the lung cells.

Jan 1, 1998

By M. J. Ankeny

Coal-mine haulage ranks second as a cause of coal-mine fatalities, and the prevention of such accidents will materially improve progress in safety in the coal-mining industry. Beginning March 1950, Federal coal-mine inspectors were made responsible for completely investigating all fatal accidents in and around coal mines. During these 10 months, Federal coal-mine inspectors investigated 447 fatal accidents. This is a study of 121 of the fatal haulage accidents investigated, which constituted 27 percent of fatalities from all causes. Haulage employees represent only 12 to 15 percent of mine personnel, but, on the basis of accident frequency, their work is the most hazardous in coal mines. Fatal haulage accidents occurred in 53 bituminous coal-producing counties representing 14 States and Alaska. The physical conditions represent a cross section of' producing coal beds. Mining and transportation methods vary, from those of small hand-loading mines to those of modern mechanized mines.

Jan 1, 1951

By J. A. HUFF, V. V. BAKER

This circular contains a statement of the statutory provisions of the several States regarding the appointment , qualifications , and remuneration of State mine inspectors . States have been omitted where no specific provision has been made by the State law for mine inspectors .

Jul 1, 1931

By William G. Pariseau

Elastic-plastic finite-element simulation of cut-and-fill stoping in deep, narrow veins shows substantial quantitative agreement with field measurements of stope closure and fill pressure made at two mines in the Coeur d'Alene mining district of northern Idaho. The simulation procedure, validated by field data, was used in an analytical study of vein-wall closure and sill-pillar stress as influenced by fill modulus, rock modulus, and premining stress. Ratios of closure and pillar stress in the filled stopes to closure and pillar stress in the unfilled stopes are used as prediction indices for fill performance. In general, the support capability of fill increases dramatically as the ratio of fill modulus to rock modulus approaches 1. A significant reduction in closure .from the open stope--up to 75 percent--occurs with a relatively low-quality 10-ksi-modulus fill (rock modulus of 1,000 ksi). However, a higher quality fill is needed to achieve a substantial reduction in pillar stress from that of the open stope. A 100-ksi-modulus fill reduces pillar stress in both the 36-foot and l6-foot pillars (vein width is 10 feet) by about 50 percent relative to the open stope.

Jan 1, 1976

By V. M. Benson

A simplified, routine method for determining lithium in lithium-bearing rock is presented. The sample is decomposed by repeated treatments with nitric, hydrofluoric, and perchloric acids. Since this procedure does not appreciably dissolve beryl, interference by beryllium (the principal interfering cation) is minimized for most samples. The salts are brought into solution with water and enough citric acid-ammonium citrate buffer is added to make the final volumetric dilution 0.20 M with respect to citrate. The addition of citrate greatly reduces anion interference in the hydrogen-oxygen flame, slightly increases the intensity of the lithium 671 millimicron emission line, and reduces the effect of most of the interfering cations to the extent that analytical separations are not necessary. The accuracy of results of single determinations of lithium in a pegmatite containing spodumene, lithium-bearing mica, and beryl are approximately equal to that obtained by other flame methods, INTRODUCTION This investigation was undertaken in Bureau of Mines laboratories to develop a reliable, rapid, routine analytical method for determining lithium in lithium-bearing minerals. The requirements of the procedure were that the method should be applicable to the analysis of a variety of lithium-bearing ores and test products, and the results would be reasonably accurate for materials containing 0.05 to 8 percent Li20.

Jan 1, 1961

By K. E. Tame

The Bureau of Mines is studying possible modifications in conventional uranium ore-processing steps to confine and permit controlled disposal of radioactive wastes. Surveys of Ra226 contamination of liquid wastes from uranium mills indicated that the Vanadium Corporation of America plant at Durango, Colo., had one of the more urgent problems. A possible procedure for minimizing the waste disposal problem was to reuse the waste solution in the mill--in effect, erasing the need for disposal of liquid waste. In examining this possibility, interlocked bench-scale leaching and solvent extraction tests simulating the Durango flowsheet were made. The simulated reuse of barren raffinate for leaching and washing was carried through three separate campaigns of 9, 12, and 35 cycles each.

Jan 1, 1961

By O. C. Blade

Production of crude petroleum in the Middle East (southwestern Asia) and in South America has increased greatly during recent years and has become a significant factor in the world's production of crude oil. Crude oil from fields in the Middle East increased from 256,164,000 barrels in 1946 to 305,833,000 barrels in 1947 and 417,201,000 barrels in 1948. Production from South American fields increased from 446,417,000 barrels in 1946 to 518,652,000 barrels in 1947 and 574,837,000 barrels in 1948. Crude-oil production from Canadian fields increased from 7,726,876 barrels in 1947 to 12,370,875 barrels in 1948, most of the increase being attributable to two fields, Leduc and Redwater, both represented by analyses in this report. Present indications are that production of crude petroleum from all these regions will continue to increase.

Jan 1, 1950

By W. F. Marshall

This Bureau of Mines report discusses tests conducted with four different catalytic reactor designs to determine the influences of exhaust treatment systems on emissions from diesel engines. Although there was significant differences in oxidation efficiencies at light to intermediate engine loads, all four catalysts were very effective in reducing emissions at heavy loads. Compositional determinations included carbon monoxide, carbon dioxide, unburned hydrocarbons, oxides of nitrogen, aldehydes, sulfur dioxide, sulfates, and particulate loading. Particulate size, exhaust odor intensity, and the character of the unburned hydrocarbon component were also determined.

Jan 1, 1978

Although alternating-current (a.-c.) power systems and equipment have been used in coal mining for many years, most mines in the United States are powered mainly by direct current (d.-c.). There are several logical reasons for this, but the use of d.-c, equipment is, in most instances, a direct outgrowth of the original practice of using such power for haulage systems. For traction equipment such as the electric trolley locomotive the d.-c. motor has ideal operating characteristics, and thus it has been widely used for haulage locomotive service. The first efforts at electrification of coal mines started with the haulage system and from there branched out to include the many types of electrically powered mining machinery used in the industry today.

Jan 1, 1960

By C. W. Davis

Two general schemes have been used for the determination of gold and silver in material containing considerable quantities of copper ; one is known as the " all fire " method , and the other as the , " combination " , or " wet and dry" method . The all fire crucible method , using an excess charge of litharge , has been found satisfactory when the copper content of an ore is under 6 per cent , ( Loevy , J. , Zur Edelmetallbestimmung in hochprozentigen Kupfererzen : Chem. Ztg . Jarhrg . 35 , 1911 , p . 278 ) , or where the precious metal value is so great that a small sample can be used . In the latter case , silica is added until the copper ratio is sufficiently low . If there is more than 6 per cent of copper in an ore , the lead button obtained from a crucible fusion will require repeated scorification before . it can be cupelled successfully . Rescorification is not only tedious , but also causes a slag loss of precious metals . In combination methods , the copper is dissolved , and the gold and silver in the residue . is determined by fire assay Although some combination methods have given satisfactory results for gold and silver , they are not applicable when an estimation of the platinum metals is required . Since substances containing platinum are frequently high in copper , a study of methods which might be used for the estimation of small quantities of gold , silver , and the platinum metals in such material was considered worth while . The estimation of platinum in ores by fire assay methods has been described in Technical Paper 270 of the bureau; ( Davis , C.W. , The detection and estimation of platinum in ores : U. S. Bureau of Mines Tech . Paper 270 , 1921. ) the present paper , which is supplementary to that report , deals chiefly with the application of combination methods , taking them up to the point where the fire assay is to be applied .

Mar 1, 1921