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By C. J. Walker, J. S. Miller

This work was done in an attempt to find a simple solution to the problem of simultaneously changing terminal rate and terminal pressure under conditions of unsteady - state flow in porous media . Although the original aim was not realized , a method for encasing a sandstone core that would permit high - pressure ( 200 to 980 psi ) flow tests and the use of electronic equipment to measure pressures at points along the core during unsteady - state gas depletion was found to be feasible . The sandstone core used in this study was from the Bandera formation of Pennsylvanian age , Redfield , Kans . The core , cylindrical in shape with a 3.5 - inch diameter and 6- foot length , had a porosity of 15 percent and a permeability of 9 millidarcys .

Jan 1, 1963

By Bernard M. Larsen, Clyde F. Williams, Edward P. Barrett

"Introduction.The Bureau of Mines at its Northwest Experiment station has been studying the production of sponge iron for the past four years, and during 1923 progress advanced to the point industrial applications can be safely considered. A furnace was operated commercially at silver City, Utah, producing about three tons of sponge iron daily.The Bureau was led to undertake this work by the interest in the use of sponge iron for copper precipitation and for conversion to iron and steel in the electric furnace.If a piece of iron oxide is completely reduced at such a low temperature (850 to 900° C) that no sintering or fusion takes place, then the piece of metallic iron formed has the same size and shape as the original piece of oxide on account of the removal of oxygen, the structure is finely porous, exposing a large surface of iron, and the apparent density is less than that of the original piece of iron oxide. This material is called ""sponge iron"". Chemically, it is a very reactive material."

Nov 1, 1924

By C. E. Jordan

The fundamental properties of dielectric separation were studied to provide insight into the design and operating characteristics of a dielectric separator. Force equations on mineral particles were derived and evaluated experimentally. Responses to variations in the electrical voltage and frequency, feed rate, particle size, dielectric fluid, and dielectric constant were tested theoretically and experimentally, using a 5-cm-diam dielectric separator. High-dielectric mineral recovery was proportional to the calculated effective dielectric force volume (EDFV) that surrounded each drum-electrode wire. Electrode spacing was the most sensitive design parameter; spacing of less than 0.4 cm was required for a good separation. Dielectric separation was effective for separating minerals with dielectric constants that differed by approximately 2 or more.

Jan 1, 1985

By M. J. Sapko

The pressure and flame development of the methane-air-nitrogen system was investigated in the Bureau's l2-foot-diameter sphere to define buoyancy effects and to develop relationships for predicting venting requirements. Pressure rise (?P) is defined as a function of time (t) and nitrogen dilution and is shown to deviate noticeably from the cubic law (?P = kt3), depending upon the period of combustion and the mixture composition. Corresponding flame speed (Sf) and burning velocity (Su) data are given which show that Sf is time dependent and that Na dilution has a greater effect than air dilution in inhibiting the flame propagation. The Su data agree with "accepted" values and are unique in that they are based on much larger flames than those used in other investigations. Downward propagation limits are shown to depend mainly upon buoyant forces, which can affect the burning of even stoichiometric CH4-air systems. Theoretical expressions, based on the mixture burning velocity and expansion ratio, are given for predicting the venting requirements for ignitions of hydrocarbon-air-nitrogen mixtures in spherical or cubical enclosures.

Jan 1, 1976

By W. L. Staker

The Bureau of Mines investigated the use of shredded automobile scrap for copper cementation. Air agitation was used to improve the cementation rate and prevent excessive buildup of copper on the iron. The pieces of scrap were too large to be properly evaluated in the laboratory; therefore, a pilot scale test unit was constructed and the process tested at field locations. Pregnant solution was obtained from industrial leaching operations, processed in the test unit and the barren solution and cement copper were returned to the plant process stream. The test results showed that the air-agitated launder containing auto-mobile scrap was an effective means for recovering copper from leach solutions. A continuous l4-day test run was made without a noticeable decrease in cementation efficiency. The most suitable scrap product was obtained from incinerated automobile hulks shredded in a hammer type of shredder. However, it was necessary to remove small pieces such as nuts and bolts because they interfered with the discharge of the copper product.

Jan 1, 1976

By D. K. Deardorff, Laurance L. Oden, H. Kato, M. I. Copeland

The equilibrium relationship of hafnium and tantalum was studied to facilitate alloy and property investigations . The data obtained are presented graphically as the equilibrium diagram . Alloys were prepared from high - purity components by nonconsumabletungsten- electrode arc melting . Data for the equilibrium diagram were obtained by optical pyrometry , metallography , X- ray diffraction of heat treated specimens , X- ray diffraction using a high- temperature camera , and differential thermal analysis . During the investigations , a casting apparatus was constructed , and the existing melting - point apparatus was improved . The bcc allotrope of hafnium forms a continuous series of solid solutions , called beta , with tantalum which exhibit a minimum melting point at 20 wt pct tantalum and 2,110 ° C. At 24 wt pct tantalum and 1,050 ° C , hafnium- rich beta decomposes in a monotectoid reaction to yield alpha and tantalum- rich beta . The monotectoid isotherm extends from 5.5 to 60 wt pct tantalum . The twophase region , in which hafnium- rich and tantalum- rich beta solid solutions are immiscible , rises to a maximum temperature of 1,265 ° C at 38 wt pct tantalum . The solubility of hafnium in tantalum decreases from 40 wt pct at the monotectoid temperature to 20 wt pct at 750 ° C.

Jan 1, 1964

By K. K. Kelley

The heats of formation of two lead vanadates (Pb2V207 and Pb3V208) and manganese vanadate (MnV206) were determined by hydrochloric acid solution calorimetry, supplementing previous Bureau of Mines measurements of the vanadates of calcium, magnesium} and sodium. Heat and free energy data for 11 vanadates were assembled on a common basis. The stability of comparable vanadates (with respect to the oxides) increases in the following order: Magnesium, manganese, lead, calcium, sodium.

Jan 1, 1963

By F. P. Haver

Because State and Federal agencies have limited the amount of sulfur oxides that can be discharged to the atmosphere, most copper smelters plan to convert the S02 in offgases to sulfuric acid. In some cases, however, it might be preferable to use a nonsmelting method to fix the sulfur in the form of a discardable product. Research by the Federal Bureau of Mines has shown that sulfur in copper concentrate can be converted into insoluble anhydrite (CaS04) by roasting the concentrate with lime (CaO). After leaching the calcine to recover metal values, the residue may be discarded without harm to the environment. The process can use a rougher flotation product, thus reducing separation costs and saving valuable minerals (for example, molybdenite) that are now lost in making cleaner concentrate. In tests, rougher concentrate was pelletized with the theoretical amount of lime and roasted for 1 hour in a 6-1/2-inch-ID by 11-foot-long rotary kiln at 700° C. Sulfur retention was about 97 percent. Leaching the calcine with 20 percent RCI extracted approximately 99 percent of the copper, 73 percent of the iron, and 91 percent of the molybdenum. After the molybdenum was removed from the leach solution by adsorption on activated carbon, copper with a purity in excess of 99 percent was obtained by cementation on sponge iron. The strip solution then could be spray-roasted at 500° C to recover the RCI for recycle and obtain F2O3 as a byproduct.

Jan 1, 1975

By H. P. Hermance

The Ely mine, which at one time was the largest producer of copper in the United States, has been idle for the past 30 years. A remarkably continuous ore shoot probably averaging 100 feet wide and 19 feet thick was mined on about a 25° slope for 3,400 feet on the incline. The ore was massive sulfides containing chalcopyrite, pyrrhotite, pyrite, and sphalerite. The estimated production of the Ely mine is 400,000 tons of ore averaging 3.3 percent copper. Because of the critical position of copper during the recent war, a search for extensions and recurrences of parallel ore shoots at the Ely deposit seemed warranted. The Bureau of Mines surveyed selected areas by geophysical methods, diamond-drilled nine holes, and sampled mine dumps during its investigations, which began in 1942 and terminated in 1946. The diamond drilling totaled 5,229 feet. The logs of the holes include chemical analyses of mineralized sections.

Jan 1, 1949

By B. W. Gandrud

[The Bureau of Mines is conducting an extensive investigation of coal preparation in the Alabama coal fields in cooperation with the University of Alabama coal-mine operators. In this investigation the drainage characteristics of typical coals from the Warrior and Cahaba fields were studied]

Jan 1, 1941

By H. W. Gillett, E. L. Mack

"This report describes the trend of developments in electric brass-furnace practice in the last two years, and supplements Bureau of Mines Bulletin 202, ""Electric Brass-Furnace Practice"", which was published in 1922. In that bulletin it -as pointed out that some of the lines on which electric brass-furnace progress would take place were clear, but others were less so.Developments in foreign countries.Foreign brass-melters have not yet adopted electric melting to an extent comparable to its use in the United States. It is doubtful Whether all foreign countries combined use 100 electric brass furnaces; of these about 35 are of American make (Ajax, Detroit, Baily) and are operating in Canada, Mexico, England, France, Japan, Sweden, Switzerland, Spain, Norway, Germany, Argentina and Czecho-Slovakia.`The Rennerfelt furnace finds some use in Sweden (1)c, notwithstanding its high metal loss on alloys high in zinc, Two German firms are reported(2) to be using the Rochling-Rodenhauser induction furnace on bronze, the average energy consumption being given as 400 kw.-h. per ton. No comment is made on any trouble from the ""pinch effect"", A firm in Switzerland is reported (3) to use three 600-lb., direct-arc furnaces of its own design to melt babbitt, antimonial lead, coinage silver, nickel, copper, and brass. The metal loss on yellow-brass turnings is high. Use Of a direct-arc furnace in England, with precautions aimed to prevent surface overheating, vas abandoned (4) in favor of an Ajax furnace."

Apr 1, 1924

By Joseph Berman

The wolframite mineral series was studied to determine the effect of the FeO - MnO ratio on unit cell symmetry and thermal stability. This work was undertaken to evaluate the analytical procedures now in use for wolframite in scheelite and to aid in the development of improved methods of analysis. Wolframite grains were hand-picked, crushed, and screened; impurities were removed by selective magnetic separations using a Frantz isodynamic separator. The samples were further checked by optical spectroscopic and microscopic examination.

Jan 1, 1957

By Jim F. Lemons

The Bureau of Mines Minerals Availability System collected and analyzed data for 34 nonlaterite and 9 nickeliferous laterite domestic chromite deposits in order to assess their viability as sources of chromium under present technologic and economic conditions. These 43 deposits, none currently in production, contain approximately 6.3 and 22.3 million metric tons of Cr203 at the demonstrated and identified resource levels, respectively. Approximately 4.6 and 15.6 million metric tons of Cr203 are recoverable at the demonstrated and identified levels, respectively, for the 34 nonlaterite deposits. None of these resources are economically recoverable at January 1981 market prices. Production of metallurgical-grade chromite (market price $128 to $144) would require a minimum chromite market price of $237 per metric ton. Chemical-grade chromite production (market price $74 to $85) would require a chromite market price in excess of $188 per metric ton. From the 34 nonlaterite deposits, roughly 5.4 and 17.6 million metric tons of ferrochrome could be produced at the demonstrated and identified resource levels, respectively; however, a minimum market price of $770 per metric ton of ferrochrome would be required to stimulate production. The nine nickeliferous laterite deposits were not evaluated through production stages because of uncertainties in process technology and cost.

Jan 1, 1982

By R. V. Higgins

In a recent report3/ the authors presented a rapid method of calculating, by means of a desk calculator, the future performance of oil reservoirs in which the motivating agent was gas. The accuracy of the method was tested by data obtained from an electronic computer. Because of the accuracy obtained for the limited number of calculations performed, considerable interest has been expressed in the electronic computer program used to obtain the comparative data by an analytical solution. Accordingly, the computer procedures for the analytical solution are presented in this report. In an earlier report, 4/ a reservoir appraisal procedure was published in which an iterative method was used. Many requests were received for the computer program used to obtain the values given in that paper. That program, with some modifications, also is presented in this report. The modifications are given because of the progress that his been made in computers, and because much of the program for the analytical solution is usable for the iterative procedure.

Jan 1, 1960

By James W. Ballard, H. H. Schrenk

"The X-ray method of quantitative determination is advantageous because it permits determination of compounds rather -than ions or elements; for example, the direct determination of quartz in silicates,4/,5/,6/ The method also takes into account the finest particles of a sample, which may be lost in wet chemical methods because of solubility or in petrographic methods because of limitation of the microscope. The sample is usually reduced to a powder and is easily prepared,7/ only a few milligrams of material being necessary. The sample and its chemical composition are not destroyed and may be used for further analysis by X-ray diffraction or by other methods.This paper presents in detail some of the more essential problems that arise in the application of X-ray diffraction to quantitative chemical analysis, Photometric measurements are discussed in connection with line intensities and the choice of X-ray film. The internal standard method, successfully used in spectrographic analysis, is applied.Copper K-alpha X-rays from a demountable research-type X-ray tube were used with a camera of 20 centimeters radius with a cast-lead-slit collimating system. A combination of a tilted wedge and a lead-slit collimating system permitted irradiation of a large amount of sample with X-rays. This tended to minimize errors due to possible inhonogeneity of the sample, to decrease the time of exposure, and to keep the lines on the X-ray film to a minimum width. There was sufficient dispersion of the lines for satisfactory analysis of most samples. Power was furnished the tube by a. source of constant high potential consisting of a synchronous motor generator furnishing 500-cycle power to a 100-kv. transformer, rectifying valves, and a condenser filter circuit. The X-ray tube was operated as a gas-type tube at 35 kv, and 20 ma,, the exposure times varying from 1 to 2 hours. The constant output of X-rays from the tube, indicated bar an exposure meter built for the purpose, was satisfactory.The recording microphotometer8/has been described. It was found preferable to a nonrecording instrument for measuring blackening of lines above a background on X-ray films. This background, which usually occurs, is sometimes complicated by numerous peaks from lines of complex diffraction patterns. is microphotometer record of the pattern, therefore, facilitates the location of the background 'and the measurement of the heights of the peaks and thus contributes to the accuracy of a determination."

Jun 1, 1946

By John Gross

Studies in grinding efficiencies carried out at the Midvale plant of the U. S. Smelting, Refining & Mining Co. and at the Tooele plant of the International Smelting Co. Were made possible by the cooperation of these two companies with the U. S. Bureau of Mines. Mr. Alan Probert of the U. S. Smelting, Refining & Mining Co. and Mr. E. C. Peterson of the International Smelting Co., devoted their entire time to the work during the respective tests, and their services are hereby gratefully acknowledged. It is a pleasure to acknowledge also the assistance and kindness of the staffs of both companies in making it possible, at considerable trouble and expense, to sample the entire mill circuits and in furnishing the necessary supplies and special apparatus required in the work.

Jan 1, 1929

By C. H. Riggs

This report describes the development, oil recovery, and potentialities of productive formations in the Hall-Gurney field, Russell County, Kans. It is presented as part of a general program to aid and promote increased recovery from petroleum reservoirs. The report is based on studies of well logs, drill cuttings, and oil-and water-production histories of individual wells and leases. The geological interpretations follow closely those in published literature with only slight local modifications. Oil and water analyses, made at a Bureau of Mines research center, were supplemented by many analyses obtained from oil-producing and service companies. The Hall-Gurney field, in south central Russell County, Kans., (fig. 1) was discovered in 1931 but was not developed extensively until 1941. By 1960 the rate of oil production from the field had declined to the extent that many wells were abandoned. In some areas natural productive forces have effected good recovery. However, in other areas inefficient waterflooding, both natural and accidental, has adversely affected recovery potentialities.

Jan 1, 1963

By R. L. Lincoln

The effects of adding from 1 to 50 atomic percent (a/o) to vanadium were investigated by the Bureau of Mines. Properties studied included as-cast and annealed hardness, microstructure, fabricability at room temperature and elevated temperature, tensile strength, electrical resistivity, and oxidation resistance at 625° and 800° 2. Additions of small amounts of hafnium resulted in lessened as-cast hardness, decreased electrical resistivity, impaired roll- ability, increased oxidation resistance, and greater tensile strength. Larger amount of hafnium caused greater as-cast hardness, increased electrical resistivity, further impaired rollability, continued increase in oxidation resistance, and lessened tensile strength. INTRODUCTION The purpose of this study was to determine the effect of hafnium additions on the properties of vanadium and to learn if this binary alloy had any special or unusual properties. This investigation is a part of a larger research project in which new and expanded uses of vanadium are being sought. Domes tic vanadium is found frequently in combination with uranium, and because of the demand for uranium as a nuclear fuel, there now exists a surplus of vanadium-bearing minerals and vanadium pentoxide as a byproduct of uranium production. Primary principles of conservation demand that greater use be made of this readily available surplus; finding suitable metals to alloy with vanadium to enhance its properties is one way to increase its utilization. This report is the result of an investigation of the effects on the properties of vanadium when hafnium is added in amounts from 1 to 50 a/o.

Jan 1, 1962

By Michael J. Brnich

On November 20, 1968, a massive explosion rocked the underground workings of Mountaineer Coal Co.?s Farmington No. 9 Mine in West Virginia. Of the 99 miners who were working in the mine at the time of the explosion, only 21 survived and escaped the mine. This group included eight who were rescued from the Mahan?s Run air shaft. Nearly 40 years after the event, researchers from the NIOSH Pittsburgh Research Laboratory conducted oral history interviews with two of the eight survivors rescued from the shaft. The Farmington No. 9 Mine disaster ultimately led to passage of the Federal Coal Mine Health and Safety Act of 1969 (amended in 1977).

May 1, 2009

By Wesley A. Grosh

The Toncrae-Howard copper deposits in Floyd County, Va., were first mined about 1800. The property has been operated or under development at various times since then for iron, copper or sulfur, although the total production has been small. The deposit consists of a vein or zone of sulfide mineralization in schist composed mainly of pyrrhotite with minor copper values in the primary zone and some rich areas of copper mineralization in the altered zone. The Bureau of Mines, in an attempt to develop minable copper ore during the war, opened part of the mine for examination and sampling, deepened the shaft and other underground work, and drilled 29 holes totaling 2,187 feet.

Jan 1, 1948