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By J. H. E. Jeffes, K. T. Jacob

The activity coefficients of oxygen in liquid Pb-Sn alloys have been measured between 550 and 1100°C by use of solid oxide galvanic cells: Pt, Ni-NiO | Zr02 Solid electrolyte | O (Pb + Sn), Cermet, Pt; and Pt, Fe-FeO | Zr02 Solid electrolyte | 0(Pb + Sn), Cermet, Pt. Alcock and Richardson's quasi-chemical equation, with the coordination number of atoms set to 2, is found to predict successfully the activity coefficients of oxygen in these alloys. The relative partial molar enthalpy and entropy of oxygen at 1 atom per cent in the alloys have been calculated from the variation of the activity coefficient with temperature. The addition of Sn to an unsaturated solution of O in Pb is shown to decrease significantly both the partial molar enthalpy and entropy of O. As the measurements were restricted to a narrow range between 750 and 1100°C in Pb-rich alloys, however, the pronounced variation of the partial molar enthalpy of O with temperature at constant alloy composition predicted by the quasi-chemical model could not be verified.

Dec 1, 1971

By Ruddle R. W.

An outline account is given of the smelting of copper and the chemistry of the process. A table provides compositions of the more important minerals from which copper is won by smelting. Roasting is discussed as is smelting using reverberatory furnaces, blast furnaces and flash smelting. A brief discussion of converting covers the upright (Great Falls) converter and the horizontal (Peirce-Smith) converter.

Jan 1, 1953

By Z. Sawlowicz

Finely dispersed, primary sulphide mineralisation in the Cu-Fe sulphide zones of copper-bearing shale of the Polish part of the Permian Kupferschiefer is mainly present in the form of framboids and spherules. This type of mineralisation is especially well preserved in organic-rich shale, where it often dominates over a later diagenetic mineralisation that consists of large grains and veins. In microscopic observations special attention was paid to composite grains of copper and iron sulphides. The results suggest that the Cu-Fe and Cu sulphides precipitated in the Kupferschiefer sediment before pyritisation of the framboids had ceased and that they replaced metastable precursors of pyrite. The precipitation of copper sulphides could have been delayed owing to the formation of Cu-organic complexes.

Jan 4, 1992

By NA NA

Listing safety award winners, £I43M has been added to proceeds from coal privatisation in the year to March 1997, bringing total revenues to over £1.3bn, some company news in brief.

Jan 8, 1997

By P A. Collier

The general view of the author is that all the good intentions of manufacturers can fail completely if the variations in circumstances in underground mining are not considered at all times. With a belief that it is the customer that has the experience and know ledge of problems which occur on long installations. Reilloc talk with customers in coal mines around the world, and have done so from their inception. With considerable experience in their home market, their technical approach was received with enthusiasm by coal companies in both Australia and South Africa, and whilst experience was obtained in other countries, it is the particularly close working relationship in these two areas that is covered in this paper. The refinement of manufacturing techniques and the fine tuning of the specification to which the chain is made was developed in conjunction with factual underground experience obtained by customers as they sought to improve their productivity and a reduction in working costs. With a reliable product the mines are able to concentrate on improved operational techniques to extend the useful working life and plan for multi-panel usage of the chain.

Jan 5, 1996

By R. Phillips

The low concentration of diamond in workable deposits requires very large samples for grade estimation, and results, even then, may be erratic and difficult to interpret. Although the Poisson probability distribution cannot accurately describe the occurrence of diamond, it is suggested that it gives a better estimate of grade than conventional methods, even from single samples. Examples illustrate the simple calculation required.

Dec 1, 1971

Jan 1, 1947

By T. Piirainen, T. Alapieti

"The Koillismaa layered igneous complex is the result of igneous activity that occurred 2436±5 m.y. ago. Its crystallization took place in three separate but connected magma chambers, the total volume of which is estimated at more than 2000 km'. These chambers were located partly in a feeder system within Archaean granitoids and partly in an unconformity between these grani­ toids and Early Proterozoic supracrustal rocks. The composition of the parental magma that initially filled the chambers is thought to have been that of a relatively MgO-rich tholeiite. Sulphides and platinum-group minerals are mainly concentrated in the marginal series of the western part, where they are encountered over a distance of 25 km. This marginal series is an originally nearly horizontal series of rock types that displays a reversed differentiation trend, grading inwards from gabbroic to ultramafic rocks, followed bv rocks of the layered series. The chilled margin is not encountered anywhere in its original position at the contact, probably as a consequence of magmatic erosion, but remnants are to be found in the form of elongated xenoliths. Partly melted siliceous fragments from gneissic country rock typical of the lower part of the marginal series indicate pronounced contamination.Chalcopyrite, pentlandite and pyrrhotite±pyrite are the predominant sulphides. The accessory sulphide minerals include covellite, violarite, marcasite, mackinawite, sphalerite and argentian pentlandite. Platinum-group minerals are represented by froodite, michenerite, merenskyite and sperrylite. Other accessories that have been identified are electrum and native copper and gold. The mean of the Cu/(Cu+Ni) ratio in the mineralizations is 0.67 and Pt/(Pt+Pd) 0.31.It is suggested that the sulphide phase was formed in the marginal series as the solubility of sulphur in the basic magma was lowered by contamination, possibly assisted by some other factors. The sulphur isotope data support the juvenile origin of the sulphur."

Jan 1, 1984

By R. R. Liebenberg, M. I. Brittan

The kinetics of the copper segregation process has been investigated. The experimental strategy used to isolate the rate-controlling reaction step is described. This step was found to be the chloridisation of the oxide copper minerals in the ore. The link between the rate of chloridisation and the overall rate of segregation is demonstrated experimentally. The influence on the kinetics of the various parameters in a TORCO system is examined and the implications are discussed

Dec 1, 1971

Discussions of the papers with a written contribution on Paper No. 11 and authors' written replies. Also brief obituary of Dr. T. David Jones on p146.

Jan 1, 1947

By NA NA

A round up of recent industry matters. Davis Derby acquisition of Safecom UEP Ltd. Record Output by Longannet Mine.

Jan 7, 1997

By L. J. Barnes, R. O. Koch, J. H. Versteegh, P. J. H. Scheeren, F. J. Janssen

Following two years of laboratory research with bench scale reactors, a 9 m3 experimental process demonstration reactor was installed at Budelco's zinc refinery to treat their underlying groundwater. A 600-fold scale-up was successfully achieved. It has demonstrated that this anaerobic microbial process can remove a wide range of heavy metals and sulphate to the required levels. Extended operation of the demonstration unit has shown that the process is robust, can withstand wide variations in feed composition, rapidly recovers from operational upsets and is easy to start up and shut down. The metal sludge produced can be processed in a metal refinery to recover both metals and sulphur.

Jan 12, 1992

By G. H. Blackwell

Sequences in open pit mining must be planned and regularly revised to incorporate changes in the variables which affect profitability. Interactive computer planning with colour graphic facilities is an effective tool for this purpose in the short and medium term. An interactive computer planning system for medium-size, low grade porphyry copper-molybdenum open pits is described. The planning system proved especially valuable during the critical stages of pushback mining when deep, inner pit ore was nearly depleted and the erratic grades of the next pushback provided ore and marginal material at a time of depressed metal prices.

Jan 8, 1993

By T. J. White, R. A. Farnfield

Early computerised blast monitoring equipment consisted of a digital version of the existing analogue machines with, perhaps, a few enhancements. Many additional facilities have since been developed to enable the efficient collection of high quality data. These developments are examined with reference to digital sampling, triggering systems, the storage of complete recordings and signal processing. Recent advances have been made in the use of blast monitoring systems that comprise multiple blast monitoring locations with centralised control and data collection. Software has been developed to help record blast parameters and assess environmental effects. Computer databases have many advantages over their paper counterparts. Data can be easily retrieved and processed. The scaled distances used in the prediction and control of peak particle velocities can be calculated rapidly when the data are obtained directly from a database. Since the whole vibration signal can now be recorded, signal processing can be used to provide information such as signal length, dominant frequency and response spectra.

Jan 4, 1993

By L. T. Matthews, C. E. Loo

During sintering, porous ore particles are easily assimilated by liquid melt. Two simple models of the process are considered: the dissolution of a solid by a liquid and the penetration of a liquid into a porous solid. Laboratory sintering studies covering a range of experimental conditions were undertaken to characterise the assimilation of large particles of ore and flux by melts formed from different mixes of fines. For ores, the process appeared to be complicated by the detachment of fines from the ore surface prior to melt formation, according to the mass of adhering fines and surface roughness of the particle. This delayed the onset of assimilation and sometimes reduced it, although melt penetration was fast and effective. Studies using different temperature profiles suggested that the assimilation of haematite was controlled by the transport of Fe2O3 away from the surface of ore particles. The assimilation of limestone depended more on thermal conditions than on the three magnesia-bearing minerals considered. Changing the composition of the initial melt significantly altered the extent of assimilation of ores and limestone, but again had a less marked effect on the magnesia-bearing fluxes.

Jan 8, 1992

By D. J. Fray, F. Tailoka

Microporous ceramic tubes (15 micrometre pore diameter) and PVC membranes (10 micrometre diameter) have been used as spargers in the electrowinning of copper from concentrated and dilute chloride electrolytes. At a current density of 600 A/m2 and a nitrogen gas sparging flow rate (at NTP) of 1.53 cm3/s per unit electrode length, it was possible to electrowin planar rather than powdery deposits with copper concentrations as low as 0.157 M. To obtain a planar deposit at higher concentrations of cupric chloride the most realistic optimum current density appears to be between 1 000 and 1 500 A/m2.

Jan 4, 1993

By R. Winand, P. Harlet

he cathodes produced are of electrorefined grade; metallographic structure and surface roughness are controlled to a depth of 1.3 cm (single-side deposits); silver levels in the cathode are regulated by the presence in solution of Cl- and Br- ions; organics must be used at very low concentrations (around 0.1 mg/l with a consumption of about 0.01 mg/l/hr). The required concentrations of additives were established according to a well-defined strategy based on the consumption of organics at the cathode by a mass transfer limited-process.

Jan 4, 1992

By R. G. Siddall, W. Gale

In the UK the development of the science of strata control has been strengthened by a resurgence of interest in the specialism of roofbolting and its associated techniques. The evolution of the theories and practices of strata bolting in roadway stabilisation is discussed. Practical experiences are considered, principally the use of Australian techniques, the relationship between bond strength and annulus and the effects of stress in the ground. Areas of new technology such as cable bolting, injection anchors and on-board bolters are also discussed. The recent advances in computer technology and rock testing equipment and methods have provided the opportunity to simulate ground behaviour under various conditions. Computer modelling developments and the use of techniques to predict ground behaviour are described.

Jan 4, 1992

By R. R. Hart, R. A. Evans

This paper outlines the the methods currently being used in the West Wales Area for preventing the occurrence of any outbreak of spontaneous combustion. Stress is placed on the importance of correlating the position of a Rider Seam which is prone to spontaneous combustion. The recent introduction of the UNOR Recorder has contributed to the ability to monitor the CO content of the general body of the air during any incident. The use of modern sealants and improved methods of applying them have enabled the few instances of spontaneous combustion in South Wales to be treated promptly and efficiently. The authors describe the current spontaneous combustion problems at two collieries.

May 23, 1905

By Groom P.

Discussion of the paper presented at the Midland Institute of Mining, Civil, and Mechanical Engineers' general meeting held in Leeds, March 21st, 1916, with T. Beach, vice-president, in the chair included contributions by Beach T., Fearnsides W.G., Lloyd W.D., Gill J. and Nadin R.

Dec 1, 1916