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By Mozley R

Contaminated sediments are a multinational problem. A crucial factor in solving an environmental problem is knowledge of, not only the amounts of polluted soil, the contaminants involved and their concentration, but also the historical background of the problem. Processing polluted soil is a tailor made activity based on rational decisions resulting from a detailed treatability study. Lack of information about characteristic properties of a specific sludge/pollution combination is the main obstacle in the route from first ascertaining that a particular harbour subsoil is polluted, to final identification of the full scale treatment plant. In the first instance, information must be generated regarding the distribution of pollutants in relation to the distribution of the original geophysical components. Based on this information rational decisions can be made on separation at a particular cutpoint and what sequential techniques should be involved for a certain fraction. For this purpose a `fingerprint method' is presented especially developed for investigation of polluted soil and sediments. The heart of the fingerprint method is a series of sequential hydrocyclone separations, by which a series of products is generated. The objective of the fingerprint method is to select an optimised treatment procedure in which the pollutants are concentrated in as small a volume of material as possible, leaving the bulk of the material clean. The pollutants can then readily be destroyed or isolated from the environment. The philosophy and advantages of the fingerprint method are demonstrated for a harbour sludge containing heavy metals as main pollutants. Hydrocyclone separation combined with flotation of both the coarse and fine fraction resulted in reusable and dischargeable products. Flotation of the fraction of fines was carried out by means of an experimental flotation cyclone enabling the selective recovery of mineral particles with diameters less than 10 microns. The overall conclusion is that design and engineering of treatment flow schemes for polluted dredged materials is a tailor made activity based on rational decisions resulting from the fingerprint information.

Jan 1, 1993

A major problem in the continuous casting of aluminium killed strip steel is the incidence of black and grey lines in the strip surface caused by the alumina inclusions. One place for limiting the number of alumina inclusions is by providing favourable fluid flow conditions in the ladle so that the inclusions float out to the surface or adhere to the ladle wall. In laboratory equipment 20 kg of steel was melted in an alumina crucible of 14 cm diameter in an induction furnace. Deoxidation was carried out while the melt was constantly stirred by argon bubbling. Bubble frequencies were measured at the lance tip using a microphone technique. High speed cine photo- graphy was incorporated to measure melt top surface velocities. Experimental results indicate that the rate of removal of inclusions is a function of both the gas input and the power input. However due to unfavourable surface area to volume ratio, reoxidation of the melt took place. Some other experimental difficulties in working at high temperatures are also discussed such as lance design, melting arrangement and sampling techniques.

Jan 1, 1984

By W A. Ducker, R-H Yoon, M Mao

Froth flotation relies on an attractive force between a particle and a bubble to selectively extract particles from a mixture. The range and magnitude of this attractive force is an area of ongoing investigation. We describe measurements of the effect of dissolved gases on the long-range attractive surface forces between a silica plate and a glass sphere in aqueous octadecyltrimethylammonium chloride (C18TACl) solutions. The measurements follow on the work of Sakamoto et al (2002) who have concluded that long-range interactions occur in air-equilibrated surfactant solutions but not in degassed solutions. In the present work, we have measured attractive forces that have a much larger in magnitude than the expected van der Waals force in solutions that were degassed by the same procedure used by Sakamoto et al (2002). We find that the forces are most attractive at 5 + 10-6 M C18TACl, which is close to the charge compensation point (ccp) of the glass sphere. At this concentration, the attractive force decays exponentially with distance and the decay length is 34 in air-saturated solution, and 38 nm in degassed solutions. In both air-equilibrated and degassed solution, the force is quite sensitive to the concentration of surfactant. The force is also sensitive to the pH. We note that our degassing procedure increases the pH of the solution from about 5.7 to 6.6 (presumably by removal of dissolved CO2). We find that the forces measured in degassed solution can be reproduced by using a solution that was equilibrated in air, then the pH was increased by addition of NaOH. Therefore, we conclude that the main effect of degassing in our experiments is to raise the pH. We show that the range and magnitude of the attractive force decreases in the presence of salt (NaCl). This suggests an electrostatic mechanism for the attraction. Possible mechanisms for the attractive force are examined, including the mechanisms that rely on a patchy coverage of surfactant on the silica surface.

Jan 1, 2005

By Phillips D. N, Herbert H. K, Fletcher A. C, Lewis R. K

Quartzite is a common feedstock used for the production of silicon by reduction at high temperatures in a submerged electric arc furnace. Silica fume, formed as a by-product in this process, contains crystalline silica in the respirable fraction. The crystalline silica in the fume represents entrained quartz derived from unreacted quartzite raw material within the furnace. A knowledge of the fragmentation of quartzite feedstock, in response to thermal disaggregation in the furnace, is important in feedstock selection to help minimise (a) the amount of crystalline silica in fume, critical from an occupational health and safety perspective, and (b) impurity levels necessary to achieve the highest possible purity of product silicon. In this study, a series of quartzites has been assessed in terms of the above requirements and correlations drawn between mineralogical and chemical characteristics. Alkaline solubility correlates with grain-size and level of stored strain in the quartz matrix. Grain-size affects the surface area available for attack while stored strain enhances the chemical reactivity of the strained matrix as well as profoundly influencing the disaggregation and microfracturing characteristics of strained grains and, hence, available surface area for chemical reaction.

Jan 1, 1995

By Cox N

Fragmentation control is perhaps the most critical aspect of quarrying operations, potentially impacting on the costs of all down stream processes, and sometimes even on the economic viability of an operation. The focal points of studies to control fragmentation are generally the pattern of blastholes, the accuracy of drilling, and the most appropriate powder factor. Recent studies suggest that the performance, and consistency of performance, of explosive detonation in the blastholes may also be a significant factor impacting on blast performance in hard rock quarries. This paper presents the results of studies of bulk emulsion and watergel explosive performance, using blasthole velocity of detonation measurements, and its impact on fragmentation. Field studies show a strong correlation between blasthole VoD and blast fragmentation. Another aspect of explosive performance impacting on ease of excavation of blasted rock is muckpile displacement, from which estimates of effective heave energy have been made for different bulk slurry (emulsion and watergel) products.

Jan 1, 1995

By Hohnen CA, Limerick JM, Hall DRT

An uniquely-designed flash furnace for smelting of nickel concentrate and for the recovering of metal values from the slag generated has been in successful use for nearly six years. Within the last eighteen months the ability of the furnace to treat slag arising from converting operations without significant reduction in capacity has also been successfully demonstrated. Previously, converter slag had been treated separately in an electric furnace. The salient features of smelter developments are outlined and slag chemistry is discussed. The low cost method for the introduction of coal to partially replace light fuel oil is reviewed and total energy requirements evaluated.

Jan 1, 1984

The physical phenomena which influence gas flow in the bosh and hearth of a blast furnace are discussed including the hold-up of slag as a mechanism which can result in a flooding condition. An equation is defined which describes the limitation to wind volume arising from the flooding condition. Implications of the various factors influencing bosh and hearth gas flow on furnace operation are discussed. Coke quality is shown to be the most important factor in the aerodynamics of these zones and coke requirements are defined for the Port Kembla No. 5 BF which has an inner volume of 2670 m3.

Jan 1, 1975

Blasting is known to be both an important and an easily quantified cost factor in rock breaking operations. However, the indirect costs and benefits of the blasting operation are not easily determined due to the irreversibility of the mechanisms involved and the multiplicity of influencing factors. A general conceptual model showing the relationship between blasting and mining costs is well known, but serious attempts to address the critical real relationships have all floundered on the fact that not enough is yet known about either detonation physics or blasting effects. This can only be remedied to the extent that blasting instrumentation enables researchers to pin down not only the relationship between the detonation process and its impact on a particular environment, but also the downhill costs of handling the rock, repairing any damage and building in "Safety Factors" to provide for imponderables. It is vital to standaraize on specifications for instrumentation and measurement techniques and there is a need to review what has been achieved in blasting expertise so as to focus on the most fruitful paths for future work.

Jan 1, 1990

By Fletcher G

This paper will outline the design process, and the constmction and rehabilitation techniques proposed for the external waste dumps associated with the mining of the Wolfang Basin coal measures.The basin is located to the north of Clermont and immediately west of the Bowen Basin in Central Queensland, Australia. Development of the Clermont Coal Mine is planned for the mid-1990s after adequate sales commitments are obtained to allow the project to proceed.

Jan 1, 1992

By Botz R. W

Macroscopic and microscopic studies of the outburst-prone Gemini Coal (Bowen Basin) showed that outbursts were associated with a localized inertinite-rich ply. Previous studies of the Gemini Coal had shown a general relationship between desorption rate, regarded as a good measure of outburst proneness, and inertinite content of coal samples.Desorption rates increased with increasing inertinite content and were highest for inertodetrinite-rich samples. These results suggest that inertinite content and composition play a significant role in outbursting and may be useful in identifying outburst-prone coals, which could be confirmed by desorption measurements.Consequently outburst-prone areas in the Upper Permian coal measures ofthe Sydney, Gunnedah and Bowen Basins have been defined using a combination ofthe parameters, inertinite content, depth ofcover and coal rank. In the Upper Permian, inertinite-rich coals are confined mainly to the top of the coal measures, except in the Sydney and Gunnedah Basins where an inertinite-rich interval (Bayswater Coal and correlatives) is also present towards the base of these measures. Only a small area ofthe central Sydney Basin, butmuch ofthe north-eastern and north-central part of the exposed Bowen Basin is considered outburst prone on the basis of these parameters.The most outburst-prone inertodetrinite-rich lithologies have a patchy and unpredictable distribution in the top of the Upper Permian coal measures. They can be defined only by sampling and petrographic analysis at the subsection level.

Jan 1, 1986

Major changes occurred in the management of loss prevention and risk management at operations in North and South America due to increased insurance premiums following the Olympic Dam fire in Australia in 2001. There are many different scenarios on how fires can develop and the estimated maximum losses (EML) those fires can incur. The EML is utilised by insurance companies to determine the cost of insurance premiums. The cost of insurance can be controlled at existing and newly designed solvent extraction (SX) plants by using risk reduction methods and design criteria to limit the fire exposure. A review of data collected during several loss prevention risk assessments can show how a budget can be protected from dramatically increased premiums and see which design of SX plant and fire protection standards best apply to your operations. The paper will investigate the pitfalls of existing materials of construction, capacity, geography, management practices, fire risk minimisation, and fire suppression systems. Intelligent engineering and managerial improvements implemented by the operations in the Americas in the past two years have further minimised the fire potential and benefited companies in insurance renewal negotiations.

Jan 1, 2003

By M Surtees

The Limpopo region in southern Africa is considered to be a favourable target for the discovery of base and precious metal mineral deposits. The integration of gravity, geomagnetic, LANDSAT data and geotectonic history is used to formulate an ore deposit model which can be used in the implementation of mineral exploration programmes. Field work was carried out to test and refine the model.

Jan 1, 1993

By M Darvall And R Fare, D Dormer

The Argo Archaean lode gold deposit is hosted within a structurally complex shear zone system, 70 km south of Kalgoorlie, and 3 km west of the crustal-scale Boulder û Lefroy Fault. Argo is an active underground mine currently producing at a rate of 120 koz pa with a Probable and Proven Reserve as at December 2005 of 2.19 Mt at 5.94 g/t Au (419 koz), a reduction on the December 2004 Probable and Proven Reserve of 4.58 Mt at 5.74 g/t Au (845 koz). This Reserve is hosted in six separate gold bearing lodes within the Argo shear system. Presently, a further six subeconomic shears are recognised. The 2005 Reserve figure represents a reduction of 426 koz compared to the 2004 Reserve as a result of a thorough review of the geological interpretation/resource model, and engineering factors applied to the Resource/Reserve, and depletion due to mining. Year on year Resource/Reserve figures at Argo had gradually increased as additional information on the system became available and mining methods were increasingly resolved with early production. The portal for Argo underground mine was cut in June 2002 within the highly profitable Argo open pit. The proposed æAvocaÆ bottom-up mining method required extensive lead time between development and the commencement of stoping in April 2004. During development considerable additional complexity in the Resource was encountered. Additional structures were identified, and complex splay interactions affecting the geology impacted on development. Intensive concurrent exploration in the footwall to the main lode during this period was the main cause of the increase in the Resource/Reserve figures during early development. As development progressed, lower grade continuity was observed than was previously interpreted. At the same time, drilling of deeper portions of the deposit and subsequent reinterpretation of the geological model significantly reduced strike lengths of economic mineralisation. Radical changes to the mining methods were required to improve productivities and to satisfy geotechnical considerations. The changes altered the engineering factors applied, which resulted in a reduction in the Reserve figures.

Jan 1, 2006

By Wygralk A, Hallenstein CP

On a world scale, many Mid-Proterozoic fluvial sediments are prospective for low grade, large-tonnage gold deposits. A significant area of the Northern Territory is covered by such Mid-Proterozoic sediments, the gold potential of which has been barely tested. The geological knowledge of these sediments is summarised. The Westmoreland Conglomerate, the basal Mid-Proterozoic formation of the McArthur Basin, has been subjected to detailed sedimentological studies in order to determine the paleoenvironments and to assess the possibility of paleoplacer occurrences. The results indicate that the sandstones and conglomerates of the formation were deposited by braided rivers and debris flows as an alluvial fan which originated in source areas to the north east. The formation contains several upward-fining cycles of sedimentation, which are related to repeated periods of uplift in the source areas. The formation of placer-type gold occurrences is possible in such depositional environments. Very limited heavy mineral sampling has indicated a cassiterite- wolframite-gold suite in the sediments of the Westmoreland Conglomerate. Disconformities at the base of sedimentation cycles are deemed to be the most likely sites for large-tonnage paleoplacer concentrations.

Jan 1, 1984

According to our experimental results, the following oxygen probe recommended, that is, the magnesia stabilized zirconia was employed as a solid electrolyte and Fe.FexO solid elect- rode was used as a reference electrode. Using such an oxygen probe, we tried to measure the oxygen potentials in molten metals, mattes and gases in the following fields of non-ferrous metal industry, molten copper in the side launder before casting, molten crude lead in the forehearth of ISP blast furnace, molten copper mattes in the forehearth of blast furnace and in the settler of flash smelting furnace, gas in the settler of copper flash smelting furnace and flue gas in the electric furnace for ferro-silicon. In the past ten years or so, many experi- mental results in the field of fundamental studies have confirmed that the equilibrium oxygen potential could be measured conveniently and accurately by an electrochemical method using a zirconia solid electrolyte. Recently, such an electrochemical technique has been also applied to a device for physicochemical invest- igation or process control in the non-ferrous metal industry. Such a device consists of an oxygen con- centration cell with stabilized zirconia, and it is commonly called an "oxygen probe" or "oxygen sensor".

Jan 1, 1980

Production scheduling is an important element of the mine planning process. The production schedule specifies the quantities of mineral to extract, the source of this ore, the timing of extraction and, where necessary, the quantity and timing of backfill placement. These details are important in linking long-term strategic goals to short-term operational planning. Mine scheduling techniques form the basis for communicating information concerning the overall impact of design and planning changes to a wide range of people at many levels within an organisation. Consequently the techniques used for mine scheduling must support the decision-making process by consistently providing high quality schedules in response to revised and updated data. A new mixed integer programming (MIP) model has been developed to generate optimal production schedules for underground stoping operations. The model maximised the before-tax Net Present Value of the production schedule while satisfying constraints such as contained metal tonnage, hoisting capacity, stope geometry relationships and stope backfilling demands. Zero-one variables were used to represent the decision to extract or backfill each stope in a particular time period. Continuous variables, capable of having non-integer values, were used to denote the quantity of ore or backfill associated with a specific stope in a given time period. A case study is presented to demonstrate the significant improvement in before-tax NPV over a comparative manual production schedule in a large underground mine. The MIP model allows for further modification to reduce solution times and meet the needs of individual mines.

Jan 1, 1995

By Ishikawa K, Kikuchi T, Tokairin Y

Roadheader, developed from coal cutting machines, is generally classified as a tunnel excavation machine for soft rocks in respect to excavation mechanism, machine structure, weight, engine output and so on. In recent tunnel works, however, there is an increasing demand for changing from blasting to mechanical excavation by roadheaders to avoid environmental problems such as noise and vibration. But there exist various difficulties in excavation of harder rocks by roadheaders. In order to explore the possibilities of roadheader excavation, we performed field and laboratory experiments. In the field experiment, roadheader model S-125 (Mitui Miike Machinery Co.,Ltd.) was tested for various rocks of wide range of hardness, and excavation capacity and wear of picks were measured. In the laboratory test, cutting performance of the picks was tested by our cutter testing machine. This report describes thr: of these experiments and discussions :n possibility of applying boom-type tunnelling machines to hard rock excavation based on these experimental data.

Jan 1, 1987

By M Roper, M Lovitt

WMC Resources Olympic Dam Operation located in South Australia, is a poly metallic underground sublevel open stoping (SLOS) mining operation with a current annual production rate in excess of 9.0 Mt. Stope size, geometries, geotechnical considerations, drilling and blasting are critical components in stope performance. These factors are further influenced by stringent ventilation requirements due to the presence of airborne radioactive contaminants from uranium mineralisation. Stope planning is complex and mass blasting methodologies have been trialled at Olympic Dam with the view to reducing the frequency of stope blasts, improving stope stability, productivity and ultimately improving overall stope performance. A key aspect in the ability to undertake underground mass blasts of this scale is the application of i-konTM electronic initiation technology by Orica. In the past two years in excess of three million tonnes has been initiated utilising this electronic technology, with an average blast of 250 000 t ranging to the largest to date being 580 000 t. By providing flexibility in blast designs, the use of electronic detonators has allowed mass firings over multiple sublevels. This has resulted in a significant reduction in stope extraction steps compared to conventional pyrotechnic firings. The benefits of this reduction in the number of stope blasts are wide ranging from improved stability of interim stope voids between blasts, reduced blasthole damage, improved blast vibration management and reduction of complex changes to ventilation systems for blasting.

Jan 1, 2004

BECAUSE of the attention given in recent years to the flotation process, there is an extensive range of equipment available to any staff detailed for: the design of a flotation mill. This statement applies not only to the flotation machines, but also to equipment for crushing and grinding, elevating the pulp, dehydrating of concentrates, and the methods of driving the various equipment.Distributed through the Proceedings and Transactions of various metallurgical societies and journals there are many excellent descriptions of flotation mills, their equipment and performance.Whilst these articles describe-in many cases in detail-the equipment in the mills to which they refer, the reasons which govern the choice of each particular equipment are not usually given.

Jan 1, 1929

Surface oxidation is one of the most important factors that influence the flotation selectivity and recovery in the processing of complex sulphide ores. It is an inherent part of surface chemical reactions that determine whether the surface film formed on a sulphide mineral will act as a hydrophobic or hydrophilic one. Because of the highly complex surface chemistry and mineralogy involved the results of flotation tests may often be difficult to interpret. In this paper, the flotation behaviour of nickel-copper ores processed in the Sudbury area is discussed with emphasis on the effect of oxidation on individual minerals, primarily pyrrhotite. In general, moderate oxidation of a freshly ground ore promotes the flotability of all principal sulphides in the ore leading to a bulk flotation concentrate. The ease of individual mineral flotability under normal aeration conditions, which is chalcopyrite > pentlandite > pyrrotite, changes to pentlandite > chalcopyrite > pyrrhotite under oxygen-deficient conditions. This behaviour is correlated with the catalytic activity of these minerals for oxygen reduction. On the other hand, preferential oxidation of pyrrhotite may lead to a selectivity increase in flotation. Such a behaviour has been noted in the flotation of a pyrrhotite-rich process stream. The results have been discussed in the light of fundamental electrochemical interactions involving pentlandite, chalcopyrite, pyrrhotite, pyrite and grinding media and a mechanism has been proposed to explain the selectivity.

Jan 1, 1993