Search Documents

By Amer S, Novais A. Q, Limpo Gil J

A proprietary hydrometallurgical ammonium chloride process for the recovery of not only zinc, but also copper, lead and silver from sulphidic zinc-rich concentrates has been developed at bench scale by CENIM and INETI (ex-LNET) as part of a research project supported by the Commission of the European Community (DGXII). This paper deals with the innovative chemical aspects applied to this chloride process and also with the more relevant data relating to mass balance, heat balance and process economics. Under mild temperature and oxygen pressure leaching conditions it is possible to extract practically all the zinc together with the other metals of interest and to precipitate simultaneously the solubilised iron fraction as goethite. The pH is kept close to neutrality in spite of the ammonia released in the leaching of the non-ferrous sulphides. A buffer effect is observed mostly due to the formation of zinc ammines which are very soluble in this medium. The zinc is further extracted by D2EHPA, the acidity being neutralised by the ammonia. Most of the ammonium chloride is naturally regenerated in this step. The zinc is recovered as zinc cathodes in a conventional sulphate electrowinning circuit. All the main raw material consumptions excluding the concentrate, such as oxygen, lime and ammonium chloride are linked to the sulphate formation in the leaching step which must be kept as low as possible by decreasing the reaction time under neutral conditions. The process analysis is complemented by the economic evaluation of a reference case. Difficulties encountered in finding a more convenient method of assessing the economics of the process in the absence of a reference price for a complex sulphide concentrate are examined and discussed. The reason why this analysis was performed with a much more optimistic metal prices scenario is also highlighted. The process economics are primarily dependent on the zinc market quotations and of course on the concentrate cost. Around 70 per cent of the total revenue is due to zinc sales. Assuming an internal rate of return of 17 per cent, the price of the concentrate can be as high as 255 $US/t for a plant capacity of 320 000 t/y (90 000 t/y of zinc).

Jan 1, 1993

By Zamel GI

The utilisation of fossil fuels, including coal (of which Australia is a large producer and exporter) is a significant contributor to the emission of greenhouse gases. Methane gas, formed during the coalification process, is present in coal seams to varying levels depending on the rank and depth of the deposit. This gas usually escapes to the atmosphere during mining operations without prior conversion to C02 or utilisation as fuel. The quantity of methane released can represent from less than one percent to more than five percent of the carbon content of the coal mined. Per unit of carbon, methane has a greenhouse impact many times that of C02. The emission of uncombusted methane to the atmosphere can therefore represent a greenhouse impact of similar porportions to that of the CO2 formed by combusting the mined coal. However, greenhouse emissions from coal can be minimised by collecting the coal seam methane and converting it to water vapour and the less damaging form, CO2. If such conversion is carried out while performing useful work, the methane can further reduce greenhouse emissions by displacing other fossil fuels. Technology has been developed to allow coal seam methane gas to be economically collected in a pure form, uncontaminated with air. This pure methane can be used to supplement natural gas supplies, to generate power or for the production of chemicals or substitute transport fuels. By collecting and utilising coal seam methane, the greenhouse impact from the mining and use of coal can be minimised, with significant reductions possible in the case of gassy deposits.

Jan 1, 1989

By S A. Prevec

"An EXTENDED ABSTRACT is available for download. A full-length paper was not prepared for this presentation. Traditional models employed to genetically link associated chromite and platinum-group elements have favoured crustal contamination as the primary process for inducing sulfide and oxide saturation. The association of chromite ores with crustal contamination is well established in the literature. However, in the 1970s (cf Irvine, 1973, 1975), Irvine demonstrated that crustal contamination was in fact problematic as a tool for inducing chromite precipitation in mafic to ultramafic magmas. His results are re-examined here, along with some attempts to reconcile them with the effects of adding Fe to the models. It is concluded that crustal contamination is indeed problematic based on phase relationships alone. However, the role of fluids as a compensating agent is evaluated, which may explain why crustal contamination may indeed facilitate oxide and sulfide precipitation.CITATION:Prevec, S A, 2015. Chromite and platinum-group elements coprecipitation by crustal contamination or magma mixing revisited – genetic and exploration implications, in Proceedings PACRIM 2015 Congress, pp 311–316 (The Australasian Institute of Mining and Metallurgy: Melbourne)."

Mar 18, 2015

Although the bromo-cyanide or Diehl process for the extraction of gold from its ores is used on several of the Kalgoorlie mines, very little information has been published on the original process, and no details are available from the various mines now using it. The following description of the process as carried on at the Hannan's Star plant, where several modifications were introduced by the author, will therefore be of interest to mining men, and it is hoped that some discussion on this paper will provide further useful information to the mining community.The process was first installed on the Hannan's Star mine, where a full working plant was erected by the London-Hamburg Co. In their contract they guaranteed a 91 per cent. extraction on a sulphide ore of 15 dwt value. This was considered a very high extraction at the time, and the plant successfully carried out its work.The new features in the process were the finer grinding of the ore, for which purpose the tube mill was introduced, and the addition of a solution of bromo-cyanide to the vats under ordinary cyanide treatment, whereby a higher extraction was obtained in a shorter time. The main difficulty in the process was the easy manufacture of the bromo-cyanide solution, but this was eventually overcome. The mixed salts now supplied by the LondonHamburg Co. are in every way satisfactory, and are supplied at such a price that the process compares favourably with any other from a cost point of view.

Jan 1, 1907

By S F. Simmons, A McOnie, J L. Mauk

Three cross sections, 200 m apart, display the distribution of indicator hydrothermal minerals across the Empire zone of the Golden Cross epithermal Au-Ag deposit, Waihi, New Zealand. These minerals are used to interpret the temperature and composition of hydrothermal fluids. The distribution of interstratified illite-montmorillonite and illite indicate that temperatures ranged from 140 to >220¦C, with temperatures above 220¦C predominating. The mineral assemblage of quartz-adularia-chlorite-illite-calcite-pyrite envelops the Empire vein system and stockwork, and reflects formation from an alkali chloride water whereas the mineral assemblage of replacement calcite-interstratified illite û montmorillonite-kaolinite forms a carapace and reflects formation from a CO2-rich steam-heated water. Alkali chloride waters appear responsible for the epithermal Au-Ag mineralisation.

Jan 1, 1995

By Hayward P. G

Complex ores, characterised by intimate intergrowths between minerals, have previously been treated by flotation with limited success. The most common problem has been that the liberation size is often finer than the lower size limit for selection flotation. A technique has been developed in which the problem is overcome by the use of a selective agglomeration procedure in which the values are coalesced with oil to a size suitable for flotation prior to introduction into the flotation machine. A complex lead ore was characterised by QEM*SEM mineralogy as having a mean galena liberation size of 15 ¦m. The best recovery of lead at 50 per cent Pb grade by standard flotation was 53 per cent. After application of the procedure, 86 per cent recovery was obtained after a single cleaner step. The oil functions as a bridging liquid in the presence of conventional collectors which render the mineral oleophillic.

Jan 1, 1991

By K C. Corin, C T. O’Connor

In recent years it has been shown that the concept of using partial molar excess Gibbs energy (G̅ex) to explain the behaviour of collectors in the recovery of minerals can be usefully applied to explain flotation performance. Fundamentally this is because hydrophobicity of a mineral particle on which a collector is adsorbed may be strongly related to the fact that the alkyl chain associated with the collector behaves in the same way as any hydrocarbon would in an aqueous medium. This hydrocarbon-water system represents a classical non-ideal mixture, and such mixtures are quantified thermodynamically by determining the activity coefficient of the hydrocarbon moiety of the collector and hence its G̅ex in the mixture. It has been shown that G̅ex is a more rigorous indicator of the contributions of various alkyl groups of a collector than HLB (Corin and O’Connor, 2014) and was also able to explain aspects of froth behaviour (Harris and O’Connor, 2017) and hydrophobicity (O’Connor, 2021). The present paper is aimed at extending the above concepts in two different ways. Firstly, a study is undertaken of a range of results previously reported in which various reagents containing different alkyl groups were analysed in terms of their effect on contact angle and their performance as flotation reagents in terms of recovery. These results sustain the previous observations that there is a robust positive relationship between hydrophobicity as indicated by flotation recovery and contact angle and G̅ex of the alkyl group associated with the collector. Secondly, on the basis of the observation that increases in G̅ex are indicative of increases in the hydrophobicity of the mineral particle-collector aggregate, a study was undertaken to examine the effect of ions typical of electrolytes in water as well as the effect of the presence of alcohols and of pH on G̅ex of the collector alkyl group. In the former two instances the absence of any correlation between G̅ex and recoveries supported the proposition of the respective authors of these studies that the major effect of these electrolytes and added alcohols may be on particle–bubble attachment rather than on the hydrophobicity of the mineral/collector in the aqueous system. On the other hand, the effect of pH on G̅ex correlated reasonably well with changes reported in the literature on the effect of pH on recovery and contact angle.

Aug 24, 2022

By D W. Stevens

Mechanical sampling provides a definitive value for the product sampled but the results are not instantaneous, meaning that decisions on process control can only be made hours after the sample is taken. Chemicals are added, tailings are sent to waste, stockyards are laid and the data for the decision-making is historical. Online analysers provide instantaneous information, allowing operators to make immediate and cost-saving decisions on the process. However, pending the specific online analysis application, there is a need for reference sampling for dynamic calibration/bias updating of the analysers so that they can deliver the desired precision and accuracy. What would be the economic justification for combining mechanical sampling with online analysis to reduce laboratory costs and provide immediate process control with certainty of accuracy? Approved sampling according to the Theory of Sampling, with immediate process control information.CITATION:Stevens, D W, 2014. Justification for integrating mechanical sampling with online analysis, in Proceedings Sampling 2014 , pp 135–138 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 29, 2014

By Glastonbury J. R

Commercial operation of the Sherritt Gordon process in Australia for the leaching of nickel sulphides has promoted an investi- gation of the factors which influence extraction kinetics. This portion of the investigation has been directed towards the physical and chemical nature of the concentrate and the physical evi- dence of the mode of extraction. Details of the particle size distribution, mineral composition and chemical composition are given. The dis- tribution of various minerals in different size fractions and magnetic fractions is discussed. An electron microprobe was used to determine the composition of individual grains in the concentrate. The solid residue from an ammonia oxi- dation leach was subjected to microphotograph- ic examination, X-ray diffraction analysis and scanning by an electron microprobe. Clear evidence was obtained for a shrinking core mode of kinetic extraction with an amorphous iron oxide product layer contrary to previous reports that the latter is pseudomorphic with the original mineral.

Jan 1, 1973

Now that Japan has achieved a remarkable high growth and joined the ranks of economic powers, she is required to take a stance proper to her new position toward international co- operation among Western advanced countries, economic/technical aids to Southeast Asian and Pacific LDCs, and others. As a field subject to such international cooperation programs, the development/use of coal resources has been winning increasing attention in recent years. Coal is positioned as one of promising alternative energies. With Southeast Asia plus Japan and the EEC serving as the two nucleus polar regions, total coal demand in the free world is projected to jump 37% in the year 2000 from the present level and steaming coal imports in the world, primarily destined for power generation, almost double the 1983 level. Such being the situations, Japan's tech- nologies related to coal resource development, if successfully introduced into coal-producing countries to help them boost their production, can directly lead to international cooperation that Japan is now required to fulfill. At home, however, the Japanese coal industry has been just on the wane due to various press- ing problems, such as wider differentials between overseas and domestic coal and deeper/ remorter mining. The industry was named atop in a list of the industries requiring restruct- uring at a meeting of the Economic Structure Study Committee held prior to the decision- making of the 8th coal policy, which slashed coal production planned for the last fiscal year of its life to some 10 million tons, a drop of as much as 50% from nominal output planned in the 7th policy. Under such circumstances at home and abroad, a pioneer study has been under way since fiscal 1984 as part of Japan's energy cooperation in the Pacific. The study is based on the Pacific coal flow concept hammered out by the Agency of Natural Resources and Energy of the MITI.

Jan 1, 1987

By S J. Henderson

Pumped co-disposal of coal processing waste was promoted in the 1990-2000s as a low-cost highperformance alternative to tailings dams. In particular it would avoid high up-front capital for rejects trucks and dam embankments, and would produce a combined waste deposit with better geotechnical properties than either coarse rejects or tailings. Overall, the promise was not delivered; in particular, upon discharge the waste segregated by size, and operators responded by moving the coarser waste to contain the finer waste. In consequence, not only did design analysis lag behind construction, but some of the initial expectations persisted with the result that analyses did not fully represent what was occurring on the ground. After more than twenty years inspecting, designing and tending Co-Disposal Areas (CDAs), it is apparent that they are essentially upstream constructed tailings dams with some more favourable aspects but also a few unique quirks. Although waste management technology has moved on somewhat, the high cost of changing CHPP waste circuits means that most mines with pumped codisposal will continue to discharge mixed waste slurry into CDAs. It is therefore worthwhile to share some lessons in the hope of promoting sounder design, operation and rehabilitation. These include: • Discharged waste does not form a homogeneous wholly competent deposit but instead comprises materials ranging from sandy gravel to silty clay with the distribution determined by movement of the discharge and decant structures; • CDAs circulate and contain a lot of water; • As a result of the first two points, some areas of the CDA comprise saturated fine waste that is no different from tailings and, like tailings, often behaves in an undrained manner; • Seepage is inevitable and desirable because strength improves as water is removed. However, stability is strongly impacted by pore pressures and in design these need to be rationally rather than optimistically considered; • As CDAs are built to about 40m or higher, strength-deformation characteristics of the foundation become more important; • Even if geomechanically stable, CDAs will need covers to prevent salts and acids from reaching the surface; and • Erosional stability of the cover material(s) will probably dictate maximum slopes for rehabilitation.

Jul 1, 2021

By H Han, X Wang, T Li, D Duan

"In this paper, the reduction and separation behaviour of iron and slag in carbon composite iron ore pellets has been investigated experimentally using an electric resistance furnace simulating a rotary hearth furnace process. The factors that affect the formation of iron nuggets, such as temperature, holding time, molecular ratio of C/O and basicity, are discussed. Results show that the reduction of iron ore, carburisation of reduced iron and the composition and quantity of slag are very important for producing iron nuggets. Through optimisation of process parameters, iron nuggets can be formed below 1300¦C when holding time is 20 minutes, C/O is 0.7 and basicity less than 0.5. This study provides a theoretical and technical basis for iron nugget production.CITATION:Duan, D, Han, H, Wang, X and Li, T, 2013. Iron nugget production technology in rotary hearth furnace process at lower temperature, in Proceedings Iron Ore 2013, pp 363-368 (The Australasian Institute of Mining and Metallurgy: Melbourne)."

Aug 12, 2013

By Bolton G. C

Experiments were conducted to access the feasibility of removing zinc from lead slag by sulfation or chlorination or both. Gaseous sulfation with sulfur dioxide and oxygen released only 50 per cent of zinc even under the most severe conditions. Sulfation with concentrated sulfuric acid by a fast-leach process released 95 per cent of zinc while pug-roasting released a maximum of 78 per cent of zinc. Chloridization with NaCi in the presence of sulfating gas released 50 per cent of zinc, while direct chlorination with chlorine gas and oxygen released 85 per cent of zinc and 100 per cent of lead in a chloride condensate containing little impurities.

Jan 1, 1980

By P Minkkinen

"Pierre Gy showed in his early works that the results in estimating the variance of the mean value of continuous lots depends on sampling mode (random, stratified or systematic), except in the theoretical case that the measurand is randomly distributed in the lot. The experimental variance estimate calculated from samples taken from the lot is independent of sampling mode but depends on sample size and the type of the lot heterogeneity. Variography can be used to estimate the variance of the lot mean for different sampling modes.Gy also defined weighting error, which is made if a simple average is calculated from the assays of samples taken from a continuous object (eg from a process stream) where the flow rate varies with time and is correlated with the concentration of the analyte in the stream.The effect on sampling uncertainty of the three sampling modes and their interaction with the following factors in estimating the uncertainty of the mean concentration is studied using simulated lots, and lots having heterogeneity patterns similar to those of real data sets, including the effect of: the type of heterogeneity (random, grading and clustered heterogeneity patterns) increment size and number employing composite sampling weighting error. CITATION:Minkkinen, P, 2017. Dependence of the variance of lot average on the sampling mode and heterogeneity type of the lot, in Proceedings Eighth World Conference on Sampling and Blending, pp 319–330 (The Australasian Institute of Mining and Metallurgy: Melbourne)."

May 9, 2017

By P Alspach, R Buxton, C Morgan, C Ross

Mining companies worldwide have an increasing interest in restoring indigenous ecosystems following mining. Low levels of plant nutrients and organic matter, pH extremes, heavy metals, physically challenging media, and difficult climatic conditions all hinder revegetation of steep rockdump slopes. Our techniques use colonising pioneer plants to accelerate natural soil development and plant succession processes on minesites that are difficult to revegetate with locally sourced plants by traditional techniques. Suitable treatments and pioneer species must first be identified for each rocktype. Field trials at the Stockton Coal Mine in Buller have shown that successful acceleration of moss and pioneer plant establishment is possible. Best plots showed a mean of 15 per cent moss cover and 3.3 per cent vascular cover after 12 months compared with 0.1 per cent and nil respectively for controls. Techniques have been extended to field-scale trials, using hydroseeders and dryblowers. These techniques show potential for practical land rehabilitation, whilst conserving local biodiversity.

Jan 1, 2003

By T Mizuta, T Nakano, D Ishiyama

The Tamagawa Hot Spring, from which Ra-Pb-Sr-bearing barite precipitates, is a representative hot spring in a volcanic gas-bearing hydrothermal system associated with Quaternary andesitic to dacitic magmatic activity beneath the Yakeyama Volcano. Thermal water in the Tamagawa Hot Spring is divided into three types: Cl-SO4-type (Ohbuki hot spring: pH 1.2); SO4-type (pH 1.8 to 2.9); and neutral-type (pH 6.1). The concentrations of dissolved components in the Ohbuki Cl-SO4-type thermal water are about ten times higher than in the SO4-type thermal water. The 87Sr/86Sr isotopic signatures of the Ohbuki Cl-SO4-type thermal waters (0.703992 ¦ 0.000004 to 0.704032 ¦ 0.000006) are different from those of SO4-type thermal waters (0.704245 ¦ 0.000003) formed by the interaction of andesitic volcanic rocks (0.704065 ¦ 0.000007 to 0.704093 ¦ 0.000009) and groundwater derived from river water (0.704314 ¦ 0.000012 to 0.704519 ¦ 0.000013) in a shallower part of the hot spring area. The possible origins of Sr in the Ohbuki Cl-SO4-type thermal water and in the SO4-type thermal water are different. The Sr isotopic ratios (0.704130 ¦ 0.000012 to 0.707556 ¦ 0.000014) of Aniai Formation andPreYakeyama Lake deposits occurring below the hot spring area are distinctly higher than those of the Cl-SO4-type thermal water. However, it is expected that a solidifying andesitic or dacitic magma which has similar Sr isotopic ratios of the Ohbuki Cl-SO4-type thermal water, occur in the deep portion of the Tamagawa Hot Spring. The Cl-SO4-type thermal waters having low Sr isotopic ratios do not acquire their Sr isotopic signatures by interaction with strata below the hot spring area, but they are likely to reflect water interaction with a solidifying magma with low Sr isotopic ratios. Components including rare metals in Cl-SO4 type thermal water could be transported from a deeper part. An EXTENDED ABSTRACT is available for download. A full-length paper was not prepared for this presentation.

Jan 1, 2008

By C Sylvestre

For the last 50 years, traditional safety management has improved safety performance by: • Fixing the environment (eliminating the hazard). • Improving the system (more/less rules, procedures etc). • Making safety more conscious (more/better interactions about the importance of safety). Although these approaches certainly have merit, and may be part of an overall solution, they are not enough to prevent many modern-day incidents. Today, these three approaches are used more than before, and are used better than ever before. Yet, workplace fatalities in Australia have stagnated from 2013 to 2019, as have the number of incidents, even serious ones. In the USA, workplace fatalities have increased by 15 per cent in the same period.

May 5, 2022

This paper investigates dry drilling as a feasible alternative to meet current requirements for improvements in mining productivity in an increasingly competitive world.A field test program was conducted in the surface facilities of a hard rock mine in Sudbury, Canada, to investigate the potential use of dry drilling in underground bulk mining as a conceivably faster and more economical method than wet drilling. The test work consisted of the monitoring of advance rates and bit life while a series of 165 mm diameter holes, wet and dry, were drilled with compressed air at both mine (0.69 MPa) and high (1.72 MPa) pressure levels. The results indicate that penetration rates can be increased by approximately 24 per cent by drilling dry with high air pressure and by approximately 27 per cent by drilling dry with mine air as compared with wet drilling under the same conditions. Dry drilling also has the effect of increasing bit life by up to 69 per cent. An economic analysis for typical hard rock mines indicated that drilling productivity and cost savings can be increased by approximately 23 per cent when dry drilling is utilised.The testing program indicates that dry drilling has the potential to become a feasible technique with regard to performance, productivity and costs.

Jan 1, 1991

During the past seven years silver recovery has been increased from 9 per cent to over 61 per cent. The changes in plant practiee which have led to this increase are described. Gold room clean-up procedure has been varied, so that half the additional silver is obtained as pure silver chloride, which.is converted to silver bullion for marketing.

Jan 1, 1964

By I Onederra

A better understanding of the detonation performance of an explosive charge can be gained by directly measuring pressure, temperature and velocity of detonation (VOD). This is particularly important with explosives used in the mining industry because their performance is directly influenced by the degree of confinement given by the borehole diameter and the surrounding rock mass. A project funded by the Australian Coal Association Research Program (ACARP) was initiated in early 2009 with the view to design and build cost-effective prototype instrumentation to measure the relative differences in detonation pressures and temperatures of commercial mining explosives. The project’s primary focus was on low-density explosives. Low-density (also referred to as low shock) explosives have been available in various forms for nearly 20 years. There have been significant advances in the availability, reliability and flexibility of these explosives, which now offer a range of densities and degrees of water resistance. Their detonation performance is not well understood and cannot be accurately predicted with current ideal and non-ideal detonation codes. It was therefore viewed as important to be able to directly measure pressure and temperature during the detonation process of these complex mixtures in production blastholes. Identifying the pressure release patterns of both conventional and low-density explosives under different geotechnical conditions should provide the necessary information to both validate detonation codes and better define input parameters for breakage and fragmentation models. This paper gives a general description of the prototype instrumentation developed and reports on the results obtained to date in full-scale conditions.

Nov 8, 2011