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By D Connelly

Magnetite ores can be used to produce very high-grade concentrates that are suitable feed for the direct reduction process route but the high sulfur content of some concentrates can cause substantial environmental issues. Processing of high sulfur magnetite ore is therefore increasingly problematic for the industry. Generally, the industry demands a concentrate with <0.05 per cent sulfur and <2 per cent silica. This paper reports the outcomes of a study to produce a concentrate with the requisite low sulfur content from a sulfur-rich magnetite ore. The main findings may be summarised as follows: if the sulfur is present in magnetite as nonmagnetic pyrrhotite or pyrite, it can be beneficiated using magnetic separation and hence, monoclinic pyrrhotite is magnetic and is magnetically recovered with magnetite leading to a concentrate that is too high in sulfur. X-ray diffraction and QEMSCAN analyses revealed that the magnetite concentrate was liberated at P80 30 microns and was associated with maghemite, pyrrhotite (magnetic), carbonates and hematite with very low amounts of chalcopyrite, sphalerite and arsenopyrite. Sulfur removal using flotation was the first stage of investigation and this required flash flotation in the grinding stage followed by column flotation of the initial concentrate to generate the final concentrate. At the same time, it was observed that oxidation of the pyrrhotite had a negative effect on its flotation requiring copper sulfate to activate it. Bioleaching and concentrate leaching were also considered and achieved over 90 per cent sulfur removal but were deemed unsuitable owing to the production of highly reactive wastes and high CAPEX. Reference is made to a number of operating magnetite producers and how they manage the sulfur in feed.

Sep 18, 2023

Answers to the questions "which rocks contain diamonds?" and "which indicator minerals should diamond explorers look for?" are no longer so easily obtained, now that diamonds are known to occur in lamproites and various types of lamprophyres, as well as their traditional source of kimberlites. One way of isolating those factors (host-rock"geochemistry, geographical or tectonic location, xenolith minerals, etc.) which are most critical in determining the diamond potential of a given pipe, is a detailed and critical re-examination of the huge volumes of accumulated data on kimberlites, lamproites and related rocks. A large analytical database to this end has been set up on an Apple Macintosh II microcomputer using the quasi-relational database management system 4th Dimension. Currently, it contains data for up to 90 major and trace elements, isotopic ratios and contained mineral compositions for some 4,000 rock specimens from all over the world. Many experiences in setting up this database are probably relevant to other geologists setting up their own systems: they include determining the relationships between data items; the advantages of codes over free text in representing categorical variables such as rock types; the need for rigorous error trapping and data validation; and the problem of missing data values and ambiguities thereof. The working system is now being used in a rigorous statistical assessment of the criteria which distinguish diamondiferous from non-diamondiferous rocks.

Jan 1, 1989

By Distin P. A

The extraction of platinum and rhodium from scrapped honeycomb autocatalyst into hydrochloric acid/aluminum chloride/nitric acid solutions is described. Results are given for the effects of leachant composition, temperature and catalyst pre-reduction using hydrogen. Data are also presented for the recovery, by hydrogen reduction, of platinum and rhodium dissolved in the leach solution. Parameters studied include solution composition and temperature, hydrogen pressure, and platinum seed addition.

Jan 1, 1992

By T GRAHAM-TAYLOR

A trend towards mining more complex and economically marginal orebodies, often combined with increasingly tight product specifications, increases the number of variables which need to be considered in production scheduling. Linear programming incorporating integer constraints can be used to create production schedules which are practical as well as mathematically optimum. Factors which can be taken into account include variability in product stockpiles, targets for head or product grades, production of different material types, production from different areas, production targets for loaders, and dependencies between mining blocks. For each schedule an appropriate objective for optimisation must be chosen. Examples of objectives are: to minimise or maximise grade variation; to minimise waste movement; and to minimise movement by front end loaders. A staged approach to the implementation of computer systems based on linear programming optimisation is Proposed.

Jan 1, 1992

The Late Permian intermediate to silicic talc-alkaline Drake Volcanics of New England, N.S.W., consist largely of shallow marine, redeposited volcaniclastic rocks which host epithermal Ag-Au deposits. Pervasive hydro- thermal alteration is widespread. The 200-300 m Cataract River Member includes several sedimen- tation cycles composed of massive pumice brec- cias, overlain by laminated sandstones and siltstones, interbedded with marine, fossil- iferous mudstones. Two distinct groups of cla- sts exist within the volcaniclastic beds: 1. Lithics of predominantly intermediate compos- ition lavas that have undergone subaerial epi- clastic erosion and transportation; 2.Pumice, quartz and plagioclase crystals which have not been reworked by epiclastic processes. The lithic clasts were derived locally in a sub- aerial environment within the Drake Volcanics, and pumice and crystal fragments from contem- poraneous centres of silicic volcanism else- where in New England, N.S.W. The latter group of clasts was transported to Drake by Plinian airfall or rafting, and fell and was washed on- to emergent portions of the Drake Volcanics, where reworked locally derived fragments occ- urred. Cold state subaqueous mass-flows, prod- uced by slumping, resedimented the mixed vol- caniclastic detritus into the marine basin in a series of cyclic units with massive lower parts, and laminated upper zones. Modern ana- logs of the palaeogeographic setting in New England, N.S.W., in the Late Permian are pro- vided by the Taupo Zone, New Zealand, and sou- thern Kyushu, Japan.

Jan 1, 1987

By Donald D

A number of standard tests are conventionally carried out to characterise strength properties of rock. The values of the parameters obtained are often affected by planes of weakness or defects in rock structure. For the purpose of mine design, the range in values or the class of the strength (obtained from a number of tests) is generally more important than a precise value (obtained from a single or limited number of tests). Research has been conducted to establish a relationship between an indentation index and the strength of the intact rock material from the Eastern Goldfields of Western Australia. The Tamrock Raise Boring Index (RB-i) test, which is quick and easy to perform, was selected as the indentation test. The results show that, for heterogeneous, strong to very strong rock, there is a good correlation between the indentation index and the uniaxial compressive strength and tensile strength.

Jan 1, 1996

By D Stepanenko, G Stovpchenko, L Lisova, D Togobitskaya, L Medovar

Classical electroslag remelting of consumable electrodes is a drop-by-drop melt feeding through a slag layer into a renewing molten metal bath, slowly solidifying into a homogeneous, dense, defectfree ingot in a copper water-cooled mould. The new look at the additive nature of the electroslag remelting (ESR) process in a protective atmosphere allowed us to formulate the principles of a comprehensive thermodynamic-based model that can predict dynamic changes in slag and metal composition at certain ingot remelting. The model considers drastically different slag-to-metal mass ratios at the beginning and end of remelting and predicts gas, slag and metal composition in a chain of thermodynamic subsystems. Despite consisting of calcium fluoride and stable oxides, the ESR slag can oxidise main and active elements from steel and alloys (primarily aluminium, titanium and silicon) due to chemical reactions between slag and metal. ESR is not an electrochemical process in its nature. However, slags are ionic melts and deviation in their composition causes a change in their properties, affecting both operation mode and ingot quality. Another important understanding derived from the modern metallurgy technological route is that the ability to refine metal from impurities is not a priority for the ESR because consumable electrode has already passed all stages of refining and deep degassing at ladle treatment that changes ESR slags engineering principles. The critical importance became slag’s ability to generate process heat and keep the melting composition in the metal bath unchanged (except for non-metallic inclusions assimilation). Slag engineering for ESR required a compromise between chemical inertness to a metal composition and desired physical properties deriving from technological reasons. The Directed Chemical Bonds Concept (DCBC) in a multicomponent oxide system was used to build predictive models of electric conductivity and the melting temperature of fluoride-oxide slag based on their chemical composition. Both models help to design a customised composition of effective slags for steel and alloy groups or individual grades, and they are significant steps in the development of a comprehensive model of electroslag remelting.

Aug 21, 2024

By A Specht, A Müller, V Montenegro, S Winkler, E Klaffenbach, A Schmidt

In the process of primary copper smelting in flash smelting furnace (FSF), the ratio of iron to silica (Fe/SiO2 mass ratio) primarily determines the slag viscosity and magnetite formation. Viscous slag does not only cause difficulties in daily operation, such as in tapping, it also increases the copper losses to slag. Thus, keeping the Fe/SiO2 mass ratio at the desired level is an important aspect of FSF and slag cleaning furnace (SCF) operation. In this study, the improvement of the Fe/SiO2 mass ratio was conducted in two steps: First, the optimal Fe/SiO2 mass ratio was derived based on thermodynamic data. Based on this analysis, appropriate control limits were determined. Second, this range of favourable Fe/SiO2 mass ratios was implemented into operation by an advice-based control system, which suggests the addition of silica based on the analysis of SCF slag. As this approach was successful, the same advice-based control system principle was adapted for the coke addition to the SCF. After testing the new advice-based control for several months, the production data confirm the predictions by thermodynamics: since the prediction was implemented as an advisor, the copper and magnetite content in SCF slag is significantly reduced and viscous slag is reported less often by operations.

Aug 21, 2024

By D Giles, A C. Bailey

In the first 20 years of the 21st century, just over 20 per cent of Australian mineral exploration expenditure was dedicated to iron ore, totalling >A$8 billion and >30 million metres of drilling (Australian Bureau of Statistics, 2021). Improvements in the cost, efficiency, safety, reliability and data quality of drilling have the potential to deliver significant productivity improvements, increasing the probability of discovery and reducing the time from discovery to mining. Currently in its third year of research, Mineral Exploration Cooperative Research Centre (MinEx CRC) is focused on a new set of exploration tools and new ways to deploy those tools which recognise the fundamental importance of collecting quantity and quality data from the subsurface, to enable exploration success for all minerals, including iron ore. MinEx CRC is focused on developing more productive, safer and environmentally friendly drilling methods to discover and drill-out deposits. This includes pioneering work on Coil Tube (CT) drilling technology and innovations in Diamond and Reverse Circulation (RC) drilling techniques aimed at improved drilling optimisation and automation. In parallel, MinEx is developing new technologies for collecting data whilst drilling. This is being undertaken in four separate industry-led projects utilising geophysical, seismic, downhole analytical and 3-dimensional (3D) modelling improvements. A National Drilling Initiative (NDI) is also underway, with two drilling programs completed in 2020. The NDI is a world-first collaboration of Geological Surveys, researchers and industry, which undertakes drilling in under-explored areas of potential mineral wealth in Australia and provides a test-bed for new mineral exploration technologies.

Nov 8, 2021

By Hyslop W

It is shown that coke has a major influence on the pattern of operation and on the aerodynamics of the blast furnace and that the physical and chemical characteristics of coke, at each stage in the furnace, determine its ability to satisfy requirements for iron production and coke economy. Analysis of coke sampled from operating furnaces is compared with furnace behaviour. The available data suggests the importance of segregation, strength, size change and chemical degradation of coke on furnace performance. Correlations are presented for coke breakdown ratio as a function of coke rate and hearth diameter which shows that breakdown increases with hearth diameter and with decreasing coke rate. It is also shown that the Micum tests do not reflect the coke strength in a predictable way and that solution reactions appear to play an important role in giving rise to a pitting effect on the cell walls of the coke with the resultant deterioration in coke properties. The catalytic effect of activating substances, such as alkalis, is noted and results are presented which show the effect of carbon solution on the coke strength. The importance of coke in the stack and in the bosh is discussed and flooding results are presented for BSC furnaces which show the probable driving limits for the furnaces considered. It is also shown that coke sampled from different tuyeres in a furnace gives quite different flooding limits. Other applications of the coke test work at BSC are also noted and the relevant objectives listed.

Jan 1, 1975

The Fosterville goldfield, situated 25 km east of Bendigo, Victoria was at its peak between 1894-1910 with some 47 600 ounces produced (Figure 1). Since that time intermittent mining and tailings retreatment was undertaken until Bendigo Gold Associates delineated a viable resource and commenced an open cut heap leaching operation in early 1991. Unfortunately they encountered financial difficulties and Perseverance Exploration purchased the mine in April 1992. Perseverance operated a successful heap leach operation nearby Nagambie, 100 km east of Fosterville. Based on its acquired heap leaching experience, Perseverance Exploration was able to instigate operational changes to create a successful small gold heap leach operation. The major change was the using of the original multi-use leach pad as a single-use leach pad. The available data allows for a comparison of the two operating systems.

Jan 1, 1994

Blasting is an essential component of most mining operations, and is used to reduce the rock mass to a workable size distribution, as well as to create stable openings and pit walls. Frequently, there is little difference between the designs of blasts to achieve these two functions, though more advanced operations have developed different designs for these very different functions. To assist in the appreciation of how blasting practices can impact on the stability of rock openings and pit excavations, this paper reviews the role of high pressure explosion gases on final block stability. It is assumed that the stability of all surface and underground excavations are, to a greater or lesser extent, controlled by the interaction between discrete rock blocks. Typically, these blocks will be defined by either natural, or excavation induced, jointing.

Jan 1, 1999

By Follington I. L

Various methods for stress measurement in the coal industry are briefly reviewed. Methods for presenting and interpretation of measured stress and displacement data are discussed with a view to assessing the mechanisms of failure. Arguments are presented for reviewing the current practices in this regard with reference to coal pillar and strata stability analyses.

Jan 1, 1991

As the worldÆs population and global standard of living increase, the role of metals in the economy will not diminish in the 21st century, despite substitution and dematerialisation trends. Industrial Ecology is an emerging science that attempts to bring together physical, biological and social scientists and develop the tools for good management of the planet in the long run. In engineering terms, Industrial Ecology is defined as the reconfiguring of industrial activities with full knowledge of their environmental consequences. Production and use of materials must take into account the needs of both market and environment. Dispersive uses of metals will be phased out, as is being done with lead in gasoline, and post-use recovery of materials and energy will increase. This will result in an advantage for metallurgical processes that can use as feed materials concentrates as well as metal scrap and waste streams, such as bath smelting processes and slag resistance electric furnaces. The paper also discusses how metal extraction technologies, developed in the 20th century to provide essential materials to humanity, can be applied for the benefit of both mankind and environment in the 21st century.

Jan 1, 2000

By Nairin J. D, Hayes P. C

Detailed studies of the microstructures and compositions of zinc and lead blast furnace sinters have been undertaken. An analysis of the results obtained has indicated that in many cases the microstructures of these complex materials can be explained by the solidification of melts from pseudo-ternary phase systems. Further laboratory studies have been carried out to more accurately determine the extent of primary phase fields and the liquidus temperatures in the appropriate binary and ternary systems. This approach shows considerable promise in simplifying the descriptions of slag systems used in oxidising and reduction smelting processes for lead and zinc recovery.

Jan 1, 1992

Recovery of tin and copper from concen trates containing cassiterite, stannite and chalcopyrite was studied in laboratory-scale tests designed to simulate continuous operation of the matte fuming process in which tin is recovered as SnS fume while copper accumulates in the matte. Charges made up of 300g of mixtures of the concentrate and siliceous flux were added at a uniform rate in pelletized form to crucibles containing 300g of matte and 50g of slag (both of which were recovered from previous tests), while blowing through the matte with air or oxygen-nitrogen mixtures at a rate of 3 to 5 1/min. Accurate material balances enabled the effects of process operating conditions on tin recovery and sulfur utilization to be deter- mined. When operated correctly, the matte fuming process gave tin recoveries exceeding 90 percent in spite of wide variations in the copper content of the matte and in the operat- ing conditions. Deterioration of tin recovery was associated with undersaturation of the slag with respect to silica, and with high partial pressure of sulfur dioxide (greater than approx- imately 0.2) brought about by oxygen enrichment of the blowing air. The utilization of sulfur varied widely in low grade mattes. Copper in excess of approx- imately 10% promoted formation of SO2 by the commonly accepted reaction: FeS + 1-120 2= FeO + S02 while in copper-free and lower grade mattes a substantial fraction of the oxygen was consumed in the alternative reaction FeS + i 02 = FeO + z S2.

Jan 1, 1980

By Knasmillner

During blasting body wave interaction with geometrical surfaces induces Rayleigh-waves which propagate along free surfaces, e.g. crack faces or delaminated rock layers. These Rayleigh-waves carry most of their energy within a very shallow surface layer and propagate with very little attenuation in real rock materials. Upon interaction with a crack front a very strong mixed mode stress intensity factor may result and lead to fracture initiation. On the basis of experimental photomechanical results the history of dynamic stress intensity factors Kt and K2 will be studied in Detail.

Jan 1, 1990

By Weatherhead J, Grounds J

The Nabarlek Uranium Project located in Arnhem Land in the Northern Territory of Australia was a small high-grade deposit which was the first uranium mine brought into operation following the extensive Commissioner Fox Inquiries into uranium mining during the late 1970s. The operation is almost complete and decommissioning plans have been prepared. This paper reviews all phases of the water management and tailings disposal for the project and compares results with design predictions.

Jan 1, 1988

For many crushed aggregate producers will the finest fraction minus 4 mm represent a problem. The fine material will fetch a much lower price than the coarser products, and may even be difficult to sell in some markets. The blasting operation will strongly influence the generation of fines after both blasting and crushing. Drill hole deviation together with the drill hole diameter, powder factor and velocity of detonation are the most important blasting parameters with regard to the generation of fines. Drill hole deviation is often ignored, and many operators will just reduce the drilling pattern in order to avoid hard bottom and an excessive number of boulders. The paper presents a technical and economic analysis of how drill hole deviation will lead to an increased generation of fines in crushed aggregate production. The analysis shows that the loss of sales revenues will be much higher than the extra costs for drilling and blasting caused by compensating for drill hole deviation by putting in more holes.

Jan 1, 1999

By Veal FL

Technological changes in Portland cement manufacturing during past years have reflected changes in the economics and availability of various types of fuel such as coal, fuel oil and natural gas. The industry consumes a sig- nificant quantity of both thermal and electric- al energy. The nature of the process and its chemical constraints does however permit the use of comparatively low grade fuels such as high ash coal and high sulphur oil. In striving for increased daily kiln outputs and conservation of energy, there is a worldwide trend towards the use of dry process plants. Wet process kilns of about 2 500 tonnes per day assume massive component sizes which present difficulties in manufacture, and transport to plant sites. Large capacity dry process units in excess of 8 000 tonnes per day are now in operation using precalcination techniques in which part of the fuel is introduced in the static preheater section ahead of the kiln while the balance is added to the kiln in a conventional manner. This technique has virtually doubled the potential output of any given single kiln.

Jan 1, 1976