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By B. M. Sadashiva Murthy

Increasing quantities of nutrients and pesticides in agricultural runoff in recent years has caused the more developed western nations to become concerned about diffuse agricultural pollution. Thus, the problem of diffuse pollution is of greater importance and concern for any integrated water quality management programme. The above mentioned sources and activities causing pollution to groundwater cannot be completely avoided. The best solution is to entail a firm understanding of the principles of solute transport through porous media. The complex factors that control the movement of contaminants in porous media and the resulting behavior of contaminant plume are usually intricate to assess because of interaction of many factors such as dispersion, advection, sorption, degradation, volatilization, etc. As accurate quantification of solute under field conditions is inherently difficult, the fate of nitrate and phosphate have been analyzed in laboratory column and channel studies. From the analysis of the breakthrough curves, the dispersion co-efficient for nitrates and phosphates through sandy soil was found to be 0.262 m2/d and 0.114 m2/d for column studies, 0.321 m2/d and 0.231 m2/d for channel studies respectively. The column studies revealed that the concentration of nitrates and phosphates increased steadily in the first few days (around 5 days) and then it increased rapidly after 8 to 10 days. However, it attained equilibrium after 20 days. Similarly, the channel studies revealed a steady increase in concentration of nitrates and phosphates in the first few days (1 to 2 days) and rapid increase up to 15 days and there after it attained equilibrium. In the study, one-dimensional analytical model has been developed which include the advection, dispersion, and a characteristic term called ?total elimination rate?. The comparative study of column and channel studies, and model output (in which the term total elimination rate ?K? is considered as zero) exhibited a variation of 30 to 50 % in leaching characteristics of pollutants (nitrates and phosphates).

Jan 1, 2008

By Linda Frederick

In July 1997, Krupp Canada obtained the contract to design and supply the conveyor system for Chile's Los Pelambres copper mine expansion project. Progress on the overland conveyor system is currently on schedule. It is a challenging task to convey copper ore from an open-pit mine located on a mountain site 3,000 m (9,840 ft) above sea level down 1,300 m (4,265 ft) to the processing plant at the valley floor below. The Los Pelambres conveyor system moves copper ore at a rate of 8.7 ktlh (9,600 stph) and at a speed of 6 ml sec (1,180 ftlmin) for 12,750 m (41,830 ft). The distance is divided in three conveyors, each 1,800 mm (71 in.) wide. The largest conveyor is 6 km (3.7 miles) long. To protect against avalanches and rockslides, the conveyors run through a 12-km- (7.4-mile-) long tunnel system. The lowest of the three conveyors is equipped with a shuttling head end. With this, the conveyor discharge point can be moved back and forth by 100 m (330 ft), allowing it to build up a longitudinal stockpile at its end. To meet the extreme design parameters, the limits of conveyor design had to be pushed to record-setting marks. For instance, the ST-7800 steel cord conveyor belt is the strongest belt ever installed in a conveyor system. A total drive power of 25 MW (33,535 hp), consisting of 10 2.5-MW (3,352-hp) drives, is included in the design plans. In loaded condition, the electric motors act as generators and feed electric energy back into the power grid. The motors are controlled by variable frequency inverters that provide an infinite adjustment of motor speed. This technology allows starting and stop- ping the conveyors precisely along predetermined acceleration and deceleration ramps. This is done so harmful belt jerking and stress waves can be avoided.

Jan 1, 1999

By G. L. Bloomsburg, E. G. Zahl

INTRODUCTION During the past decade, disposal of mine and mill waste material has become an increasingly important issue. Problems of structural stability and seepage effects on stability have been well addressed, and significant technological advances have been achieved [(1-4)]. The primary problem currently facing industry in the waste disposal area is environmental protection. The greatest environmental concern is over the amount of seepage or leachate entering the ground or surface water systems. Methods to determine the quantity of water seeping from a tailings pond have also been covered in the literature [(5-23)]. However, much further work is necessary to fully implement these techniques to evaluate tailings pond performance and accurately predict the various influences of disposal management on seepage from mill tailings. This study is an effort to develop those necessary techniques. The partially saturated method of analysis which is discussed here is applicable to most situations involving seepage from waste piles. In a conventional type of tailings pond, a slime layer is ordinarily built up under the ponded area. This material will consolidate slowly from capillary pressures and the weight of material deposited above it. In situations where this consolidation results in a slime layer of lower permeability than the native foundation soil, a partially saturated flow condition will usually exist in the native soil. This will result in a smaller quantity of water entering the ground-water system than would be predicted by saturated flow analysis. The finite-element program used in this study was originally developed by Neuman [(17)] and is called UNSAT2. The program will analyze problems of saturated or unsaturated, steady or nonsteady flow and can be used with a variety of boundary conditions such as constant flux, constant pressure, maximum flux, minimum pressure, and with infiltration, evaporation, and seepage surfaces. The maximum conditions are controlled by exterior factors such as atmospheric conditions; but the actual flow in the porous media is determined by properties of the porous media. In this test, the computer code was used

Jan 1, 1980

By Yoshio Hiramatsu

In Toyoha mine near Sapporo, the ground temperature is very high, perhaps due to inflow of hot mineral water, the origin of which may be rock masses intruded by the igneous activity in the Tertiary period. The rock masses are found about 2 km east of the mine, their temperature being estimated at from 770 to 870 K at a depth of 3 km. In this mine several veins bearing zinc and lead ores have been mined down to the depth of 300 m from the level of the main entry, of which altitude is 551 m above the sea level. Formerly no attempt was made at development of the deeper part of the mine than the 350 m level from the main entry. Let us indicate hereafter the levels in this mine in such a way that the level 300 m deep from the main entry is denoted as 300 mL. Since 1974, however, the 450 mL of Tajima vein has been developed by deepening No. 5 Shaft to, and by driving drifts in the level. Much hot mineral water has been flowing into the drifts from rock. After twenty-eight months from the beginning of development, the total length of excavation amounted to about 1300 m. The success in development so far may be attributed to cooling rock and air with chilled water and to adopting heat-resisting explosives and detonators. This cooling costed very much and for further development in this level a more effective and economical cooling is desired if possible. To obtain fundamental data for designing an economical cooling, the authors investigated, as a preliminary study, the heat balance in the main drift of 450 mL, by measuring the temperatures of air, rock, hot mineral water, the rates of flow of air and water and so on, in August 1976. They are now carrying out continual measurements of the variations in rock temperature, air temperature and humidity with time. The present paper describes the details of the preliminary study.

Jan 1, 1980

By K. Hanumantha Rao, K. S. E. Forssberg, A. Vidyadhar

Using pure albite and quartz minerals, the separation of albite from quartz using mixed cationic/anionic reagent schemes is assessed through Hallimond flotation, zeta potential and diffuse reflectance FTIR studies. The reagent schemes are tested in bench-scale flotation for the separation of albite from Greek Stefania feldspar ore. The single mineral flotation tests showed the feasibility of selective albite flotation from quartz at around pH 2 using a mixture of cationic diamine and anionic sulfonate collectors or a combined cationic-anionic collector of diamine-dioleate. In contrast to the selective flotation response of albite at pH 2, where albite is slightly negatively charged and quartz possess zero charge, the zeta potential and FTIR studies elucidate similar adsorption behavior of mixed collectors on both of the minerals. The infrared spectra not only showed the co-adsorption of anionic sulfonate or oleate with diamine on the surface but also showed that the diamine adsorption increases with the presence of anionic collector. The intrusion of anionic collector in between adjacent surface alkyl ammonium ions decreases electrostatic head-head repulsion, thereby increasing the diamine adsorption by increasing the hydrophobic tail-tail bonds. The discrepancy in the flotation and adsorption results at pH 2 is attributed to the coarse and fine size particles employed in these studies, respectively. The comparable adsorption on fine particles of albite and quartz at pH 2 is explained by the interaction of ammonium ions on silanol groups by hydrogen bonding besides electrostatic interactions. The bench-scale flotation results indeed showed that selective albite flotation takes place only after desliming the feed material. An albite concentrate exceeding 10% (by weight) Na20 is produced from a material containing about 6.5% (by weight) Na20, where an albite product of more than 9% (by weight) Na20 is considered to be valuable. Key words: Flotation, Adsorption, Zeta-potential, FTIR

Jan 1, 2003

By C. S. Caldwell, L. C. Thompson

Mine closure and reclamation issues have evolved over the past several years becoming further complicated by stricter standards and by the cmrent economic climate and price of gold. Many mine permits are calling for more stringent remediation of spent ore heaps and tailings. Leachate solution water quality must meet strict discharge criteria for multiple parameters besides cyanide at mine closure. Closure standards are more difficult to meet and most mines do not have an increased budget at the end of mine life to deal with the falling standards. These issues make additional gold recove1y at the end of mine life a critical problem in financing some closure operations. Another issue is the length of time that must be budgeted for heap rinsing operations. Innovative biological processes developed and applied by Pintail Systems, Inc. at numerous mine closures have indicated that bio-processes can significantly enhance gold recovery dur­ing heap cyanide bio-detox over the recoveries expected from rinse operations. If heap rinsing can be eliminated or reduced and if gold recovery can be improved at the end of mine life, many mine closures may be possible with processes that pay for themselves or generate profit. Additional advantages of the bio­detox technology is that it can be engineered to treat multiple contaminants besides Weak Acid Dissociable (WAD) cyanide. Other contaminants treated in heap process solutions include nitrates, ammonia, heavy metals, thiocyanate and total cyanide. At the Cripple Creek and Victor Mining Company Ironclad Mine near Victor, CO, 5 million tons ofrinsed, heap leached spent ore were biologically detoxified to reduce cyanide content, enhance gold recovery during bio-detox and to reduce dissolved metals in heap leachate solutions. During the bio-detox treatment period a substantial improvement in gold recovery allowed the detox oper­ation to operate as a profit center. Final gold recovery was at least twice what was expected from a normal rinse operation.

Jan 1, 1998

By Richard M. Crowell, John W. Shield, Todd J. Harvey

Facing lower gold prices, gold mine operators throughout the world are seeking ways to reduce costs for treating refractory sulfide ores. Many gold mines, currently producing oxide ores, have underlying refractory sulfide deposits and the operators could extend the mine life by processing these sulfides. Fortunately, oxidation technologies for refractory ores need not be complex nor costly. GeoBiotics, Inc. has developed heap biooxidation technologies (GEOCOAT™) for treatment of refractory gold ores and concentrates. GEOCOATTM uses simple low cost unit operations common to heap leaching of gold and copper ores. The cost effectiveness and flexibility of GEOCOAT™ heap biooxidation allows mining companies to expand operations to include refract01y ore. In addition, GEOCOAT™ can be utilized to supplement or replace existing oxidation processes such as roasting, autoclaving, or agitated tank biooxidation, and to treat a lower resource grade than is currently economic. The GEOCOAT™ technology involves coating sulfide concentrates onto sized support rocks and biooxidizing the sulfides in a heap configuration. After biooxidation the concentrate is stripped from the support rock, neutralized and leached in conventional cyanidation facilities. Ashanti Goldfields Company Ltd. (AGC) produces over 885,000 ounces of gold per year from oxide and refractory ores at its Obuasi operations in Ghana. Refractory flotation concentrates are treated in roasters and in the world's largest stirred tank biooxidation facility. In August 1998, AGC and GeoBiotics jointly constructed and operated a field demonstration heap of the GEOCOATTM process at the Obuasi operations. The heap contained I 082 tonnes of support rock and 125 tonnes of concentrate. The heap was approximately 19 meters square at the base and 3.8 meters high, and ran for 88 days after which the concentrate was reclaimed. Average gold recovery after biooxidation was 91.5% with a NaCN consumption of 8.6 kg/t. Baseline gold recovery by direct cyanidation of the concentrate was 53.8%.

Jan 1, 1999

By David Muir, Slobodanka Vukcevic

Gold is commonly associated with copper minerals, particu­larly in the more geologically recent rocks of Northern Australia, Chile and the Pacific Rim. Traditionally, oxidised copper-gold ores are selectively mined and processed for gold by cyanidation, ensuring that levels of reactive copper in the ore are kept low to minimise cyanide consumption; whilst sulphide copper-gold ores are floated and gold is ultimately recovered as the by-product from copper smelting and refining (La Brooy, 1992). Very few process­ing options exist for treating copper ores which cannot be selec­tively mined or floated, and for treating floation tailings which often contain significant gold (Muir et.al.,1989). The ammonia-cyanide leach system stands out as a unique method of selectively extracting gold without copper using economic levels of cyanide (1-2 kg/t NaCN) and ammonia (1-5 kg/t). Although first patented in 1904, it proved difficult to control and predict per formance with different ores. However, recent research and development in Western Australia by Ruane (1991), Hayes and Corrans (1992), La Brooy et.al.(1991), Muir et.al.(1993), Muir and La Brooy (1993), has led to an under­standing of the mechanism, and the commercialisation of the process at the Paris Dump (W.A.), Akjoujt (Mauritania), and in the Eastern Transvaal (Laxen,1994). Efforts are now underway to pilot and develop a tailings treatment plant at Telfer following successful laboratory trials. To date, process optimisation has relied on trial and error and large numbers of tests covering a range of conditions. Thus the results are specific to the ore. At Murdoch University, process optimisation is now focused on measuring and control­ ling Eh, pH, NH3 [Cu(II)], and Cu-CN species at the optimum levels identified from the recent mechanistic studies. In this way, the optimum composition required to process any ore should be readily established and maintained.

Jan 1, 1995

By Joseph F. Shirley

Introduction Inorganic depressants are chemicals added to the froth flotation process to maintain or produce hydrophylic surfaces on one or more minerals so they will remain in the pulp rather than attach to the air bubbles. Whether a depressant will be effective in depressing a given mineral depends on how it is used and the environment in which it is used. Some depressants must be added and conditioned into the pulp before the collector is added. Other depressants can be added in the presence of previously added collectors and effectively depress the desired minerals. Often the concentration of depressant relative to the collector concentration is critical to making an economic separation. It should be noted that some depressants will only work when specific collectors have been used. Some reagents such as sulfuric acid and hydrogen peroxide essentially act as depressants by altering the previously added collectors so that they are no longer effective. Some depressants such as sodium ferrocyanide are only effective in a very limited pH range and an essentially collector free environment. Major Depressants CaO Milk of Lime is by far the most used depressant both in tonnage and dollar value. Although it is most commonly listed as a pH modifier, it is also an important depressant for pyrite in copper and copper molybdenite flotation plants. Although a simple pH adjustment will often depress pyrite, there are times when grinding with fresh milk of lime is required to obtain optimum depression. Lime is also a molybdenite and gold depressant. NaSH Sodium hydrosulfide is by far the most commonly used reagent to depress copper and iron sulfide minerals in by-product molybdenite flotation plants. NaSH also depresses gold, silver sulfides and silver chloride. ZnSO4 Zinc sulfate is commonly used to depress sphalerite in lead-zinc and copper-lead- zinc flotation plants. It has also been used to effectively depress talc in by-product molybdenite circuits at a pH of 6.5.

Jan 1, 1986

By Dan Plazak

Discussion by Dan Plazak The authors are to be congratulated for presenting a simple and practical tool for quick estimates of ground water flow rates. At the risk of detracting from the simplicity of the method, I would like to suggest a slight refinement to the equation as presented. As the authors noted, the Jacob-Lohman equation (1952) assumes confined-aquifer conditions. To use confined-aquifer equations in water-table aquifers, Jacob (1963) presented a correction to convert water-table aquifer drawdowns [Ahw] to equivalent confined aquifer drawdowns [Ah,: 2] [Ah Ah = Ah - w(1) Cw 2H where: Ah, = Drawdown in confined aquifer: Ahw = Drawdown in water-table aquifer and H = Original saturated thickness of aquifer] Substituting the above in equation ( I) of Hanna. Azrag and Atkinson [4nT Ah - 2H ) Qj2.25 T t(2) 1 nr2 S W] Since the above expression predicts lower pump rates, it causes the Jacob-Lohman equation to agree more closely with appropriate analytical and numerical models. Figure 1, adapted from Fig. 5 of Hanna. Azrag and Atkinson, illustrates the closer agreement of the modified equation to their numerical model, as reflected in Qm/QJL ratios closer to unity. The agreement improves particularly as drawdown [Ah] becomes large in relation to aquifer thickness H. An additional advantage of the modified equation is that Hanna, Azrag and Atkinson's correction factor C is much more stable as pit depth increases. Assuming, as did Hanna, Azrag and Atkinson, that their numerical model is an accurate predictor, it is clear that the modification incorporated in equation (2) improves the accuracy of preliminary estimates of ground water flow to a pit.[ ] References Jacob, C.E and Lohman. S. W.. 1952, "Nonsteady flow to a well of constant drawdown in an extensive aquifer." Transactions, American Geophysical Union. Vol, 33, No. 4. pp. 559-569. Jacob. C. E.. 1963, `Determining the permeability of water-table aquifers,' USGS Water-Supply Paper 1536-1, pp. 245-271

Jan 1, 1995

By C. Tsamantaki

Water-bentonite suspensions exhibit a yield stress which is defined as the minimum applied stress for flow. Considerable debate exists about the yield stress being a material property, hence different measuring methods should give similar answers, but several investigators have demonstrated that it is an engineering reality. Yield stress is normally estimated indirectly from the rheogram obtained with a viscometer following an extrapolation to zero shear rate (the dynamic yield stress), but the technique may be prone to errors because of slip flow. Direct measurements, not prone to such errors, rely on an independent assessment of the yield stress, normally carried out with the vane method (the static yield stress). In this paper results are presented and compared regarding the yield stress of 14 different water-bentonite suspensions measured using both the direct and the indirect methods. In order to obtain a wide range of yield stress values, two different types and two concentrations of bentonite at various pH were tested. Rheological data were obtained using a rotational speed viscometer and a yield stress vane measuring device. Measured vane yield stress values ranged from 5 Pa to 83 Pa. Rheological data collected with the rotating viscometer were fitted using various conventional techniques (interpolation, linear and non-linear regression analysis) as well as using a golden section yield stress search methodology based on Herschel-Bulkley model, developed in house. The vane instrument measures directly the yield stress of the suspensions and requires no further data handling. A comparison of the measured values of the yield stress with the direct and the indirect method is then made for the water-bentonite samples. Not very large differences are observed among different techniques and the variations are discussed. Similar data from literature are also analyzed and the comparison shows that differences on the various estimation methods are much larger than the differences observed in this study.

Jan 1, 2006

By D. O. Miller

The effective staffing of personnel in a new concentrator facility is a key factor in the success of the operation. By selectively recruiting quality individuals, a company is in a strong position to build a positive work ethic which will become an integral part of it's culture. And culture, which is a set of standards that all employees work to uphold, is that intangible as- set that often determines whether or not a company will survive during difficult economic times. Recruiting and placement of personnel in a concentrator facility requires an emphasis on planning. Management must carefully analyze the following elements when designing a hiring plan: 1. Number of positions 2. Hiring schedule (timetable) 3. Critical positions 4. Lead-time for trainee posit ions 5. Characteristics of the ideal workforce This presentation will focus on a proven system that is efficient (and yet simple) for achieving a new concentrator facility's manpower requirements. IDENTIFYING THE STAFFING NEEDS As previously stated, the key to staffing is planning. Management will find that a basic manpower chart will provide the hiring schedule to meet deadlines. In fact, this system begins with a manpower chart (Figure 1). The chart basically works in reverse of the hiring requirements: the last scheduled hire is the first job on the list. This approach ensures that the company will not find itself compressed against the facility start-up date. A cardinal rule in recruiting a workforce is to allow sufficient time to orient and train employees to the procedures and culture of the system. Problems in selection of personnel begin when the hiring program is short-circuited for timing reasons. The quality of employee selected invariably suffers accordingly. The second section is the key to the success of the manpower program. This is the latest date by which a formal recruiting effort must begin in order for the hire date to be met. Leadtimes are usually as follows: 1. 90 days for company transfer positions 2. 60 days for experienced new hire positions 3. 30 days for trainee positions

Jan 1, 1986

By Paul D. Dupree

Introduction Trapper mine is a dip-line strip coal mine, located about 10 km (6 miles) southwest of Craig, CO. The mine provides the Craig Generating Station, operated by Colorado-Ute, with about 2 Mt (2.3 million st) of coal annually. The Trapper mine is situated on a hillside that climbs in elevation from 2 to 2.5 km (6500 to 7400 ft) at average grade of 15%. The coal seams dip at about 16% down-grade and they outcrop near the top of the hillside. They exceed maximum stripping depth in 1 to 1.7 km (3500 to 5500 ft) of pit length. Stripping in the three existing pits is performed with three Page 752 23 m3 (30 cu yd) walking draglines. Two of the pits are currently being cast blasted. Until the active cut, the Derringer pit was cast blasted only where the lower mined seam exceeded stripping capabilities and the pit was a single seam operation. Now, a 9-m (30-ft) interburden bench has been incorporated into the stripping plan. This bench protects the first seam of coal from shear when the overburden is cast blasted. The cast blasted section of the 1.6 km (53,000 ft) long pit has been increased from the 457 m (1500 ft) casted previ¬ously to 1 km (3500 ft). High speed films show the coal losses due to shear of the blast are minimal. The pit width in Derringer pit is 61 m (200 ft). This is necessary for efficient spoil side stripping of a relatively thin interburden in the two-seam section of the pit. The Enfield pit is entirely cast blasted. The single seam pit is 46 m (150 ft) wide, 1.1 km (3600 ft) long, and varies from 15 and 46 m (50 and 150 ft) in overburden depth. The overburden strata at the mine consists of medium-hard layers of sandstone, shale, and

Jan 1, 1987

By John F. M. Sims, Charles B. Green

Introduction The gold rush to the Canadian Klondike and then to the Alaskan gold camps is legend to Americans. The early years of the century also saw flourishing hard rock mining at the famous Treadwell and Alaska Juneau gold mines and the bonanza Kennecott copper mine. Over the last two decades, rich discoveries of copper, cobalt, zinc, lead, molybdenum, tin, and silver have furthered Alaska's reputation as a storehouse of US minerals. Alaska may also contain large commercial deposits of chromite, platinum, and nickel. Yet in 1984, with the exception of the Usibelli coal mine and several hundred small placer gold mines, Alaska's mineral potential remains largely undeveloped. Uncertain 70s The 1970s were years of uncertainty for the mining industry in Alaska. The discovery in 1968 of a huge reservoir of oil and natural gas in Prudhoe Bay brought the land claims of Alaska's natives to national attention and focused interest in Alaska's resource wealth. The Alaska Native Claims Settlement Act of 1971 (ANSCA) created the regional native corporations and granted them selection rights to some 178 000 km2 (44 million acres) of Alaska's 1.5 Gin' (375 million acres) - about 12% of the state's land area. The native land selection process would take years. During this time, the status of much of Alaska's land was in question. Additionally, section d(2) of ANSCA provided for the conversion of an undetermined amount of federal lands into conservation units. These consist of parks, scenic rivers, national monuments, and wildlife refuges. The debate over the d(2) lands was long and acrimonious. National conservation groups lobbied to include as much acreage as possible within restrictive classifications, regardless of its mineral or energy potential. The process was polarized into a preservation-versus-development struggle. To many Alaskans, what was at stake was the ability to develop a viable independent economy, rather than an ongoing role as economic wards of the federal government. The resulting compromise was the Alaska National Interest Lands Conservation Act of 1980 (ANILCA). ANILCA resulted in the placement of some

Jan 1, 1985

By Gale F. Hoffnagle

INTRODUCTION On November 15, 1990, President Bush signed the Clean Air Act Amendments of 1990. These Amendments cover many aspects of air pollution control. The provisions which seek to control emissions of "air toxics" may, however, be the most far-reaching and will potentially have the greatest effect on American industry. The Administration has estimated that by the year 2005 industry will be spending $6.7 billion per year on air toxics control. Meanwhile, the Business Round Table has estimated that the price will be far higher, up to $62 billion per year, depending on how EPA and the States implement the program. BASIC REQUIREMENTS Any "major" source of emissions of 189 air toxics will be required to install "MACT." The translation of this statement requires some definitions: •MAJOR SOURCE - A facility (a contiguous property under single ownership and control) which has actual emissions of 10 tons or more per year of any single one of the air toxics or 25 tons per year of any combination of air toxics. •AIR TOXICS - Congress has provided a list of the 189 chemicals on this list. Those that may be important to the mining industry are shown on Table 1. This list can be changed by petition or by EPA. •MACT - Maximum Achievable Control Technology is to be defined by EPA for each industrial source category. EPA says there are about 400 categories. The Act defines MACT as: "the average emission limit achieved by the best performing 12% of the existing sources ... for categories with 30 sources or more" or, "the average emission limitation achieved by the best performing 5 sources in the category." TABLE 1 SELECTED AIR TOXICS FROM CLEAN AIR ACT LIST IMPORTANT TO MINING INDUSTRY Antimony Compounds Arsenic compounds (inorganic including arsenic)' Beryllium Compounds' Cadmium Compounds Chromium Compounds Colbalt Compounds Cyanide Compounds (dissociation compounds) Lead Compounds' Manganese Compounds Mercury Compounds' Fine Mineral Fibers Nickel Compounds Radionuclides (including radon)1 Selenium Compounds 1Previously listed under NESHAP 2The Administration may not list elemental lead as a hazardous air pollutant.

Jan 1, 1991

By William J. Maloney

OVERVIEW Blind drilled shafts are becoming increasingly popular, particularly in the Appalachian coalfields, as a secondary and sometimes primary means of ventilation. The reasons for the rebirth of the blind shaft are mainly due to it's economics, timeliness, safety characteristics and inherent independence from underground operations. Historically blind drilling has been used to a limited degree in hard rock and tunneling ventilation. With the recent advances in cutters, bit design, equipment and lining systems, particularly in the Appalachian coalfields, blind drilled shafts are once again the shaft construction technique of choice to the educated ventilation specialist. [ ] HISTORY OF BLIND DRILLING Blind drilling has it's roots in numerous places, including the Nevada Test site, the coalfields of Appalachia and Germany along with the uranium mines of Arizona. Early technology was developed using a variety of equipment mainly of oilfield origin with oilfield drillers entering the industry on a project basis only to "pull in their horns" and return to the oil patch. Shafts completed by oilfield equipment range from the shallow 5' and 6' lined shafts on the Nevada test site to two (2) 10' lined, 730' deep shafts in Alberta for heavy oil development. Several of these shafts were completed to extraordinary depths with the record being a 90" diameter, 6,150' deep shaft being completed in the Aleutian Islands of Alaska in 1969. EQUIPMENT Oilfield equipment is still being used on the Nevada test site but elsewhere specialized blind hole equipment has been developed to enhance the efficiency of particular applications. Where steel liners are required the A-leg derrick with a simple hoist and rotary system is used. The largest user of this type equipment in the world is the former USSR where blind drilling for mine ventilation is the norm. On applications where trip time and cutter changeout are a priority, top drive hydraulic rigs have been developed which are highly automated, efficient and mobile. These rigs are particularly well suited for tunneling applications where shafts are shallow and sites are usually tight.

Jan 1, 1993

By S. A. Tims

INTRODUCTION The Falconbridge mine ore body extends about 1.6 km (1 mile) in length and the deepest developed ore is on the 6050 level below surface. The ore zone varies in width from a few inches to over 30 m (100 ft) and the average width is 4.9 m (16 ft). Access levels are driven in the ore at 53.3-m (175-ft) intervals. The principal method of mining is overhand longitudinal cut-¬and-fill. Prior to 1962 timber square-set stoping as a secondary extraction method was used for about 15% of the total production. Undercut-and-fill was intro¬duced at Falconbridge in 1962 as a potential replace¬ment for the square-set method in heavy ground. The undercut-and-fill method was developed by Inco in the 1950s, its principal application being to transverse pillar mining. Falconbridge made modifications to this method. A feature of the mine is the No. 1 flat fault which dips 0.79 rad (45°) towards the northeast. The main characteristic of the fault is the presence of large swells of ore directly under the plane of the fault. The ground under the fault area is highly fractured and associated with massive sulfides. In the past, the ore under the fault was recovered, with difficulty, by either tight cut¬and-fill or square-set stoping. In the 1970s these meth¬ods were supplanted to a large degree by the under-cut-¬and-fill method. An advantage of the current undercut-and-fill method which uses cemented fill compared to the cut-and-fill and square-set methods is the reduction of dilution due to better control of the walls. At Falconbridge mine, it is estimated that the grade of ore produced by undercut¬and-fill is improved by approximately 10% over other methods. Where undercut-and-fill is used in very weak ground, a much greater improvement in grade can be expected. Table I shows mining production for 1974. The undercut-and-fill method was first used at Falconbridge during 1962. The first longitudinal stope was prepared for undercutting by laying down laminated beams the length of the stope and installing a lagging mat floor on top of the beams. Unconsolidated tailings fill was poured on top of the mat floor. As the cut ad¬vanced under the floor, heavy posts were placed under the laminated beams at 1.8-m (6-ft) intervals. During 1966, a radical change was made to the method when tailings fill, consolidated with portland cement, replaced the unconsolidated fill. This development eliminated the laminated beams and heavy mat floor and greatly im¬proved the stability of the stope. This system, with minor variations, is currently used at Falconbridge mine. APPLICATION The undercut-and-fill method is used to mine in¬competent ground, sills or floor pillars under mined-out levels, or a block of ore isolated between levels. It is occasionally used to advantage in sequencing produc¬tion from various mining blocks. This is done by mining a block of ore cut-and-fill method and at the same time mining the ore block directly underneath by the under¬cut-and-fill method. The undercut-and-fill mill holes at Falconbridge are either boreholes, stripped timbered raises, or steel mill holes. Boreholes and rock raises tend to slough in heavy and broken ground which increases dilution when sloughing exceeds the ore width outline and also in¬creases the difficulty of moving down to start the new cut. For example, in one installation, a 1.2-m (4-ft) diam borehole sloughed to a size of 3.7 x 5.5 m (12 x 18 ft). The undercut-and-fill method usually requires a mill hole extending from the level below the ore to the top horizon of the ore block. The customary methods of providing a mill hole are: 1) A borehole is driven from level to level through the ore block and a chute installed on the bottom level (Fig. 1). 2) An existing raise is used as a mill hole. If the raise is timbered, a steel mill hole is installed inside the timber and tailings fill poured around the steel mill hole (Fig. 1). 3) An existing steel mill hole, situated at one end of a mined-out stope, is used as the mill hole for an ad¬jacent undercut-and-fill ore block. The mill hole posi¬tion is determined when planning the mining sequence of the first stope (Fig. 2).

Jan 1, 1982

By R. A. Holmes

Although manganese is a metallic element and is widely dispersed in nature, it never occurs except as a compound in combi¬nation with other elements. Use of such compounds in the production of glass is known to have occurred in early Egypt. The dioxide of manganese was considered a compound of iron until 1774 when C.W. Schule first recognized it as an element. In the same year, a Swedish mining engineer, J.G. Gahn, became the first to isolate manganese. In 1856 development of the Bessemer process of steelmaking gave economic importance to manganese, and later, in 1882 Robert Hadfield discovered the benefits of high manganese steels. GEOLOGY Physical Properties Elemental manganese is a silver-gray metal, resembling iron but harder and more brittle and used primarily in alloys (both ferrous and non-ferrous) and a wide variety of chemical compounds. Some of the physical properties of manganese include: melting point¬1 245°C; boiling point-2 150°C; density at 20°C-7.43 g/cm3; specific heat at 25.2°C-O.115 cal/g; latent heat of fusion-63.7 cal/g; hardness on Mohs scale-5.0; linear coefficient of thermal expansion from 0 to 100°C-22 x 10-6. Mineralogy There are over one hundred minerals that contain manganese. These minerals vary from those with compositions that are pre¬dominantly manganese to those having only minor percentages of manganese. Distribution of Deposits Manganese ore deposits are found worldwide and were formed in various geological environments, but only a rather limited num¬ber of deposits have high grade manganese ore in sufficient quan¬tities to be mined and utilized economically on an industrial scale. It is worth noting the fact that almost all of the significant deposits can be classified into two types of deposits: marine chemical sed¬imentary deposits, and residual (secondary) enrichment deposits. There are, however, a much larger number of geological types but these are not of commercial significance at this time. Sedimentary deposits are the most common and are usually stratiform or lenticular. Manganese minerals were formed by a chemical process during the deposition of marine sediments. They usually contain manganese oxides and carbonate minerals, some¬times interbedded together or with other sedimentary rocks such as limestone or shale. Examples of this type of deposit are the Russian ore bodies of Nikopol and Tchiatoura, as well as the Kalahari deposits in South Africa and deposits of Groote Elyandt in Aus¬tralia. Residual deposits were formed in a different way: by alteration of existing manganese deposits or by concentration of the manga¬nese minerals when other minerals were washed away by weath¬ering or ground water processes. The Nsuta deposit in Ghana, the Amapa deposit in Brazil, the Moanda deposit in Gabon, and nodules in the residual clays of the US Southern Appalachians are examples of this type of geological process. In the case of the Ghana and the Amapa deposits, this is only true for the outer layers of the deposit containing oxide minerals, the inner part being comprised of car¬bonate minerals including manganese carbonate, probably from marine origin. Some sedimentary and residual-type deposits have been metamorphosed, giving rise to small high grade ore bodies. These deposits are regionally metamorphosed, occurring in mar¬bles, slates, quartzites, schists, and gneisses. Some of these deposits, such as the Franklin, NJ, deposit are rich enough to be commercial without secondary enrichment; however, most of the exploitable deposits have been secondarily enriched. Due to the diversity and complexity of manganese deposits, both with respect to deposition and chemistry, a wide range of impurities are almost invariably present in the ores. Table 1 shows that the reserves (i.e., a measured resource that can be economically and legally extracted) are estimated at 814 x 106 tons of contained Mn, which equates to more than a 100 year supply at the current level of production. The reserve base is made up of the marginally economic reserves and sub-economic re¬sources and are some 4.5 times greater than the proven reserves. Also apparent from study of Table I is the fact that some 75% of manganese reserves are found in two countries, the USSR and South Africa. On the other hand, North America (i.e., the United States and Canada) have few significant deposits. The largest deposit, or at least one of the largest, in the United States is located at Chamberlain, SD. This deposit is sedimentary

Jan 1, 1994

By Norbert Patzelt, Johann Knecht

INTRODUCTION Grinding mills have been used in the minerals processing industry for over 100 years. Their dimensions have grown continuously during this time. Besides increasing throughput rates of grinding plants due to the depletion of high grade ores, the lower specific in- vestment costs, as well as reduced operating and maintenance requirements are major reasons for this trend. When selecting new plant equipment one must consider that design principles which have proven their reliability on sizes of today's equipment do not automatically warrant a successful operation on the ever larger size of equipment. Modern calculation methods as for instance the Finite Element method already contribute considerably to the safe design of the huge equipment being built today and are a standard tool of the design engineers. More recently, modern computer programs are also being used in order to size the equipment to meet the process requirements. Today, two design principles are on the market - one which supports the weight of such a unit on trunnion bearings through cast conical endwalls and one which is supported through slipper pad bearings arranged at the circumference of the mill shell (Fig.1). The reason for the development of this alternative grinding mill design can be found in the past. During the sixties and seventies the growing sizes of ball mills with high LID ratios caused many mill failures due to cracked endwalls. The accuracy of the calculation methods as well as the quality standards for castings were not developed to a degree required for such kind of heavy equipment. One way to overcome these problems was the increase of the manufacturing quality standards as well as the introduction of the finite element method based on the analysis of the experience available. The biggest grinding mills being built today are large size SAG mills with cast conical endwalls and trunnion bearings (Fig.2). This is due to the fact that mill manufacturers who had come from the conventional ball mill design adopted these principles as well to their SAG mills. These grinding mills perform well without special concern to the operators. Other manufacturers overcame the problems as mentioned above by eliminating completely the heavy castings and trunnion bearings and the problems associated to it (Fig.1). This design was originally applied to ball mills for the mining and other industries. Due to the success of these shell supported ball mills, this design principle was also applied to SAG mills(Fig.3). Despite of the fact that the majority of today's grinding mills are built to the conventional design it is also interesting to have a look at this alternative. Principles which have proven their reliability on sizes of today's equipment do not automatically warrant a successful operation on the ever larger equipment if bigger mill sizes are realized only based on the pantograph principle. With growing grinding mill sizes, the mass and volume flows through the equipment increases rapidly. Thus it is very important not only to concentrate on the safe design of the structural components of the equipment but as well on the process requirements. The influence of the design on important process parameters of dry and wet grinding plants are discussed thereafter. It shall be shown how modern computer programs can assist in the optimization of the design of components in order to fulfil the operational requirements of such large size equipment. PROCESS REQUIREMENTS OF LARGE SIZE GRINDING MILLS Dry Grinding Mills The world's biggest ball mill is a dry grinding ball mill having a diameter of 6.2m and an overall length of 25,5m with a drive power of 11,200 KW or 15,000HP. This grinding mill dries and grinds gold ore at a rate of 500 tons per hour at a moisture content of up to 9,5%. As shown in Fig.4 this mill was built as a shell supported unit. In fact only this design principle allowed to meet the process requirement. This mill could hardly be built with cast conical endwalls due to the constraints of the trunnion bearings limiting the mill inlet. The following case shows how modern computer programs can help to meet the design criteria of the air system of large size dry grinding plants. For dry grinding plants, the gas flow through the SAG mill has to match the drying, as well as the material transportation require-

Jan 1, 1998

By R. A. Basse, W. D. Diment, A. J. Petrina

INTRODUCTION In 1957, diamond drilling on a magnetic anomaly indicated an extensive zone of copper mineralization on what is now the Craigmont Mines property. By mid¬1958, drilling established a copper ore body. Milling commenced in September 1961 at 4536 t/d (5000 stpd) and by the end of October 1977 the mine had produced 339 662.04 t (374,363.9 st) of copper. At present, two-thirds of the mill feed is derived from underground operations and one-third from low-grade surface stockpiles. Craigmont Mines is situated 209 km (130 air miles) northeast of Vancouver (see Fig. 1), 16 km (10 miles) west of the town of Merritt, a logging, ranching, and mining community of about 7000 people. It is serviced by paved highways, Canadian Pacific Railway, British Columbia Hydro, and Inland Natural Gas Co. Water is pumped from the Nicola River, a distance of 6 km (4 miles) and a lift of 244 m (800 ft). In March 1967, the open pit mining operations at Craigmont Mines reached their economic limit and were suspended. Before this, it had been decided that a sub¬level caving method of underground mining would be used to supply ore to the concentrator after the cessation of open pit production. This chapter describes the fac¬tors influencing the choice of mining method, some of the problems encountered, mining practices, and results. GEOLOGY The ore bodies of upper Triassic age are located in a limy horizon striking east-west, closely paralleling the intrusive Guichon batholith, bounded on the south by rhyolites and on the north by graywackes, and dipping steeply to the south (Figs. 2a, b). The ore bodies are relatively narrow with a maxi¬mum width of 79 m (260 ft), a combined strike length of 853 m (2800 ft), and a vertical extent of 610 m (2000 ft). Chalcopyrite is virtually the only copper mineral, and 20% of the ore zone consists of acid solu¬ble magnetite and hematite. The area has been subjected to considerable faulting and brecciation, which is a major factor in the mining operation. Total geological reserves, at 0.7% Cu cutoff, for the deposit were 22 316 743 t (24,600,000 st) at 1.89% Cu. An additional 5 236 270 t (5,772,000 st) at 0.6% Cu were mined from the open pit. Ground Conditions The waste rocks-graywacke, andesites, and diorite -are relatively incompetent due to the high degree of fracturing and jointing, and all require varying degrees of support. The ore zones are somewhat less fractured; ground support is still required, however, although to a lesser extent than in the country rock. Ground conditions in the main ore body are better than in the smaller, nar¬rower ore bodies. Clayey fault gouge is present in most of the faults; gouge zones may be up to 6 or 9 m (20 or 30 ft) wide. The main ground problems are associated with local weakness rather than pressure. Shape of Ore Bodies (Figs. 2a, b and 3a, b) The main No. 1 ore body is approximately 244 m (800 ft) long and 46 m (150 ft) wide. It extends ver¬tically from the original top of the open pit at 4200 ele¬vation to just below the 3060 level. The No. 2 ore body is approximately 304 m (1000 ft) long, varies from stringer width at the extremities up to 79 m (260 ft) wide, and extends from 3060 level to 2400 level. Both these ore bodies have extensions re¬sulting in additional small irregular bodies. Ore bodies are mostly steep dipping, though part of the Wing ore body, an extension of No. 2 ore body, dips at 0.87 rad (50'). This ore body varies in size, but is approximately 122 m (400 ft) long, 21 m (70 ft) wide, and about 213 m (700 ft) high. No. 1 Limb ore body is a narrow extension of the No. I Main with a vertical extent of 137 m (450 ft), average width of 18 ft (60 ft), a strike length of 152 m (500 ft), and dips steeply at 1.4 rad (80°). No. 1 East is an eastern extension of the No. 1 Main with a vertical extent of 183 m (600 ft), a strike length of 91 m (300 ft), an average width of 30 m (100 ft), and dips at 1.2 to 1.4 rad (70 to 80°). No. 1 South is at the upper west end of the open pit with a vertical extent of 76 m (250 ft), a strike length

Jan 1, 1982