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By A. Visnapuu

The Bureau of Mines investigated carbonyl processing techniques for the recovery of the critical metals Ni, Co, Mn, and Cr from domestic primary and secondary sources. In most cases, the source materials require reductive precarbonylation treatment to metallize the contained Fe, Ni, and Co compounds to render them reactive with CO. The critical metals were recovered either by direct conversion to the respective carbonyls or as upgraded products by carbonyl removal of an undesirable metal. Best metal-to-metal carbonyl conversion was under CO pressure, from 80 atm upward, and at 1400 C. Carbonylation was accelerated by the addition of HzS in small quantities. CO pressure, temperature, promoter and pretreatment trends, and other factors enhancing metal carbonyl formation are presented.

Jan 1, 1987

By R. V. Ramani, R. Stefanko, G. W. Luxbacher

Computer input data for an operating mine is developed on the basis of a detailed ventilation survey which includes air quantity, air quality, pressure loss and fan performance measurements. Quantity measurements must be reviewed extensively and assumptions made about leakage quantities and airflow paths. Pressure measurements must be reviewed and developed into a pressure gradient for the mine system. Air quality measurements are used to determine methane sources and amounts. Finally, the fan test data is used to develop the correct fan characteristic curve. Quantities and pressure losses for each branch in the system are used to calculate the branch resistances which are then utilized in the ventilation simulator to model the mine system. QUANTITY BALANCE The quantity of air coming into a mine based on field measurements will rarely equal the quantity exiting the mine, even if allowances are made for methane or compressed air input to the system. The same statement can be made for airflow through any isolated part of the mine ventilation system such as individual working section or main aircourses leading to an area isolated from the rest of the mine. The reason for the apparent discrepancies is the accuracy of the indicated quantities which in turn is based on the accuracy of the individual velocity and area measurements. Even with measurements following the guidelines described in the previous section on quantity measurement, this error can only be minimized but not eliminated. As a result the ventilation system must be carefully balanced so that, for any loop, the quantity in plus any methane or compressed air injection will equal the quantity out. The continuity of flow described by the balanced system must approximate the

Jan 1, 1977

By F. Chase, D. Pappas

Pillar recovery has been associated with nearly one third of roof fall fatalities in underground coal mines during the past decade. Safe pillar recovery requires global stability and local stability. Global stability is addressed primarily through pillar design. The local stability risk factors include cut sequence, the final pillar stump, supplemental supports (timbers vs. Mobile Roof Supports (MRS)), roof bolting, and many others. The National Institute for Occupational Safety and Health (NIOSH) has evaluated each of these factors through field research and analysis of accident statistics. The paper discusses design methods and technologies that have been transferred to the mining community and implemented.

Improve surface mine haul-age truck safety and efficiency by providing a means for sensing the weight and distribution of the truck's load. Approach The safety hazards and the economic implications of overloading mine-haulage trucks were analyzed to determine the net effect of that practice on mine operations. The analysis indicated that: Ten to 25 pct overloading is typical; Higher haulage, tire, and maintenance costs occur due to overloading (a 20 pct overload was estimated to increase operating costs 7 pct per ton); Ten to 15 pct of haulage? truck injuries and fatalities are attributable to overload conditions, at a cost over one million dollars per year to the mining industry. Vehicle-weighing technology that conformed to the performance specification for an off-highway haulage truck overload detection system was selected for in-mine testing. How It Works Normally, volumetric estimates are made during the loading sequence which do not account for the varying ore density. Hence, the actual weight of a load is never precisely known. By providing a precise measurement, an overload detection system will not only indicate vehicle overloading, but will also show under-utilization of the truck. One system tested by the Bureau of Mines was the ?Load Analyzer" manufactured by Pactronics Corporation in California. This system consists of a meter-type analog readout for the cab console and three "Electrosensors" (linear variable differential transformers) attached to the main frame. Using conventional welding and brazing techniques, two sensors are attached between the front members of the engine sub-frame and the top of the left and right trailing arms (one sensor per arm). The same techniques are used to attach the third sensor to the rear centerline of the truck. between the main frame cross member and the A-frame. The readout unit on the cab console indicates by color-coding whether each sensor loading is under (green), at (yellow), or over (red) the pre-set rated load. The three-sensor configuration with in-dependent readouts also detects uneven distribution of the load.

Jan 1, 1984

By D. E. Seizinger

The Bureau of Mines has developed analytical methods, primarily gas chromatographic, for measurement of exhaust oxygenates produced from selected simple fuels. The resulting data were used to estimate levels of carbonyls and noncarbonyl oxygenates in exhaust from gasoline fuels. Estimated noncarbonyl oxygenates in gasoline exhaust may comprise as much as 30 pct of total oxygenates which include unsaturated carbonyls and noncarbonyls believed to be significant potential pollutants.

Jan 1, 1972

By John C. Franklin

The Bureau of Mines conducted extensive laboratory and limited field tests to determine whether a polymeric material could effectively reduce the emanation rate of radon gas from uranium ore. In the laboratory 46 different single-coat materials and 14 two-coat applications were tested. The laboratory tests showed that up to 100 percent of the radon gas could be sealed into the rock. Materials tested in the laboratory were polyesters, furan resins, epoxies, latices, and totally inorganic coatings. From the laboratory work six different materials were selected for field testing. The first test was single-coat materials in five static chambers; the second test used two-coat applications in an open chamber. Both tests were conducted in the Dakota mine at Grants, N. Mex. During the second test, the amanation rate of radon gas was reduced up to 62 percent.

Jan 1, 1975

By D. E. Shanks

The Bureau of Mines investigated the effects of HCI concentration and solution temperature on the solubility and crystal form of the chlorides of Co, Mn, and Ni when sparged with HCI gas at temperatures of 20°, 40°, and 60° C. Increasing HCI concentration in solution caused the chlo-rides of Co, Mn, and Ni to crystallize (salt out) because of the common ion effect. The salting-out crystallization was most effective for NiCI2, which had a solubility of 0.7 pct at 20° C and maximum HCI concentration. COCl2 salted out to a minimum solubility of 9.4 pct at 20° C and 22 pct HCI concentration and increased in solubility at greater HCI concentrations because of the formation of chloride complexes. MnCl2 was intermediate in behavior. The effect of temperature on solubility was greatest for CoCl2 and least for NiCI2, 15 and 7 pct change, respectively, over the temperature range of 20° to 60° C. The salted-out chlorides of cobalt and nickel formed the hexahydrates and those of manganese formed the tetrahydrate in saturated metal chlo-ride solutions at 20° C and low concentrations of HCI. Increasing the temperature or the HCI concentration caused a 108s in waters of hydra-tion. At 60° C, the salted-out crystals of NiCl2 formed the tetrahydrate in HCI concentrations up to 18 pct and the dihydrate at higher concentrations, while cobalt and manganese chlorides formed the dihydrates, even in water.

Jan 1, 1985

By d&apos, Kathleen J. Amico

This summary appears in Minerals Year-book volumes I-II, and III, which cover mineral production in the United States, its island possessions, the Canal Zone, and the Commonwealth of Puerto Rico, as well as the principal minerals imported into and exported from the United States. The sections of this chapter and the area chapters in volume III contain further details on production. A summary table comparing world and U.S. mineral production also is included. Mineral production may be measured at any of several stages of extraction and processing. The stage of measurement used in the chapter is normally what is termed "mine output." It usually refers to minerals in the form in which they are first extracted from the ground, but customarily includes for some minerals the product of auxiliary processing operations at or near mines.

Jan 1, 1967

By Charles L. Kimbell

Following the pattern established in the 1989 edition of this study, the concept of data availability must be addressed, because there are perceptible changes from year to year, and the availability of accurately reported, precisely defined statistics and nonstatistical information provides the only sound basis for analytical studies of any type. As the countries of eastern Europe, including the numerous states that formerly comprised the U.S.S.R., undergo the transition from centrally planned economies' to market economies, there has been a perceptible increase in information availability for rather obvious reasons. Any industrial operation seeing economic assistance from government and/or private sources outside the country in which the facility is sited must provide some appraisal of its operations at the time it seeks assistance, as well as some information on previous performance to serve as tools in evaluating its potential under the proposed development scheme for which it seeks financial assistance. This situation, coupled with governmental recognition that concealment of much of the national mineral production, trade, and consumption data for purposes of national security probably never was really necessary and certainly proved unnecessary with the end of the so-called cold war, has led to the publication of increasing amounts of both statistical and nonstatistical information in the countries undergoing economic transition.

Jan 1, 1993

By Francis Crowley

Elementary concepts of seismic wave properties are reviewed to establish a framework for discussing seismic noise and its suppression. A liberal number of references is included for those who wish to pursue the topic in detail. A base motion noise level is established for a single surface seismometer. It is argued that simple array processing and seismometer burial should regularly permit us to approach this base noise level which is found in areas free of conspicuous man-made seismic noise sources. The sensitivity of the base seismic level to a number of common disturbances is presented. Solutions that promise to hold the "effective" seismic noise at a site near the base level are given for acoustic, meteorological and fixed local surface sources. Guidelines are suggested for controlling other local man-made sources, e.g. vehicular traffic, by keeping them at sufficiently large distances away from the seismometers to keep noise at permissible levels. These guidelines are speculative and conservative. They should be the subject of future study. The ability to process against general local activity, drilling, and intra- mine sources is limited. Certainly no dramatic gain is to be expected. When strong man-made and/or intramine noise sources are not controllable, detection may well be impossible to achieve, unless the seismometer can be moved close enough to the suspected miner position, i.e. via very deep holes, to compensate for the likely vast differences in strength of the miner signal and the uncontrollable man-made noise sources. However, many intramine sources, e.g., falling water, rock bursts, explosions, etc., may well preclude the existence of a hale miner in their vicinity, and therefore any need to attempt detection of a miner at such locations. The following recommendations are made to enhance the detection and location of a miner signaling seismically. They are: 1. Seismometer burial in slim holes. 2. Narrow band detection, using multiple narrow band filters to cover the likely signal band. 3. Broadband recording and analysis for time-of-arrival estimation.

Jan 1, 1974

By R. E. Brown

The objective of this Bureau of Mines study was a laboratory-scale evaluation of the sodium sulfate refining process for removing copper from molten ferrous scrap. Maximum copper removal is achieved in carbon-saturated melts at 1,300° C. Low carbon concentrations and higher temperatures result in a less efficient copper removal and an increased sulfur concentration in the iron. Sodium sulfate refining significantly lowers the concentration of aluminum, manganese, and silicon; however, the copper removal efficiency is adversely affected by the presence of manganese and silicon. Compared with other reagents tested, sodium sulfide-forming slags were found to be the most suitable for both copper removal and sulfur control. The sulfur content of the refined iron was higher in tests conducted in acid-type refractory crucibles. Earlier studies showed that tin, a significant metallurgical impurity, is not removed by the sulfate process. During the present investigation, results showed that chlorination, using organic solid sources of chlorine, reduced the tin concentration to acceptable levels in molten iron.

Jan 1, 1975

By Eugene T. Sheridan

The Bureau of Mines annually canvasses the peat producers in the United States and publishes economic data on the industry, based upon reports from producers. This publication lists all producers that reported commercial production to the Bureau for 1959. The companies named herein represent virtually all commercial producers of peat. A few companies, however, may not have been canvassed or failed to respond, as tine survey is voluntary For producers, arid the industry has many small operations that operate intermittently. No consideration was given to the quantities of peat produced and output of the various companies listed ranged from less than 100 tons to more than 50,000 tons, Peat is included in the Bureau's annual surveys of the mineral industries because, technically, peat is a fuel. Although none is used for fuel in the United States, peat is a potential source of energy and one of our large mineral resources. The domestic peat industry produces peat chiefly for use as a soil amendment. The industry has expanded rapidly during the past decade with active operations increasing from 45 in 1947-49 4/ to 105 in 1959. Output during this period has increased 218 percent, rising from 131,782 net tons to 419,460 net tons.

Jan 1, 1960

By V. Rajaram, S. Bhattacharya, M. F. Dunn

During a mine fire or other emergency, it may be desirable to reverse the airflow in order to provide an escapeway or to isolate a fire. Also, (in colder areas, the airflow may be reversed to prevent ice buildup. When reversing main mine fans, the mine operator usually does not know what operating characteristics of flow and pressure to expect. Laboratory a field tests of vane axial main mine fans in the 7- to 9-ft diameter size range were conducted to establish forward and reverse performance characteristics under controlled conditions and at typical mine installations. The data obtained suggest that reverse performance characteristics are dependent upon the blade angle and the hub to tip ratio. There is also evidence that reverse performance can be predicted for a family of blade angles and a given hub to tip ratio. Generally, quantity of air is 30% to 65% less in reverse than when operating in the normal forward mode.

Jan 8, 1983

Several federal and state agencies have promulgated regulations that require the installation of operator protective structures on mobile equipment used in mining, construction, agriculture and logging industries. These regulations cover many different types of vehicles, from small farm tractors to large rubber-tired front-end loaders, and require structures that help protect the operator from death or injury from vehicle overturns, from falling tree tops and logs, from falling rocks, and from tree limbs in clearing operations. Two general types of vehicle operator protective structures have evolved over the past twenty years. The first of these is the "Roll-Over Protective Structure'' or "ROPS" that is essentially a "roll bar" or "roll cage" that provides a relatively safe area for the vehicle operator if the vehicle should tip over and roll. The second protective structure is the "Falling Object Protective Structure" or "FOPS" that provides overhead protection against falling material. The terms "ROPS" and "FOPS" are often used interchangeably (sometimes inaccurately) with "cabs", “canopies” , "roll bars" , protective structures" and other such descriptive names. In this report, "ROPS" describes the function of the structure; "FOPS" also describes a particular function. Thus a ROPS/FOPS could describe a cab or a canopy that provides both roll-over protection and falling object protection. “MESA” is used as an abbreviation for the Mining Enforcement and Safety Administration; "USBM" is used to abbreviate the U, S. Bureau of Mines.

By J. E. Hamak

This publication contains analyses and related source data for 165 natural gas samples from 21 States and 1 foreign country. Of the total samples, 155 were collected during calendar year 1988. The remainder were collected earlier, but releases granting permission to publish were not received until 1988. All samples were obtained and analyzed as part of U.S. Bureau of Mines investigations of the occurrences of helium in natural gases of countries with free market economies. This survey has been conducted since 1917. The analyses published herein were made by mass spectrometer and chromatograph.

Jan 1, 1989

By J. H. Maysilles

The Bureau of Mines, U.S. Department of the Interior, is investigating several types of low-grade uranium deposits. Projections indicate that an increased percentage of future production will be derived from such sources. One material studied was from the Coso Mountains of California; this material contained 0.04 to 0.12 percent U3O8. The deposit contains at least two distinct types of mineralization. The material representing the bulk of this deposit was amenable to acid leaching; 80 to 85 percent U308 extraction resulted from leaching with 20 to 40 pounds per ton of sulfuric acid. No oxidizing agent was required. This ore fraction could be treated by either agitation or percolation leaching. Uranium recovery and purification from the acid leach solution was accomplished using anion exchange followed by precipitation with hydrogen peroxide and ammonia. The second type of mineral was very refractory to acid leaching; a maximum extraction of only 44 percent was obtained with sulfuric acid. Nitric and hydrochloric acids were ineffective also.

Jan 1, 1978

By W. A. Cole

This report covers the preliminary phase of an investigation of clays, shales, and certain rocks in Wisconsin to determine the feasibility of processing lightweight aggregate in the State. The study was extended to include rotary-kiln testing of a limited number of shale samples, and to an appraisal of the Maquoketa shale resources in eastern Wisconsin. A total of 45 samples of clays, shales, and other argillaceous rocks of Wisconsin were tested. The lower Maquoketa shale is the only material found to date that offers possibilities as a source of material that can be processed in a rotary kiln for lightweight aggregate. Bedrock occurrences of the Maquoketa shale are found in the eastern and southwestern parts of the State. The populous southeastern region of Wisconsin presents a large potential marketing area for lightweight aggregate. For this reason special study was directed to the Maquoketa shale in the eastern district.

Jan 1, 1961

By John J. McClelland

The Bureau of Mines conducted a study of longwall plow operations to identify dust sources and existing control technology. Three longwalls employing either the high-speed overtaking or conventional method of mining were surveyed. Principal operating parameters and on-site dust control technology at the time of each survey are described. Short-term gravimetric and instantaneous sampling results are discussed in detail. The relationship between longwall dust levels and dust control technology was examined.

Jan 1, 1988

By M. J. Mechling, H. J. Sloman

"INTRODUCTION The practicability of providing safer methods of underground transportation for mine workmen and officials has been given much thought in recent years by advocates of safety, health, and efficiency. Numerous fatalities and disabling injuries have resulted from falls of roof, personal contact with both electrical conductors and timbers, and improper position or conduct of passengers while they were in man-trips. Unfavorable atmospheric exposure due to high-velocity air currents and sudden changes in temperature may adversely affect the health of mine workmen if they are transported in unprotected Cars.Recent installations of protected, man-trip cars, wherein such cars have been utilized to haul men to and from their stations in the mine, have resulted in a large reduction in exposure to haulage hazards. Where special-built cars have been used the probability of injuries to men during transportation in man-trips has been decreased, and the morale of the employees has been improved. A number of man-trip cars are in service in the coal-mining regions; those described in this circular are typical examples of a few installations."

Feb 1, 1948

By V. A. Marple, K. L. Rubow, B. A. Olson

"A virtual impactor personal aerosol sampler (VIPAS) bas been developed for use in diesel-equipped mines to collect size-separated samples or diesel exhaust and mine dust particles in the respirable size range. This sampler consists or three stages: a 10-mm cyclone, a 0.8- µm cutpoint virtual impactor and two filter cassettes. The large non-respirable particles are removed in a 10-mm cyclone. The respirable particles from the cyclone pass through a 0.8- µm cutpoint virtual impactor with the particles larger than and smaller than 0.8 JI.ID (mine dust and diesel exhaust particles, respectively) collected on two 37-mm filter cassettes. The sampling How rate is 2 L/min so as to be compatible with the standard respirable dust sampler and personal sampling pumps. INTRODUCTIONThe mining industry has been increasing its use of diesel-powered equipment in underground mines, especially in coal mines. With this increased usage has come an increased concern regarding the health effects associated with inhaling diesel exhaust particles since they are in the respirable particulate size range. A Mine Safety and Health Administration (MSHA) advisory committee directed MSHA to develop a sampling protocol for diesel exhaust particles to assess worker exposure (MSHA, 1988). In addition, the National Institute for Occupational Safety and Health (NIOSH) has recommended that ""whole diesel exhaust be regarded as a potential occupational carcinogen as defined in the Cancer Policy of Occupational Safety and Health Administration"" (NIOSH, 1988).Past work, with cascade impactors in both the laboratory and in underground coal mine studies, has shown that the diesel exhaust particles are primarily in the less than 0.8 µm aerodynamic diameter size range whereas the coal dust particles are primarily greater than 0.8 µm (Marple et al., 1986; Cantrell, 1987; Rubow and Marple, 1988; Rubow et al., 1990a, b; Cantrell and Rubow, 1991). This work has been jointly performed by the University of Minnesota and Bureau of Mines researchers over the last 8 years. Typical particle size distributions for a diesel-equipped coal mine and an all electric coal mine are shown in Figure l. Note that the particles in the < 0.8-µ.m mode are the diesel exhaust particles (seen only in diesel-powered mines) and the particles in the > 0.8-µ.m mode are coal particles (seen in both the electric-powered and diesel-powered coal mines). Chemical mass balance analysis was also performed on these two size fractions to determine the degree of particle cross-contamination in the two modes. This analysis showed less than 10% cross-contamination, i.e., in coal mines Jess than 10% of the diesel exhaust particulate was collected in the coarse fraction and Jess than 10% of the mine dust was collected in the fine fraction (Cantrell, 1987; Rubow et al., 1990a)."

Dec 1, 1996