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By L. Cheng, M. S. Seehra, P. S. Raghoottama

The four major IR bands of a-quartz at 1080, 797, 693 and 488 cm-1 are studied at room temperature by FTIR-Photoacoustic Spectroscopy. Using Rosencwaig-Gersho theory, equations for the PAS signal q for the thermally thin and thermally thick cases are derived and it is shown how thin to thick transition occurs and leads to saturation as the sample mass is increased. For sample mass < 2 mg, q is proportional to sample mass thus defining the region for quantitative analysis. The dependence of q on the chopping frequency f is found to vary as q f-n with n ? 0.9 for quartz, in good agreement with the RG theory.

Jan 1, 1989

By Raja V. Rarnani, Robert L. Frantz

"Co-Directors, Generic Mineral Technology Center for Respirable DustEarly in the 1980s, the U.S. Bureau of Mines initiated the concept of the Generic Center, incorporating it into its mining research program, and in 1983, the Generic Mineral Technology Center for Respirable Dust was established. The Generic Center concept was first envisioned by the U.S. Bureau of Mines as a way to bring together the various different scientific, engineering and medical research interests in the respirable dust area to effect a coordinated and efficient organization for advancing knowledge in that field. The result was a combination of the collective talents and skills of more than 100 scientists, engineers, medical personnel and graduate students, through the formation of a consortium of five major research universities, including medical facilities, to perform respirable dust research. The Generic Mineral Technology Center for Respirable Dust consortium comprises The Pennsylvania State University (with its Hershey Medical Center) and West Virginia University (with its Medical Center) as the lead universities and the University of Minnesota, Massachusetts Institute of Technology and Michigan Technological University as affiliates.Although respirable dust-related disease remains the nation's worst industrial hazard, the fundamental understanding of all aspects of respirable dust associated with the mining and milling industries, including the interaction of dust and lungs, has grown significantly over the past near-decade toward the larger effort to reduce the incidence and severity of disease caused by respirable dust. Continued progress toward making the mine work environment cleaner and healthier remains the immediate objective of the Respirable Dust Center.The Respirable Dust Center's research program and technology transfer activities, described in this paper, exemplify the Generic Center concept first envisioned by the U.S. Bureau of Mines. Interdisciplinary and interactive studies continue to result in significant progress toward making mine atmospheres cleaner and healthier."

Jan 1, 1995

By W. T. Millar

Magnetite mines in the Sterling tract, Orange County, N. Y., were operated almost continuously from pre-Revolutionary days until 1923. The Red-Back mine, one of several in this tract, was discovered in 1780; operated briefly in 1880; and abandoned, presumably because the iron ore contained considerable sulfur. The mine is in rough, mountainous country, with altitudes ranging from 500 to 1,100 feet. The magnetite deposit occurs in complex metamorphosed pre-Cambrian formation and is thought to be a replacement of limestone by magnetite. A dip-needle survey, completed in 1916, traced magnetic anomalies for a mile along the outcrop. A preliminary examination of the Red-Back mine was made by W. T. Millar, Bureau of Mines engineer, in December 1942. The Bureau of Mines bored seven diamond-drill holes aggregating 2,727.6 feet during the winter of 1943-44. A zone of magnetite mineralization was intersected in each of the holes.

Jan 1, 1949

By W. C. Phalen

"The Phosphate Rock Market:Indications, in the fertilizer market, point to a prosperous condition, caused chiefly by the growing demand for all classes of fertilizer material in spite of a shortage of supplies. Both of these conditions have been caused by the war. The shortage in phosphate rock is being relieved as production increases, but the supply has not caught up with the demand for this spring's trade, at least. Reports from Florida are to the effect that more than half the necessary quota of laborers are at work. This may not appear to be a very good showing, but even this situation is en¬couraging because there is a larger force now at work than has been the case for some time, and it is steadily, though slowly, increasing. Some of the producing companies are conducting advertising campaigns to get laborers back to the phosphate fields and attractions in the way of better housing and living conditions are being offered.Producers are far more confident about the situation than they were two months ago, and though the shortage will not be met before the end of 1920, theme is a surplus accumulating over what is going out on existing contracts.Quotations are now being offered on all Florida rock excepting land pebble and this, it is expected, will be soon quoted.Quotations on Florida rock per ton are as follows:"

Jan 1, 1920

By R. Barany

The heat of formation at 298.15 ° K of muscovite was determined by solution calorimetry . The value obtained for the heat of formation from the elements was -1,421.2 ± 1.3 kcal / mole , and the value for the heat of formation from the oxides was -55.9 ± 1.3 kcal /mole .

Jan 1, 1964

By R. V. Ramani, K. V. K. Prasad

"Solution of most engineering problems requires, in addition to vast ·numerical calculations, substantial use of practical judgement and expertise. With advances in applied mathematics and computer technology, the numerical aspects of problem solution have reached a considerable level of maturity; However; it is only .recently that approaches like the expert systems methodology have been developed to ·incorporate the Judgemental aspects as well. For rapid development and prototying of expert systems, expert system building tools or ""shells"" have become widely available. For the expert system developer, identification of the key characteristics of the problem domain and selection of the right expert system tool are of crucial importance. In this paper, the important attributes required in an expert system shell for use in the development or a mine ventilation planning expert system are discussed. These attributes are general in that most engineering problems in mining would have these requirements. Also, the results of an exercise undertaken to evaluate commercially available shells for application to mining engineering problems are presented.INRODUCTIONExpert systems (ES) are interactive computer programs which use high quality specialized knowledge in some narrow problem domain to solve complex problems in that domain. These complex problems lack structured and/or standard ways of solution and involve substantial use of subjective and experience based knowledge. One of the first expert systems was MYCIN, developed in 1974, in which subjective and heuristic knowledge of expert physicians was used to diagnose infectious diseases and provide antimicrobial therapy (Buchanan arid Shortliffe, 1984). Since MYCIN, expert systems applications have appeared in other areas such as mineral prospecting (Gaschnig, 1982), configuration of computers (McDermott, 1982) and structural engineering (Bennett and Englemore, 1979)."

Jan 1, 1989

By E. H. Denny

The coal and metal mines of the United States furnish this country with a large part of the fuel and material necessary to support our industries and thus make possible the welfare and prosperity of our people and even the continuance of our present-day scale of civilization. Mining companies furnish material to industry with one general purpose in mind -- the making of a profit on their work. Efforts are being made successfully and continually to reduce operating costs, to increase production per man, and to perform work as far as possible mechanically and with more efficiency. These efforts are made primarily to reduce costs, to increase production, or to do both - in other words to make more profits or more certain profits. In the endeavor to reduce expense companies are considering more and more the factors which enter into costs of production, among them the factor of accidents and their cost. This paper endeavors to estimate the approximate cost of accidents to the mining industry in order to present the saving possible through accident reduction or elimination.

Jan 1, 1929

By Thomas Fraser

The Convertol process, recently developed in western Germany, is a new method of cleaning and dewatering coal-washery slurries. It is a modified bulk-oil process, in which a very small quantity of heavy oil is dispersed over the surfaces of the coal particles, followed by a screen centrifuge operation in which the water and dirt (clay, shale, and pyrite particles) are thrown out through the screen perforations and the clean coal particles are retained on the screen and discharged as a dewatered, clean coal product of 8- to l0-percent surface moisture. It is reported, also, that the process oil, all of which is retained in the clean-coal product, adds to the coking power of the coal and facilitates the production of briquets, reducing the proportions of binding material required.

Jan 1, 1953

By W. E. Miller, G. S. Scott, G. W. Jones

"INTRODUCTION One of the major activities of the Bureau of Mines is the promotion of safety in mining and the mineral industries. Research is undertaken in connection with these problems to determine the explosion and ignition hazards of combustible gases, liquids, and solids and to investigate means of reducing them.Occasionally the Bureau is asked to determine inflammability or ignition temperatures to enhance safety in nonrnineral industries. From time to time it has complied with such requests when no other agency was available to do the work and the investigation could be conducted with a minimum of time and expense. The present investigation is one of this class.Nicotine (C10H14N2), a colorless combustible liquid having a boiling point of 246°C, is usually obtained from tobacco and its products by extraction processes. When heated to its boiling point it decomposes; the purified product is obtained from tobacco extractions by distillation at reduced pressures or is distilled in a current of inert gas.It has an unpleasant odor, a burning taste, and in the undiluted state is highly toxic. Under certain conditions it can be oxidised to nicotinic acid and in the near future may therefore become of considerable economic importance. Nicotinic acid is a component of the vitamin B complex now commonly used to fortify white flour and other foods that normally are deficient in these vitamins."

May 1, 1942

By W. A. Cole

As the mines get older and the active workings get Farther and farther away from the original mine openings, it becomes increasingly difficult and expensive to ventilate most coal-mines properly. At the same time, the avenues of escape for those employed underground have become so extended&apos; as often to make it impossible for them to make their way out of the mine in the event of a fire, mine explosion, or other emergency. Where such Conditions exist, the only satisfactory solution is to make new ventilation and emergency-escape openings near the active mine workings. At most mines this would necessitate sinking shafts, which is often slow and expensive.

Jan 1, 1945

By Marilyn Biviano

This analysis was conducted in response to concerns raised by the Chairman of the Energy and Commerce Committee of the House of Representatives regarding the potential impacts on automobile production, GNP and employment resulting from embargoing south African supplies of the platinum-group metals, platinum and rhodium. This analysis should be considered an addendum to the recently released study in which the direct economic costs I of a U.S. embargo on selected South African strategic and critical materials are estimated. The estimated GNP and employment impacts result when a mineral shortage reduces domestic industrial production and are in addition to the direct costs estimated in the earlier study. The direct cost to this nation resulting from a decision to embargo six south African strategic and critical minerals was estimated at $1.85 billion per year during the 1988-1992 time frame of the study. The estimated direct costs include the costs to U.S. consumers resulting from higher strategic mineral prices, lower mineral consumption, and the cost of developing higher cost domestic mineral resources. A large proportion of the costs result from the shortage of the two metals: platinum and rhodium. The average direct annual cost of embargoing is estimated at about $1.4 billion for platinum and $384 million for rhodium.2

Jan 1, 1988

By R. Hogg

"Agglomeration processes and agglomerate characteristics are largely controlled by the forces of interaction between particles. The nature and typical magnitude of these interaction forces are evaluated relative to the external forces commonly present in agglomeration systems. The specific roles of the interaction forces in the various stages of agglomerate formation and growth and their effects on the integrity and mechanical strength of agglomerates are briefly reviewed. Because the interaction forces affect different aspects of agglomerate development in different ways, conflicting requirements can arise. Examples of such conflicts are given and used to demonstrate the importance of evaluating the effects of interaction forces etc., in the context of the overall agglomeration process and its ultimate objectives.INTRODUCTIONThe term agglomeration is generally used to refer to processes whereby discrete particles are caused, or allowed, to associate into clumps in which the individual particles retain their identity but are held together by relatively weak, usually physical forces. Various other designations are given to these processes, depending on the specific circumstances under which agglomeration occurs. The terms balling and pelletizing are often used to describe agglomeration in dry or semi-dry powders; coagulation and flocculation are used to refer to agglomeration of particles dispersed in fluids. Common to all of these cases is the fact that the formation, growth and integrity of the agglomerates depend primarily on the forces acting on and between particles. The same forces are, of course, responsible for manyaspects of the behavior of colloidal systems and their study and evaluation constitute the,basis for colloid and interface science.FORCES ACTING ON FINE PARTICLES AND AGGLOMERATES It is convenient to classify the forces acting on and between particles into two general types: external forces and interaction forces. It should he recognized, however, that a sharp distinction is not always possible.External Forces Gravity and inertial forces act on all particles and their magnitude is proportional to particle mass, i.e. they vary with the cube of particle size. Such forces are oftensignificant for large agglomerates but may be negligible for individual, fine particles.Hydrodynamic (""drag"") forces are important, for particles suspended in fluids. For very small particles, the drag force is directly proportional to size (Stokes' Law) while for very large particles or agglomerates it varies with approximately the square of size (Newton's Law). A useful procedure for estimating drag forces over a broad range of particle sizes and physical conditions has been given by Concha (1)."

Jan 1, 1989

By Deborah A. Spotts

Researchers at the Bureau of Mines have developed a technique for re- generating chromic acid-sulfuric acid etching solutions used in metal surface treatment operations. The technique utilizes a diaphragm cell equipped with a cation-selective membrane to oxidize cr3+ to cr6+ at the anode and to remove copper, the major metallic contaminant, at the cathode. Normally, spent etchant is discarded after approximately 3 days of use. Using the electrolytic cell, the etchant can be used for a year without replacement, From data obtained from industrial-scale cells, the installation of a regeneration cell with a 1,000-gal catholyte- holding tank has been estimated to save at least $240 per day, The payback period for the investment is estimated to be about 10 mo or less. Because the magnitude of these cost savings will vary at different locations, several graphs are presented to aid in calculating payback for a specific site. Using these graphs and the capital costs presented in this study, the payback period can be determined for installing a regeneration cell with a 500- or a 1,000-gal catholyte-holding tank in an existing surface treatment plant.

Jan 1, 1983

By F. Garcia, J. Cervik

Recent advances in the commercial separation of gases using membranes have renewed interest in the possibility of applying this technology to the recovery of methane ( CH4 ) from mining operations . This Bureau of Mines report briefly reviews the history of the development of membranes for gas separation , the theory of how they work , and their application to the separation of methane from air and associated problems . However , methane -air mixtures are difficult to separate with membranes because the pertinent gas couples , 02 - N2 , 02 - CH4 , and N2 -CH4 , have poor separation characteristics , as indicated by their separation factors of about 3 or less . Even if these separation factors were substantially higher , there is doubt that methane could be recovered economically from the low concentrations in mine ventilation exhaust ( 2 vol pct or less ) . The exhaust pressures are not sufficient for adequate separation . The power cost of compressing the methane recovered . these mixtures would far exceed the value of New discoveries could make separation of gob hole methane - air mixtures practical . These mixtures have much higher concentrations of methane (from 30 to 100 vol pct ) ; however , for safety reasons , be limited to gob gas with 60 vol pct CH4 or more .

Jan 1, 1988

By V. F. Parry

Under the present emergency every consumer should store as much coal as he can. Although there is no shortage of coal, there is likely to be a shortage of labor to mine excessive quantities in the fall, and railroads cannot be expected to deliver coal promptly on account of the need for transporting war materials. Some miners must join the armed forces, and those who are left may be unable to mine coal as rapidly as you will need it when winter comes. When the first cold days arrive, there may be a shortage of trucks to deliver coal. Deliveries may be planned in advance, and your turn might not come until it is too late.

Jan 1, 1942

By H. S. Caldwell

This report describes work by the Bureau of Mines on the vacuum distilla¬tion of some of the more volatile metals such as cadmium, zinc, and magnesium from lead and tin. Evacuation within a distillation apparatus allows rapid diffusion of vapor away from the evaporation surface and prevents reaction of the vapor with residual gases. A reduction of pressure to several tenths of a millimeter makes possible practicable distillation rates, at temperatures for which the partial pressure of the metal vapor exceeds 10-3 atmosphere. The rate and selectivity of distillation depend primarily on the volatility and molal ratios of the alloy metals, and their chemical activity to each other. For very rapid evaporation or low concentration of the more volatile constituent, the rate is determined by the rate of diffusion of the evaporating metal, to the surface of the melt. Cadmium, zinc, magnesium, and tellurium were found to volatilize readily from both lead and tin. Tellurium appears to volatilize as an intermetallic compound rather than the pure metal. Antimony could not be removed from lead at 1,000° C.; the condensate was nearly all lead. Antimony, bismuth, and lead were removed from tin.

Jan 1, 1960

By Paul W. Jeran

Subsidence was monitored by the U.S. Bureau of Mines over the ends of longwall panels operating in the Pittsburgh, Kittanning, and No. 2 Gas Coalbeds of the northern Appalachian Coal Basin. The final subsidence over the finishing ends of three panels in the Pittsburgh Coalbed are compared with the subsidence measured over the rib at these panels. The characteristics of subsidence are different. At Mine A, data over the start of a longwall panel shows similar characteristics to the subsidence measured over the rib. Subsidence over the fmishing ends of panels in the Kittanning and No.2 Gas Coalbeds are also different from the subsidence over the rib. The use of a subsidence prediction model based on data gathered over the rib of a panel will not yield accurate results if it is applied to the finishing end of a longwall panel. Acceptable results may be obtained along the centerline over the starting end of a panel.

Jan 1, 1991

By Guy A. Johnson

This Bureau of Mines report summarizes the results of efforts to develop reasonably priced, reliable mine shaft fire and smoke protection hardware for metal and nonmetal mines. The hardware was incorporated into a viable prototype system that would minimize fire and smoke hazards. The design of the system had to be sufficiently flexible to be utilized in a wide variety of metal and nonmetal mine shaft and shaft station configurations. As a result of long-term, rugged field tests, an improved (second generation) system was developed. The hardware is now commercially available.

Jan 1, 1978

By P. G. Kovalchik

Overexposure to noise remains a widespread, serious health hazard in the US mining and other industries despite 25 years of regulation. Most categories of illnesses and injuries associated with mining have improved, with the exception of hearing loss. The drilling of rock in a confined work environment contributes to high levels of noise exposure in mining. The National Institute for Occupational Safety and Health (NIOSH) is conducting research to reduce the noise exposures of jackleg drill operators and to prevent additional cases of noise induced hearing loss (NIHL) by developing and evaluating low-cost retrofit noise controls for equipment. This report describes the procedure for the measurement and reporting of noise from portable pneumatic tools such as jackleg drills. The technique used in this research allows for the determination of the source A-weighted sound power levels and the radiation patterns in octave and 1/3 octave bands. Overall sound power level is also determined. This paper also reports the results obtained by using this procedure to evaluate a SECO S215 standard production drill and a CSIR Miningtek prototype rock drill incorporating engineering noise control measures. It was found that by using the manufacture?s recommended operating pressure of 496 kPa (72 psi) that the CSIR prototype?s sound power was 10 dB(A) less then that of the SECO S215.

Jan 1, 2009

By G. L. Oldright, Virgil Miller

"INTRODUCTION The first ten papers of the series on smelting in the lead blast furnace described the operation at the custom smelter of the International Smelting Co., Tooele, Utah, and at the plant of the Bunker Hill Smelting Co., Kellogg, Idaho, which handled a very rich lead concentrate. These previous papers may be considered a picture of the traditional lead smelter treating custom ores and of the smelter that will treat the type of product likely to be made in the future - lead concentrates of an increasingly rich grade.The great plant at Trail is of special interest to those smelting lead products containing much zinc and faced with the necessity of transforming all of their byproducts into commodities which may be sold profitably. The plant is equipped to produce electrolytic zinc, lead, copper, silver, bismuth, and cadmium. Part of the sulphur evolved from treating the ores is converted into sulphuric acid. Complete fertilizers for agricultural purposes are also produced.The smelter of lead ores has long considered that zinc is one of the most difficult ingredients that he has to handle. Even with the gretat improvement in flotation practice today, the residues from electrolytic zinc plants leaching zinc concentrates must still be smelted for their lead content. Of the total gangue material not separated from the lead concentrate sent to the smelter, zinc is still one of the most notable in percentage. The most successful way of coordinating the over-all operations of a concentrator, an electrolytic zinc plant, and a smelter provided with a plant for re-treating the blast-furnace slag for its lead and zinc content must be of interest to many treating complex ores.ACKNOWLEDGMENTThe data in this paper were collected in cooperation with the Consolidated Mining & Smelting Co. of Canada, Limited, and its entire technical staff. Detailed acknowledgments of assistance received are given in the papers from which this one is briefed."

Sep 1, 1934