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By E. Ghali, C. Su, G. Houlachi

"The influence of lead ions on zinc electrowinning process was investigated by means of electrochemical noise measurements (ENMs) and cyclic voltammetry in conjunction with scanning electron microscopy and X-ray diffraction. All electrochemical experiments were performed in sulphuric acid electrolyte containing different lead ion concentrations as impurity. Lead was added in six trace levels between 0.05–0.8 mg/L in the bath. The lead content of the zinc deposits was dependent on the introduced lead concentrations. The overpotential associated with zinc electrodeposition shifted to higher values with the increase of lead concentration in the solution. An appropriate correlation was found between the different concentrations of lead in the electrolyte and the morphology of zinc deposit by ENM. The results showed that the increase of lead ion concentrations is generally accompanied with the decrease of skew and increase of kurtosis values that could be related to the morphology of zinc deposit. Effectively, the morphology changes from well-defined hexagonal platelets to large hexagonal, layered platelets and finally to non-symmetric refined crystalline structure, respectively.INTRODUCTION In commercial zinc electrowinning, zinc oxide is leached from the roasted calcine with an aqueous acid sulfate electrolyte. Then the zinc-rich solution is purified and transferred into an electrolytic cell. During electrolysis, zinc is deposited on aluminum cathode where lead-silver or pure lead is served as anode. Electrodeposition of zinc could be influenced by several parameters such as bath acidity, temperature, current density, the nature and concentration of impurities as well as additives in electrolyte. Metallic impurities play a complex role during zinc electrowinning and they can adversely"

Jan 1, 2016

By L. M. Guayacán-Carrillo, G. Armand, A. Noiret, D. Seyedi, S. Ghabezloo, J. Sulem

"The main purpose of this paper is to analyze the convergence measurements in a drift excavated in the Callovo-Oxfordian claystone. The drift axis is in the direction of the major principal horizontal stress whereas the stress state is quasi-isotropic in the drift’s section. The initial geometry of the drift being circular, the anisotropic character of the deformation is taken into account by assuming that the drift shape evolves in an elliptical shape. The convergence measurement data on six different points around the drift are analyzed to identify the main axes of the deformation ellipse, following the methodology proposed by Vu et al. (2013, Rock Mech Rock Eng, 46, 231-246). Then, using the semi-empirical law proposed by Sulem et al. (1987, Int J Rock Mech Min Sci, 24, 145–154), the convergence evolution is fitted independently for each axis of the ellipse. This method permits to distinguish two effects: the face advance effect and the time-dependent behavior of the ground. The results for the two directions of the ellipse axes show very close values for the parameters describing the time-dependent properties of the ground, the distance of influence of the face, and the extension of the decompressed zone around the gallery. Such model can provide valuable insights for predictions of the convergence evolution in the long-term. INTRODUCTIONDeep disposal of radioactive waste has been studied in France for more than two decades. The French National Radioactive Waste Management Agency (Andra) began in 2000 the construction of an Underground Research Laboratory (URL) with the main goal of demonstrating the feasibility of a geological repository in Callovo-Oxfordian claystone. Several research programs have taken place to improve the knowledge of the rock properties and its response to the excavation progress. The optimization of supports design for long-term behavior is an important point to develop. A network of experimental drifts has been constructed with variations on: excavation method, structure geometry, supports system and orientations with respect to in-situ principal stresses’ directions. In each drift different sections have been instrumented to monitor the convergence evolution and the rock deformation. Continuous monitoring of the excavated zone around the drifts revealed the development of a fractured zone (extensional and shear fractures) induced by the excavation. The extent of this fractured zone depends on both the drift orientation and the in-situ stress field (Armand et al., 2014). Indeed, the fractures distribution has an important influence on the convergence of the drifts."

Jan 1, 2015

By R. Gordon, J. Palich, W. Qian

The EarthProbe DCIP system deploys tightly spaced electrodes connected to a centralized data acquisition system that enables arbitrary selection of current and potential electrodes through relays. Rapid data collection (approximately 1000 readings per hour) and advanced signal processing allow for efficient use of conventional and novel arrays and the removal of natural and cultural noise. What is unique about the system is its electrode and borehole cable design, which allows seamless integration of borehole and surface measurements. EarthProbe operates in four configurations - surface, borehole, borehole-to-borehole, and surface-to-borehole (a variant of the borehole-to-borehole configuration).

Jan 1, 2011

By Mohammad. M. Khajeh

Rock mechanical properties are important parameters in geomechanical simulation. Considering stochastic heterogeneous models rather than conventional homogeneous layer cake models leads to more realistic simulation results and uncertainty assessment. These heterogeneous models are usually fine scale models generated by geostatistical techniques. Although considering high resolution property models is desirable, geomechanical simulation with a fine scale model is not computationally feasible for full?field, coupled geomechanical-flow simulation. Upscaling of property models is necessary to move from fine scale/high resolution property models to coarser scale/low resolution models appropriate for simulation. Local numerical upscaling was proposed by Khajeh et al. (2012) to describe the macroscopic elastic behavior of complex heterogeneous media and is expanded upon in this work. This numerical technique is not restricted to specific geologies as typical analytical techniques are. Moreover, transversely isotropic deformation is considered rather than the usual assumption of isotropic deformation. To compare the accuracy of the upscaling methodology, in this study shear strain is considered as the geomechanical response of a synthetic facies model and the response of the coarse scale model is compared to other conventional analytical averaging techniques. It is found that the numerical upscaling technique better approximates the geomechanical response of the fine scale model.

Jun 1, 2012

"Coupon testing has been used to investigate stress corrosion cracking (SCC) of rockbolts in a laboratory based experimental program. This program has focused on the use of ASTM G39 three- and four-point bent beam coupon specimens, immersed in an acidified sodium chloride test solution containing hydrogen sulfide. The specimens were loaded to a range of stresses from zero, to just above the materials yield strength. It was found that only specimens above an applied stress of 580MPa failed by means of SCC, showing that rockbolts loaded to near their yield strength may be susceptible to SCC in-situ.INTRODUCTIONStress corrosion cracking (SCC) is a failure mechanism that affects material through the growth of hairline cracks when exposed to a corrosive medium while under stress (Jones and Ricker, 1999). SCC has been found to affect rockbolts in the Australian underground coal mining industry and has the capacity to cause the catastrophic failure of ground support systems, potentially leading to falls of ground in underground excavations, injury or death to mine personnel, damage or loss of equipment, and loss of productivity through the loss of roadway access (Crosky et al, 2002).Coupon testing utilises small scale samples that are intended to be indicative of the behaviour exhibited by a material in-situ (ASTM G39). The small scale, and usually high surface area to volume ratio of coupon specimens mean that they corrode at faster rate proportional to their mass, greatly reducing testing times. The small scale of the specimens allows them to be more easily prepared and handled, loaning them to mass manufacturing techniques.A previous study conducted by Vandermaat et al (2012b) into the use of three- and four-point coupon testing in-situ in an underground coal mine failed to result in SCC of the specimens. This paper serves as a follow up laboratory investigation in order to understand why these specimens did not fail. Previous studies into the SCC in rockbolts carried out by Gamboa and Atrens (2003) determined that rockbolt steel has a critical stress threshold of approximately 90% of the material ultimate tensile strength (800-900MPa). This study will focus on this critical stress threshold as a possible explanation for the lack of failure in the in-situ specimens (Vandermaat, 2012b)."

Jan 1, 2015

The tensile test results of as-cast A356.2 grain-refined alloy castings show that the tensile strength can be improved by strontium modification (`SrM'), superheating at 900°C OM, and melt thermal treatment of the Sr-modified alloy melt (`SrMTT'). Both SrM and SrMTT processes can greatly improve the ductility (percent elongation) of the as-cast alloy. During solution heat treatment at 540°C, eutectic Si particles undergo fragmentation, spheroidization, and coarsening, thereby affecting their morphology. The effects of solution heat treatment on the tensile properties of the variously treated A356.2 alloy castings can be summed up as follows: the yield strength of the castings is significantly improved after 8 h solution heat treatment due to the precipitation of Mg2Si, after which it remains more or less the same with the further increase in solution treatment time up to 80 h; the ultimate tensile strength is also greatly improved within the first 8 h of solution heat treatment and then remains at the same level thereafter, up to 80h of solution treatment. The improvement in UTS is attributed to Mg2Si precipitation, dissolution of Si within the aluminum matrix, and changes in the Si particle morphology (spheroidization). The ductility of the as-received grain refined non-modified (`NM'), grain refined and superheated at 900°C (`SH'), and melt thermal-treated grain refined (`MTT') A356.2 alloy castings can be improved considerably with solution heat treatment e.g. from ~6% in the as-cast non-modified casting to ~10% after 80 h solution treatment.

Jan 1, 2011

By W. J. Adams

It is recognized that within life cycle assessment that the eco-toxicity potentials (TPs) derived for metals require additional research to improve their reliability. Current models used to develop TPs do not include important fate process for metals such as speciation and bioavailability. Toxicity potentials are standard values used in LCA to enable a comparison of potential toxic impacts between substances. Huijbrechts (2001) calculated toxicity potentials for 181 substances utilizing the USES model for six impact categories, i.e. freshwater aquatic ecotoxicity, marine aquatic ecotoxicity, freshwater sediment ecotoxicity, marine sediment ecotoxicity, terrestrial ecotoxicity and human toxicity (not considered here). Marine ecotox potential for metals is typically high using this approach, whereas most open ocean metal concentrations are very low. A sensitivity analysis of the USES-LCA model was undertaken using copper as an example. Results indicate: fate processes on the global scale are driving the marine water and sediment TPs for copper most; the second most important fate parameter is sedimentation from the water and burial in deep sediment layers; inclusion of speciation and bio-availability processes would be very beneficial; more accurate estimates of input parameters should be used, and the PNECwater and PNECsediment and all partition coefficients for metals should be updated in the model.

Jan 1, 2007

By Y. M. Shneerson, E. E. Zhmarin, E. M. Vigdorchik

One of the Gipronickel Institute activities is research and development of customized leaching technologies. The work is performed in several steps. Leaching kinetics are studied on a lab-scale according to a special procedure. Experimental data are processed using mathematical models of batch and continuous processes. Reliability of kinetic data and preliminary calculations is verified experimentally in laboratory reactors of various capacities. If necessary, certain parameters of the mathematical model are adjusted after pilot plant tests in continuous mode ( 4-reactor train, each with 25 L capacity). The specified kinetic characteristics along with the mathematical model are used for further development of industrial leaching technology.

Jan 1, 2005

By D. O. DeGagné, J. F. Archibald

Spray-on polymer linings, as partial or full replacement for traditional forms of area rock support, have seen rapid growth in interest within Canada. A wide variety of lining types, ranging from polymer chemical to water-based cementitious materials, have been developed and commercially introduced to the underground mining market. Following approximately one decade of development work, several general conclusions have been reached regarding the performance of this class of area support media, these being that: health and safety assessment of the broad range of materials has shown the majority of them to be acceptable and safe for underground use; significant ground support potential can be offered by them, being equivalent to or better than capabilities offered by traditional support forms such as bolt-and-screen or shotcrete, and; their abilities to be rapidly deployed and provide near instantaneous support restraint offer considerable operational and cost benefits to underground operators. A review of currently available liner materials, their historic development within the Canadian mining industry, and overviews of support, health and safety, operational considerations and cost benefits are provided in this paper.

Jan 1, 2001

By J. F. Wang, Y. Jin, Z. L. Wang

Smelting reduction as an ironmaking technology for the 21st century has been challenging the traditional blast furnace. The process has many attractive advantages over the blast furnace, however, the massive by-produced coal gas mainly containing CO, H2 and CO2 requires further treatment. From a chemical engineering view, coal gas is a valuable chemical stock and can be transformed into hydrogen-rich synthesis gas. Hydrogen can be directly used as clean fuel and synthesis gas can be used for the production of some important chemicals such as methanol, ammonia and dimethyl ether. Among those chemicals, dimethyl ether as an alternative clean fuel for diesel engine and liquefied petroleum gas has been drawing more attention. It has excellent environmentally-benign behaviours not only in compression ignition combustion, but also in the much lower emission of SOx and NOx. In this work, a combined technology of smelt reduction ironmaking and direct synthesis of dimethyl ether, which will strongly promote the energy efficiency, environmental protection and resource recovery, is proposed and described in detail.

Jan 1, 2004

By E. Demedde

Carbon anodes in aluminium reduction cells are continuously consumed during electrolysis. In prebake cells the anodes are replaced at regular intervals. The spent anodes, called butts, are often allowed to cool in air while emitting fluorides into the building from the hot alumina cover and the adhering bath. In modem smelters spent anodes are placed inside enclosures and fluoride emissions during cooling are effectively reduced. Fluoride emissions from spent anodes were estimated by considering the kinetics of fluoride formation, a heat transfer analysis of the cooling anode butt and the ventilation flow from a cavity. Fluoride emissions from large anode butts cooling inside enclosures were compared with those cooling in air. Good agreement with published experimental values was obtained for enclosures having different leakage opemngs, when a hydrofluorination reaction of the spent anodes was included.

Jan 1, 2006

By Alexander Potapov, Lawrence Nordell

A Conjugate Anvil-Hammer Mill (CAHM) has the potential to replace conventional crushers and SAG mills, with their respective conveyors and stockpiles, in a SABC circuit. It may improve comminution circuit efficiency by 100%. CAHM compresses rock in a more efficient way, similar to 19th century stamp mills, which follows the fundamental research of Schönert (1990 & 1996). CAHM efficiency is being proven through the use of ROCKY (2011) Discrete Element Method (DEM). ROCKY features allow it to simulate realistic comminution. CAHM is customizable with many geometries that are rock-property specific. ROCKY’s wear modeling compliments the structural integrity of the design.

Jan 1, 2012

By Navid Bahrani

Introduction ? Today?s economic market is motivating underground mining companies to increase development advance rates and enhance their NPVs. ? For example, block cave mining involves development of kilometers of drifts with multiple pillars. ? The cyclic nature of drill and blast, and its inherent tendency to damage the surrounding excavation rock mass and increase support demand often result in poor advance rates ? This has motivated mining companies to replace the conventional drill-and-blast as the main excavation method with alternative methods such as mechanized excavation. ? There is little experience with mechanized or non-explosive excavation methods in hard rock metalliferous underground mining.

Oct 1, 2010

By I. Yarita

Magnesium alloys have the lowest density among the metals in practical use, and have properties such high specific strength, electromagnetic interference shielding and good vibration damping. Thus, there are many applications of these materials in automotive and electric parts. However, there is a little use of the products of metal forming of these materials because of poor plastic deformability in the normal temperature range and their high cost of production. To expand the range of application of products manufactured by metal forming, rolling technology for producing thin sheets having good mechanical and surface qualities is required. In this study, hot-rolled Mg-alloy sheets are experimentally rolled with or without lubrication in the temperature range from 293 K to 523 K. Rolling force, plastic deformability and surface quality are investigated, and the grain structures and their uniformity are observed. The effect of friction between the roll and the deforming material on the uniformity of the grain structure is discussed. Moreover, rolled materials are annealed and their mechanical properties are investigated by the tensile test and compared with those of as-rolled materials. The effects of the rolling conditions on the mechanical properties are discussed.

Jan 1, 2006

By H. J. Ni, M. Y. Huang, S. W. Chen

The effects of several fluxes on purification, microstructures and properties of A00 aluminium have been studied. The experimental results and analyses indicate that many cracks and large porosities exist in the surface film above the melt purified by C2Cl6 and that the film is floe and mostly composed of AhO3 and pure aluminum, which carries many carbon particles and AlCh not fully volatilized. And then over 50% of the all-melting residue is pure aluminum, which is one of the major reasons for high melting loss. Moreover, because of a mass of gas bubbles and a state of seethe, there exist many inclusions which size is under l0µm in the microstructure of A00 aluminum purified with C2Cl6 or fluxes containing C2Cl6- With this purifying method, the aluminum crystal grains are extended along the radius that was observed firstly and the average crystal size of A00 aluminum are about 100µm~150µm. In addition, small size inclusions have little affected on tensile strength and micro inclusions under l0µm have little affected on elongation.

Jan 1, 2006

By Kremena Dedelyanova

The paper presents research of mechanism for the creation of air bubbles in vibratory a column flotation machine. Factors are discussed that influence the increase in the duration of the bubble in the area of contact with the mineral particles. Formulas are derived for the parameter effect of vibrations, applicable to the design of flotation machine. The collision efficiency of the bubbles in a vibratory column flotation machine is determined.

Aug 1, 2013

By P. Reyes

The Codelco Chile El Teniente Division Caletones Smelter has an objective to smelt 1,250,000 tonnes per year of copper concentrate. This is a great challenge for the smelter facilities and particularly for the acid plants. The analysis ensuring that there are no obstacles to achieve the production capacity was of great importance. Therefore a series of activities were undertaken as well as studies dedicated to reach the target. This paper presents work focused on a fluid dynamic study, translated in an operation methodology of integrated handling of the smelting and converting gases with the objective to optimize the gas flow and S02 concentration. The optimization should be done employing the current installations, equipment and instrumentation and/or minor modifications. In the first part of the work the condition of the instrumentation involved in the gas handling was checked, improvements determined and the corresponding corrective actions were carried out. The proposed operation method consists of operation of the Cleaning Gas Plant 2 (TC' s gases) and operation of Gas Cleaning Plant 1 (the remaining gas plus the gases from CPS). The implementation of the operation method involves the modification of the valve of the gas into the duct to plant 1 from On to Off to modulate flow. After modification a three days test was carried out. To evaluate the tests, a "Sulphur Capture" indicator was used. During the test the behaviour of the effluent treatment plants was closely examined. No problems or unusual operating conditions were observed. The reduced flow of gas to Gas Cleaning Plant No. 1 permitted the start up of the 2nd test day treating most of the gas received by Gas Cleaning Plant No. 2. The operation was carried out with the limitation not to increase the effluent pond level, which was maintained constant.

Jan 1, 2007

By J. L. Bowlby

TWO years ago, at the annual meeting of this Society, the writer presented a paper dealing with various aspects of the water problems existing in the Cape Breton coal-mining area. Much of that paper was of a theoretical nature, in that an attempt was made to get at the fundamental principles underlying the problems, in order to establish a sort of background against which future results could be laid. Up to that time, only Central power plant in Glace Bay had been under observation, and, since the work had been in progress only a year, it was recognized that there were strong possibilities that certain variations in procedure might have to be introduced as w; became better acquainted with our problem. We were by no means certain that we had covered all the facts of the case. The present paper will therefore be of the nature of a progress report, rather than a formal contribution to the Society. Subjects of a theoretical or academic nature will be avoided as far as possible, attention being confined chiefly to the results obtained during the past two years. In looking over the work with low-pressure boilers, there are certain general conclusions that can apparently be safely drawn. Wherever possible, proper operating conditions will be expressed in terms of appropriate units. Absence of corrosion in boilers where the alkalinity has been maintained within the pH range 11.0 to 11.4 forces one to the conclusion that these are safe working limits. Previous experience had shown that corrosion would occur if the alkalinity were much reduced. Higher alkalinities are un-necessary, more expensive, and are said to introduce the possibility of pitting. We made no attempt to obtain quantitative data in respect to pitting. It is said to occur at pH 12.0. Consequently, conditions of alkalinity were main-tained well below this figure. In the above paragraph, the pH range 11.0 to 11.4 applies to boiler waters which have received the lime and soda treatment. The general practice, when this treatment is employed, is to use 1.0 lb. lime to 7.0 lb. washing soda. At Central power plant, soda-ash is at present substituted for washing soda, the equivalent proportions being kept the same. But not all the plants are on the lime and soda treatment. At Waterford Lake, a 1: 1 mixture of soda-ash and trisodium phosphate is satisfactorily employed, and in Sydney Mines and at No. 3 power plant in Sydney, good results are being obtained at a somewhat greater cost with a commercial phosphate treatment.

Jan 1, 1936

By F. L. Pellet, S. Maiolino

"The determination of rock bolt contribution to reinforced joint shear strength is still a challenge, especially for assessing reinforced rock mass stability. For this purpose, several experimental studies have been performed during the last decades, mostly on small scale rock joint and bolt specimens. However, to accurately assess the rock bolt contribution, scale effect has to be accounted for. For this reason full scale lab tests are required as an alternative to in situ tests for which boundary conditions are more difficult to control.In this paper the results of an experimental program carried out with a large shear box, dedicated to test bolts in full scale conditions is presented. Different rock bolt diameters and different rock bolts inclination with respect to the shear plane were tested Experimental results were satisfactorily compared with an analytical model which is able to compute the contribution of the rock bolt to the shear strength of the joint as well the associated displacement of the joint. These conclusions allows us to validate the model in order to help the designer of reinforced rock engineering structures, such as slope or underground openings, to precise the optimum installation of rock bolts. INTRODUCTIONFully grouted rock bolts are commonly used for rock masses reinforcement to ensure the stability of rock slopes and underground cavities. For this purpose, the determination of rock bolt contribution to reinforced joint shear strength is of the utmost importance. During the last decades, several experimental studies have been performed to investigate the behavior of bolted rock joint. For obvious reasons, almost all the experiments were achieved on small scale bolted rock joint specimens (Bjurström, 1974; Azuar, 1977; Dight, 1983; Egger & Fernandes, 1983; Schubert, 1984; Spang & Egger, 1990; Egger & Zabuski, 1991). These studies made it possible to assess the influence of different parameters such as the bolt’s diameter, the number of bolts, the angle between the bolt and the joint, the nature of the rock, the friction and the dilatation angle of the joint. However, to accurately assess the rock bolt contribution, scale effect has to be accounted for (Vallier et al., 2010). For this reason full scale lab tests have been performed as an alternative to in situ test for which boundary conditions are more difficult to control."

Jan 1, 2015

By A. J. W. Law

"This paper deals with the organization of the central office technical areas and the role played during the feasibility studies, construction and operating phases of Les Mines Selbaie.HistoryThe Engineering Department was originally formed as a part of the Exploration Department, to examine the feasibility of advanced exploration prospects being brought to the company. In 1968, with the discovery of the South Bay property in northwestern Ontario, the department became part of a Mining Division and was expanded, so that it could provide more advanced mine feasibility studies, control of construction engineering and procurement and initial mine design. As is generally the case, the mine design function was handled with in-house capability, while plant, mill and const ruction functions used outside consultants.The 1974 discovery of the Selbaie deposits, started a period o f growth in the capabilities o f the department. The complex nature of these deposits, required that skills were added in the mining, metallurgical and plant areas. During the early feasibility study period these skills were provided by the engineering company of the parent group, but when it was realized that production from the deposits was likely, permanent staff was added."

Jan 1, 1990