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By A. Klingberg, M. Svensson, N. Smolko Schwarzmayr

"Removal of silicates and carbonates from sedimentary phosphate ores by the use of new synthetic collector/formulations was investigated in a comparative study with traditionally used collector systems as references. In the direct carbonate flotation the new formulations showed higher efficiency, contributed to an improved balance of P2O5 recovery and P2O5 enrichment in the recovered material. Efficiency of the new formulations containing synthetic surfactants was 1.5–2 times better than potassium salt of fatty acid sulfonate based formulations that are traditionally used for that purpose. The new formulations also provided up to 7% increase in P2O5 recovery at the same P2O5 grade. The new synthetic collectors for removal of silicates showed extremely good selectivity towards silica bearing minerals. The selectivity factor for the flotation tests when new formulations were used was 32–52 and for the flotation tests with the traditional collectors: 20–32. The ratio between distribution of an amount of silicates (as SiO2) and distribution of phosphate in the froth (waste) is defined as the selectivity factor. The new formulations provided more than 2% decrease of the amount of SiO2 at the same P2O5 recovery.INTRODUCTIONPopulation growth and decrease of arable land are the main reasons for constant increase of consumption of apatite (phosphate ore) in the fertilization field (Lannefors, Gorochovceva, Klingberg, Lima, & Gustafsson, 2015). Fertilizers play a key role for farmers to produce more with less land. The phosphate component of the fertilizer is vital for producing healthy and large amount of crop. As a result the demand for phosphate rock is growing.The largest producers of phosphate rock are the Unites States, Morocco, Tunisia, China, Russia, and Brazil. The term “phosphate ore” includes all phosphate-bearing minerals and rocks, but only two of them are of industrial interest: apatite (igneous origin) and sedimentary phosphate (Peres, Araujo, El-Shall, Zhang, & Abdel-Khalek, 2007). The majority of the world’s phosphate deposits are of the sedimentary type. There are two different types of sedimentary phosphates: siliceous and carbonaceous which are categorized based on gangue minerals (such as quartz, carbonates, mica, and clay)."

Jan 1, 2016

By Yanping Xiao, Ton van Sandwijk, Gus Van Weert, Larry McHugh, Thomas Zabev

"All attempts to remove significant amounts of arsenic from enargite via neutral or reductive pyro routes have required operating temperatures between 600 and 700 º C, too high to propose an equipment development program. Operating at reduced pressures, or using hydrogen or elemental sulphur as a sweeping gas did not help to lower these temperatures. Admixing iron powder gave excellent results, but still required 700 º C. By fortuity, in recent experiments to produce tennantite from an enargite mineral sample, it was observed that enargite was completely converted to bornite, chalcopyrite with minor residual tennantite within an hour at 400-450 ºC. This is believed to be due to the presence of pyrite in the mineral sample treated. All earlier decomposition work appears to have been done on predominantly enargite (i.e. low pyrite) samples, or at high operating temperatures, ignoring possible reactions at lower temperature. The decomposition of enargite into iron substituted tennantite plus some bornite under evolution of liquid elemental sulphur, followed by further decomposition of this tennantite into bornite and volatile arsenic sulphides, appears experimentally feasible at these low temperatures and mimics described ore genesis pathways at > 250 ºC in saline solutions. We suggest two pathways to describe the observed experimental results:20 Cu3AsS4 + 12 FeS2 ???5 Cu10Fe2As4S13 + 2 Cu5FeS4 + 31 S(l)31 S(l) ???31 S(g) (evaporation)5 Cu10Fe2As4S13 ???10 Cu5FeS4 + 10 AsS(g) + 5 As2S3(g)"

Jan 1, 2014

By J. N. Hilton, D. Moffett, E. Barnes

"A recent pilot-plant program carried out at Rio Algom's Quirke uranium mine at Elliot Lake, Ontario is described. The goal of the research was the production of tailings basin effluents which were low in total radium-226. The process tested involved precipitation of radium with barium chloride and sedimentation in plastic-lined settling ponds. Adjustment of the tailings basin overflow from its normal value of pH 9.5 by addition of sulphuric acid to about pH 7.5 was found to give approximately a five-fold improvement in total radium-226 removal. A five-month demonstration test resulted in an effluent with a mean total radium-226 activity of44 pCi/L after 2.5 days settling time and 29 pCi/L after 5 days. The results from the demonstration program are used to propose a schedule of achievable total radium-226 activities where precipitation and sedimentation are employed. The maximum suggested values for 5 days nominal settling time are: 30 pCi/L in an annual mean, 45 pCi/L in a monthly mean. 60pCiIL in a weekly mean and 80 pCi/L in any single grab sample.IntroductionRadium-226 has been removed from effluents at the Elliot Lake uranium mines since the introduction of the first barium chloride treatment system in 1965. Current practice, which has changed little over the years, consists of radium-barium sulphate precipitation by the addition of a low do se of barium chloride to the clear overflow from the tailings basin(l·2l. Provision is made for the precipitate to settle in large natural or constructed ponds and lagoons. The residence time in these ponds, which depends on the site, ranges from 3 to 35 days, with varying degrees of efficiency being achieved."

Jan 1, 1981

By José J. Suárez

Abstract: Globally, the mining industry is expected to face the following challenges through 2020: 1. Sustaining growth amidst fierce competition 2. Containing cost increases and managing through the cycle 3. Attracting and retaining talent 4. Managing environmental concerns and improving sustainability 5. Managing volatility risks in commodity markets Our experience and research reveals that the higher performing global miners are adopting many of the following strategies: (1) Adopt a Global, Agile Operating Model (2) Be the Developer of Choice (3) Drive Capital Efficiency (4) Be the Employer of Choice (5) Integrate the End-to-End Business Model (6) Move to the Virtual Mining Value Chain This paper/presentation will provide data obtained through research on five (5) challenges facing the mining industry, and on the six (6) strategies that high performing global miners are adopting.

May 1, 2013

By Gary Pattrick

A new class of spongy Au catalysts is studied for the selective catalytic reduction of NOx by propene under leanburn conditions. The spongy catalyst is an unsupported powdered Au that consists of micrometer particles (~5 microns) that have nanometer scale (~10 nm) internal skeletal structures. The effects of alloying 1 ? 50 atom % platinum group metals (M= Pt, Pd, Rh) and 5 wt% first row transition metals (M = Ti, Mn, Fe, Co) were studied. Even low additions of PGMs (1 at.%) cause significant shifts to lower temperature regions of activity and the largest shift is obtained for Rh. For Rh this is interpreted as a strong synergistic interaction between Rh and Au. Possibly related to the Rh effect, Co is the only other metal studied that lowers the temperature of NOx reduction. The other first row transition metals inhibit the reduction reaction.

Oct 1, 2003

By C. Y. Lim, H. W. Kim, M. S. Kim, J. H. Cho, Y. S. Lee

Al - 5.5 wt% Mg - 0.3 wt% Cu alloy strip was successfully fabricated by horizontal-type twinroll casting (TRC). For producing sound strips with no surface defect, the casting was conducted at various roll rotation speed, and the sound strip could be obtained at relatively low casting speed (3 rpm). The cast strip was homogenized at 450 °C for 10 hours, and then cold rolled with a reduction rate of 78%, followed by a final annealing at 450 °C for 1 hour. The annealed sheets showed good mechanical properties with approximately 330 MPa in tensile strength and 27 % in elongation, but exhibited strong anisotropy depending on the tensile directions. For the homogenized sheets, warm rolling was also conducted at 200, 300, and 400 °C. The tensile test results of the warm-rolled sheets showed that the rolling at medium temperature (300 °C) was proper to fabricate the sheets with relatively good mechanical properties and low anisotropy.

Jan 1, 2014

By Robert A. Gault, T. Scott Ercit, Mehmet F. Taner

"Abstract -Vanadium mineralization occurs in oxide-rich horizons within the layered gabbro zones of the upper parts of the Bell River Complex, Matagami, Québec and the Lac Doré Complex, Chibougamau, Québec. The vanadium-rich horizons are well defined on the ground and in aeromagnetic surveys by their high magnetic susceptibility; consequently, magnetic susceptibility can be an indicator of vanadium mineralization. The main oxide minerals are ilmenite and titanian magnetite, containing 20% to 70% of volume and the ratio of titanian magnetite to ilmenite is relatively constant, ranging from about 1:1 to 2:1. Their sizes are less than 5 µm to greater than 1 mm to 2 mm, occurring as coarse- to medium-grained subhedral crystals intergrown with cumulate silicate minerals (plagioclase, pyroxene, etc.). Electron microprobe analyses indicate that the ilmenite grains are mineralogically and compositionally homogeneous and have low V contents (average 0.18% equivalent V2O5). In contrast, the titanian magnetite grains are inhomogeneous, consisting of trellisworks of ilmenite lamellae in Ti-poor, V-rich magnetite [less than 2 wt% TiO2, and 1.41% equiv. V2O5 (1.16% V2O3) for 20 analyses]. Thus, the magnetite is the principal ore mineral of vanadium; it hosts vanadium in the form of V3+, not V5+, as is commonly and erroneously reported. We have also devised a flowchart for the beneficiation of vanadium-titanium ores. Sommaire - La minéralisation de vanadium se trouve dans des horizons riches en minéraux oxydés de la partie supérieure des zones de gabbros lités des Complexes de la Rivière Bell, Matagami, Québec et du Lac Doré, Chibougamau, Québec. Des horizons riches en vanadium ont été bien définis sur le terrain et dans les levés aéromagnétiques par leur susceptibilité magnétique élevée; conséquemment, la susceptibilité magnétique est l’indicateur directe du contenu en vanadium. Les principaux minéraux oxydés sont l’ilménite et la magnétite titanifère, contenant 20% à 70% du volume et le rapport de magnétite titanifère à ilménite est relativement constant, allant d’environ 1:1 à 2:1. Leur dimension varie de 5 µm à plus grande que 1 mm à 2 mm, apparaissant sous forme de cristaux subidiomorphes, de grains grossiers à médiums, intercroissant avec la gangue silicatée (plagioclase, pyroxène, etc.) de la texture de cumulat. Les analyses à la microsonde électronique montrent que les grains d’ilménite sont minéralogiquement et chimiquement homogènes avec un faible contenu en V (moyenne 0.18% équiv. V2O5 ). Contrairement, les grains de magnétite titanifère sont hétérogènes, contenant des lamelles d’ilménite en "trellisworks"; ces grains sont pauvres en Ti et riches en V pour la portion magnétite de la magnétite titanifère [surtout contenant moins de 2 wt. % TiO2, et en moyenne 1.41% équiv. (1.16% V2O3) pour 20 analyses]. Ainsi, la magnétite est le principal minerai de vanadium; elle renferme du vanadium sous forme de V3+ et non de V5+, tel qu’il a été communément et à tort rapporté. Nous avons aussi défini un "flowchart" pour la bénéficiation des minerais de vanadium-titanium."

Jan 1, 1998

By L. Bichler, C. J. Verdon

In this work, the effect of doping yttria stabilized zirconia (YSZ) with 5, 10 and 15 mol% erbium oxide (Er2O3, erbia) was investigated using spark plasma sintering (SPS) technique. Sintering was carried out at 1300°C with 30 and 60MPa uniaxial pressures and a 5min hold time. Densification kinetics were studied using displacement response from the SPS machine. As-sintered microstructure characterization was carried out via scanning electron microscopy (SEM) and X-ray diffraction (XRD) techniques, while chemical composition was characterized by energy dispersive X-ray spectroscopy (EDS). The results suggest that sintering carried out at 60MPa produced high density composites even though erbia dopants were found to inhibit material densification and grain growth during sintering. 5, 10 and 15mol% erbia- YSZ had cubic crystal structures, as verified by XRD analysis.

Jan 1, 2014

By Morris J. Viljoen, David R. Young

"The zone of economic interest at H.J. Joel Gold Mine is the VS5/Beatrix Composite Reef, a quartz-pebble conglomerate of Archean age. The reef occurs at the base of the Eldorado Formation, Central Rand Group, of the Witwatersrand Supergroup. At least three stratigraphically distinct conglomerates form this economic zone. In order of deposition these are the Footwall, Beatrix, and the VS5/Beatrix reefs. The Footwall and Beatrix reefs are equated with the Aandenk Formation with transport directions toward the northwest, whereas the VS5lBeatrix Reef is of Eldorado age, with transport directions toward the south. The change in the drainage direction was caused by a major basin-wide tectonic event that occurred prior to the deposition of the Eldorado Formation. The Beatrix Reef was formed in a proximal, braided, fluvial environment by a process of aggrading gravel bars between channelways. The VS5/Beatrix Reef was formed by the desegregation of pre-existing Beatrix Reef with the introduction of new material containing much shale detritus and is seen to have been deposited in a more -distal, braided, fluvial environment, similar to the Beatrix Reef.The average gold concentrations are different for each conglomerate; the Beatrix at 32.1 ppm Au, the Footwall at 24.4 ppm Au, and the VS5/Beatrix at only 12.4 ppm Au. A sedimentary gold concentrating process related to higher energy braid channels was primarily responsible for these high gold grades. Not only the basal unconformity surface, but also, internal degredation surfaces, were prime sites for concentration. An understanding of the spatial distribution of these differing conglomerates and their braid channels forming the economic reef zone is necessary in predicting ore grades for future mining."

Jan 1, 1994

By Joseph Carlston

With environmental regulations continuing to restrict the discharge of phosphorus from wastewater treatment facilities, traditional methods of phosphorus removal are proving inadequate. To achieve the phosphorus control necessary, a new coagulant used for phosphorus removal, cerium chloride, has been studied in several municipal and industrial wastewater treatment facilities that must meet a phosphorus discharge limit of 0.5 mg/L or lower. These studies demonstrated the high phosphorus removal capabilities of cerium chloride, with the results illustrating the ability for cerium chloride to reduce phosphorus to low concentrations in the effluent using a lower volume of product as compared to traditional coagulants, such as ferric chloride. This reduction is due to the unique ability of cerium chloride to remove phosphorus as cerium phosphate, whereas iron- and aluminum-based coagulants rely on adsorption and co-precipitation.

Jan 1, 2014

By C. H. Ash

"Abstract-The Red Chris Cu-Au deposit (522.7 Mt at 0.35% Cu and 0.27 g/t Au), northwestern British Columbia, is one of several pre-accretionary porphyry systems in the Cordillera of western Canada. It is hosted by an Early Jurassic hornblende monzonite to quartz monzodiorite porphyry which forms part of a suite of dikes and stocks that intrude Late Triassic volcanic strata. Major and trace element chemical data suggest that these Early Jurassic intrusions have compositions which fall on the boundary between alkalic and calc-alkalic compositions. Alteration and mineralization in the Red Chris deposit are more typical of calc-alkaline porphyry systems with abundant potassic, sericitic and argillic assemblages and quartz-rich stockworks. It lacks Na- and Ca-bearing silicate assemblages which characterize the alkalic porphyry deposits of British Columbia. One of the more unusual features of the deposit is the abundance of carbonate alteration and veins which occur throughout the hydrothermal history of the deposit. This type of alteration and veining is more typical of alkalic porphyry deposits. The composition of the carbonates vary both temporally and spatially with different alteration zones. Potassic zones, which are characterized by orthoclase±albite±quartz±chalcopyrite±bornite± magnetite±hematite and Au/Cu ratios of 1:1 (g/t Au:% Cu), contain minor siderite veins and alteration. Quartz-sericite-carbonate (QSC) zones overprint earlier potassic alteration and comprise quartz+ankerite+sericite+pyrite+chalcopyrite with Au/Cu ratios of 0.5:1 (g/t Au:% Cu). Ankerite is the main carbonate in this stage but has a variable composition with a more Fe-rich variety associated with mineralized veins. Localized chlorite-carbonate alteration zones, characterized by chlorite+ carbonate+quartz±kaolinite±pyrite±gypsum and high Au/Cu ratios [2 to 3.5:1; (g/t Au:% Cu)], contain predominantly calcite. Late stage carbonate-gypsum veins have an ankerite to dolomite composition which is very similar to the regional carbonate alteration and veins."

Jan 1, 1997

By P. A. Gonzalez Contreras

Scorodite is considered as a secondary mineral formed from the product of weathering of primary minerals by chemical or biological reactions. In the case of biological scorodite formation, microorganisms mimic and accelerate what in nature takes a very long time, i.e. biocrystallisation. The goal of the biological scorodite formation is to form very stable arsenic crystals suitable for long-term and safe disposal. The biological formation of scorodite is a novel combination of biological oxidation, biocrystallisation, and proper bioreactor design to achieve the biological formation of scorodite crystals in one step. We have explored simultaneous biological arsenic and iron oxidation at 30ºC and at 70ºC leading to arsenic-jarosite phases and scorodite, respectively. As biologically formed scorodite crystals are very stable (TCLP < 1 mg/L As (V)), the risk of arsenic toxicity is minimized when leaching takes place. This process is suitable for arsenic concentrations above 0.5 g/l As achieving up to 20 mg/l As in the effluent. This biological scorodite formation system is a selfsufficient bio-oxidation system and therefore many new applications can be explored such as reprocessing of arsenic trioxide, orpiment or calcium arsenate to scorodite crystals for a stable and safe disposal.

Jan 1, 2014

By L. Cáceres, G. Leinenweber, P. Bustamante

"Given the severe scarcity of fresh water sources in Northern Chile the use of seawater has become the only alternative to allow mining expansion. This option however poses several technological challenges as a result of the high concentration of natural salts that promote various forms of metal corrosion. Therefore the steel piping protection has been a constant challenge for design engineers responsible for solving the problems of corrosion. Known protection alternatives are varied and expensive, a few of them are rubber coatings, protection based centrifuged concrete, extra wall thickness of pipes in combination with corrosion inhibitors, extra wall thickness of pipes without using corrosion inhibitors, and the use of highly corrosion resistant steel materials.In this framework the aim was to study the corrosion kinetics of carbon steel pipe API 5L X70 under electrochemical and weight loss testing. The test conditions include a range of seawater velocities between 0.2 to 3.0 m/s.For electrochemical experiments the API 5L X70 steel specimen was a 4 mm diameter disk embedded in an 8 mm diameter Teflon rod and exposed to seawater. Duplicated coupons were placed in a standard test apparatus that was built according to the standard ASTM D 2688 – 94.The main results were: a) corrosion mechanism explained in terms of the counterparts partial processes which are the hydrogen evolution and oxygen reduction reaction; b) for the test specimen a corrosion band like feature that suggest a lateral dispersion of aggressive solutions from corrosion pits; c) a range of corrosion rates between 1 and 1.96 mm/year for flow rates between 0.2 and 3.0 m/s; and d) a convenient inhibitor dose between 20–25 mg/L for optimum inhibition efficiency to obtain a maximum value of 80% for corrosion efficiency."

Jan 1, 2016

By X. -G. Chen, A. M. Nabawy

A novel manufacturing technique for Al-TiB2 nanocomposites has been developed, in which TiB2 nanoparticles were incorporated into liquid aluminum under mechanical stirring and in the presence of a K2ZrF6 flux-wetting agent. The microstructure of the Al-TiB2 nanocomposites was studied using scanning electron microscopy (SEM) and transmission electron microscopy (TEM). The microhardness test was conducted to investigate the strengthening effect of TiB2 on the aluminum matrix. The TiB2 nanoparticles were successfully incorporated and dispersed into the aluminum melt in the presence of the K2ZrF6 flux during mechanical stirring. In the as-cast microstructure, most nanoparticles segregated in the interdendritic regions as a result of particle redistribution during solidification. The addition of 2, 5 and 10 wt% TiB2 nanoparticles increased the composite hardness by 60, 90 and 150% respectively when compared to commercial purity aluminum, indicating that the TiB2 nanoparticles imposed a significant strengthening effect on the aluminum matrix. The role of K2ZrF6 flux agent on the incorporation of nanoparticles into aluminum melt was discussed.

Jan 1, 2014

By Raymond D. Potts

"Minntac is a taconite mining, concentrating and pelletizing operation located near the town of Mountain Iron, Minnesota, U.S.A. It is totally owned and operated by USX Corporation and represents its largest source of domestic iron units. Minntac began producing fluxed pellets in 1988 and has produced both acid and fluxed pellets since then. This paper compares the acid and fluxed pellets produced at Minntac. It reviews modifications that have been made to the plant flowsheet and discusses areas recognized for improvement since the beginning of fluxed pellet production. It also comments briefly on the performance of Minntac fluxed pellets in USX blast furnaces and the future of fluxed pellets at Minntac.IntroductionMinntac was built in three steps with each step designed to produce 6 million long tons of acid pellets per year. The actual production has varied though. Figure I shows the production by year at Mirmtac. Step I began production in 1967, Step 2 in 1972 and Step 3 in 1978. Mirmtac produced 16.5 million tons in 1979 but only 3.5 million tons in 1982 when the facility was shut down for six months because of the lack of demand for pellets. Since the initial start up, Mirmtac has produced over 200 million long tons of pellets. Until 1987, all the pellets produced were ""acid"" pellets. In 1987, equipment to produce ""fluxed"" pellets was installed and tested. In 1988, full scale production of fluxed pellets began."

Jan 1, 1991

By Fazel G. Jahromi, Ahmad Ghahreman

"Several studies were performed on the atmospheric leaching of copper sulfide minerals in the presence of activated carbon and a new catalyst, AF 5. AF 5 is a carbon based catalyst with similar properties to those of activated carbon however much better mechanical properties. The activated carbon surface chemistry has been investigated in various studies; however the connection of the surface chemistry of activated carbon and AF 5 with the sulfide minerals during the atmospheric leaching process is not well-understood yet. Based on the surface analysis, AF 5 showed higher surface area than activated carbon (AC). Adsorption and oxidation of copper, arsenic and iron ions in the presence of different activated carbon were investigated. Adsorption properties of both catalysts were similar and 18-24% of iron, 12-18% of copper and 10% of arsenic adsorbed on the catalysts surface form 5 g/L Fe(III) and Cu(II) and 2 g/L As(III) at 80°C. In oxidation experiments, both catalysts reduced Fe(III) and Cu(II) ions and re-oxidized the reduced species in the presence of oxygen and oxidized As(III) ions. The addition of oxidizing ions can enhance the oxidation process kinetics and increase the catalytic capability of carbon.INTRODUCTION Hydrometallurgical processes of copper sulfide concentrates are under development and various different methods have been proposed to increase the atmospheric leaching rate of copper sulfide minerals. These methods include using different media, reagents, and catalysts. Among different methods, leaching of the copper sulfide minerals in the chloride media has some advantages over sulfate media. Smaller scale of operation, increased leaching rates, and lower sulfate formation are some of the benefits of the chloride leaching media over other similar media. Moreover, using ferric and cupric ions as oxidants and utilizing activated carbon as a catalyst has been proven to enhance the leaching rate of copper sulfide minerals effectively. Activated carbon (AC) and AF 5 (micro porous carbon based catalyst) are two of the most efficient and practical catalysts in copper sulfide leaching processes. AC can enhance the copper recovery of enargite in chloride media from 69% to 92% after 96 hours of leaching under the similar conditions (Jahromi & Ghahreman, 2016). It has been shown that AC at acidic pH can generate hydrogen peroxide in the presence of oxygen which can leach copper minerals (Ahmumada et al., 2002)."

Jan 1, 2017

By Boyd Davis, Vladimiros Papangelakis, Douglass Duffy, Michael Carlos

"The processing of lateritic saprolite in hyper-concentrated magnesium chloride brines offers several potential advantages for the hydrometallurgical production of nickel. An aggressive HCl-MgCl2 leach at atmospheric pressure can significantly reduce magnesium dissolution, and offers the ability to recover HCl and MgO by a less energy intensive process than conventional techniques via the formation of magnesium hydroxychlorides. Inevitably, the high chloride concentration renders iron fully soluble during leaching and thus requires subsequent iron control and disposal steps. Experimental measurements coupled with OLITM modeling were conducted to investigate the behaviour of iron in concentrated magnesium chloride brines, in terms of chemistry (nature of iron species) and solubility limits. The solubility of ferric chloride in magnesium chloride solutions of concentrations and temperatures relevant to this process was controlled by a previously unreported solid phase: 2.5FeCl3·MgCl2·7.5H2O. Iron precipitation tests on synthetic leach solutions without seeding indicate a metastable akaganeite precipitate which transitions to hematite upon equilibration. Magnesium chloride solubility in ferric chloride solutions was also investigated to allow the simulation of a ternary phase diagram for the MgCl2-FeCl3-H2O system, in order to determine process conditions that avoid unwanted chloride precipitation.INTRODUCTION In the search for more economical processes to treat lateritic saprolite for nickel production, chloride hydrometallurgy has been increasingly investigated. While High Pressure Acid Leaching (HPAL) can frequently economically treat lateritic limonite, the presence of saprolite negatively affects process economics. The higher magnesium content of saprolite increases acid consumption, because magnesium sulphate, unlike iron and aluminum sulphates, does not hydrolyze in HPAL. This soluble magnesium decreases the sulphuric acid strength by an amount greater than the amount of acid stoichiometrically required to leach magnesium, which must also be disposed of or recovered (Jankovic, Papangelakis, & Lvov, 2009). Due to these issues, pyrometallurgy is most commonly employed to treat lateritic saprolite, via the Rotary Kiln-Electric Furnace (RKEF) process; this process uses a rotary kiln to dry and partially reduce nickel and iron oxides before sending the calcine to an electric furnace for smelting to produce a ferronickel product for the stainless steel market. Although the problems encountered during hydrometallurgical processing are avoided and nickel recoveries are high, high capital and energy costs prevent the application of this process to lower grade lateritic saprolite deposits (De Bakker, 2011)."

Jan 1, 2016

Weekly Capacity ? Current Schedule Rate (198.5 tonnes / hour) X Skip Time (112.7 hours) X Effectiveness (85%) = Weekly Capacity (19,015 tonnes) Capacity Conclusions - Existing hoists optimized are best option for Fraser Morgan (>20M + schedule for other). - Peak will have to be managed. - Critical to have equipment & infrastructure in best possible condition to ensure reliability.

Feb 1, 2008

By Paul Clayton

Case Study ? Site: BMA Saragi Coal Mine Queensland Australia ? Model: Marion 8050 ? YOM: Mid 1970s ? Boom: 97M ? Bucket: Original capacity of 100 Tonnes upgraded to 125 tonnes at time of filtration upgrade. ? Apps: Swing, Hoist & Drag Gearboxes ? Oil: Oil Castrol Alpha TT1200 Viscosity of 1208 cSt @ 40° C (104° F) 720ltr Oil Volume Trial and Installation Justifications ? To reduce gearbox overhauls. Typical schedule being 5 years. ? Bucket upgrade from 100 tonnes to 125 tonnes. Increased gearbox demand and stress. ? Increase of overhauls out to 10 years + ? Saving per Dragline estimated to be US$8-10M in downtime and maintenance if successful. ? In compliance with BHPBilliton Global Maintenance FLAC program ? Fuels, Lubricants, Air and Coolants ? Cost Justification ? Downtime: 4 days ? Lost production: $420,000 ? Cost of parts: $162,000 ? Labour and misc: $41,000 Gearbox failure cost $623,000

May 1, 2008

Bahuerachi Project Characteristics Why it?s nicer at Bahuerachi Mexico is a mining country Low political, regulatory and trade risk Low social/permitting risk Proximity to infrastructure Road Power grid (8 km) Rail line (25 km) High grade zones (skarns), CRD and near surface oxide component are sweet spots to the overall system. Size of low grade system points to potential long mine life?and numerous new targets developing. Timelines-2006? 90 to 100 combined RC and core holes to go! MAIN ZONE Drilling ? Goat ?Finish Mid April ? Main Zone, going North, depth of testing dependent, estimated for May ? North Lobe-May ? Commission independent resource estimate by May 06 for results of first pass drilling to date ?tonnesand grades ?Main Zone Milestone. ? Continue infill or expanded drilling to July (minimum) ? 1stpass RC scheduled until September OTHER Targets ? Begin drill testing North Skarn target Mid-April, minimum 5 drill holes, 1,000 meters. Ongoing expansion of target with surface work (mapping) ? Road to Colome(Skarnin north of Main Zone) as part of porphyry program ? Tule(southern) porphyry and skarn system-soils and mapping OUTSTANDING events Metallurgical report on floating and leaching tests (Sulphide/oxides).

May 1, 2006