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By A R. Bullis

Metal Mines Limited (Bancroft Division) was incorporated m 1964 to take over the assets of Faraday Uranium Mines Ltd., including their uranium deposit near Bancroft. Ontario. This paper outlines the geology of the Bancroft area, and. then go on to describe the principle rock types m the mine workings, especially the pegmatite, which is the host rock for the uranium mineralization. The structure and mineralogy of the orebodies are thoroughly covered, and, after a summary of the production and ore re-serve figures, the paper concludes with suggestions for further exploration work. Location and History M ETAL Mines Limited, Bancroft Division, is located in Faraday township, Hastings county, Ontario. The main production shaft and concentrator are about: Y2 mile north of Highway 28 and about 5 miles west of the village of Bancroft (Figure 1). The presence of radioactive minerals in the Ban-croft-Wilberforce area has been known since the early 1920's. Uraninite was found at the Richardson deposit near Wilberforce in 1922, and some attempts were made to produce radium from the deposits of the area between 1929 and 1931.

Jan 1, 1965

By J. T. Kalala

The High Pressure Grinding Roll (HPGR) is gaining acceptance in the mineral processing industry and has become a competitive technology in reducing the specific energy consumption in Mineral processing plants. The amount of samples required for HPGR amenability testwork and HPGR wear tests is usually high and often cannot be available at early stage of projects were only a few drill cores are available. Although HPGR was initiated from small scale piston die compression tests, the development of small scale piston die test to predict the performance of HPGR has been slow. The objectives of this paper was to present the designs, operating procedure of piston-die press and operating conditions which have resulted in similar particle size distribution obtained from a piston die test and HPGR Labwal unit starting from the same feed size distribution. Testwork were conducted using a 2 MN piston-die press and a Labwal HPGR unit on major South African ore types, viz, gold, platinum and iron ores. The results obtained show that piston-die test can generate data to predict energy consumption, product size distribution, and even to evaluate the edge effect.

Jan 1, 2012

By Robert L. Tremblay

Dans le but de voir si une région comme la Gaspésie, qui a subi la derniere glaciation , se prête avantageusement à la méthode de prospection alluvionnaire, environ 800 concentrés de minéraux lourds furent prélevés dans les districts électoraux de Matane et de Gaspé-Nord. Les différentes phases minérales présentes dans les concentrés ont été examinées à la loupe binoculaire. Afin de mieux valoriser ce type d'inforrnat ion, nous avons été arnenés à expérimenter et à mettre en oeuvre des techniques multivariables adaptées au traltement d'une information semi-quantitative en utilisant le principe d'un codage logique préalable. La structuration des résultats de la Gaspésie a conduit à l'élaboration de cartes de synthèse qui constituent un support nécessaire à l'interprétatlon des répartitions plus ponctuelles des minéraux "utiles" sur le plan de la recherche minière.

Jan 1, 1978

RISKGATE is an interactive online risk management system developed by the Minerals Industry Safety and Health Centre (MISHC; University of Queensland) to maximise health and safety performance in the mining industry through implementing continual improvement in management of major unwanted events. A comprehensive knowledge base has been captured for risk management of tyres, collisions, fires, isolation, strata underground, ground control open cut, explosions, explosives, manual tasks and slips/trips/falls. This will be extended to outburst, coal burst and bumps, interface displays and controls, tailings dams and inrush in 2013. RISKGATE presents substantive and leading edge controls to assist industry stakeholders in the design, management and reporting of organisational and regulatory compliance requirements. From a broader industry perspective, RISKGATE provides an environment for knowledge capture and knowledge exchange to drive innovation and best practice in the identification, assessment and management of risk. By capturing operational knowledge from industry experts, RISKGATE provides a cumulative corporate memory at a time of high personnel turnover in the coal industry. All major Australian mining companies are contributing topic experts to this broad industry initiative. In the first 24 months, nine coal mining companies nominated over 80 different experts who contributed over 400 days of individual time to the knowledge capture workshops. RISKGATE is the largest single Australian Coal Association Research Program (ACARP) occupational health and safety (OHS) initiative to date.

Aug 1, 2013

By L. Xia, B. Hart, G. Gingras, M. Furlotte

Plant and laboratory test work was performed in order to optimize a copper/zinc flotation separation circuit at Matagami concentrator, Canada. The testing identified a significant difference between the laboratory testing and the plant flotation, particularly for the sphalerite recovery in the rougher copper concentrate. Tests indicate that sphalerite recovery of the flotation concentrate in the laboratory testing was significantly higher than in the plant. The ToF-SIMS surface analysis identifies surface species responsible for the discrepancy in Zn recovery. It shows that sphalerite flotation is in response to the collector attachment and a significant enrichment of Cu on the surface of sphalerite grains. A comparative surface chemical analysis was performed on both sphalerite and chalcopyrite grains from the plant flotation and laboratory testing in order to identify surface species variability between the two testing. Two significant observations were revealed. First, there is considerably more hydrophilic iron oxyhydroxide on sphalerite surface from the plant flotation sample relative to those from the lab testing. The secondary coating likely completely or partially passivates sphalerite surfaces, reducing Cu enrichment and hence sphalerite floatability. Secondly, comparing the surface chemistry on sphalerite and chalcopyrite, the hydrophilic iron oxyhydroxide species have preference for the sphalerite grains relative to chalcopyrite. Despite numerous studies on the effect of galvanic coupling during grinding, there is limited documented evidence on the effect of the milling environment on the flotation and plant operations. This observation suggests that interaction between sulphide minerals and grinding media have a significant influence on subsequent flotation. This paper discusses the results of a detailed surface chemical evaluation of sphalerite grains from both the plant and laboratory testing in the context of grinding environments and pulp chemistry.

Jan 1, 2016

By M. M. Williams

WESTERN CAN ADA'S coal industry has experienced a serious set-back since 1949, following a pattern well known to its counterpart in the United States. The loss in coal markets in Western Canada has been particularly severe as the discovery of large reserves of oil and natural gas and the subsequent construction of re-fineries and pipelines roughly coincided with the dieselization of both main railways. While the coal industry will have to face a further decline in markets of long standing, others with a large growth potential can be se-cured if present marketing methods are changed where needed and if fundamental and applied research programmes are actively pursued. The energy and chemical potential of Western Canada's coals will eventually find their place in the ever-growing needs of industry and electric power producers. Electric power generation would appear to offer the largest and most immediate market for coal. If the coal industry is to serve this market adequately and gain as much of it as possible, coal operators ? must have a good knowledge of certain characteristics -of the electric utility industry and its fuel requirements. This paper is prepared primarily to set out some of these characteristics, but also discusses other probable markets for coal.

Jan 1, 1958

By D. C. Fuller

"CoaLiquid, Inc. (CLI) has been in the coal-oil-mixture (COM) business for over five years. The initial pilot processing facility was replaced by a 2000 barrel per day commercial production facility in August 1979. For over two years CLI has been expanding its efforts and conducting large-scale production and combustion demonstrations successfully in many locations across the United States. To facilitate the marketing effort, CLI has recently constructed a special trailer containing all equipment needed for a temporary COM retrofit.CoaLiquid has conducted commercial-scale combustion demonstrations in the following types of combustion units: kilns, calciners, industrial boilers, blast furnaces and driers.IntroductionCoaLiquid, Inc. officially dedicated its plant on August 31, 1979, at a ceremony presided over by the then Governor of Kentucky, The Honorable Julian Carroll. The dedication marked the culmination of over three years of research and development work and marked the beginning of a new era of coal-oil-mixtures as a commercial commodity in the marketplace. As the first such plant in the United States, it set the tone for construction to follow.CLI was originally owned and managed by a group of entrepreneurs from Kentucky who had developed the process and constructed the plant on purely private investment and conventional financing. Beginning in late 1976, with a pilot-scale operation, also located in Shelbyville, Kentucky (near Louisville), CLI began producing a stable mixture of 50070 coal, 30% to 40% oil and 10% to 20% water by weight. The technology employed was developed by Eric C. Cottell of Long Island, New York and is covered by U.S. Letters Patent No. 3,941,552. Since the pilot plant operation, CoaLiquid has made many refinements to its process and in fact has added new technology to its portfolio of patents and patents pending. Further refinements to the product now produce a stable mixture of 50% coal, 40% No.6 fuel oil and 10% water by weight."

Jan 1, 1985

By Ralph W. Edie

"IntroductionTHIS PAPER deals with chemical and mineralogical changes in wall-rocks associated with pitchblende mineralization in the Gold-fields area of Saskatchewan. The localities at which the rock specimens studied were collected, and descriptions of the various rock-types referred to, are given in a previous paper by the author (5).The geological field work upon which this paper is based was carried out while the writer was employed by the Eldorado Mining and Refining Company during the summers of 1948, 1949 and 1950. The laboratory work§ consisted largely of quantitative spectrographic analyses for both major and minor elements, supplemented by an examination of 250 thin sections of both altered and unaltered rocks.Character of the AlterationHydrothermal alteration, with associated pitchbende mineralization, is widespread in the Goldfields area of Saskatchewan. The most intense alteration is restricted to the immediate vicinity of fault or breccia zones, but large areas are affected to a minor extent.In detail, the relationship between alteration and pitchblende mineralization is complex, as individual veins do not in general have separate alteration halos. Pitchblende generally occurs in gash-like calcite veins or stringers in wide, fractured zones associated with faulting. Large, lenticular and tabular masses of slightly to intensely altered rock occur in the same wide fracture zones as the mineralized veins. However, vein deposition appears to be-long to a later fracturing period, after hydrothermal alteration was more or: less completed. Generally, the veins transect and are confined to highly altered rock, but on the other hand many highly altered zones intersected in diamond drill-core are barren of mineralized veins."

Jan 1, 1953

By D. Haraguchi, S. Izawa, C. Tokoro, S. Owada

"Arsenic is widely known as a toxic element for humans, animals and plants. Because of more stringent wastewater standards not only in Japan but also around the world, research for appropriate and efficient treatment method for arsenic is becoming increasingly important. Coprecipitation or adsorption process using ferrihydrite is widely implemented for dilute As(V) removal from wastewater. In this study, the sorption mechanism of dilute As(V) with ferrihydrite in coprecipitation or adsorption process was investigated. To accomplish this, we conducted batch experiments of coprecipitation or adsorption and compared these results for sorption isotherm and zeta potential. These experimental results showed that sorption mechanism in coprecipitation process depends on the initial As/Fe molar ratio; simple twodimensional adsorption onto the surface of ferrihydrite when the initial As/Fe molar ratio was < 0.4, and some three-dimensional uptake with ferrihydrite when it was = 0.4. We also evaluated the sorption mechanim by analysis of X-ray diffraction (XRD) and X-ray Absorption Fine Structure (XAFS). XRD or XAFS spectra showed that surface precipitation of amorphous ferric arsenate was formed when the initial as/Fe molar ratio was = 0.4, beyond the thermodynamic bulk precipitation range for ferric arsenate.INTRODUCTIONArsenic is toxic to animals, including humans, and long-term exposure to arsenic via drinkingwater causes cancer of the skin, lungs, urinary bladder, and kidneys, as well as other effects on the skin such as changes in pigmentation and thickening (Ghosha et al., 2008). Elevated levels of arsenic are often present in the environment as a result of the weathering and dissolution of minerals as well as in response to numerous anthropogenic sources including the discharge of mine wastes, coal fly ash and the use of pesticides that contain arsenic (Nriagu, 1994; Singh et al., 2007). Indeed, the potential for arsenic exposure affects many people, as evidenced by several million people in Bangladesh and India being at risk of exposure via drinking water obtained from contaminated groundwater sources (Ahmed, 2001).Acid mine drainage (AMD) containing arsenic is a global environmental problem (Dold, 2008; Liang and Thomson, 2008) that also affects Japan, which has many abandoned or closed mines that have been generating AMD for the last few decades (Masuda et al., 2008). Several such facilities in Japan produce AMD containing dilute concentrations of arsenic that exceed Japanese effluent standards (0.1 mg/dm3) (METI, 2006). For example, AMD from the abandoned Horobetsu sulfur mine, the largest AMD source in Japan, contains approximately 10 mg/dm3 arsenic."

Jan 1, 2012

By J. Peterson

A review of blast designs and improved blasting practices at the Ekati??Diamond Mine is presented along with the results of three blast-monitoring experiments. Blast monitoring was undertaken to investigate blast damage mechanisms in the mine&apos;s well jointed rock mass. Rock mass damage caused by production, pre-shear and wall control blasts was measured. Ekati??uses 270mm holes for production blasting, and 165mm holes loaded with a decoupled charge for pre-shearing. The production blasts are loaded with bulk emulsion / ANFO blends. The mine plan involves using 30m double benches. A 30m high pre-shear is drilled and blasted prior to the production blasting that is done with sequential 15m benches. This paper summarizes the monitoring equipment and data gathered to date.

May 1, 2001

By C. M. Díaz, P. J. Mackey, P. Coursol

In a recent paper [1], the present authors discussed calculated energy consumption numbers in copper sulphide concentrate smelting for four different smelting technologies. For the present study, from among these technologies, they selected the Noranda/Teniente continuous bath smelting followed by Peirce Smith (PS) converting route to investigate the impact on total energy requirement of some key process variations, such as tuyere injection of dry concentrate vs. slingering of wet concentrate over the molten bath, continuous converting vs. conventional batch PS converting and commercially proven slag cleaning alternatives. In their calculations, the authors used the same thermochemical model and methodology used in their earlier paper. This approach to explore plant design options provides an interesting basis for evaluating flowsheet modifications that could lead to significant copper smelting energy savings. The METSIM software was used in the present paper to carry out heat and mass balance computations for 8 different flowsheet configurations. The results are presented and discussed in the paper with respect to copper recoveries, energy requirements and CO2 emissions.

Jan 1, 2011

By D. Weston

"IntroductionIn preserving this paper, the author would like to acknowledge the basic development work carried out by the Consolidated Mining & Smelting Company of Canada, without whose initiative the development of the Aerofoll mill would not have been possible. In particular, he would like to pay tribute to the late Mr. C. T. Oughtred, Superintendent of Concentration for Cominco, whose vision and research-mindedness was the chief contributing factor in the carrying alo.ng of the original development.He would like also to acknowledge the help and co-operation of the staff of the Mines Branch, Department of Mines and Technical Surveys, Ottawa, without which the finalization of the un.it and its application would have been many additional years in coming to industry; and the assistance and encouragement given so freely by Mr. C. W. Dowsett, Consulting Metallurgical Engineer, Ventures Limited, and Professor A. M. Gaudin, Massachusetts Institute of Technology."

Jan 1, 1950

By H. B. Merlin

"The past demands for energy and the contributions by the major sources are shown for the world and regions, and for Canada. Three forecasts of future demand are presented. By the year 2000, the world will be consuming energy at a rate of 670-700 x 1015 Btu/year. Canada's rate is estimated at 20 x 1015 Btu/year. Electricity will increase its portion of energy from 7.5 per cent to 15 per cent, and more than 40 per cent of the primary energy w1ll. be required to generate 1t. World, regional and Canad1an forecasts are g1ven for total electricity generated and for electricity generated in nuclear stations. The integral world requirement for energy by the year 2000 will be over 12 x 10 18 Btu. Current recoverable fossil and hydro reserves are about 18 x 1018 Btu. The total reserves are estimated to be seven times greater.World production of electricity in nuclear stations by the year 2000 will be almost three times the electricity produced in the world today. The amount of fuel consumed in generating this electricity will depend upon the types and mix of reactors installed. The heavy water reactors, alone or in conjunction with fast breeders and liquid fuel reactors, are the most efficient users of uranium and thorium resources. The heavy water reactors are also the most efficient producers of plutonium which will be required as fuel for fast breeders."

Jan 1, 1969

By L. Li, K. Jiang

China is the world largest producer and consumer of zinc. Beijing General Research Institute of Mining and Metallurgy (BGRIMM) is one of major research and engineering institutes for nonferrous metallurgy in China. This paper (presentation) introduces the development of China’s zinc smelting industry, key production processes and main producers. The process research and development are reviewed as well as BGRIMM’s R&D activities in the last decade. China&apos;s refined zinc production was 4,829kt in 2012, accounting for 38.6% of world production. Primary production was 4,722kt. There are around 150 refined zinc producers in China. The traditional fluid bed roasting - leaching jarosite is still a dominant process for primary production and its production accounts for about 60% of country&apos;s total production. However, the direct leaching process is gaining market share. Seven direct leaching plants with 330kt/a capacity, including autoclave leaching and the Outotec direct leaching, have been put into production by June 2013. Five autoclave leaching projects with 590kt/a capacity are in the pipe line and are expected to be commissioned in 2014 and 2015. To cut the production cost and improve smelter economics, process research to optimize the production flow sheet, to improve the iron removal and to enhance the recovery of co-existed rare metals were carried out. The development trends of China’s zinc smelting industry from the view of cutting production cost, improving energy efficiency, increasing comprehensive utilization are discussed accordingly.

Jan 1, 2014

By Š. Šachlová, T. Lokajícek, M. Petružálek, T. Svitek, A. Štastná

During the past 20 years, alkali silicate reaction (ASR) as a cause of concrete deterioration has been studied by a wide range of experimental methods such as microstructural and macrostructural analysis, bulk chemical analysis, X-ray and neutron diffraction analysis, etc. All of these data are compared with expansion values of mortar bars (following ASTM standard C 1260). Recent studies indicate the useful application of non-destructive methods with the aim of better reflecting mechanical properties and the degree of deterioration of real concrete. Ultrasonic testing methods (including ultrasonic pulse velocity UPV) are widely used to determine material mechanical properties and the changes induced by a variety of mechanical or chemical processes. However, only a few laboratory studies of ASR focused on ultrasonic testing of mortar bars. Due to this fact, a heating chamber was designed and constructed to enable ultrasonic sounding of mortar bar specimens while stored in accelerating solution. Regular ultrasonic sounding of mortar bars reveals significant dependence of ultrasonic data such as longitudinal P-wave velocity, signal energy, signal amplitude and signal frequency on mortar bar storage time. Ultrasonic data were subjected to time domain as well as frequency domain analysis. Different storage conditions were used to determine the effect of ASR on ultrasonic parameters. Mortar bars, prepared in the same manner with one type of aggregate, were stored in cold or warm water or in an accelerating warm medium. Ultrasonic data accurately reflects the differences in hardening and deterioration of tested mortar bars due to different storage conditions. Ultrasonic results showed very good correlation with the results of ASTM standard expansion tests and much higher sensitivity to ASR-induced concrete deterioration. Expansion tests showed 1% measured length differences in comparison with up to 80% resolution of ultrasonic data. The ultrasonic testing proved to be a suitable laboratory method for investigating ASR-related processes and could lead to an improvement of standard testing procedures.

Jan 1, 2015

By A. C. A. Howe, J. C. Rowntree

"The Bernie Lake pegmatite near Lac Du Bonnet in southern Manitoba is a complexly zoned pegmatite containing several lithium-bearing units in addition to the western world's largest known reserve of cesium. The pegmatite forms a flat-lying ellipsoidal body within an east-west-trending Precambrian amphibolite. The pegmatite enclosed by this vertically schistose amphibolite lies near the eastern tip of a granitic intrusive. The relationship of this intrusive to the pegmatite is obscured by Bernie lake. To date, the pegmatite body has been delineated aver an area of approximately 80 acres; it attains a maximum thickness of 280 feet. Several distinct zones, including three assemblages of economic importance, comprise the pegmatite itself. The combined spodumene and lepidolite assemblages provide a recoverable defined lithium ore reserve of almost 5 million tons averaging more than 2 per cent lithium oxide. The recoverable cesium ore of the pollucite assemblage provides 300,000 tons averaging more than 20 per cent cesium oxide; this represents more than half of the western world's pollucite reserve. The Bernie Lake pegmatite deposit, owned by Chemalloy Minerals Limited, is well located with respect to the growing United States markets, and its reserves of cesium are large enough to enable it, under favourable economic circumstances, to become the major producer of this metal in North America."

Jan 1, 1967

By A. H. Burns

"Regenerative and recuperative burner systems require advanced combustion techniques to minimize NOx emissions. Various methods of pollutant minimization and furnace design considerations are described. Cited examples are a large high temperature furnace and a small Zinc vaporizing furnace. The concept of total carbon footprint is introduced. The application of Biomass combustion as an effective method of cost and green-house gas (GHG) reduction is discussed. Practical considerations of scale, location and process limitations are discussed. Two examples of biomass fired equipment are cited. Ideal sites have large biomass resources available locally. Processed biomass fuels will be an important substitute for fossil fuel. INTRODUCTIONIn 1992, I presented a paper entitled Combustion Strategies In The Modern Industrial Environment (1992). At that time an abundant supply of cheap fossil fuel made many of the measures I talked about difficult to justify for anything but new equipment.Since 1992 we, as a society, have demonstrated an ability to accelerate the pace of industrial and societal change. The term industrial revolution applied to this age of incessant change is completely meaningless, implying a discrete moment in historical time. What our society has built is a system capable of unfettered, continuous and accelerating technological change. With this change comes an increasing demand for energy and materials.This year is the anniversary of the Titanic disaster, a moment in time when technological certainty met the caprice of nature and gave us a brutal reminder of what can happen to us if we underestimate that power (Mowbray, 1912). In the intervening interval we have regained the technological arrogance that was lost in 1912 bringing us back to the problems of climate change and the need for sustainable industrial activities.We use advanced mathematics to describe many complex systems, sometimes with disastrous results. For example there has been a recent attempt to model the global economy as a completely deterministic system. This premise is flawed at its foundation as human nature and emotion are indeterminate constants in the equations, yielding probabilistic solutions at best. As engineers we are all familiar with stiff problems. The solution to such a problem is meaningless and we have all had the misfortune to live through and rue the effects of that miscalculation over the last few years."

Jan 1, 2012

By A. C. Elliott, A. J. Lafreniere

THE Hamilton Works of The Steel Company of Canada is a fully integrated steel plant with an annual capacity of three million tons. Located on the south shore of -Hamilton bay, it is in the centre of Hamilton's industrial belt. The heavy concentration of industrial activities found in this area, accompanied metallurgical well-known sources of pollution which are normal to urban areas is creating a pollution problem which concerns both industry and the general public. The Steel Company of Canada has recognized this problem and, accordingly, has adopted the policy of integrating suitable pollution control devices into its new installations. Much effort is also being expended to control the emissions of air contaminants from the existing equipment. At the Hamilton Works, there are two main sources of metallurgical dust emissions to the atmosphere -the Open Hearth furnaces and the Sinter Plant. Of these two, the Open Hearth furnaces are, undoubtedly, the largest single source of

Jan 1, 1962

By Richard A. McIvor

"All mine shaft conveyances in Canada and most of the United States that are supported by a single hoist rope or attachment point and used for transporting persons are required by regulation to be equipped with safety catches and mechanisms. These safety mechanisms, commonly called safety dogs, are designed to stop and hold a free falling conveyance, with a full personnel load, in the event of a hoist rope or attachment component failure. The conveyance’s safety mechanism must be tested under dynamic conditions before it is used to transport personnel. This paper will discuss free-fall testing and it’s results on conveyance free-fall tests performed in the test tower at INCO Limited, Sudbury, Ontario.Topics covered will be free-fall tests on various wood types such as B.C. fir, Karri wood and Trusjoist MacMillan Limited Parallamwood (PSL), comparison of deceleration rates versus free-fall velocity and the influence of safety dog tooth design on deceleration rates."

Jan 1, 1996

By D. Duffy, V. Papangelakis

"MgCl2 brines present a number of potential advantages for the processing of saprolite ores for nickel production. With a chloride system it is economically requisite to recover hydrochloric acid, which can be performed in a more energy efficient manner by precipitation and subsequent decomposition, as compared with conventional pyrohydrolysis. In addition, concentrated MgCl2 solutions enhance the activity of acid used, allow atmospheric leaching at elevated temperature and inhibit magnesium dissolution, which reduces acid consumption and increases metal selectivity. Leaching and iron control experiments have been conducted in concentrated MgCl2 brines, up to 4.5 m, to determine the most amenable process conditions. INTRODUCTIONChloride metallurgy has received an increasing amount of attention in recent years, especially with respect to the treatment of nickel laterites. Although the limonitic fraction can sometimes be economically treated by High Pressure Acid Leaching (HPAL), acid-consumption problems are encountered with the higher magnesium content of the saprolite fraction. As magnesium does not hydrolyze under HPAL conditions, as iron and aluminum do, any sulphuric acid used to leach magnesium is subsequently neutralized and wasted. In addition, this magnesium must later be disposed of in some fashion, further complicating the process. The most common method used to process saprolite is the Rotary Kiln-Electric Furnace (RKEF). This uses a kiln to dry and preferentially reduce nickel, before sending the calcine to an electric furnace. Although nickel recoveries are high, and the problems of acid consumption are avoided, the capital and energy costs associated with this process are high (de Bakker, 2011).The problems outlined above have led to the investigation of an atmospheric chloride process for the treatment of saprolite ores. The use of a chloride system presents a number of advantages, but also a few limitations. Metal chlorides tend to be very soluble, with a few notable exceptions (silver, mercury and lead), allowing for smaller processing equipment through more concentrated solutions. This solubility also serves to reduce the potential for scale formation. In addition, a hydrochloric acid leach is more aggressive than a comparable sulphuric acid system, and the activity of the hydrogen ion can be augmented by further chloride addition (Peek, 2011). This activity augmentation in concentrated chloride systems, first reported by Jansz, has repeatedly been referenced as a motivating factor behind chloride hydrometallurgy (Jansz, 1983; Harris and Magee, 2003; Harris et al., 2004; Demopoulos et al., 2008; McDonald and Whittington, 2008; Demopoulos, 2011; Peek, 2011; Verhulst and Lakshmanan, 2011). This activity increase allows a similar amount of acid to perform more in a concentrated solution than in a dilute solution, decreasing overall acid requirements. As such, much focus has been placed on leaching in concentrated chloride systems, or brines, using calcium, magnesium or sodium as the cation (McDonald and Whittington, 2008)."

Jan 1, 2012