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By Standish N

The heterogeneous reactions of carbonaceous materials with oxidising gases are basic to all combustion phenomena and to many gasification processes. The carbon- carbon dioxide reaction at elevated temperatures (Reactivity) plays important roles in many metallurgical operations like iron blast furnace and ferro-alloys smeltings, zinc and lead smelting, alumina reduction, cupola operation and direct reduction processes. The stoichiometry but not the mechanism of the reaction between CO2 and carbon is represented by the equation (Boudouard reaction) CO2 + C 2CO (1) This reaction is more complex than that between carbon monoxide and metal oxides, which involves essentially a transfer of oxygen from the oxide to carbon monoxide to generate carbon dioxide without any change in gas volume, whereas the volume of the product gas of Equation (1) is twice that of the reactant gas. In the present paper an attempt has been made to review critically the reactivity measurements of various carbonaceous materials in carbon dioxide atmosphere. Steps in C-CO2 reactions, surface reaction mechanism, role of mass transfer on reaction kinetics, dynamic oxygen exchange reaction and rate equations and rate controlling steps are discussed. Various methods of reactivity measurements with their pros and cons are also presented. Effects of pertinent process variables on the reactivity of carbon are also described in detail.

Jan 1, 1986

By Baohm C, Barker T

There have been significant changes in the Australian mineral sands industry in recent years due to changing supply and demand conditions, new product opportunities and opportunities for rationalisation of operations. Earnings within the industry have typically been volatile and this has been reflected in the share prices of listed mineral sands companies. Apart from the effects of variations in the state of the economy on the industry, share prices have also reflected the extent to which a company's earnings volatility is due to capital structure, the relative proportion of fixed costs to total costs and the nature of th'- sales mechanism. At the time of writing, the high prevailing share prices for industry participants and the current outlook for the industry would suggest that the time is opportune for raising equity capital. The immediate outlook for the industry and its various product segments appears favourable but beyond this the usual uncertainties remain. The new tax environment will cause most companies in the industry to have to rethink their dividend and capital structure policies. Most shareholders will now be concerned to maximize dividend receipts and minimise exposure to capital gains tax. Companies in the industry that have relied fairly strongly on earnings retention to help finance growth in the past will- need to look to increased equity raisings in the Future.

Jan 1, 1986

By Lauricella P. F, Hendri D

In the Mesel sediment-hosted disseminated gold deposit, the spatial distribution of hydrothermal alteration is controlled by steeply dipping faults and shallowly dipping lithologies. Hydrothermal alteration of carbonate rock is characterised by decalcification, dolomitisation and silicification. Intense argillic alteration occurs in a laccolithic andesite intrusion adjacent to decalcified and silicified carbonate units. Sulphide minerals (pyrite, realgar, orpiment, stibnite and cinnabar) accompany hydrothermal alteration and precious metal mineralisation. The trace elements Ag, As, Sb and Hg are zoned spatially throughout the deposit. Mesel contains a mineable gold reserve of 7.8 million tonnes at 7.3 g/t Au. Gold mineralisation is preferentially localised in carbonate rocks adjacent to and beneath the andesite intrusion. The ore body consists of a central, near-vertical, high grade "feeder" system flanked by tabular, inward dipping, moderate grade "ouflow" zones. Mineralisation is controlled predominantly by two steeply dipping faults with high grade (>10 g/t) gold zones centred about structural intersections and fault splays. Gold is submicron size and locked in very fine grained (

Jan 1, 1995

By Elliot B. J

Cobalt is principally produced by hydrometallurgical means from the copper-cobalt ores of Zambia and Zaire. In addition cobalt is commonly found in minor quantities in association with nickel and copper-nickel orebodies. Generally the level of cobalt common to these latter orebodies does not warrant separate processing unless the metal price reaches levels last achieved in 1979 and 1980. For pyrometallurgical processing the distribution of cobalt and the factors which affect the distribution of cobalt between matte and slag are not well understood. A limited amount of fundamental research has been completed on cobalt distribution both for simple oxide and matte systems. The paper briefly reviews the relevant literature on theoretical aspects of cobalt distribution between metal and slag and the deportment of cobalt in sulphide smelting circuits. The deportment of cobalt in the Kalgoorlie Nickel Smelter circuit is critically analysed and areas where recovery improvements may be achieved are highlighted.

Jan 1, 1989

By J Chßvez, J Rosa del Castillo, J Rui

Environmental Impact Assessment (EIA) and Feasibility Studies (FS) were carried out to evaluate the potential use of treated acid mine drainage (AMD) occurring at the Kingsmill Tunnel in the Central Andes of Peru. The 11 km long tunnel drains the underground works of the Morococha Mining District and discharges about 1.25 m3/sec of AMD directly into the Yauli River in the Amazon Basin. The communities living downstream cannot use the Yauli River water due to its low pH and elevated concentrations of metals (eg Cu, Zn, Fe, Mn, As, Cd) and sulfate. Studies carried out for this project included technical feasibility, EIA, economic viability and social impact assessment phases. During the æTechnical FeasibilityÆ phase, the treated AMD was produced by simulating a high density sludge (HDS) lime neutralisation/ precipitation process and was evaluated for various potential uses. Mining companies located in Morococha, in particular Centromin Peru SA, and the Water Works Company of the City of Lima (Sedapal) collaborated with Golder Associates during the studies. The Canadian International Development Agency (CIDA) provided the financial assistance. The results of the physical, chemical, biological and toxicological analyses demonstrated that the AMD could be sufficiently treated to be potentially used to supplement the drinking water supply of Lima, and for agricultural (eg irrigation and livestock) and recreational purposes. Process design and scale-up parameters were also determined for implementation of the full-scale treatment facility at the site. The use of the treated AMD as a drinking water supplement would be economically feasible.

Jan 1, 2003

By Browner R, Kyle J

The adsorption of gold cyanide by the weak base ion exchange resins, PAZ-4¦ and Duolite A-7C, the neutral polymeric adsorbent, Amberlite XAD7¦, and the strong base resins, PAZ-8~a and IRA-400 have been studied in both low and high salinity waters, and their performance compared with activated carbon. A systematic study has also been made of the effect of different ions (Na+, Cat+, Mgt+, Cl', SO4) ) on the gold adsorption capacity and kinetics of these resins. The results indicate that, contrary to popular belief, the ion exchange resin, can perform effectively in highly saline environments. The performance of the neutral polymeric adsorbent im- proves with increasing salinity but cannot match the performance of the ion-exchange resins.

Jan 1, 1991

In discussing the Asia-Pacific region weare talking about a region which has more than 60% of the world's population, a regional economy which will in 10 years be larger than the European Economic Community, and a group of countries with some of the highest electricity generation growth rates in the world. It is economically the most dynamic region in the world.

Jan 1, 1990

By R Vleggaar

In addressing a short-term operational need for the relocation of a tailings storage facility reclaim pond, a mine has achieved a host of water management objectives. Through effective planning and adoption of a strategic æwhole of mine lifeÆ approach, the mine has achieved significant environmental, social and economic benefits. A review of all water management aspects across the site identified a host of other interrelated water issues and concerns which, if dealt with individually, would prove too costly for individual operational departments. When considered as a whole, however, the issues became opportunities and provided the stimulus for integration of the site water management system. The development of site water and solute balance models provided the tool by which a number of water management options/strategies could be evaluated. The conceptual design and costing of the proposed water infrastructure further facilitated the evaluation of the multiple benefits to be gained from each option. A business case could then be made to mine management for the preferred option. The recommended water management strategy finally recommended to the mine not only provided a tailings storage facility (TSF) reclaim pond, but also provided for:increased wastewater recovery from the TSF, the capture of all waste rock dump run-off, additional water harvesting from local creeks, increased wastewater reuse, improved environmental water management, infrastructure that could be used by the local community after mine closure, and overall cost savings. This paper illustrates how effective water management planning can provide both short-term economic and environmental benefits, as well as long-term social benefits.

Jan 1, 2006

By Smith IEM

Some samples from arc-type volcanic suites collected in northern New Zealand and southeastern Papua New Guinea show rare earth element (REE) and Y abundances which are enriched relative to the those typical of their respective associations. This enrichment appears to be the result of an alteration process which selectively mobilises the REE and re-precipitates them as REE-bearing minerals in veins and interstitial patches. The alteration is on a micron scale and is not detected in routine petrographic examination. The spectre of REE mobility in young apparently fresh rocks is important to igneous geochemists who use REE abundances to constrain petrogenetic models and may also be important because it indicates the operation of a natural REE enrichment process which could operate in the formation of economic REE deposits.

Jan 1, 1990

Solution transport of gold and silver has occurred as a result of the chemical weathering of many Western Australian epigenetic gold deposits. Evidence for the remobilization of gold exists in the form of small crystalline octahedra, mustard gold, flake gold, and coatings on iron-oxide. This "secondary" gold is of high purity (low silver content). It is believed that the high chloride content of laterite profiles combined with the acid produced by the oxidation and hydrolysis (ferrolysis) of iron has caused dissolution of Au/Ag and Au/Te alloys. Gold, and less frequently silver, is subsequently reprecipitated in the profile nearby.Pyrite, which is a ubiquitous accessory of gold in vein or lode systems, is probably an important source of iron for the development of acidity. Where carbonate is abundant in the primary assemblage, neutralization directs the oxidation of sulphide to a path which produces thiosulphate, and an alternative type of Au/Ag oxidation process. Sulphide/carbonate ratios in the vein system, and adjacent wallrock are seen as important in determining the course and extent of remobilization in the oxidized zone of gold deposits.

Jan 1, 1984

By Singh JK, Singh R

With a view to producing increased target output every year, Indian coal mining industry is fast moving towards mechanisation but the present approach of mechanisation suffers from lack of standardisation, mainly due to nonavailability of the cutting data for various machine/rock combinations. The coal seams of the country are relatively hard in nature and the coaling machines are reported to be affecting production and productivity of the coal mine and the very trend of niechanisation. This paper presents the result of extensive study performed to visualise the cutting characteristics of coal seams of compressive strength ranging from 20 MPa to 65 NIPa. In a specially designed drag bit type coal plough rig, continuous recording of cutting forces was done with the help of a microprocessor based data logger and the specific energy of cuttability was evaluated at different depth of cut and speed of cutting. The geomechanical properties such as compressive strength, orientation and frequency of cleats etc. and different indices of coal seams were measured in the laboratory and field and relationship was developed for easy determination of specific energy.

Jan 1, 1992

The originally estimated mine life at Kidston (starting 1984) was 12 years. Through a continuing process of re-evaluation and improvement in the operation and by expanding the geological knowledge in the region, the mine life has been considerably extended. With falling grades and harder ore, the additional reserves have come with increasing risk - not only in an economic sense associated with diminishing profit margins but also operationally, requiring innovative milling technology and geotechnical designs to provide a lower cost environment for continued profitable mine production.

Jan 1, 1994

By Okura T, Hino J

Coal utilization for copper flash smelting in Japan was initiated due to the sudden upheaval in the price of oil in the last ten years. A major portion of the heavy fuel oil has already been replaced by coal resulting in a corresponding decrease in energy costs. In addition to energy cost savings, an interesting metallurgical phenomenon was observed in flash smelting operations. Unlike oil combustion, coal is not burned completely in the shaft. A considerable fraction of coal particles remain on the surface of slag and are burned at the settler. Chemical investigation has shown that oxygen potentials at the settler have consequently decreased, bringing the slag and matte phases into reducing conditions, thus oxidation and reduction can coexist in one flash smelting unit. As a result, a decrease in magnetite and copper contents in the slag, elimination of furnace hearth build-up and dissolution of intermediate layer between matte and slag have been observed. In general, these led to improvements of furnace operations. However, thermodynamic investigations have shown that some minor elements such as As, Sb, Bi and Pb concentrate from slag to matte. Results evaluated on the basis of thermodynamic data relatively agree with practical observa- tions. Consequently, for coal utilization in flash smelting operations it will be necessary to control oxygen potentials from the stand- points of copper loss in slag and minor element Distributions.

Jan 1, 1987

The basic purpose of blast design is to produce rock in a size range which is within the requirements of the materials handling system. Once this is achieved, one would like to find the fragmentation which minimises total production costs. The former objective requires that fragmentation be assessed by some means, possibly as simple as counting the number of oversize rocks. To determine the 'optimum' fragmentation, however, accurate knowledge of the complete fragmentation distribution is required. The use of muckpile surface images to determine blast fragmentation is the only feasible technique when one does not want to disturb the production cycle; however, a number of problems exist with the use of images amongst which are determining size from a two-dimensional particle shape, estimating the fines which are missing due to image resolution, the size of a 'representative' sample, errors due to the distortion of particle images, etc This paper briefly describes methods of determining rock size from images and expands on the various errors which exist in assessing fragmentation by photographs. Methods to minimise and account for the errors are given, when possible.

Jan 1, 1976

By D Nourry

Optimising the blast is a major issue in the blasting business. It generally means acting on the blasting pattern (drilling, charging, detonating) in order to get a given æresultÆ. This result may either be related to economic reasons, such as the fragmentation influencing productivity, or technical reasons, for example vibrations and projections. Within the frame of the EEC funded Brite-Euram project entitled æBlast-ControlÆ, involving academic research and applied expertise, a general methodology was developed to approach such a problem and currently applied to the industrial partners of the project and final end-users of the generated results. These partners are the limestone ALZO quarry of the CALCINOR group in the north of Spain and the dolomite DMD (Dolomies-de-Marche-les-Dames) quarry of the LHOIST group in the east of Belgium. A first part of the project, over 18 months, was dedicated to establishing a clear relationship between productivity of operations from drilling to primary crushing and the fragmentation resulting from the blast. Extensive monitoring of blasting, production performance and fragmentation data was carried out and automatically collected into a database on both quarries. As expected, it appeared that excessive amounts of fines or boulders were substantially reducing productivity and thus profitability of the operation. Furthermore, an æoptimalÆ fragmentation was assessed for the quarries to run at the best (high throughput, low cost). The second and last part, for the remaining 18 months, was then dedicated to adapting the blasting practice in order to orientate the fragmentation towards a æbetterÆ one. A very common problem normally addressed by any consultant. Nevertheless, the target was not limited to solving the problem for these two quarries, but also to develop a generic method to address this blasting adaptation process and to implement it into a computerised tool. At this stage, it is then obvious that portability of the method and the system are major qualities to be looked for. This paper is aimed to present how this method was developed, how the system was implemented and how it was finally used.

Jan 1, 2001

New Caledonia is a major metallogenic unit of the south-western Pacific Rim. Its mineral production is of world significance and it has an unusually well diversified mining history. New Caledonia's main metallogenetic potential is, however, associated with its unique ophiolitic complex and its important mineral- izations of nickel, chrome, cobalt and iron. Gold has been found in all the four basic tectonic elements of New Caledonia: the Central Massif, the West Coast basalts, the ophiolitic complex and the Caledonian North. Some analogies are attempted. Only the Caledonian North has supported mining operations (213 kg Au). More recently tenuous gold indications have been found within the ophiolitic complex, possibly associated with Oligocene plutonism.

Jan 1, 1987

By A J. Moore

Predictive assessment of surface blast vibration requires the identification and quantification of significant factors, and the summation of their combined effect. Methods available for the prediction of significant factors are described, and examples are given of the combined use of these methods to evaluate alternative proposals.

Jan 1, 1999

By Fuller P. G

The purpose and current practice of cable trusses in underground coal mines is briefly outlined and details of various cable truss designs are presented. The main part of the paper describes the in-situ performance of cable trusses installed as secondary supports in gateroads and recovery roads of longwall coalfaces. The performance analysis is based on the results of in-situ monitoring carried out at a number of sites at two underground coal mines within Australia. Truss performance has been assessed as load developed in relation to roof convergence, face position and time. Additionally, the influence of strata conditions, installation pattern/density, roadway layout and geometry have been taken into account. An analytical model has been developed to predict truss loads. The principal variables are listed and the basis of the model is described. Based upon behaviour observed in the field the model has been progressively upgraded and validated against measured performance. Guidelines on truss performance and factors which influence it are presented and the implications of these to the use of cable trusses is discussed. Possible methods for improving truss performance in certain strata conditions are outlined and some comments are made on the value of cable trussing compared to cable bolting in these Situations.

Jan 1, 1992

By K B. Barnard, M D. Urbani

A synergistic solvent extraction (SX) system for nickel and cobalt recovery using Versatic 10 and decyl-4-pyridinecarboxylate was tested with BHP Billiton pilot plant leach solution. Another synergistic SX system for cobalt and zinc recovery was successfully tested using Baja MiningÆs pilot plant leach solutions. Synergistic SX systems have also been developed to separate iron, zinc and copper from nickel and cobalt for Minara Resources and to separate manganese from magnesium and calcium in waste stream for HiTec Energy. The gypsum precipitation problem at the former Bulong operation could have been alleviated using a Versatic 10 and CLX50 synergistic SX system. These synergistic systems have shown high selectivity for target metals over impurity metals and would largely improve SX plant operation. Maintaining a æhealthyÆ organic is very important for efficient plant operation. Careful analysis of plant organic at CSIRO has been used as a tool to pre-empt and/or solve problems in operating circuits. Work performed to assist operators has included assessing plant organic solutions to highlight impurity build-up with time, assessing reagent stability under prescribed operating conditions, correlating organic composition with impurity transfer and crud analysis. An independent estimate has determined that work in this area by CSIRO has provided over $50 M in benefits to the industry.

Jan 1, 2005

The application of modern sciences prior to nineteenseventies have resulted in the placing of Continental Drift theory into broader concept of Plate Tectonics. The concept is applied to explain the Cenozoic Tectonics of North Sumatera.Oceanic crust flooring the Indian Ocean is moving northeasterly and being obliquely subducted at a Benioff zone along the western margin of Asian Plate, marked by the Sunda Trench in the west coast of Sumatera. This phenomenon was generated since late Mesozoic, continued during Cenozoic era up to present day, resulted an exellent example of arc-trench system which can be traced along SW - NE transect of North Sumatera.The oblique-subducting plate of Indian Ocean beneath Asian Plate, together with spreading of Andaman seafloor beginning in Pliocen epoch, have led to the origin of Sumateran Fault System; the System extends throughout the length of Sumatera island. In the region under review it comprises almost contiguous set of broadly SE-trending. Evidences for transcurent-dextral displacement have been observed.

Jan 1, 1990