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By J. W. Gabelman

A study of spatial relations between uranium and other metal deposits and hydro thermally altered rocks in western Colorado demonstrated districtwide and regional zoning. The pattern was later found repeated elsewhere in the Western Hemisphere Cordillera. District mineralization centers are pipelike bodies of pervasively altered rock from which intensity-temperature-pressure gradients decreased outwardly. Uranium occurs in several zonal environments but usually is economic only in outermost zones. The general similarity of zones throughout the tectoni-cally and metallogenically uniform Cordillera may reflect a consistent hydrothermal process involving zoning. By determining positions of zones it should be possible to select for examination the most favorable small portions of districts or provinces. Mineralogical zoning has been discussed by Lindgren,l3 Graton,lo Emmons,' Blanchard,' Park and many others. It is commonly found to some extent in most mineralized areas. The existence of nonmetallic alteration envelopes around lode metal deposits and their relation to metallization were first emphasized by Lovering,l4 Burbank, Sales and Meyer," Sales,2o McKinstry,I7 Lovering and others15 and Schmitt. Also, large areas of nonmetallic alteration containing porphyry-type replacement metal disseminations have long been recognized and are described by Schwartz,25-28 Kerr and others" and Gilully. In some districts, e. g., Bingham Canyon, Utah, and Santa Rita, N.M., base metal lode deposits and their alteration envelopes are zoned around large altered areas which contain porphyry copper replacement disseminations; however, the spatial and genetic relations between lodes and replacement disseminations and their associated alterations do not seem to have received sufficient attention. Bodies of altered rock containing porphyry-type replacement disseminations are many times larger than the alteration envelopes containing lode deposits. The two types are rarely superimposed. They occur adjacent to or independent of one another, but they are believed to be related through the mechanism of zoning as suggested by Gabelman and Boyer. 5'6 Most of the significant lode metal deposits are distributed around central pipelike bodies of strong, pervasive, nonmetallic alteration which may or may

Jan 1, 1962

By T. S. Lundy, F. R. Winslow

DIFFUSION coefficients of Hf181 in the high-tem-perature bcc phase of reactor-grade hafnium were determined at temperatures of 1795° to 1995°C by standard lathe-sectioning techniques. The temperature dependence of the data may be described by an Arrhenius-type expression for this limited temperature interval. However, hafnium is classed with the "anomalous" bcc metals zirconium, titanium, and y uranium by the low values of Do and Q observed in this study. The hafnium metal was received as 1/2-in.-diameter crystal bar. Analyses by the Analytical Chemistry Division of Oak Ridge National Laboratory showed the major impurity to be zirconium— about 2.1 pct. The total interstitial content was about 225 ppm with 190 ppm of this oxygen. The Hf"' was supplied as HfC12 in HC1 solution by the Isotopes Division of Oak Ridge National Laboratory. The hafnium bar was cut into disk-shaped specimens 3/8 in. long. One of the flat faces of each specimen was metallographically treated and then the isotope was deposited by vacuum evaporation from a tungsten filament. A 3 by 3 in. NaI (Tl) crystal with a single-channel analyzer was used for counting y rays with energies of 0.3 to 0.7 Mev. The as-deposited layers of isotope had counting rates of about 200 counts per sec. Specimens were annealed in argon in a tantalum resistance furnace. Temperatures were measured with a microoptical pyrometer calibrated for the particular furnace sighting conditions. All sectioning was done by standard lathe techniques. Section weights were determined on a semimicrobalance. A density of 12.5 g per cu cm was used in determinations of section thicknesses. Activities associated with the various sections were measured and the penetration data were treated using the computer code by winslow.' In all cases, except for specimens annealed at temperatures below 1795°C, normal Gaussian penetration behavior resulted. At lower temperatures, plots of In A(x) vs x2 were nonlinear [~(x) = relative activity at a distance x from the

Jan 1, 1965

By J. N. Hobstetter, J. J. Becker

Slip lines in deformed copper single crystals exhibit very pronounced cross-slip and clustering if the stress axes are not too far from <100>. This orientation dependence seems to persist whether or not attempts are made to reduce the bending constraints of ordinary mechanical tests. THE purpose of this paper is to report some microscopic features of the plastic deformation of copper single crystals. The material used was OFHC copper obtained from the American Brass Co. Single crystals about 3 in. long and 5/16 in. in diameter were made by lowering graphite crucibles containing this copper out of the hot zone of a vertical tubular furnace at a rate of 1 1/4 in. per hr. The furnace atmosphere was nitrogen. The orientations of the crystals were determined by the back-reflection Laue technique.&apos; The X-ray spots usually indicated a slight lineage structure of not more than a degree or two. The crystallography of slip is discussed in Schmid and Boas.&apos; The terms classical slip, cross-slip, and conjugate slip are used here with the same meanings as in ref. 3. Compression Specimen 17 (Fig. 1) was selected because the resolved shearing stresses on eight slip systems dif- fered at most by a factor of 1.2. It was hoped that in this situation such effects as cross-slip might be made more prominent. Two intersecting planes parallel to the stress axis were ground on the crystal, using optical abrasive on a lead lap. The large plane was approximately perpendicular to the plane of the axis and the primary slip direction. Its exact orientation was determined by X-ray. The smaller made an angle of 49" with the larger, measured by reflecting a small light source. The specimen was etched with nitric acid until its diameter had been reduced 0.010 in., and then was given a metallographic polish and very

Jan 1, 1954

By Warren L. Howes

THIS paper deals primarily with an investigation of ball-mill liners that was conducted by the writer over a period of six years at the Mammoth mill in Arizona. The investigation covered a wide variety of designs of liners in both primary and secondary mills. The comparative results are presented herein as evidence of the extent to which design influenced liner life and mill performance. FLOWSHEET The feed to the Mammoth mill was a complex, oxidized, gold-silver-lead-molybdenum-vanadium ore with rhyolite, andesite and granite as gangue. Although the ore varied between stopes, the long-term average in character remained substantially the same. Capacity was 560 tons per day. [t] Fig. I shows an abbreviated flowsheet of the grinding section of the mill. PRIMARY BALL MILL A 3-ft. Symons shorthead crusher in open circuit crushed to ¼ -in. maximum one-way dimension the feed to the 5 by 10-ft. Marcy open-end ball mill. The mill rotated at 80 per cent of critical speed and was charged with 4-in. forged steel balls. Cast balls were used for a few months at a slight reduction in ball cost, but breakage of the large balls reduced the ball size and grinding capacity to a point where the over-all costs suffered out of proportion to the saving in cost of balls. For metallurgical reasons, the finished product of the mill was maintained at minus 8-mesh. This coarse product, plus the very abrasive ore and the absence of fines in the feed, caused abnormally rapid wear of the mill liners. The resultant high operating cost led to the most extensive phase of the investigation. [ ] In order to clarify the difference in design of the various types of liners used, Fig. 2 shows the profiles with the arrangement in which grinding balls of maximum size would lie on the face of the liners. The results with each type of shell liner in the primary mill are shown in Table I.

Jan 1, 1943

By C. A. Eligwe, F. W. DeVries, A. E. Torma

This study is an investigation on using hydrogen peroxide for tank-leaching of uranium with sulfuric acid. The optimum sulfuric acid concentration was found to be 0.03 mole 11 -&apos;for a 25% pulp density suspension. The order of reaction with respect to sulfuric acid concentration was found to be ns0.75. The best results vith hydrogen peroxide were obtained at a 4.64 molar ratio of 6202 to U in the ore. The order of reaction was found to be zero with respect to hydrogen peroxide concentration. The theoretical maximum rate effect of Hz02 on uranium extraction was derived as Vm = 8.15 x mole &-&apos;min-&apos;. The highest rate experimentally attained was 8.09 x mole kL&apos;min-&apos;. It was found that the uranium extrac- tion was not affected by the pulp density up to the 50% used in this study. However, the final yieldswere significantly higher (over 90%) for leaches carried out in the presence of Hz02 than (less than 90%) for leaches carried out in the absence of H202. The reaction was found to follow a first order course with respect to substrate concentration (pulp density) regardless of the presence of H202. The effect of temperature was more explicit at moderate tempetatures (30 to 55 C) than at lower (10 C) or at higher (70 C) temperatures. At this latter temperature an almost complete extraction was realized even without H202. The apparent activation energies were found to be AEa = 2.68 kJ mole-&apos; in the absence of H202, 0.5 kJ mole-&apos;with Hz02 at 40 C to 70 C. and 4.72 kJ mole-&apos; with Hz02 at 10 C to 40 C. All these activation energy values suggested that the uranium extraction process is diffusion controlled regardless of the presence of H202. Further, the change in activation energy in the presence of Hz02 indicates the possibility of change in the reaction mechanisms at lower and higher temperatures.

Jan 1, 1980

By James D. Sisler

Among the various studies made by the Coal Fact Finding Commission, appointed by President Warren G. Harding in 1922 to investigate all phases of the coal-mining industry in the United States and to report to Congress, was one concerning the amount and nature of losses in mining bituminous coal in the eastern part of the United States. This study was carried on under the direction of the U. S. Bureau of Mines. The writer was appointed field engineer to investigate the problem in Ohio, Pennsylvania and West Virginia. Some 400 mines were studied in these three states and conclusions were drawn from many sources of data. The summary report written by George S. Rice and J. W. Paul states that "the field reports indicate that the recovery in Ohio will remain about as at present, except in the Belmont district; whereas in Pennsylvania it will gradually improve, and in West Virginia it will improve rapidly." Since 1922, the writer has been interested in gathering material to substantiate or contradict these prophecies. Nature of Coal Losses There are six general causes of losses of coal in mining: (1) coal left on the roof and bottom; (2) coal lost in room, entry and panel pillars; (3) coal lost in oil-well or gas-well pillars; (4) coal lost under buildings, railroads and boundaries; (5) coal lost in handling and prepayation, underground and surface; (6) coal lost by rolls, thin or dirty areas and under streams. Local economic aspects that dominate the type of mining conditions determine to some extent whether certain losses are avoidable or unavoidable. In general, however, unavoidable losses include coal lost in the protection of buildings, streams, railroads, restricted properties and around oil and gas wells. Barrier pillars and other safety pillars are unavoidable losses as long as their size does not exceed the minimum for adequate safety. Natural physical conditions beyond human control, such as rock faults, clay veins, partings and binders, bad top and bottom, rolls and horsebacks, cause unavoidable losses. Unavoidable losses

Jan 1, 1931

By Mark A. Ammon

The two most widely used methods of measuring hardness are the Brinell and the scleroscope. In the Brinell method a hardened steel ball is pressed into the steel under a definite load and the area of the resulting depression is measured. The load in kg. per sq. mm. of the area of the depression is taken as a measure of the hardness. Within certain limits the hardness number so determined is independent of the load or the size of the ball. In the scleroscope method a small weight carrying a diamond point is dropped through a glass tube upon the steel and the amount of rebound is taken as proportional to the hard-&apos; ness. In both methods the scale of hardness is an arbitrary one; however, they agree in a comparative may, that is, a steel showing 50 per cent. increase in hardness by the Brinell test mill show approximately 50 per cent. increase in hardness by the scleroscope test. Yet upon consideration of the two methods it appears that, upon a steel which has been carbonized, this should not be the case ; for the scleroscope method gives almost exclusively the surface-hardness, and the condition of the material below the surface has but a slight bearing upon the hardness number. The results given by the Brinell method should, however, be the exact opposite; for the depth of penetration &apos;of a ball pressed into the steel would be dependent to a large extent upon the condition of the material below the surface. This is particularly obvious when it is considered that the size of the ball ordinarily used in the Brinell method is 1 cm. (about 8 in.) in diameter under a load of 3,000 kg., while the diamond point of the scleroscope is in the neighborhood of 0.01 in. across, fitted in a hammer of about 0.5 oz. weight and dropping from a height of 10 inches.

Jan 1, 1913

By Oswald J. Heinrich

The serious objections to the Leblanc soda process may be enumerated as follows: 1st. The total loss of sulphur employed, equal to about one-third of soda produced. Various processes have been proposed to regain this sulphur, but none have come into practical operation on a large scale. 2d. The great balk of waste products, equal to nearly twice the amount of soda, which forms a serious annoyance about the works. 3d. The complicated series of operations necessary. 4th. The large amount of labor and fuel required. 5th. The prodoction of noxious gases which necessitate extensive condensing arrangements. 6th. The large capital necessary for the . erection and maintenance of the plant, These objections have long been recognized, and many attempts have been made during the last thirty or forty years, to discover and introduce a cheaper and more direct method for the manufacture of this important staple. The reaction between bicarbonate of ammonia and common salt, whereby bicarbonate of soda, insoluble in a solution of chloride of ammonium, is precipitated, has been closely studied for the last twentyfour years, on account of its simplicity and the purity of the product it affords. This ammonia-soda process is now so far developed, that while it is not in position to entirely replace the Leblanc process, yet it can successfully compete with it where the conditions and localities are favorable. The advantages of the ammonia-soda process may be summed up as follows : 1st. It is independent of the essential agent in the Leblanc process, via., sulphuric acid, and hence can be established in those localities where salt is abundant, and yet where sulphuric acid could not be made, or where it could not be transported profitably. 2d. The ammonia-soda process being a " wet" process, the evaporation of salt brines to obtain the solid salt required in the Leblanc process, is rendered unnecessary. 3d. The direct conversion of chloride of sodium into bicarbonate of soda, which can readily be converted into the maketable monocar-

Jan 1, 1879

By Alan D. Smith

Mine roof fall characteristics of 250 falls in 5 different room-and-pillar coal mines, located in Pike, Martin, and Floyd counties, were investigated to determine the relationship of selected parameters associated with roof failure and the assumed condition of the mine roof before failure. The selected parameters used in the study included: presence of cracks and water before the occurrence of fall, sloughing of coal ribs, floor heave condition, type of roof support (resin or mechanical anchor bolts), distance to coal face, and time of occurrence of fall after initial coal extraction. In addition, research hypotheses, utilizing multiple linear regression techniques, were generated to test the relationship among the selected parameters and mine roof condition. The results indicated that the vast majority of falls portrayed some presence of water before the actual fall, occurred in less than 30 weeks after initial coal excavation, located usually greater than 30 meters from nearest coal face, gave evidence of cracks in mine roof before occurrence of fall, generally portrayed a good roof condition before the fall, showed presence of sloughing of coal ribs, and gave no occurrence of floor heave before occurrence of fall. In terms of the characteristics of the original support systems in the mine roof falls studied, most roofs were either supported by mechanical-anchor bolts or resin or full-column bolts; very rarely did the roof appear to fail if supported by posts or cribs. A detail inspection of the hypothesis and model comparison results gave supporting evidence that the condition of the roof is not dependent on the usual indicators of potential failure, such as presence of cracks and moisture. In fact, in most cases of mine roof failure, the immediate roof condition was rated as good or better, which gives little or no indication of pending failure and collapse. Hence, a combination of factors that are not easily accessible to measurement, are the dominant factors in the determination of roof fall-potential areas.

Jan 1, 1984

By E. W. Shilling Harwick Johnson

The separation of hematite by hysteretic repulsion was first brought to the attention of the public in 1922, by W. M. Mordeyl. Three years later another paper2 was published and after another four years a third paper3 appeared in the South African publications. Certain data were lacking in these papers. In order to continue the work intelligently a knowledge of the shapes of the hysteresis curves for certain minerals was very necessary. This information was not available until the present year4. It was known that reduction of certain ores rendered them amenable to this process of separation but definite data in the form of curves showing exactly the effect of such treatment were lacking. Probably our best source of information on the separation of minerals by the use of alternating-current magnetic fields today is the reports from the U. S. Bureau of Mines5"7. It is not the purpose of this paper to tell the reader in detail how to make a commercial separator. Experimental models have recently been made? and the results obtained have been so good that it is the opinion of the authors that the public will soon take an active interest in the subject and its development. The writers have constructed a separator that is considerably different in construction and operation from the two types described by Mr. Davis. This will be described, but the real purpose of this paper is to outline certain experiments and give curves showing data that have a fundamental bearing upon the practical construction of a separator of this type. Specular hematite is usually considered nonmagnetic; that is, it is very feebly magnetic as compared to some other minerals. If specular hematite is placed in a steady magnetic field there is no apparent attraction. At the moment of closing the switch, however, some particles may be seen to move. If the field is alternating, the particles are con-

Jan 1, 1936

By Anthony Anable

The definite trend to stricter specifications with respect to hydraulic concrete has become increasingly manifest in the last six years or so; but it remained for the vast reclamation projects of the Bureau of Reclamation of the Department of the Interior of the last few years to focus attention on this trend, and to demonstrate how thousands of tons of concrete-making aggregates can be produced continuously and automatically with a control of fineness comparable with that obtained with small samples in well equipped private and governmental laboratories. Pioneer work in this direction was done, to be sure, by private companies, notably the Kaiser Paving Co. of San Francisco, prior to the present vast public works program. Then in 1931 came the first great aggregates-preparation plant of the Six Companies, Inc. to supply construction materials for Boulder Darn1 in Nevada, and now, in 1936, the aggregates plant of the Mason-Walsh-Atkinson-Kier Co., general contractors on the Grand Coulee darn in Washington. At Boulder dam and to an even greater degree at Grand Coulee dam, sand production is recognized as probably the most important single element affecting the physical characteristics of the concrete. For in the construction of dams accurate grading of the fine aggregate has considerable bearing on the attainment of a uniform and homogeneous concrete of a high degree of workability and placeability and, at the same time, combining high density and low cement content. Low cement content is of value not only from the standpoint of ceonomy but also because the use of an unnecessarily rich concrete causes certain undesirable characteristics to develop. This paper will relate how at Grand Coulee dam methods that are more advanced than ever before are producing four sizes of gravel and a sand having a fineness modulus of 2.5-3.0. The design capacity is 1000 tons an hour. Significantly, the methods and equipment employed arc broadly those that have been used for a generation in metallurgical mills for accurately sizing and grading both precious

Jan 1, 1938

By A. Hellawell

Binary alloys of compositions intermediate between solid-solubility limits and eutectic compositions have been completely separated into primary phases and eutectic by freezing unidirec-tionally at very slow rates (10-6 to 10-5 cm per sec). The alloys examined were Pb-1 wt pct Ag, Al-20 wt pct Cu, and Al-42 wt pct Cu. The compositions and proportions were close to those expected from the phase diagrams and provided information about the solid/liquid interface at certain free zing rates. DURING the directional freezing of an alloy the solute distribution is controlled by the efficiency of mixing in the liquid,&apos;" whereas diffusion in the solid state is of negligible importance. It is known3 that mixing by convection is very efficient, but complete segregation is only achieved at very slow freezing rates4-6 or with forced stirring in the liquid. &apos; Yue9 and Yue and clark10 have previously illus- trated partial separation of primary phases in alloys close to eutectic compositions. In the present work, taking binary alloys of compositions intermediate between the limits of solid solubility and eutectic compositions, it has been possible to achieve complete separation of the primary phases by directional freezing at very slow rates. METHODS AND RESULTS The alloys concerned were Pb-1 wt pct Ag, A1-20 wt pct Cu, and A1-42 wt pct Cu. As may be seen from the relevant diagrams,11 these alloys should segregate into approximately equal proportions of primary solid solutions and alloy of eutectic compositions. Specimens, -12 cm long and 1 cm wide, were frozen in horizontal tubes by withdrawal from a furnace. The lead alloy, prepared from materials of 99.999 pct purity, was sealed into evacuated Pyrex tubes and the aluminum alloy of similar purity contained in graphite boats under vacuum. The molten alloys were seeded with some 3 cm of solid to prevent irregular initial freezing rates and the last portions to freeze were ignored. At the slow freezing

Jan 1, 1965

By Anthony Anable

The definite trend to stricter specifications with respect to hydraulic concrete has become increasingly manifest in the last six years or so; but it remained for the vast reclamation projects of the Bureau of Reclamation of the Department of the Interior of the last few years to focus attention on this trend, and to demonstrate how thousands of tons of concrete-making aggregates can be produced continuously and automatically with a control of fineness comparable with that obtained with small samples in well equipped private and governmental laboratories. Pioneer work in this direction was done, to be sure, by private companies, notably the Kaiser Paving Co. of San Francisco, prior to the present vast public works program. Then in 1931 came the first great aggregates-preparation plant of the Six Companies, Inc. to supply construction materials for Boulder Darn1 in Nevada, and now, in 1936, the aggregates plant of the Mason-Walsh-Atkinson-Kier Co., general contractors on the Grand Coulee darn in Washington. At Boulder dam and to an even greater degree at Grand Coulee dam, sand production is recognized as probably the most important single element affecting the physical characteristics of the concrete. For in the construction of dams accurate grading of the fine aggregate has considerable bearing on the attainment of a uniform and homogeneous concrete of a high degree of workability and placeability and, at the same time, combining high density and low cement content. Low cement content is of value not only from the standpoint of ceonomy but also because the use of an unnecessarily rich concrete causes certain undesirable characteristics to develop. This paper will relate how at Grand Coulee dam methods that are more advanced than ever before are producing four sizes of gravel and a sand having a fineness modulus of 2.5-3.0. The design capacity is 1000 tons an hour. Significantly, the methods and equipment employed arc broadly those that have been used for a generation in metallurgical mills for accurately sizing and grading both precious

Jan 1, 1938

By E. W. Shilling Harwick Johnson

The separation of hematite by hysteretic repulsion was first brought to the attention of the public in 1922, by W. M. Mordeyl. Three years later another paper2 was published and after another four years a third paper3 appeared in the South African publications. Certain data were lacking in these papers. In order to continue the work intelligently a knowledge of the shapes of the hysteresis curves for certain minerals was very necessary. This information was not available until the present year4. It was known that reduction of certain ores rendered them amenable to this process of separation but definite data in the form of curves showing exactly the effect of such treatment were lacking. Probably our best source of information on the separation of minerals by the use of alternating-current magnetic fields today is the reports from the U. S. Bureau of Mines5"7. It is not the purpose of this paper to tell the reader in detail how to make a commercial separator. Experimental models have recently been made? and the results obtained have been so good that it is the opinion of the authors that the public will soon take an active interest in the subject and its development. The writers have constructed a separator that is considerably different in construction and operation from the two types described by Mr. Davis. This will be described, but the real purpose of this paper is to outline certain experiments and give curves showing data that have a fundamental bearing upon the practical construction of a separator of this type. Specular hematite is usually considered nonmagnetic; that is, it is very feebly magnetic as compared to some other minerals. If specular hematite is placed in a steady magnetic field there is no apparent attraction. At the moment of closing the switch, however, some particles may be seen to move. If the field is alternating, the particles are con-

Jan 1, 1936

By P. B. Scotland

THE mines of the Arizona Copper Co. are situated in the Morenci-Metcalf copper district in southeastern Arizona. This copper-bearing district covers a triangular mountainous area of about 3 square miles, rising abruptly from the gravel plateau of the surrounding country. In this area, an immense intrusion of porphyry has displaced, shattered, and engulfed the shales, limestones, and quartzites formerly bedded on the basal granite. Outcrops of oxide ore were discovered in 1873, and these surface ores were found to connect in depth with large bodies of high-grade oxide ores in the limestones and shales. The smelting of these ores in blast furnaces continued until about 1893, when the rapid exhaustion of the high-grade ore led to the discovery and exploitation of the low-grade sulphide ores in the adjoining porphyry. Methods of concentration were then devised and the low-grade ores finally rendered profitable. The Arizona Copper Co. and the Detroit Copper Mining Co., operating in the same district, were the pioneers in the successful development of the low-grade "porphyry" properties of to-day. The largest mines of the Arizona Copper Co. are the Humboldt and Clay at Morenci, and the Coronado, Metcalf, and King at Metcalf. These mines produce about 4,000 tons daily of concentrating ore containing from 2.5 to 2.8 per cent. copper. The topography of the country is very rugged and mining operations are conducted principally through adit levels. A few of the mines are opened by shafts, the deepest being 1,100 ft., in the Coronado mine. ORE OCCURRENCE The low-grade sulphide ore occurs as: (1) disseminated deposits in the main stock of quartz porphyry; (2) lode deposits in fault fissures in granite. The high-grade oxide ores were found as tabular deposits in limestone and shale close to contacts with porphyry. Low-grade oxide ore formed the outcrop of some-&apos; the sulphide orebodies; the majority of the outcrops, however, were barren.

Jan 2, 1915

By Louis L. Stott

It is well known that the oxide of beryllium was identified as a new "earth" in 17971 and the metal first isolated in 18272. The history of the many difficulties encountered by early investigators, the laboratory achievements of Lebeau3, Fichter4 and Oesterheld5, and the eventual development of methods for commercial production are well covered in the literature, particularly in the authoritative published work of Siemens and Halskes reviewing their comprehensive investigation of the element. Accordingly it has seemed desirable to restrict this paper to the properties and uses of beryllium and its alloys. PRopeRties of Beryllium A comprehensive summary of the available data on the properties of beryllium is given in " Gmelius Handbuch der Anorganischen Chemie7." The metal is steel gray in color. A fractured surface exhibits a bright luster, which does not appear to change with long exposure to air, probably because of a thin, transparent protective oxide coating. The specific gravity is approximately 1.8. Although there is no recorded actual determination of Young&apos;s modulus of elasticity, it has been estimateds, according to Fessenden&apos;s law, to be 30,000 kg. per sq. mm., or about 30 per cent higher than steel. Beryllium appears to have an electrical conductivity approximately 1/12 that of copper. The physical constants as available in the literature are given in Table 1. One of the outstanding properties of beryllium is its great affinity for oxygen, nitrogen, sulfur and carbon. One gram of beryllium takes up 1.774 grams of oxygen and will liberate approximately 15.23 kilogram-calories in the combination. The metal apparently reacts with all known oxides at high temperatures; in fact, beryllium will alloy with thorium and zirconium if melted in crucibles of their oxides. The true physical properties of beryllium are still somewhat in doubt, since very small amounts of impurities appear to cause a large variation

Jan 1, 1936

CONTENTS PAGE FULTON, CHARLES H., and READ, J. BURNS-A New Roasting Furnace for Zinc Flotation Concentrate. Discussed by Charles H. Fulton, Arthur S. Dwight, B. M. O&apos;Harra, Kurt Stock 1 STOCK, KURT.-Redistillation of Zinc. Discussed by G. E. Dalbey, Kurt Stock.. 3 BEASLEY, F. E.-High Zinc in Lead Blast-furnace Slags. Discussed by R. C. Canby, R. L. Lloyd, C. R. Haywood, G. E. Dalbey, A. S. Dwight, E. P. Mathewson, A. L. Walker, B. M. O&apos;Harra, and C. P. Linville 4 STEELE, E. W.-Application of Pulverized Coal to Copper Refinery Furnaces. Discussed by F. R. Pyne, E. P. Mathewson 11 LINVILLE, C. P.-Recovery of Arsenic and Other Valuable Constituents from Speiss. Discussed by C. R. Hayward, C. P. Linville, G. E. Dalbey, A. S. Dwight, Edward F. Kern, Karl Eilers, E. P. Mathewson 12 A New Roasting Furnace for Zinc Flotation Concentrate Discussion of the paper of CHARLES H. FULTON and J. BURNS READ, presented at the New York Meeting, February, 1925, and issued, as Paper No. 1362-D, with MINING AND METALLURGY,. October, 1924. G. E. DALBEY, East Berlin, Conn. What would be the, effect on the formation of sulfates of an increased water vapor content in the roasting gases? CHARLES H. FULTON.-I cannot answer that from our experience. The question of the formation of sulfate in the roasting of zinc is mainly one of temperature and the concentration of S02 and S03 in the gases. We found we could roast almost completely to sulfate if the concentration was kept at the proper point. We, however, did not care to do this because we wished to make a 5 to 6 per cent. S02 gas for sulfuric-acid work. The sulfating of the zinc oxide in the proper concentration of gases goes on very rapidly. There are certain places in the furnace system such as the Cottrell and in a part of the dust chamber in which the roasted

Jan 6, 1925

By J. S. Levine

A series of four displacement experiments has been run in a large alundum core. Flow potential distribution in each liquid phase was measured continuously through oil-wet and water-wet capillary barriers, using a null-point pressure balance, and saturated distribution was determined from electrical resistivity measurements. A method has been devised for calculating the effective (and relative) permeability to each phase at any time and at any point in the flow system for the transient displacement process. Relative permeability points have been calculated and average curves drawn for oil displacing water and water displacing oil. The values of dynamic capillary pressure have also been determined. Data have been substituted into the generalized Buckley-Leverett fractional flow equation and a comparison between actual and theoretical breakthrough recoveries is shown. Displacement experiments have been performed in the laboratory for many years in an effort to determine the effect of a number of parameters on multiphase flow in porous materials. In the literature of petroleum technology, Wyckoff and Botset&apos; were among the first to develop the relative permeability concept and to show experimentally that oil, gas, and water can flow simultaneously through a porous medium in a precise way governed by certain fluid properties, by the relative saturation of each fluid, and by characteristics of the medium itself. Somewhat later, Leverett2 and Hassler, Brunner, and Deahl11 developed some theoretical concepts of capillary behavior in porous materials. The work of Buckley and Leverett3 presented a theoretical analysis of immiscible liquid displacement based on the equation of continuity and the Darcy equation for viscous flow of each fluid. Subsequent investigators attempting to verify the Buckley-Leverett equation have, in general, deliberately neglected the capillary pressure term or have performed experiments in such a manner that it could be neglected. Terwilliger, et al4 in 1951, obtained agreement between theory and experiment for the constant rate displacement of water by gas in a long vertical sand column. Rapoport and Leas5 have investigated the

Jan 1, 1955

By Joseph W. Richards

This method of briquetting flue-dust, or flue-dust mixed with fine ores, or, in a few exceptional cases, coke-dust, has come into large commercial use in Europe, and a small plant is already in operation in the United States. It promisea to become of such great importance to the iron industry of the United States that the following description will certainly interest the majority of our pig-iron producers. Discovered in 1908, the process Tests upon the observation of Dr. Schumacher that blast-furnace flue-dust, while possessing of itself no binding or cementing properties, acquires strong cementing properties if mixed with a very small amount of certain salt solutions, the amount of which is so small that the resulting cementation appears to be rather by catalytic action of the salts added than by the mass-action of such chemicals. To be more specific, fresh blast-furnace flue-dust mixed with from 5 to 10 per cent. of its weight of magnesium chloride or calcium chloride solution—that is to say, with from 0.25 to 2 per cent. of its weight of magnesium chloride or calcium chloride—acquires the property of setting within a short time, from 15 to 60 min., and forming a hard cemented briquette. Alkaline solutions appear to have no action such as described, and they even interfere, if present, with the action of the magnesium and calcium solutions. When treated in this way the flue-dust briquette sets very hard, apparently from pure excess of cementing- and setting-power. It is, therefore, possible to mix with the flue-dust a considerable proportion of inert ore or like material, which has no setting-power by this process, and thus to make a compound briquette containing large quantities of ore mixed with flue-dust, but in which the flue-dust may be regarded as the cement or binding-material. A particularly strongly cementing flue-

Jan 1, 1913

By Guy W. Crane

The geology of the Tintie mining district, fully treated, would occupy an elaborate monograph. This less comprehensive paper is devoted primarily to the occurrence and origin of the orebodies of the district, while space is given to those phases of the general geology only which seem necessary to a proper setting of such a discussion. The first geological report on the Tintic district to be issued was that by Tower and Smith, published in 1899, in the form of a paper in Part III of the Nineteenth Annual Report of the U. S. Geological Survey, and also as Folio No. 65, Geologic Atlas of the United States. About four years ago a second investigation was begun by Waldemar Lindgren and G. F. Loughlin, of the U. S. Geological Survey. With the exception of a paper on the oxidized zinc ores of the Tintic district by Mr. Loughlin, the results of their work are still unpublished. The writer&apos;s acquaintance with the district began in the fall of 1913, and has extended over a period of about two years. 1. Location The Tintic district lies about 65 miles due south of Salt Lake City, and on the west central slope of the Tintic Mountains, a short range, which forms the connecting link between the Oquirrh Mountains on the north and the Canyon Range on the south—the group constituting the first of the Basin ranges to the west of the Wasatch Mountains. The productive portion of the district embraces an area about 6 miles long and 2 miles wide, which is divided between Juab and Utah Counties. Within this area are the towns of Eureka, Mammoth, Robinson, Silver City, and Knightsville. All these points are tapped by the Denver & Rio Grande and S. P., L. A. & S. L. Railways. 2. Topography As in most of the Basin ranges, topographic relief is strong, dropping rapidly from peaks of 8,100 ft. above sea level to elevations of 5,600 ft. in Tintic Valley on the west and 4,500 ft. in Goshen Valley on the east.

Jan 1, 1916