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By Versiane A. Leão

The adsorption of oleic acid and amine, by Expanded Hydrophobized Vermiculite (EHV) was studied. In appropriate conditions EHV is a good adsorbent for these flotation re-agents and the best results are obtained at situations where the chemicals are at non-dissociated form. The adsorbent shows good chemical stability and may been used in many adsorption-desorption cycles.

Jan 1, 1996

By Leonardo Mota, Felipe Perissé Duarte Lopes, Marcelo Gomes da Silva, Sergio Neves Monteiro, Helion Vargas

"Natural fibers, as a class of material, are attracting the interest of engineering sectors owing to specific advantages such as comparatively reduced cost and lower density as well as environmental benefits associated with renewability and biodegradability. For industrial applications, thermal properties, among others, are required. These are major requirements, especially in the case of an insulating natural fiber. In the present work, thermal properties of the curaua were investigated by photothermal techniques, i.e., the open photoacoustic cell and a method based upon the monitoring of the temperature evolution as a function of time. This investigation, in tum, permitted to evaluate two important thermal properties: the thermal diffusivity and the specific heat capacity of the curaua fibers. Indirectly, by means of simple mathematical relations, the thermal conductivity was also obtained. The results were compared with other materials and characterize the curaua fiber as an efficient insulator.IntroductionMaterials are gaining attention in recent years owing to their benefits for the environment as compared to synthetics. Being biodegradable, yearly renewable and recyclable, the natural planted-based are considered fully sustainable [1]. In particular, their life-cycle, from growing to industrial processing, absorbs as much C02 as it is emitted and makes them neutral with respect to greenhouse gases responsible for global warming [2]. Typical examples of these environmentfriendly materials are the lignocellulosic fibers that have been used in simple items such as ropes, baskets, textile, modest roofing, etc, since the beginning of our civilization [3]. In the past few decades, these natural fibers have been extensively investigated [ 4-1 O] as a possible reinforcement phase of polymer composites in substitution for synthetic fibers. In fact, engineering application of lignocellulosic composites are today in the market, especially in the automobile industry [11-13]. Out of the hundreds available natural fibers, only part of them exhibits superior properties to be qualified for composite reinforcement."

Jan 1, 2011

By Jun Chang, Jin-hui Peng, Jing Chen, Li-bo Zhang

The leaching of indium from refractory zinc oxide flue dust(ZOFD) is attempted to utilize microwave sulfating roasting process, followed by water leaching. The ZOFD and roasted product were characterized by XRD and SEM/EDS analysis. The effects of various roasting parameters, such as roasting temperature/duration, the proportion of sulfuric acid, as well as the leaching parameters such as the leaching duration and liquid/solid ratio, were assessed. The results indicate that nearly 97% of indium could be leached under the following conditions: mass ratio of concentrated sulfuric acid to ZOFD to be 0.5, roasting temperature of 150 ℃ and duration of 1.5 hours; while the optimal leaching conditions hold at temperature of 25 ℃ for 1 hour, with 4:1 of liquid/solid ratio. The indium leaching rate by the microwave roasting increased by 8% as compared with the conventional roasting process under identical conditions.

Jan 1, 2015

By Thomas Niehoff, Yin Qing, Wei Zhongling, Liu Yongguo, Zhang Deliang, Tang Le

The gold ore of Shandong Gold Mining (Xinhui) was a refractory ore, which contained multi metallic sulfides (ZnS and PbS etc.) and carbonaceous. The gold ore concentrate came into leaching process and thickener and zinc replacement to recover gold. In order to improve gold recovery, the GOLDOX™ hydrometallurgy process was studied in Shandong Gold (Xinhui) by bench scale and 6 month plant scale test supported by Linde Gas. It was shown that the process promoted the leaching kinetics and improved gold recovery. The residue grade reduced 0.22 g/t in average after oxygen was applied. This indicates an operating profit increase 850,000 yuan/a in the plant. It was setting a good example for similar gold mine plant and would promote the oxygen application in Chinese gold mining industry.

Jan 1, 2015

By Run Huang, Xuewei Lv, Lei Lei, Guibao Qiu, Chenguang Bai

"The TiO2-rich slag and pig iron can be produced from ilmenite concentrate by the electric furnace process. In this study, ilmenite concentrate was reduced in a vertical furnace equipped with a weighting data acquisition system. The effects of reducing agent (carbon) amount on the iron reduction were studied. The phase transformation, morphology and chemical compositions of reduced samples were investigated by X-ray diffractometry (XRD), scanning electron microscopy (SEM) and energy dispersive spectroscopy (EDS), respectively. It was found that the reductive degree of ilmenite concentrate increased with the increase of reducing time. The phases of reduced samples were mostly iron, rutile, Ti3O5 and Fe2TiO5. The mass loss percentage increased with increasing the carbon amount from 8% to 12%. When the carbon amount exceeded 12%, the mass loss percentage decreased with the increasing of carbon amount.IntroductionIlmenite and rutile are the main raw materials for producing titania pigment and titanium metal. With the development of the titanium industry, huge amounts of titanium resources are needed. As sources of high-grade titania mineral decrease worldwide, more attention should be paid to the processes involving low grade mineral such as ilmenite ore. In ilmenite, MgO and CaO are the gangue parts. Therefore, the ilmenite refining becomes more and more popular. In the previous studies, the methods of ilmenite refining are electric furnace smelting, direct acid leaching, selective chlorination and thermal reduction [1]. Electric furnace smelting method is widely used in the titanium industry, however, which consumes a great deal of energies and has a high CO2 emission. Its essence is to remove iron oxides and obtain a high titania slag. So the thermal reduction of ilmenite concentrate is an important step in titanium industry, which can decrease carbon reagent consumption and save energy.Over the past several decades, many studies have been carried out on the mechanism and kinetics of the reduction of different ilmenite ores, which are as follows: The carbothermal reduction of Panzhihua ilmenite initiated at about 860 oC. In the temperatures ranging from 900 oC to 1400 oC, the reaction rate was changed like a shape of “M”. That was to say that the reaction rate increased with the growth of temperature at first, then decreased, afterward increased again and at last the reaction was arrested [2]. The Mohammad A.R group [3, 4] showed that the carbothermal reduction of primary ilmenite concentrate was faster in hydrogen and initiated at a lower reduced temperature than in argon and helium. The reduction in argon and helium had about the same rate and extent. Titanium oxycarbide started at 1000°C in hydrogen. The conversion of primary ilmenite concentrate to metallic iron and titanium oxycarbide at 1200 °C was completed in 300 minutes. Monoxide as the reductant to reduce ilmenite had been studied intensively by a few research groups [5, 6]. The rate and the degree of reduction depended on the formation of a metallic shell of iron which inhibited the transfer of CO to the reaction zones; titanium had a strong effect on the mechanism and rate of reduction of iron oxides. Wang and Yuan [7] studied the reductive kinetics of the reaction between a natural ilmenite and carbon. At temperature below 1100°C, chemical reaction was the rate controlling step, at 1100 to 1250°C mixed controlling was rate controlling step, above 1250°C diffusion through the product layer controlled the reaction. Zhang [8] investigated the reduction of natural, sintered and preoxidized ilmenite concentrates in hydrogen methane mixtures. Preoxidation and sintering of ilmenite concentrates changed their phase composition and caused a sharp decrease in specific surface area of raw materials and an increase in carburization temperature. Sintering also increased the metallization temperature of iron."

Jan 1, 2011

By Shengfan Zhou, XUEWEN WANG, Changjun Jiang, Mingyu Wang

In the process of extracting vanadium from stone coal by sulfuric acid leaching - P204 solvent extraction, Fe(III) can accumulate in the organic phase which reduces the extraction of vanadium. In order to eliminate the effects of the accumulation of iron, oxalic acid was used as the stripping agent to strip the Fe(III). The effects of oxalic acid concentration, phase ratio O/A, stripping time and shake velocity on the stripping of Fe(III) were studied. The results showed that the Fe(III) stripping rate can reach beyond 96% at the room temperature with 70g/L oxalic acid using an O/A of 2 at 160 rpm shake velocity for 20min. After 2-stage stripping, the concentration of Fe(III) in organic phase was 0.008g/L.

Jan 1, 2016

By Lijun Lu, Honghui Fang

This article carried out the experimental study on using desulfurization ash in steel slag composite material. This was done by investigating the desulfurization ash content in formula one and formula two samples on the influence of setting time and strength of mortar. Through this study the following conclusions were reached for formula one: (1) a setting time of more than 10 hours is required, (2) a dosage of desulfurization ash of 1 ~ 2% is optimal, where flexural strength is reduced by 10% ~ 23% and compressive strength reduced by 5.7% ~ 16.4%. The conclusions of formula two were: (1) when the dosage of desulfurization ash is within 5%, the setting time is within 10 hours; (2) when the dosage of desulfurization ash is 1 ~ 2%, the flexural strength is increased by 5 ~ 7% and the compressive strength is reduced by 1 ~ 2%. The results show that the formula two is better.

Jan 1, 2015

By Gerardo Fuentes

The stoichiometry and kinetics of the hydrothermal reaction of enargite in copper sulphate solutions was investigated in the range 140–300 °C, and particle size under 15 and 50 μm. The stoichiometric experiment was performed at 300 °C, using one gram of sample (96% enargite, 4% tennantite) and 100 mL of copper sulphate solution (10 gpl) at 1.2 pH. Enargite reacted completely after 80 min. A solid product was obtained and characterized by XRD. The main product was chalcocite (M) and some traces of djurleite and chalcocite (Q). Tennantite did not react under these conditions. The kinetic experiments were conducted at 140 °C, 190 °C, 250 °C and 300 °C. From fitted data and Arrhenius equation the calculated activation energy (Ea) was 51 kJ/mol. According to the hydrothermal transformations studied, the reactivity of different phases found in the copper concentrates was bornite > chalcopyrite > covellite > sphalerite > pyrite > enargite > tennantite.

By Xun Hu, Jian Pan, Hongbin Yu, Deqing Zhu, Yanhong Luo

Lump ores are one kind of important burdens for blast furnace (BF), their metallurgical properties have significant influence on BF performance. In this paper, the relationships between the mineralogy of five natural lump ores and the metallurgical performance have been studied. The mineralogy study includes mineral compositions, microstructure and porosity, and the metallurgical performance covers reducibility index (RI), low-temperature reduction degradation index (RDI) and decrepitation index (DI). The results show that the complex lump containing hematite, and goethite has better overall metallurgical performance. For single lump, the RI of goetihte ores is higher, the RDI and the DI is strongly influenced by porosity. The hematite and magnetite ores have good anti-decrepitation and anti-RDI, but generally the RI is lower due to lower porosity, and the RI is related to the grain size, the smaller grain size is, the better reduction will be.

Jan 1, 2015

By Guangliang Wu, Dongchang Huang, Xinbin Liu

Oxidation Kinetics of SPHC was analyzed by TGA, and the curve of oxidation weight gain with different temperature was acquired. It is found that, when the oxidation temperature is between 500 and 600 , all the curves are linear; when the oxidation temperature is above 700 , the curves are close to parabolic. At the temperature of 900 , the oxidation weight gain increases dramatically. The TGA results indicate that the activation energy of SPHC steel is 146.19 kJ/mol at the temperature of 500 900 , and an oxidation kinetic model was set up for variable temperature. Based on the temperature change during rolling process, numerical simulation of oxide scales evolution was carried out for SPHC steel, and the simulation result agreed well with measured ones. It can provide a basis for estimating the scale growth and controlling the temperature on site.

Jan 1, 2016

By A. S. Usmani

The flow associated with the pouring of molten metal into moulds has been modelled on the basis of certain simplifying assumptions. A finite element based Navier-Stokes equation solver has been used to analyse the flow. The velocities obtained from the Navier-Stokes equation solver are used to advect a pseudo-concentration function for modelling the fluid front. A simple problem with a known analytical solution is solved first to test the model. Subsequently, several more examples with varied geometrical configurations are modelled, including one with curved flow boundaries.

Jan 1, 1992

By J. Grogan

Leaching of galvanized steel coatings allows the steel substrate to be used as a zinc-free scrap source to steel and iron furnaces. In this study the behaviors of sulfuric acid leaching solutions are investigated. The ranked significance of the variables are shown to be acid concentration > temperature > zinc concentration. Examination of the leaching mechanism finds the rate-limiting step to be the cathodic hydrogen reduction reaction. This rate is not only influenced by acid concentration, but also by the hydrogen reduction exchange current density. Dezincing leaching rates are improved by taking advantage of the higher exchange current density of the iron substrate versus the zinc coating. This is accomplished in practice by increasing the exposed interfacial zinc:iron surface area through shredding. Also, a leach control mechanism is proposed through online monitoring of the zinc-iron couple mixed potential.

By C. B. Piazzarollo

Ceramic materials exhibit dispersion results after being subjected to various levels of stress, from the point of view of mechanical strength. With the focus on sustainable development and to improve the strength of these material, was incorporated ornamental rock waste into clay in up to 10% in mass to conform some samples, that was fired to 750ºC, 850ºC and 950ºC and submitted to technological tests. This paper presents an analysis of the technological properties of the samples through the use of Weibull statistic to determine which the best firing temperature for these red ceramic materials. The Weibull Modulus indicates a greater homogeneity for samples with 10R at 950ºC.

Jan 1, 2015

By Ailton S. Ferreira, Rubén J. Sanchez Rodriguez, Sergio N. Monteiro, Felipe Perissé D. Lopes, Teresa E. Castillo

"Polyester composites reinforced with natural lignocellulosic fibers have, in recent times, been gaining attention in engineering areas as lighter and cheaper alternatives for traditional composites such as the ""fiberglass"". One of the strongest, the curaua fiber, is today being considered as reinforcement of composites for automobile interior parts. In fact, several research works are currently being dedicated to curaua fiber composites since physical and mechanical properties are required for practical uses. In this work, the thermal behavior of polyester composites reinforced with up to 30 % in volume of curaua fibers was investigated by differential scanning calorimetry, DSC. The results showed endothermic and exothermic events associated with water release and possible molecular chain amorphous transformation. Comparison with similar composites permitted to propose mechanism that explains this DSC thermal behavior.IntroductionThe modem composite materials, especially those reinforced with synthetic fibers such as glass and carbon, have been used since last century to attend the demands required by most technological fields, from home appliances to aerospace [1]. In fact, fiber composites offer significant advantages over monolitic materials, such as common metallic alloys, plastic and ceramics. One of the most important is the ratio between the ultimate stress and the density, known as the specific strength. For example, in common glass fiber polymer composites, the so called ""fiberglass'', the specific strength of around 400 MPa.cm3/g is higher than any conventional monolitic material. However, drawbacks exist. The energy required to fabricate ""fiberglass"" generates large emissions of C02, which are responsible for global warming. Moreover, ""fiberglass"" is not recyclable and cannot be incinerated [2]. As a result, most synthetic fiber composites end up in landfills or contribute to rivers and oceans pollution."

Jan 1, 2011

By P. A. Treasure

The EMEW® cell has been developed to overcome a number of inherent limitations in conventional electrowinning technology, particularly the high cost and restricted process windows characteristic of conventional hardware. The technology has been widely demonstrated to achieve high performance for various metals under chemical conditions well outside the limits required for efficient operation of conventional cells. This process flexibility offers significant opportunities for cost savings. in recovery of zinc from primary and secondary sources. The EMEW® technology is now available on a fully engineered basis, as a versatile commercial alternative to conventional electrowinning hardware. Application of the EMEW® cell for recovery of secondary zinc material offers significant advantages to the recycling industry. For example, a selective caustic leach can be used where there are high levels of iron or other contaminants in the target material. The reagent requirement is minimal as most of the caustic is regenerated in the bell and zinc dust that may be required for electrolyte purification is produced in the cell. A high purity zinc powder or cathode is produced in the cell. In the case of acidic zinc electrolytes, the cell is capable of operating over a much wider range of operating conditions than a conventional cell.

Jan 1, 2000

By Shengfan Zhou, XUEWEN WANG, Bianfang Chen, Mingyu Wang

Vanadium was leached from roasted stone coal by NaOH solution, and the effect of leaching temperature, leaching time, addition of NaOH, liquid to solid ratio, the grinding fineness of stone coal, and stirring speed on the vanadium leaching rate was studied. The kinetics analysis for the process is presented by the shrinking core model. The results show that the vanadium leaching ratio of roasted stone coal can be beyond 75% at the 6% NaOH addition, leaching temperature of 95°C, leaching time of 7h, liquid to solid ratio of 1.2mL/g, and grinding fineness of 0.111mm. The leaching process is controlled by interfacial reaction kinetics and the apparent activation energy was 59.36kJ/mol.

Jan 1, 2016

By V. I. Lakshmanan, R. Roy

Base metals and PGMs are currently recovered from sulfide concentrates using pyrometallurgical processes. These processes suffer from several limitations such as being capital intensive, scaling problems, S02 emissions and long delay in value recognition. Alternative hydrometallurgical technologies have so far not been successful and currently total pressure oxidation and partial pressure oxidation hydrometallurgical technologies are being evaluated. Process Research ORTECH has developed a unique hydrometallurgical process to recover base metals and precious metals using mixed chloride technology. In a first stage leach, base metals are recovered and elemental sulfur is liberated from hydrogen sulfide formed during this leaching stage. During second stage leach, precious metals are recovered using proven separation technologies. Some of the advantages of the process are the recovery of elemental sulfur from sulfide sulfur, recycle of the chloride lixiviant thereby eliminating effluent treatment steps and use of excess energy from the Claus reactor for the pyrohydrolysis step.

Jan 1, 2011

By Qiang Zhong, Qian Li, Yongbin Yang, Tao Jiang

Thermogravimetric analysis (TGA) has been used to research the pyrolysis and combustion processes of coal used in rotary kiln of iron ore oxide pellet. Furthermore, the effects of air flow and oxygen concentration on the combustion behavior of coal were examined with TGA. The results showed that two individual stages can be distinguished for the pyrolysis of coal, the water evaporation stage and the de-volatilization stage. And the information on ignition and burnout characteristics can be obtained from the combustion process analyzed by TGA. Large air flow almost has no effect to the combustion process except that it enhances combustion intensity. However, the combustion process is further accelerated under oxygen-enriched conditions. With all experimental results, it could provide an attractive approach of analyzing coal for the rotary kiln process.

Jan 1, 2016

By Xi-chang Shi, Yun-feng Fu, Bai-zhen Chen, Hui Xu, Xiang Xiao

"Extracting boric acid from saline brine by boron specific ion-exchange resin was investigated. Effects of resin amount, temperature, time and stirring speed on boron adsorption rate were studied in the experiments. The results indicated that the XSC-700 resin showed excellent boron absorbability and it performed better property for elution. The maximum boron adsorption capacity was 6.16 mg/ml in the optimum conditions: the resin concentration of 5 ml/(100 ml brine), the temperature of 60°C, the time of 5-6h and the stirring speed of 100 r/min. Boron was eluted from the resin with HCl and boric acid was crystallized by evaporating the eluate. The product of boric acid was in pure form as confirmed by XRD and other analysis techniques.1 IntroductionBoron has a number of minerals in nature such as tincal, colemanite, ulexite, and kemite, etc. [1-2]. Boron and its compounds are chemical materials of significant value. The principal industrial uses of boron compounds are in the production of glass, porcelain, enamels and detergents. Other uses include fertilizers, metallurgy, and nuclear shielding [3-4]. In recent years, because of the large-scale mining boron ore, ore resources are drained gradually. With the development of science and technology, the boron mineral resources will be unsatisfied with the future requirement. There exits abundant boron resources in salt lakes which cover about 40% of the total reserves in China. If we can obtain boron from salt lakes, it will produce great economic interests [5-6]. Therefore, actively seeking boron from salt lake and other resources in suitable conditions has become a hot spot in the research organizations of boron resources development and utilization in the world [7].There are many methods such as acid crystallization, solvent extraction and ion exchange processes suggested effective for boron extraction from aqueous solutions. Acid crystallization method has the shortcomings of complicated procedures, the pollution caused by hydrochloric and other ingredients returning to salt lakes during the extraction process. Although solvent extraction process increases the boron acid recovery efficiency, the cost of production is high [8-9]. However, Chelating resin extracting boron has the characteristics of simple process, easy operation and no pollution. It was reported that chelating resins containing functional groups show a high selectivity for boron extraction [10-12]. Therefore, ion exchange technique which is now the most practical application of significance and most extensively used ha"

Jan 1, 2011

By Sen-xiang Yang, Xin-teng Liang, Gui-jun Li, Jian-hua Zeng, Yong Chen

"This research is based on PANSTEEL 120t steelmaking converter technology to have the quantitative description of the time needed in uniform mixing of molten steel in the converter with the computer. In present work, the numerical simulation approach is used to analyze oxygen lance nozzle, the flow condition of oxygen and flow status of molten steel in the converter. The various oxygen jet flows that come out from different angles and the flow status of all kinds of jet flows in the converter have also been simulated. All of the simulation parameters are based on the specifically practical conditions according to the physical conditions of PANSTEEL 120 t steelmaking converter. Through numerical simulation, the angle parameter of the oxygen lance nozzle is 16 °. The optimized oxygen lance 536-16 has a good performance in industrial application. This kind of phenomenon shows that the ways and processes of numerical simulation in this research are right.IntroductionThe oxygen lance system is the significant process in semi-steel making converter. It's related to whether the converter or even the whole system can function well. While in actual production, many problems emerge in the process of using the former oxygen lance, such as re-drying, slopping, high lance position, dead burning and even blowing out. In continuous fast-paced process, the unstableness of oxygen lance will lead to speed droop or even stop pouring. Analysis shows that all these problems are not only related to the raw materials but also the design of oxygen lance. Bad oxygen lance's scorification kinetics condition and low content of FeOn in early slag are the direct factors that we cannot easily control in steelmaking at present [l]. Therefore, the good scorification kinetics condition which is related to nozzle has good influence on BOF steel making."

Jan 1, 2013