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By R. Scheffel, R. Washnock, G. Zarate

"The second survey of global copper leaching operations has been completed, the data published in 1998 has been updated. A survey questionnaire was sent to 40 identified copper leach operations around the world including those leach properties still in operation that responded to the 1998 survey. This paper lists the results of 26 operations that responded to the survey. Selected information from the survey is represented in graphical form. INTRODUCTION Copper leaching was first performed by truck dumping huge monolithic stockpiles of ore and flooding the surface with leach solution or lixiviant with little understanding to the parameters that support optimum recovery of the metal. Heap leaching has evolved into a controlled process whereby a complex low grade ore is stacked in shallow lifts (under 10 m in most cases). The ore is usually crushed and agglomerated, conveyor stacked on an engineered containment system (leach pad) and irrigated in a controlled manner. The lixiviant chemistry is designed to extract the optimum amount of metal from the ore. At first glance, heap leaching appears to be simple in nature. In fact, it is a very complex process. A plethora of technologies such as material handling, environmental control, analytical techniques, solution chemistry, hydrology and many others contribute to the design and operation of a heap leach. Heap leaching requires an inter-disciplinary approach between geologists, mining engineers and metallurgists. Many operational factors affect heap leaching. The process must address climatic factors, flexible operation, quality control before and after leaching, physical characteristics of the ore, geology, mineralogy, reagent consumption, solution application rate and methods (wobblers or emitters), particle size, and favorable conditions for bacterial growth and survival. Predicting, troubleshooting, and optimization of leach recovery is a significant challenge when considering the number of variables involved and their interactions The survey updates many of these key operating parameters to the current state of the art. It should provide the reader an excellent benchmarking summary of these factors on a site-by-site basis."

Jan 1, 2016

By Hee-Young Chung, In-Mo Lee, Jeongjun Park, Hangseok Choi, Seok-Won Lee

"When using a Tunnel Boring Machine (TBM) during tunneling work, unexpected ground conditions can be encountered that are not predicted in the design stage. These reduce the stability of tunnels, and can result in considerable economic losses. This paper analyzes the potential risk events that may occur due to risky ground conditions. A resistivity survey is utilized to predict the risky ground conditions ahead of the tunnel face during construction. The potential risk events are evaluated considering both the occurrence probability and the impact. A TBM risk management system that can suggest proper solution methods for potential risk events is also developed. Multi-Criterion Decision Making (MCDM) is utilized to determine the optimal solution method to handle risk events. Lastly, an actual construction site, at which a risk event occurred during tunnel construction, is analyzed utilizing the Earth Pressure Balance (EPB) Shield TBM, to verify the efficacy of the proposed system.INTRODUCTION The Tunnel Boring Machine (TBM) method has been widely adopted in numerous tunneling projects because, as a mechanized tunneling method, it is also environmentally friendly, exhibiting minimal noise and vibration when compared with conventional tunneling method. In addition, it provides considerable economic benefits that allow for a high advance rate for long drives during construction. However, the TBM method has a limitation, as it is unable to deal with unexpected situations during construction, as the system is not capable of moving backwards. This leads to delays or even stoppages, and a corresponding increase in construction costs due to the need to arrange for alternative equipment and solutions. It is essential to retain systematic management in order to prevent or deal with unforeseen consequences such as the collapse of a tunnel face, ground surface upheaval or settlement, and construction delay due to water leakage during construction. Therefore, a systematic risk management system that is applicable during the construction stage of the TBM tunnel should be developed, taking into account the predicted risky ground conditions ahead of the tunnel face in advance."

Jan 1, 2016

By Dean Nichols, Matt Ortel

Explosive accidents in the United States have brought increased attention to emergency operation plans (EOP) at all facilities that manufacture, transport, or store hazardous materials – particularly explosive materials. Explosions are sudden, powerful, and complex events that are difficult to characterize in terms of the thermal, over pressure, and debris effects. Industry, regulatory, and public officials require emergency response planners to not only anticipate the blast effects of an explosion, but also to prepare an appropriate response.

Jan 1, 2016

By Scott G. Giltner, Terry Millar, Ben Bringhurst

"Kennecott Utah Copper (KUC) Smelter scheduled a rebuild of their flash smelting furnace forSeptember, 2014. KUC’s goal in this project was to reduce the rebuild time from 65 to 55 days by using explosives to break the matte and brick layers of the uptake shaft and hearth sections of the furnace. Previous rebuilds had employed the slower technique of mechanical breakers to remove the matte and brick layers which took 22 days. KUC has many years of experience in removing slag from the uptake shaft, but they had never used explosives to remove the hearth. As far as KUC was aware, no other smelter operation had attempted a hearth removal in this way."

Jan 1, 2016

By C. McAllister, D. Preece, J. Berendzen

The Multiple Blasthole Fragmentation (MBF) model was developed recently and has been reported in previous papers. The MBF model accepts inputs from the blast design, such as: location and orientation of each blast hole, stemming length, blast hole diameter, multiple decking, bench height, initiation sequence, etc. It models the effect on fragmentation of delay timing with its associated scatter for each blast hole. MBF has a statistical modeling capability for geological random variation of the attenuation of particle velocities. Also simulated is wave reinforcement due to the interaction of simultaneously arriving waves or diminishing cooperative contribution from long delay intervals between charges.

Jan 1, 2016

By Bibhu Mohanty, Sheng Huang

Accurate measure of fragment size distribution is a key objective in all blasting and crushing operations. Several generic distribution functions have been devised to describe the degree of fragmentation for the representative range of fragments from selected measurements. The application of four distribution functions, i.e. Rosin-Rammler, Swebrec, Grady and Gilvarry, in describing fragment size distribution of impact-induced fragmentation of a limestone rock has been investigated. A modified Hopkinson Pressure Bar experimental set-up is used to control both impact velocity and energy input into the target rock. The feed size in the sample holder is varied from 6.35mm to 15.88mm in three ranges and the impact velocity up to 14m/s. The size distribution in the product is determined by sieve analysis for a range of impacts. The experimental results are fitted to the four distribution functions to examine their relative accuracy and reliability.

Jan 1, 2016

"In mechanized mining, poor equipment efficiency (availability, utilization, productivity, and quality) can endanger the success of the operation. This case study will show how an initiative to improve equipment performance developed into a comprehensive turnaround plan for the mine that placed it in the forefront of performance achievement.As part of a company-wide review process, poor overall equipment effectiveness (OEE) was identified as a major reason for the mine not achieving its targets. A project to improve the OEE identified eight improvement areas (elements) that contributed significantly to the poor performances. Measurement metrics were determined for these elements, followed by determination of baseline and target (improved) key performance indicators (KPIs). Cost savings associated with the improved efficiencies were calculated and tracked throughout the project. The mine team determined the specific actions required to achieve the target KPI in each element. These were individually developed and managed like mini-projectswith allocated responsibilities for delivery. The paper will indicate how this OEE improvement initiative triggered an improvement in almost all sections of the mine. Soon after launch, the initiative gathered momentum as the KPIs starting to improve. A visible tracking system exists at the mine and each employee can see the improvements and feel the success. The original eight elements were extended by five more, and the mini-projects grew as participants saw the success of the initiative.This paper concludes that through management and worker involvement, visible measurement and controls, and carefully chosen improvement elements, the mine was turned around. It is now achieving and exceeding its targets, and employee relations and motivation as well as safety have improved considerably. All of these achievements are reflected in the bottom line."

Jan 1, 2016

"Each and every flotation plant must produce daily/weekly/monthly production reports in which metal balances for payable and penalising elements are presented. Several factors including ore heterogeneity and harsh production environment affect the reproducibility of the reported data. Best practices of metal accounting thus prescribe that production reports be accompanied by measurement quality reports quantifying the reproducibility (a data quality metric often expressed as a relative standard deviation) of each data reported. Ignoring the irreproducibility of measurements may lead to the perception that random errors have been totally eliminated through statistical data reconciliation, which is wrong. This paper aims at explaining the full lifecycle management of reproducibility estimation from the outset at the measurement process to its reporting after having been through the statistical data reconciliation process. Indeed, the reproducibility of reported data can be obtained by performing a sensitivity analysis. Necessary conditions for obtaining a truly representative assessment of measurement reproducibility are stated. Typical levels of measurement reproducibility found in operating flotation plants are also reported. These numbers can be used as benchmarks for reproducibility levels that can be realistically expected.IntroductionEach and every flotation plant must produce daily/weekly/monthly production reports in which metal balances for payable and penalising elements are presented. Such production reports are the most expected output from a metal accounting system (MAS). The duly recurrence of this task combined with an insufficient level of automation has somehow contributed to the misleading perception that it is mainly a clerical work. However, as shown in Figure 1, a MAS encompasses way more than just a reporting system. Acknowledging that the content of production reports indubitably origin from raw measurements has important implications for how both the reports and MAS should be monitored."

Jan 1, 2016

By Thomas L. Barkley

"In early 2015 the Seed Waveform method was used to measure the Geologic response of the MesabiIron Formation to explosives energy input. This single charge wave form was then used to design acritical first blast at a newly developed Taconite mine. This initial blast had several irregular restrictions on design and performance. It had a very unusual “Frying Pan” shape, the regulatory agency required that no fly rock land in State owned waters less than 200 feet (61 m) away, there was no open face to blast to. Design criteria included the need to detonate the blast with two sinking cuts, and have the sinking cuts meet through a narrow neck between the cuts. All these had to be met using a 16 inch (406mm) diameter hole."

Jan 1, 2016

By J. P. Germiquet

"Rock properties have a material impact on mining processes, including drilling performance. An investigation using point loaded index (PLI) data converted to uniaxial compressive strength (UCS) has revealed that a direct relationship between grain size and UCS exists at Mogalakwena Mine. This correlation is best seen in unaltered rock, with lower correlations for altered rock types. Measurements from the new RockMa system installed on drill rigs can be used to obtain rock strength data to validate the current rock strength domains and create additional data for the next benches below. An investigation of penetration rates in different lithologies shows that rock composition plays an important role in determining drill performance. Additionally, there is an inverse relationship between rock strength and drilling penetration rate – a measure of how efficiently a hole is drilled.The domaining of grain-size-adjusted UCS at Mogalakwena Mine will allow more accurate scheduling of drill rigs through increased knowledge of rock strength in various areas. Successful rock strength domaining has the potential to be incorporated into blast indexing and predicting crushing/milling performance.IntroductionThe optimization of mining and processing through geometallurgical characterization of ore are key drivers of value realization (Deutch, 2013). Rock strength is one such property and is affected by, among other variables, composition, texture, and grain size (Ozturk, Nasuf, and Kahraman, 2014). Mogalakwena Mine is exploiting the intrusive Platreef PGE (platinum group element)-bearing orebody which forms part of the northern limb of the Bushveld Complex. This complex orebody exhibits areas of metasomatic alteration, metamorphism, and sporadic mineralization of the footwall and hangingwall (Nex et al., 2006). Understanding this variability is paramount due to the implications for rock strength and hardness, which in turn affect crushing, milling, and liberation efficiency. These variables must be known prior to blasting in order to optimize mine and plant processes using in-situ variables. This necessitates predictive modelling (Deutch, 2013). Geological and geotechnical data was sourced from the Overysel (OY) exploration database for the study. Point load testing was done for each borehole and the results converted to uniaxial compressive strength (UCS) (Akram and Bakar, 2007). The relationship of lithology, texture, and grain size with UCS revealed an inverse relationship between grain size and UCS in unaltered rock. The relationship was not present in altered rock types. A comparison of mean strength and hardness results indicated that Bond work index and UCS may be related. Drilling performance is affected by UCS (Bourgoyne et al., 1986), and this was proven using recent measurements obtained during drilling. Lastly, grain-sizeadjusted UCS values were applied to a 3D model for the OY property."

Jan 1, 2016

By William C. B. Gates

Demolition blasting next to an active railroad can be very challenging because of track safety, blasting vibrations, potential track fouling by blast debris, and short work windows on a live track. Recently, in eastern Washington, one of the major railroad companies has been aggressively constructing a second main track to accommodate the expected increase in rail traffic of natural resource products. To accommodate construction of the second line, the railroad company used blasting demolition techniques to remove an old railroad trestle pier on the Milwaukee Road that was in the footprint of the new track bed. The trestle bridged the present rail line and flanked the track with two massive 550-ton (499 tonne) twin-columned steel reinforced concrete piers. The railroad contracted with a specialized contractor to remove the south pier using blasting demolition techniques. The blasting design presented the following challenges: blasting during live track conditions and short work windows; designing a V-notch blast pattern to ensure the pier fell away from the live track; drilling, loading, and timing of the shot; maintaining blasting vibrations at the track below 4 in./sec (102 mm/sec); maintaining ambient overpressure noise below 133 dB; control of fly rock and debris; and track protection and emergency debris removal plan.

Jan 1, 2016

By Dave Rose, David G. Meadows, Mike Westendorf

"Copper Mountain’s concentrator was commissioned in May 2011. The circuit consists of a 34’ x 20’ EGL SAG mill, a Raptor 900 pebble crusher and two 24’ x 39’6” ball mills. Each mill is equipped with a 2 x 8500 HP dual pinion drive system. The plant was designed to process 1585 mtph of SAG feed. From startup, the mill struggled to meet the required production rates. Over time, a major initiative that involved blasting and fragmentation, optimization of the SAG mill in terms of discharge grates, ball size and slurry density, and operation of up to three mobile pre-crushing plants resulted in significant increases in throughput. In parallel, a number of modeling tools, including JK SimMet, were run based on plant benchmarking exercises. Samples collected at the mine site during ramp up confirmed the very competent nature of the ore with drop weight - A*b values of less than 24 being recorded on a variety of plant feeds and lithologies. After due consideration including demonstration of proof of concept, a new pre-crushing circuit incorporating an XL2000 cone crusher and associated screening equipment was designed, constructed and commissioned at the site in August 2014. This paper reviews the history of the original circuit design, the various optimization steps taken and impacts, together with the final pre-crushing circuit and net results.IntroductionThe Copper Mountain Mine is located approximately 20 km south of Princeton, British Columbia, Canada (refer to Figure 1). The region has a long history of copper mining dating back to 1923. The Copper Mountain camp occurs in the 'eastern volcanic belt' of the Nicola Group (Monger, 1989). It is an alkali copper-gold deposit in which the volcanic strata are intruded by early Jurassic dykes, sills, irregular plugs and zoned plutons (Woodsworth et al., 1992). The stratified rocks are relatively fresh with slight metamorphism in the local contact regions."

Jan 1, 2016

By B. A. Sparkes, J. H. Reeves

"The St. Lawrence Granite hosts vein-type fluorite mineralization that was mined until 1977. Recent drilling identified a significant fluorite-bearing structure hosted in adjacent meta-sedimentary country rocks. Several phases of vein fill and brecciation indicate there are three phases of fluorite mineralization, of which the later two phases are volumetrically significant. The earliest fluorite is purple and occurs along joint and fracture surfaces, in fault-breccia matrices, and as stockwork veins. The second phase comprises primarily red, yellow, blue-green, and white colours of fluorite. The latest phase is green with lesser clear fluorite. Identification of fluorite veins in the meta-sedimentary rocks opens up new areas for exploration.RÉSUMÉ Le granite St. Lawrence contient une minéralisation filonienne de fluorite, laquelle a été exploitée jusqu’en 1977. De récents forages ont permis d’identifier une structure importante contenant de la fluorite encaissée dans des roches métasédimentaires adjacentes. Les nombreuses phases de remplissage de filons et de formation de brèches indiquent qu’il y a eu trois phases de minéralisation de fluorite et les deux dernières sont importantes d’un point de vue volumétrique. La plus ancienne fluorite est mauve et se trouve le long de surfaces de joints et de fractures, dans les matrices de brèches de failles et en tant que stockwerks filoniens. La deuxième phase comprend surtout des fluorites de couleurs rouge, jaune, bleu-vert et blanc. La fluorite de la plus récente phase est verte avec des quantités moindres de fluorite claire. L’identification des filons de fluorite dans les roches métasédimentaires ouvre de nouveaux secteurs pour l’exploration."

Jan 1, 2016

By Koji Nakanishi, Masayoshi Karasawa, Yasuhiro Morimoto

"Shin-Yokohama station (tentative name), one of the station of the Sotetsu - Tokyu through line (ST line), is under construction by the OPEN – CUT method. The Underground Soil–Cement Steel Diaphragm Wall is implemented as an earth retaining wall. This earth retaining wall is utilized as a main body of a subway station. It is the first time to utilize this earth retaining wall as the main body. There are two difficult issues for this project. One is that this station is planned under busy major road and there are many underground utilities, for example, an electrical transmission line. Because of that, construction area is limited. The other is that this station is located in a thick soft clay layer. This layer has a high risk of consolidation settlement because of draining during main excavation. Thus, high water tightness is required for this earth retaining wall. This paper reports design and construction methods for the Underground Soil–Cement Steel Diaphragm wall introduced as a part of the body of the subway station.1. OUTLINE OF SHIN-YOKOHAMA STATION 1-1. Location and structure of Shin-Yokohama Station Shin-Yokohama station is an intermediate station on the ST line connected to the Tokaido-Shinkansen bullet train, the JR-Yokohama line and the Yokohama Municipal Subway. Access to Tokyo and the Tokaido- Shinkansen from the eastern part of Yokohama city will be improved by this project. In addition, the number of estimated passengers of this station is one hundred thousand people/day because a soccer stadium (Nissan Stadium: 72,000 people), a huge indoor arena and a hotel are located in this area. This station consists of 4 stories and 3 spans (Max width; 29m, Depth; 33m, Length; 325.5m). Completion image is shown in Figure 2. Generally, stations have 1 platform and 2 trucks. But this station has 2 platforms and 3 tracks because some of ST line trains return at this station and a train deadheads from Hazawa station to this station in an emergency. This station is planned as 4 stories underground station, and the platform is on the lowest story. The reason why this station is in such a deeper position is to prevent the alignment from interfering with the Yokohama Municipal Subway station and foundation piles for bridge piers existing along the alignment. Even under the constraint conditions, earth covering should be shallow as much as possible. As a result, the tunnel edge is very close to the foundation pile, and the gap is only about 2m (Figure 3). In addition, passengers will be able to change trains easily from the ST line to the Yokohama Municipal Subway or vice versa at this station."

Jan 1, 2016

By Nirmal Weerasekara, Lian X. Liu, The University of Queensland, Weiguo Xie, Benjamin Bonfils, Ping Yu

A mill model structure based on the population mass balance framework incorporating breakage characteristics, slurry and solids transport, product classification and discharge and energy consumption was reported in XXVII IMPC and named the Generic Tumbling Mill Model Structure Version I (GTMMS I). In this work, a new 4D (four dimensional) appearance function sub-model based on the experimental results of the JK Rotary Breakage Tester (JK RBT) was developed to describe the breakage characteristics and was applied to this new model structure. The newly developed 4D appearance function model has fewer fitting parameters and is more generic in nature. Most importantly, it is applicable to both high and low energy impact breakage. It is therefore much more versatile in comparison to the existing JKMRC t10- tn appearance function and the size-dependent JK M-p-q t10-tn appearance function. In addition, the Discrete Element Method (DEM) energy distribution model was integrated into the new model structure. With DEM results providing energy distribution information inside the mill directly, the selection function and the back-calculation method used in the existing JKSimMet modelling method are not needed in this model structure. With the above two revolutionary innovations, the previous model structure was upgraded to the Generic Tumbling Mill Model Structure Version II (GTMMS II). Furthermore, the new model structure is dynamic in nature with time-stepping technique for non-steady-state simulation. A case of the dynamic grinding of a SAG mill was studied to validate the GTMMS II. The model simulation results agreed well with the plant data. With the newly developed 4D appearance function model, the incorporation of DEM energy distribution and transport function, the GTMMS II is an important step forward towards mechanistic modelling of tumbling mills.

Jan 1, 2016

By Ewan Selers, Gary Cavanough

Drilling automation technology is well advanced and automated drill rigs are in use at a number of operating mines. This is not the case for the other drill and blast processes due to significant technical challenges to overcome. These challenges, with regard to the current “on bench” practices, include placing the initiators, loading the explosive and connecting up the initiation system. Although difficult, these challenges will be solved with engineering advances.

Jan 1, 2016

By V. G. Papangelakis, G. A. Moldoveanu

"One of the major commercially viable secondary sources of rare earths elements (REE) are the ion-adsorption ores, containing 0.05-0.3 wt% rare earth oxides physically adsorbed on the surface of clay minerals formed during weathering of lanthanide-rich rocks. Although ion-adsorption deposits are substantially lower grade than other types of rare earth sources, this is offset by the easier mining and processing costs and the low content of radioactive elements. The conventional extraction route involves ion exchange leaching with monovalent cation solutions (usually ammonium sulphate) under ambient conditions; during the process, the lanthanides are desorbed and transferred into solution, being replaced by the exchange cation. While ammonium ions are known to perform best, there is increased environmental motivation to investigate alternative lixiviants in order to minimize ammonium sulphate impact via reducing its use without considerable loss in rare earth recovery.The objective of the present research was to screen various cations salts (alkaline and alkalineearth metals present as sulphates, chlorides and acetates, respectively) in order to comparatively evaluate lanthanide desorption levels and provide a theoretical base of the observed behaviour. The overall aim is to gain a better understanding of how both cation and anion may affect the overall REE recovery from ores in order to provide alternative processing routes. The distinct exchange capabilities of cations were explained in terms of differences in cation hydration enthalpy within the same group, i.e. Cs+ > NH4 + > K+ > Na+ > Li+ and Ba2+ > Ca2+ > Mg2+. For the same cation, it was determined that REE extraction efficiency follows the order sulphate > acetate > chloride, based on dissimilarities in constants of formation values. Various process implications scenarios will be described based on using mixed cations and anion matrices."

Jan 1, 2016

By Charles A. Stone, Eric C. Wang

"Top-down wall construction was selected to excavate the tunnel portal headwall areas of the ORB East End Crossing tunnel. Benefits included an expedited construction schedule realized by staging excavation and rock support with development of temporary construction access roads. Rock mass properties, proximity to right-of-way lines, and blasting impacts were considered to design suitable lift heights, intermediate bench locations, and permanent ground support systems to provide supported permanent excavations. Carbonate rock formations contained adverse subsurface geotechnical features including solution cavities, clay seams, weathered joints, pinnacled rock, and boulders, which were addressed by flexibility in design. The resulting over-break conditions and long-term water infiltration issues required economic design solutions. This paper discusses the unique considerations required during design of top-down tunnel portal headwalls excavated in carbonate rock formations including temporary excavation and permanent ground support systems which provided flexibility for unforeseen over-break, minimized construction delays, and provided long-term stability. PROJECT BACKGROUND The East End Crossing is an approximate 8-mile highway connection of the Louisville-Southern Indiana Ohio River Bridges East End Crossing (ORBEE) project. Currently under construction, this connection will link State Road 265 in Indiana with the Gene Snyder Freeway in Kentucky to form an outer loop bypassing the Louisville-Southern Indiana metropolitan area. This highway project features a 2,510-foot long, three-span cable-stayed bridge over the Ohio River, and a 1,680-foot long tunnel. The project, being managed by the Indiana Finance Authority and Indiana Department of Transportation, is scheduled to open to traffic by the end of 2016. The new twin three-lane tunnel under the historic Drumanard Estate requires steep cut excavations for approach and tunnel portal walls on the order of 60 feet deep through overburden soil and carbonate bedrock formations. This paper focuses on the design considerations for the permanent support of the top-down wall construction of the tunnel portal headwalls and approach retaining walls."

Jan 1, 2016

By N. Hiroyoshi, R. D. Corpuz, M. Ito, Hokkaido University, C. B. Tabelin, S. Veerawattananun

"Acid mine drainage (AMD), the very acidic and heavy metal-contaminated leachate generated when pyrite-bearing rocks are exposed to surface oxidizing conditions, is a serious environmental problem encountered after the closure of mines and mineral processing operations. In this study, we investigated the effects of soluble phases and metallic oxides, which are commonly found in strongly weathered pyritic wastes, on pyrite oxidation. Strongly weathered pyrite containing melanterite (FeSO4·7H2O) as the main soluble phase was obtained from Furikusa mine, Japan. The sample was washed using two methods to vary the relative amounts of melanterite in the sample. The effect of metallic oxides on pyrite oxidation was evaluated using ultrapure hematite suspensions. Our results showed that under acidic conditions, the effect of soluble salts on the oxidation of pyrite was stronger than hematite. More thorough washing of the sample resulted in the formation of an arsenic-bearing iron-oxyhydroxysulfate coating that minimized pyrite dissolution. This oxidized layer became relatively thicker and mechanically stronger when hematite was introduced after the more thorough removal of soluble salts. Characterization of this “coating” coupled with geochemical modeling suggest that it is most probably composed of two materials: schwertmannite and scorodite. Based on these results, a new approach to suppress pyrite oxidation by directly using iron-oxyhydroxysulfate as coating material is introduced.INTRODUCTION Acid mine drainage (AMD), the very acidic and heavy metals-contaminated leachate produced in closed/abandoned mine sites (Evangelou, 1995), mineral processing and coal cleaning tailings (Evangelou, 1995), and tunnel construction waste rocks (Tabelin and Igarashi, 2009, Tabelin et al., 2012), is one of the oldest and probably the most serious environmental problem of anthropogenic origin. When released to the environment, it rapidly pollutes river, soil and groundwater systems leading to the destruction of affected ecosystems. AMD is produced when pyrite (FeS2), one of the primary gangue minerals in sulfide ores and coals, is exposed to oxidizing conditions as illustrated by the following reactions:"

Jan 1, 2016

By Peter A. Adcock, Rob Fraser

Interest in monitoring nucleation overpotential in electrometallurgical processes dates back some 40 years or more. Conversely, remarkable progress has been made in recent years on describing in detail the processes involved in the formation of thin films by electrodeposition. The newer body of work underscores a need for greater clarity in speaking about the role of nucleation and in the acquisition and interpretation of nucleation overpotential measurements – the aim of this paper. In electrometallurgy, it is generally desirable to form deposits that remain smooth, compact, and relatively fine-grained while the deposit grows to a thickness on the order of 5-10 mm, about 100 times thicker than technological thin films. Hence, we distinguish two kinds of nucleation that can result in formation of new grains:- (1) initial nucleation (onto the substrate surface) of islands that coalesce into growing deposit, and (2) ongoing nucleation of new grains on the deposit surface long after the substrate has been covered and ceases to have a direct influence. Nucleation overpotential of the first type should be measured on an electrode surface truly representative of a real industrial substrate. The second type requires judicious choice of electrode material – an “ideal foreign substrate”. In general neither the industrial substrate nor native metal to be deposited is suitable for measurement of the second type of nucleation overpotential, because of interference by other processes. For the future, clear terminology is needed to distinguish these two types of nucleation potential. The second is the one for which the type of plot dubbed by Moats and Derrick as an “Adcock plot” and by us as a “Kerby-Adcock plot” was first conceived and correlated with relatively thick zinc electrodeposits. The data of Moats and Derrick showing trends for copper electrodeposition on stainless steel and on copper electrodes are interpreted within this framework.

Jan 1, 2016