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By Duane A. Smith

They are gone now. Gone like that long ago generation that gave them birth. The Homestake Mine, nestled in the northern Black Hills, closed in 2001 after 125 years, the longest run of any major American gold mine. The Homestake Mining Co., which guided its destiny for those many years, is gone too. It merged with Barrick Gold. The Hearst family, which guided the early destiny of both, has long since gone beyond its mining heritage and into the national and even international spotlight. The mine and the company passed from the scene with as little fanfare as heralded their birth, amid the Black Hills gold rush of the 1870s. They both grew into American mining legends, as did the town they sired and nurtured, Lead. In a real sense, the mine and the company symbolized one of the last links to a vanished world and a mining era.

Jan 1, 2003

By C E. J de Ronde, J L. Mauk

Sulfide chimney samples collected during the 1998 - 1999 R/V Atlantis û DSV Alvin 3 - 30 research cruise have been examined and classified into four types, based on common characteristics. Chimney morphology is the most important characteristic and resulted in the following groups: 1. flutes, 2. cones, 3. wide-flats, and 4. beehives. Other characteristics resulted in the classification of subgroups within the flute, cone and wide-flat groups. The combination of characteristics, including; the presence of an orifice, internal chimney fabrics, wall thickness, extent of weathering, and the presence of Alvinella worm casts, enable evolutionary trends between the different chimneys types to be established. These trends indicate that with time, flutes evolve from immature zoned chimneys with a central orifice and smooth thin-walls, into cone chimneys with thick walls and massive fabrics which have their orifices infilled by massive sulfides, and a rough exterior. Repeated mineralisation within, cones may result in the formation of wide-flat chimneys. Beehive chimneys can form at any time during chimney growth.

Jan 1, 2003

By A F. Cooper

Otago Schist in the Mount Patriarch, High Burn and Cameron Creek areas of northwest Otago grades from textural grade IIA in the east to textural grade III in the west. The entire region is of the actinolite-pumpellyite metamorphic facies. Lithologies in the area are interbedded turbidite sequences comprising pelite and psammite together with pebble conglomerate, greenschist and metachert horizons. The mineral assemblage of the schist is typically quartz-albite-epidote-actinolite-pumpellyite-chlorite-stilpnomelane-calcite. A good foliation is well defined in the area and is predominantly parallel to bedding, except in hinges of mesoscopic isoclinal folds. The structure of the area appears to be defined by a large southwest plunging isoclinal fold defined by bedding with a steeply dipping axial planar foliation. Kink folding and dextral strike-slip faulting in the area postdates the ductile phase of deformation. Pods of rhodonite, rhodochrosite, spessartine garnet, coombsite, caryopilite, Mnstilpnomelane and Ni-Cu-Zn sulphides were found in concordant metachert layers in the Mount Patriarch area. Metachert was also found in float in the Cameron Creek area. Malachite occurrences relating to copper mineralisation were also noted in a green metachert horizon on the eastern flank of Mount Patriarch. The coombsite, in only the third observation worldwide, is the most Fe-rich variety reported.

Jan 1, 2003

By Rogerio C. Guimarães, Antonio E. C. Peres

The production of phosphate concentrates (phosphate rock) from slimes represents a challenge to the phosphate industry worldwide. In Brazil, this challenge is particularly relevant due to the consistently low P2O5 grades and the igneous origin. The Brazilian phosphate deposits are made up mainly of apatite from alkaline chimneys, representing 80% of the Brazilian reserves; phosphorite deposits contribute 18% and the other sources (guano, phosphorous bauxite, and apatite from veins) reach 2%. The Brazilian industry beneficiates phosphate ores that are mineralogically more complex than those treated elsewhere. The low apatite grade, inherent to the igneous Brazilian ores, added to the mineralogical complexity due to the weathering of the rocks, has represented a permanent challenge to the Brazilian process engineers. The total measured, indicated and inferred reserves reach 3.2 million tonnes of ore with average grade 11% P2O5. The development of local technology for phosphate beneficiation started in the 1960’s. The first industrial experiences of producing phosphate rock from slimes (-44µm or -325#) fraction started at Arafertil, currently Bunge Fertilizantes SA, in Araxá, in the 1980’s. This production corresponds, nowadays, to 35% of the total production of concentrates in the company (830,000t/year) in a circuit consisting of desliming in 40mm microcyclones and concentration in flotation columns, corn starch and fatty acids being utilised as reagents. The performance of slimes flotation and the process control, at Bunge´s concentrator, were improved after the introduction of column flotation technology, in the first half of the nineties. The column flotation technology for slimes recovery was expanded to other Brazilian concentrators still in the nineties: Ultrafértil (Catalão – GO), Bunge (Cajati – SP), Fosfértil (Tapira – MG) and Copebrás (Catalão – GO). At present the Brazilian production of phosphate rock is approximately 4.5Mt/year, with a strong trend for a market increase. Genuinely Brazilian technology is utilised for the processing of slimes, the concentrates representing 11 to 13% of the overall production. The production of apatite concentrates from slimes was relevant to increase phosphate recovery and reduce costs, contributing to the growth of the fertilisers industry.

Jan 1, 2003

By Alan Jorgansen, Dave Hummer, Scott Scovira

Kennecott Energy's Colowyo Coal Mine is the largest open pit coal mine in Colorado and produces 5.5 MM tons per year. Colowyo uses the terrace mining method to recover up to seven seams of rolling coal ranging in thickness from 5 to 20 feet. Draglines are used to strip overburden ranging from 60 to 120 feet thick off two coal seams. These two seams are characterized by soft and fold fractured coal and in past practice cast blasting caused excessive coal damage. As a result, to ensure minimal coal damage and high coal recoveries, the overburden was excavated in two passes. The first pass removed the upper overburden to within 10 to 20 feet of the coal seam. The second pass removed the remaining overburden above the coal. Two-pass mining was effective in controlling coal damage, but also carried significant additional costs.

Jan 1, 2003

By J. Cygankiewicz

Efficient prevention of mine fires is impossible without predicting the self heating processes in the given geological and mining conditions. The respective forecasting method is presented in this paper based on the following assumptions: - factor deciding on fire hazard in the underground workings is the process of heating of coal from the primary rock temperature to the critical temperature when the heating rate growth rapidly - another important factor is the fire incubation time defined as time needed to achieve the critical temperature. This time is determined by balance of heat and mass in the heated coal - contact of crushed coal with oxygen in air cause some exothermic processes as : physical and chemical sorption of oxygen , oxidation reaction and evaporation of humidity Heated coal transfers its thermal energy to the environment by conductivity to the rocks and by convection to the flowing gases. The heating is possible if thermal energy generated from coal is greater then the share transferred to the environment. The paper presents the laboratory method of measurement of heat generation in adiabatic conditions. Also the mathematical model with examples of computation enabling to forecast the self heating process of crushed coal is presented.

Jan 1, 2003

Editor’s note: As usual, the June issue features an industrial minerals review. And some thanks are in order. Thank you to the industrial minerals annual-review editor, to the technical committees chair and vice chairs and to the authors of the individual commodity profiles. Jim Norman of GeoTrans Inc. is the industrial minerals annual-review editor. Gary Tomaino, Specialty Minerals Inc., is the chair of the SME industrial minerals technical committees. Technical committee vice chairs include: •Lucy McCartan, U.S. Geological Survey, agricultural minerals as well as sorbents, filter and process aids. •Steve Herron, Oglebay Norton Performance Minerals, ceramics and refractory materials. •Srinivas Veeramasuneni, U.S. Gypsum, chemical raw materials. •William Langer, U.S. Geological Survey, construction materials. •Vanessa Santos, Independent, fillers and pigments. •Richard Berg, Montana College of Mineral Science and Technology, specialty minerals. Their help makes possible this June industrial minerals issue. On behalf of the readers, the editors thank them.

Jan 1, 2003

By Thiemo Hagedorn, Gerhard Weissbach, Ralph Bergmann, Wilhelm J. Kogelmann

The objective of this unique method is to multiply the advance rate of conventional tunneling while improving both ground control and the safety of the crew. The high advance rate is achieved by concurrent rock excavation and installation of concrete lining at fully synchronized work phases. The novel TACHUSMATIC system consists of a high-production, robotic cutter boom, an automated slip form and continuous mucking and conveying. This novel system utilizes the inherent bearing capacity of the rock that is activated by a small, initial deformation. The supporting resistance is then provided both by the rock mass itself and the pumped in concrete lining. During the hardening of the concrete, the hydraulic cylinders of the TACHUSMATIC automatically apply the appropriate support resistance, thus providing safe ground control. This novel tunneling system is practically a fully automated, fail-safe NATM that does not require highly skilled engineers and crew. The TACHUSMATIC can be used for construction of circular, rectangular and horseshoe-shaped tunnels. When equipped with the Alpine Multi-Tool Miner (MTM) systems, the machine can work in a wide range of ground and rock conditions. The use of novel, diamond-tipped cutter bits (picks) will increase hard rock cutting capabilities and will significantly reduce pick consumption. Because of its moderate cost, the novel system is an economic alternative to conventional tunneling even at short drivages. A new installation is cost-effective for tunnels longer than 750 meters (2,500 ft.) At a typical tunneling project, the cost permeter is about 25% lower than with conventional methods.

Jan 1, 2003

By Sun Chuanyao, Jia Muxin

Generally, if the bond valence (BV) between metal ion and oxygen of the mineral is greater than 0.8, only surface species –Me-O-H or –Me-O exposures on the mineral interface, if the BV is between 0.2-0.8, the metal ion exposures on the interface, and if the BV is less than 0.2 the metal ion dissolves into water. The PZCs of oxide minerals and island silicate minerals are determined by the bond valence of the bond in the mineral crystals, the higher the bond valence the lower the PZC of the mineral. So the PZC sequence of Al2SiO5 minerals is kyanite> andalusite> sillimanite. The general rule for framework silicate minerals is as: The higher the Al content, the lower the PZC of the mineral, when the ratio of Al to Si in the tetrahedron skeleton is below 1:3. The higher the Al content, the higher the PZC of the mineral, when the ratio of Al to Si in the skeleton is between 1:3 and 1:1. The general rule for layer silicate minerals is summarized as: the three-layer silicate minerals have much lower PZCs than that of the two-layer silicate minerals. The threelayer silicate mineral with the octahedron layer occupied by lower charged cations has lower PZC than that of the three-layer silicate mineral with the octahedron layer occupied by higher charged cations. The twolayer silicate mineral with the octahedron layer occupied by lower charged cations has higher PZC than that of the two-layer silicate mineral with the octahedron layer occupied by higher charged cations. The layer silicate mineral with Al substitution in the tetrahedron layer has lower PZC than that of the layer silicate mineral without Al substitution in the tetrahedron layer. Such pyroxene minerals whose M1 is occupied by a trivalence cation and the M2 is occupied by a monovalence cation has lower PZCs than those both M1 and M2 are all occupied by bivalence cations. Such hornblende minerals whose M2 is occupied by a trivalence cation and the M4 is occupied by a monovalence cation has lower PZCs than those both M2 and M4 are all occupied by bivalence cations. There is no Si4+ or 4 coordinated Al3+ exposures on the surface of framework silicate minerals, the metal ions of three layer or chain silicate minerals are compact between tetrahedron layersor chains, they hinder the metal ions to interact with oleate acid radical, the metal ion octahedron layer exposures on the surface of a two layer silicate mineral, but the the oleate acid radical can not attach to a metal ion by replacing a –OH- that connects three metal cations in the same time, So the floatability of such silicate mineral is bad. The metal octahedron chain style of an island silicate mineral affects it floatability, the mineral exposures octahedron chain metals with two dangling bonds in two directions floats better than the mineral exposures octahedron chain metals with two dangling bonds in one direction.

Jan 1, 2003

By Jack Elorenta

We often hear that, "Blasting was an art, but now blasting is now a science". 'Scientific' blasting implies that we have quantified and reproducible measurements of the feedstock and product of the blasting process. However, the industry's reluctance to adopt two key technologies, drill monitoring and optical size analyzers, sheds doubt on the claims of scientific blasting.

Jan 1, 2003

By Flavio Rojos-Tapia, Samuel Sánchez-Pino, Marcelo Fernández-García, Samuel Sánchez-Baquedano, Rainer M. Imhof

"Pneumatic flotation was introduced to the Chilean copper mining industry in 1993 by Ingeniería de Minerales S.A., being implementation in 1994/95. The technology is based on the designs and development of Dr. Rainer Imhof from Germany and from Chilean copper processing experience.Pneumatic flotation has been successfully used for sulphide and oxide copper minerals and copper slag, iron ores (reverse flotation), gold and promising results with molybdenum as product. Extremely hard conditions were applied in flotation process such as roughing, cleaning, scavenging. Pneumatic flotation can be applied for any type of mineral which has to be separated by flotation. Even very dense and heavy slurries can be processed, the range of the particle sizes to be collected is very wide, and the number of cleaning stages needed normally is one in our experience until now.The good performance of the technique can be explained by the high gas hold-up and the very effective micro-turbulences which boosts the attachment to the bubbles changing dramatically the flotation time concept. Some economic high lights are: less energy consumption, less maintenance costs, simple and reliable to operate and it is required a small area to install the circuits.As a result of the Chilean mining industry experience, it can be concluded that the pneumatic flotation can be regarded as an excellent alternative to the conventional way of Mineral Processing.INTRODUCTIONDerived from seventies, works in Germany about pneumatic flotation with Prof. Simonis (Technical University of Berlin) and Prof. Bahr (Technical University of Clausthal), it has been developed an interesting flotation technology in Mineral Processing, with the designs developed by Dr. Rainer Imhof, who has been known for more than ten years (Imhof, 1998) by his contribution at Ekof, KHD, Allmineral and the actual company Maelgwyn Mineral Services where he is a Technical Director. Ingeniería de Minerales S.A. has been working ten years deeply involved with the technology developed by Dr. Imhof and is more than ten years experienced with pneumatic flotation, from Wits University and Mintek in South Africa (Sánchez, 1990), (Sánchez, 1990)."

Jan 1, 2003

By Sami Hindstrom, Travis Orser, John Starkey

"A great deal of effort has been expended in the last 11 years by the authors and others to identify the correct power required to grind ore in a SAG mill, by developing ore hardness variability functions for the ore body to be mined. This paper describes the next step in the SAG design process, which is choosing a SAG mill to accomplish the required specified design performance.At the test work stage, each ore hardness data point is a unique and discreet bit of information that represents the energy required to grind the ore represented by that sample at optimum SAG conditions. When the design criteria are set, it is now considered necessary that the required power draw in the mill chosen be provided at optimum conditions as well.Based on actual 3-ft diameter pilot plant results, we can now show that the grinding efficiency and throughput drop when the optimum load limit is exceeded. Future work is expected to show a similar reduction in efficiency when exceeding optimum speed. Providing specified power by exceeding these optimum conditions is not adequate and leads to a lower cost but underperforming SAG mill.It is possible in some cases to modify a SAG circuit to force it to perform better, but this often takes time, much effort and costly modifications. In most cases the capital spent on a properly sized SAG mill may prevent production losses that would be many times greater over the extended start up period. This is the direct result of choosing the proper SAG mill at the start.INTRODUCTIONThe sequential steps required for the design of any grinding circuit, have changed dramatically in the last seven years. Previously, it was considered necessary to do six foot diameter SAG mill pilot plant tests on representative samples of minus six inch ore (F80), in order to understand design requirements. It can now be shown that this method is costly and not likely to produce the desired result because it is difficult to recover six-inch material from deep within a new mine. The representative nature of the sample is often compromised when the sample is selected."

Jan 1, 2003

By Lloyd A. Morley

This Bureau of Mines publication presents a comprehensive review of mine electrical power-system theory and practice. It discusses fundamental theory and the vital aspects to be considered in planning and designing mine electrical power systems. The report is divided into three major sections. The first presents the history of electricity in mining and the fundamentals of electrical phenomena and components. The second focuses on power-system components: motors, grounding systems, cables, and protective equipment and devices. The final section includes mine power-center equipment, switchhouses and substations, batteries, and mine maintenance.

Jan 1, 2003

By D T. Feinstein, M B. Gotkowitz

In Wisconsin, state laws and regulations governing metallic mine permitting stipulate that protection of groundwater quality be assured indefinitely through all phases of the mining project, including development, active mining, reclamation, and long-term closure. By rule, the Wisconsin Department of Natural Resources (WDNR) requires that permit applicants use a numerical model to assist in the assessment of compliance with this requirement for all proposed mine-waste facilities. As a part of the compliance assessment, model calculations are used to predict groundwater solute concentrations through time at designated boundaries for comparison to current groundwater quality standards. In practice, this modelling requirement has involved the application of numerical solute-transport models. Our review of a solute-transport model submitted by the developers of a proposed mine near Crandon, Wisconsin, provides us with an opportunity to assess the usefulness of transport modelling as a permitting requirement. Recent evaluations of solute-transport models by other workers suggest limitations in predictive accuracy. Our review of the model submitted for this project also identified important limitations due primarily to uncertainty in calibration of model parameters at the undeveloped site. The utility of any model to predict project compliance or non-compliance with numerical standards is limited by the range of uncertainty of key model parameters, such as dispersivity and porosity. Uncertainty in the future behaviour of the solute source(s) also reduces the predictive power. Moreover, the site characterisation provided by the model may have limited power to describe the site condition post-development. Although these inherent shortcomings accompany the use of solute transport models at undeveloped sites, the requirement for model development and the ensuing technical review has substantially assisted in our evaluation of site conditions and project design. Through this process we have identified elements of the waste facility design that are crucial to the environmental viability of the project, resulting in modifications to original project proposals. While results from this model review will be used to evaluate compliance, additional benefits come from the identification of critical design features that enhance groundwater protection.

Jan 1, 2003

By Chris Larsen, Ian Orford, Marilene Renaud, Mike Cooper, Lud Strah

"An AG/SAG mill was commissioned at the Brunswick Mine concentrator in October 1998. This paper discusses the original liner design for the bi-directional AG/SAG mill, observed liner wear, subsequent liner design modifications, and benefits. The mill liners consist of steel top hat shell liners, steel end liners, rubber grates and rubber lined pulp lifters.Lifter profile and plate thickness measurements were made on monthly shop days. Trends of wear rates were used to project when liners required replacement. Wear profile information was also used to determine where liner re-design would improve wear life or minimize scrap loss. Charge motion simulation modeling was used as a tool to assist liner design modifications.INTRODUCTIONThe Noranda Inc. Brunswick Mine, located near Bathurst, New Brunswick, is a large underground lead/zinc mine with a nominal production rate of 10,000 tonnes per day. The Brunswick concentrator commenced operation in 1964 with conventional surface crushing followed by rod and ball milling to reduce run of mine ore to the required size to feed two parallel flotation circuits. In 1998 the AG (autogenous grinding) mill was commissioned for a nominal production rate of 9,000 tonnes per day replacing two surface crushing plants, three rod mills and three primary ball mills. In May of 1999 the mining rate was increased and the service of the AG mill was changed to a SAG (semi-autogenous grinding) mill with the addition of 4 inch steel balls (4% volume). The mill operates in closed circuit with 0.66 meter horizontal cyclones to produce a ground product of 90 micron nominal size (K80).The AG/SAG mill liners are steel (Norsteel, chrome-moly steel) with rubber grates and rubber lined pulp lifters.The original liner design was based on studying other AG/SAG mills and recommendations by the liner supplier, Norcast. Design factors taken into account were total cost of lining (including material and labour), protection of mill shell and impact on operating performance."

Jan 1, 2003

By John C. Gathje, Rick Moritz, Wilhelm de Beer, Gary L. Simmons

"Froth flotation has a long history of success for the recovery and concentration of a wide variety of minerals of commercial interest. Both the art and science of flotation have progressed greatly, and as our knowledge has increased so has our ability to improve mineral separations and recoveries.One area of interest in recent years has been the flotation of refractory gold ores to recover the goldbearing sulfides. In many instances, the use of conventional air flotation to concentrate these values has achieved only limited success. However, as a result of intensive research, Newmont Mining has expanded the boundaries of flotation, and it can now be used to successfully treat many gold-bearing sulfide ores as well as platinum and palladium ores. This has been achieved through the use of the patented N2TEC technology, which utilizes nitrogen as an inert gas in the flotation process."

Jan 1, 2003

By Matti Kongas, Kari Saloheimo, Antti Remes

"The paper studies the control performance of the flotation process as a function of the measurement accuracy and sampling frequency of an on-stream XRF analyzer, using a simple dynamic model. An additional aim is to assess how the economical result of a mineral flotation process depends on the quality of process control based on the on-line elemental assays.An on-stream XRF analyzer measures the concentrations of slurry lines in a continuous cycle from several process points. The control performance depends on the analytical accuracy and sampling frequency of the concentration measurement. With a long cycle time, the state of the process changes before a new measurement becomes available. With short measurement times the statistical variance of the counted Xray pulses increases, increasing the random error in the analysis. In addition, the measurement accuracy depends on the concentration of the component to be measured from the slurry.To quantify the effect of analysis error and frequency to process control, a simple dynamic process model is created in the Matlab environment. Data from a copper flotation circuit is used as a test case. The process model comprises a first order reaction equation and the grade-recovery -relationship estimated from process data. The control was modeled using the control strategies implemented into a rule based advanced control system. The economical performance of the control was studied by calculating the overall net smelter return at various analyzer parameter combinations."

Jan 1, 2003

By Hamid-Reza Manouchehri

"The triboelectric charge attributes of some silicate minerals (i.e., feldspar, quartz and wollastonite) after contacting different triboecharging medium made of different materials were studied. The charge acquisitions by different size fractions of minerals were monitored and accordingly the energetic work function values, i.e., the main parameter determining the entity of triboelectric charges acquired by mineral grains, of the examined minerals were estimated. Moreover the separation behavior of different size fractions of these minerals through the electric field of a laboratory free-falling separator when the mineral grains are charged by different tribochargers were observed and considered as the electrical separation potential of the examined minerals.Furthermore, the role of adsorption of different chemical species on triboelectric charge characteristics and charge acquisition of mineral samples were described from theoretical point of view and the effects of some chemical reagents on triboelectric charge acquisition of the examined minerals were studied. In addition the separation behavior of chemically conditioned quartz, feldspar and wollastonite minerals, using different anionic and cationic reagents, through the electric field of a free-fall electrostatic separator before and after chemical conditioning were monitored.Finally an attempt was made to translate the findings from single mineral systems to a complex silicate ore, containing mainly of feldspars, quartz, and wollastonite. Different separation tests under various conditions were conducted to this complex silicate ore. Before passing through the separation device, the ore sample was conditioned by different cationic and anionic reagents and then was triboelectricaly charged by different tribocharging medium in order to find the effective reagent and tribocharging medium for separating silicates. Besides the role of temperature and humidity of the surrounding ambient in separation behavior were considered."

Jan 1, 2003

By Roberto C. G. Oliveira, Scott C. Brown, Brij M. Moudgil

"The wettability or surface energy of particle surfaces dictates a number of multiphase ensemble interactions that have a significant impact in mineral processing. Dispersion, bulk powder handling and flotation are just a few of the processes that are largely influenced by the degree of hydrophillicity or hydrophobicity on particulate surfaces. Because of the importance of surface wettability, a number of simple, precise and accurate techniques for accessing surface wettability or contact angle on macroscopic flat surfaces have been developed. However, these techniques cannot be directly applied to the particulate surfaces that are often in query. Though a number of techniques are available for accessing the wettability of particulate surfaces, these methods are either relative, application specific or prohibitively tedious. In the present study, key features of existing techniques are combined to formulate an improved method to delineate particle wettability that is simple, versatile and capable of providing reproducible measurements in an industrial environment.Through the use of an inert adhesive and an inert macroscopic surface as a support, it is illustrated that precise measurements of particle wettability are obtainable under suboptimal or ‘shop floor’ conditions. The measurement of the maximum external meniscus height formed between a test liquid and a particlecoated rod is employed to estimate phenomenological contact angles on particles ranging form a few nanometers to several hundred microns in size."

Jan 1, 2003

By P. N. Mohan Das, K. Harikrishna Bhat

"The major ilmenite reserves are located in India at Chavara (CH), Manavalakurichi ( MK) and Chatrapur, Orissa (OR). India stands first in terms of ilmenite reserves, which are estimated to be 278 million tonnes out of which, 142 million tonnes are processable. Mineralo-chemical analysis showed that Chavara ilmenite is the most weathered one with about 60% TiO2 while Chatrapur is the least weathered with about 50% TiO2. XRD and SEM studies of different magnetic fractions of these three mineral deposits established the co-existence of ilmenite with pseudorutile, rutile and haematite phases in substantially varying amounts. It is observed that the tropical weathering rather than the source rock difference has apparently played an important role in imparting major compositional and structural dissimilarities among the ilmenites in different places. Further, the chemical analysis, XRD and SEM characterisation of differently weathered samples of MK ilmenite separated by the magnetic fractionation showed that the degree of alteration was invariably associated with the decrease in magnetism, increase in the rutile phase and the change in Fe2+/Fe3+ ratio of ilmenite grains. Magnetically separated fractions when subjected to metallisation with carbonaceous reductant such as coke showed that the degree of reduction increases with the degree of alteration and with the decrease in the Fe2+/Fe3+ ratio.In the processing of ilmenite through the Becher process, aeration rusting of pre - reduced ilmenite is found to be the rate-limiting step thus, affecting the productivity and economy of the process. Investigations have proved that the addition of some organic compounds such as glyoxal, sucrose etc., to the system accelerates the reaction to such an extent that the rusting time has been reduced to less than half. The formation of acids by the these organic compounds during the rusting reaction was proved responsible for maintaining the pH of the solution in the range 3-4 at which iron hydroxide do not precipitate and block the pores in the reacting surface of the grain."

Jan 1, 2003