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By David Schroeder, John Chipman

Jan 1, 1964

By Clarence E. Sims

An effort has been made to give both a comprehensive and simplified picture of the origin, modes of formation, and characteristics of nonmetallic inclusions in steel. Exogenous inclusions, those formed by mechanical entrainment or heterogeneous reaction, have their principal source in ladle refractories. Mechanical emulsion is not considered a likely mechanism. Endogenous inclusions, resulting from homogeneous reactions, are formed mainly during cooling and freezing. They are principally oxides and sulfides but include some nitrides and carbides. Deoxidation affects both the quantity and character of such oxide inclusions and significantly affects the size and shape of sulfides. The importance of inclusions is largely in their effect on mechanical properties. It is fitting and proper that we should honor the memory of those technical giants who have left such a rich heritage to our profession. Today, according to annual custom, we pay tribute to such a man. To have been chosen to play a part in this observance prompts in me an inordinate pride while I am humble before the responsibilities of my task. The ranks are growing thin of those who had the good fortune to come under the personal influence of Professor Howe, but the number who continue to benefit from his legacy of technical wisdom con-stantly increases. I am among the latter. One has only to read his works to appreciate his unusual ability to take data and observations from many sources and give them a clear and comprehensive

Jan 1, 1960

By Maxwell Gensamer

Jan 1, 1960

By E. T. Turkdogan, P. Grieveson

It is shown experimentally that, by making use of the coupled S-O reaction in ionic melts, it is possible to transfer slclJur or oxygen from a lozv to a high chemical potential through an ionic nzenzbrane. This uphill transfer of sulfur is accompanied by a counter downhill transfer of oxygen and vice versa. The Materials balance shows that the amoulits of sul -fur and oxygen lost or gained by one system are the same as those gained or lost by the other systenz — the two systejns being separated by an iofzic membmne. The systems used in these experi?nents were solid Mn-MnS-Mno and liquid Fe-S-0. Sufficient results were obtained Lo study the kinetics of the transfer and the indications are that the counter diffusion of sulfide and oxide iojzs in the membrane is the rate controlling process. WHEN an ionic oxide-melt reacts with an atmosphere containing sulfur and oxygen-bear ing gases the following reaction occurs: 1/2 S2 (gas) +O2- (melt) = S2- (melt) + 1/2 0, (gas) [1] Under the restrictions that i) electric conductance in the melt is purely ionic and ii) each constituent element in the melt does not change valence, the solution of an atom of sulfur in the melt will result in the evolution of an atom of oxygen, so that the electric neutrality is maintained. For a given temperature and melt composition, the equilibrium concentration of sulfur in the melt is determined by the ratio, po2 /ps2 , in the gas phase and not by the individual partial pressures of oxygen and sulfur. This has been demonstrated by a number of investigators, for example by Richardson and withers', Fincham and Richardson,la by St Pierre and Chipman,' and by Turkdogan and Darken.3 In his Howe Memorial Lecture for 1961, Darken discussed the possibility of uphill pumping of sulfur through an ionic membrane at the expense of oxygen. TO test the validity of this concept associated with coupled reactions, experiments were carried out in the following manner. A presintered mixture of Mn-MnS-MnO and prefused mixture of Fe-S-0, contained in platinum and iridium crucibles, respectively, and separated by a thin layer of soda-glass (to act as an ionic membrane), were placed side by side in an evacuated silica capsule and sealed. This was then kept at 1400°K for a required time to allow Reaction [11 to occur via the ionic membrane. When partial equilibrium is reached, the ratios Po2 /pS2, for systems on either side of the membrane, are equal and the flux of sulfur and oxygen through the membrane becomes zero, although the individual partial pressures po2 andp,, in these two systems may differ considerably.

Jan 1, 1962

By J. P. Sancho, L. F. Verdeja, J. I. Verdeja

"This paper analyzes the present state of the different processes competing to keep their market shares within the future iron and steel business sector.The continuous transformations in the steel making process are also studied here. These transformations have happened especially during the two last decades obviously favouring steel price, properties, quality and environmental compatibility in the new millennium. IntroductionIn the early 1980s, world steel production reached a historic figure; specifically in 1982, the amount was 645 Mt (Verdeja et al., 1993). This might have been one of the reasons why the United States, Japan and the European Community drew up a declaration of principles after which the leading industries and sectors in the following century’s development would be: advanced materials, also known by the very diffuse term of new materials; information technologies; and biotechnology (Eager, 1998).On the threshold of the 21st century, it can be inferred that information technologies (computers and telecommunications) have progressed spectacularly. Nevertheless, there have been downsides too; technology develops so quickly that after a few months the products are obsolete. Environmental problems may also appear in a few years due to storing so many useless devices. At the same time, the achievements of biotechnology did not meet the optimistic forecasts made in the early 1980s.On the other hand, it is also curious that some solutions for the environmental problems generated by star technologies of the new millennium, such as computers and biotechnology, are closely linked to the iron and steel industry. For example, blast furnaces in Germany and Japan are prepared for burning residua by introducing polymer materials from computers and other electronic prepared devices through their tuyeres, while cement tube furnaces can destroy any organic residua from different origins."

Jan 1, 2002

By Clyde E. Williams, JAMES L. GREGG

THIS review of the past year's progress in iron and steel metallurgy presents examples of only a few of the interesting or important accomplishments made in the United States. In the field of iron ore concentration increased attention was given to the study of the more difficultly separated wash ores and some progress was made in tabling. One difficulty with the table, in concentrating iron ore where the percentage of concentrate in the feed is large, has been the removal of fine silica from the thick layer .of concentrates in the cleaning zone. One company has -Made an important contribution toward the solution of this problem by an extension of the well-known plateau principle. By a special riffling of the plateau section of the table, the concentrates are crowded together. This action forces the fine silica to the top of the bed in the cleaning zone, whence the cross-flowing currents of water -can wash it into the middling product. Some work has been done on the application of froth flotation to the concentration of iron ores. Laboratory experiments were made at the Colorado School of Mines in which hematite was, successfully floated. Using oleic acid as a frothing and collecting agent and sodium carbonate as the conditioning agent, a high recovery of rich ,concentrate was obtained. A laboratory flotation unit is in use at Taconite, on the Mesabi range, and a commer-

Jan 1, 1932

By Horst Konig

This paper illustrates that, with the application of new processes, smaller steel plants using local raw materials can be economical and advisable. It also introduces the problems connected with the direct reduction processes, which use non-coking coal or gas as reducing agents, and which are employed in connection with conventional reduction to produce excellent results. Electric smelting is also discussed, and some practical examples of operating plants are given.

Jan 1, 1970

By C. D. King

A QUARTER century ago this country was producing an extraordinary quantity of iron and steel, with a decisive influence on the outcome of the first World War. Today this country is again demonstrating its industrial capacity with telling results. If this lapse of time has confirmed the opinion that man learns little from experience with respect to human relationships, at least we can derive some consolation from the knowledge that in the same period we have made huge strides industrially, and particularly in the steel industry. The differences represented by 25 years are striking, and have resulted from a multitude of changes that have contributed to the present-day high state of our pig iron and steel manufacture.

Jan 1, 1944

By L. Su, S. Liu, K. Jiang, K. Xie

The reduction of iron dissolution and acid consumption is fairly important in the extraction of Ni and Co from laterite ores from both economic and efficiency perspectives. BGRIMM conducted detailed research to investigate the behavior of iron in a nickel laterite leaching process. The mineralogy of Ni and Co was studied. In limonite ore about 76% of nickel is present in goethite while in saprolite ore 79% of nickel is associated with magnesium and silicon minerals. Test work revealed that limonite can be decomposed completely with enough acid concentration during atmospheric leaching. More than 98% of Ni and Co were leached into solution while 85% of the iron was also dissolved with 130-140 g/L iron in solution. Iron precipitates as hematite in the temperature range 250-270?C without neutralization reagents. That’s why limonite is treated by high pressure acid leaching (HPAL) technology to achieve nickel extraction and iron precipitation in the same autoclave. BGRIMM’s test results indicated that the remaining acid in atmospheric leaching solution and acid released by iron precipitation at a lower temperature was enough to leach saprolite efficiently. The so-called inverse leaching technology leaches limonite at atmospheric condition and the leaching slurry combined with saprolite is pumped into an autoclave to leach saprolite at 150-170?C. In the autoclave iron precipitates as hematite without acid consumption. Total nickel and cobalt extractions in the test program were more than 90% with iron content in solution below 8 g/L. In this inverse process iron dissolves in the atmospheric leaching stage and precipitates as hematite in the low temperature leaching stage. Compared with HPAL the leaching temperature is reduced to 150-170 ºC from 250-270 ºC. Compared to atmospheric tank leaching acid consumption is reduced from 850-950 kg/t ore (atmospheric) to 550-650 kg/t ore (inverse).

Jan 1, 2016

By G. W. Josephson

WHILE methods of utilizing blast-furnace slag have been developing, a great deal of literature on the subject has accumulated, but no comprehensive summary of information that would be helpful to engineers, contractors, architects, chemists, and others in under-standing and more successfully using this byproduct of the iron and steel industry has been published in the English language. The National Slag Association recognized the need for such a publication, and the Problems Committee of the Association under-took in 1943 to accumulate the necessary material. Over a period of several years this committee compiled pertinent information in manuscript form, and in 1948 the Bureau of Mines and the National Slag Association made an agreement whereby the Bureau was to prepare the data for publication as a cooperative bulletin of the Bureau of Mines and the National Slag Association.

Jan 1, 1949

By Boyd Davis, Vladimiros Papangelakis, Douglass Duffy, Michael Carlos

"The processing of lateritic saprolite in hyper-concentrated magnesium chloride brines offers several potential advantages for the hydrometallurgical production of nickel. An aggressive HCl-MgCl2 leach at atmospheric pressure can significantly reduce magnesium dissolution, and offers the ability to recover HCl and MgO by a less energy intensive process than conventional techniques via the formation of magnesium hydroxychlorides. Inevitably, the high chloride concentration renders iron fully soluble during leaching and thus requires subsequent iron control and disposal steps. Experimental measurements coupled with OLITM modeling were conducted to investigate the behaviour of iron in concentrated magnesium chloride brines, in terms of chemistry (nature of iron species) and solubility limits. The solubility of ferric chloride in magnesium chloride solutions of concentrations and temperatures relevant to this process was controlled by a previously unreported solid phase: 2.5FeCl3·MgCl2·7.5H2O. Iron precipitation tests on synthetic leach solutions without seeding indicate a metastable akaganeite precipitate which transitions to hematite upon equilibration. Magnesium chloride solubility in ferric chloride solutions was also investigated to allow the simulation of a ternary phase diagram for the MgCl2-FeCl3-H2O system, in order to determine process conditions that avoid unwanted chloride precipitation.INTRODUCTION In the search for more economical processes to treat lateritic saprolite for nickel production, chloride hydrometallurgy has been increasingly investigated. While High Pressure Acid Leaching (HPAL) can frequently economically treat lateritic limonite, the presence of saprolite negatively affects process economics. The higher magnesium content of saprolite increases acid consumption, because magnesium sulphate, unlike iron and aluminum sulphates, does not hydrolyze in HPAL. This soluble magnesium decreases the sulphuric acid strength by an amount greater than the amount of acid stoichiometrically required to leach magnesium, which must also be disposed of or recovered (Jankovic, Papangelakis, & Lvov, 2009). Due to these issues, pyrometallurgy is most commonly employed to treat lateritic saprolite, via the Rotary Kiln-Electric Furnace (RKEF) process; this process uses a rotary kiln to dry and partially reduce nickel and iron oxides before sending the calcine to an electric furnace for smelting to produce a ferronickel product for the stainless steel market. Although the problems encountered during hydrometallurgical processing are avoided and nickel recoveries are high, high capital and energy costs prevent the application of this process to lower grade lateritic saprolite deposits (De Bakker, 2011)."

Jan 1, 2016

Iron Concentrate Synthesised from Waste Ferrous Sulfate Produced in Titanium White Preparation

Sep 13, 2010

By J. E. Nesset, S. R. Rao, J. A. Finch

"For base metal sulphides, iron rejection starts in mineral processing. This review focuses on changes in plant practice specifically to improve iron sulphide rejection by control of contaminant ion effects and discusses selected general innovations in mineral processing that can be expected to play a role. One group of changes to control contaminant ions is in size reduction (the use of stage grinding and inert stirred milling) and another is in system chemistry (order of reagent addition and exploitation of the flexibility of sulphoxy reagents). Plant examples illustrate the successes, indicating that there are several options available. The general innovations start by considering the new tools for measuring gas dispersion properties and quantifying froth characteristics by imaging. Examples of their application to improve concentrate quality illustrate the potential. Other innovations stress adapting geostatistics to model variation in milling and flotation response to provide feed forward control and rigorous application of statistical experimental methodology in plant test work. An example from one concentrator shows improvements in concentrate quality from application of basic principles can be impressive.INTRODUCTIONThe more iron control (rejection) that can be accomplished in mineral processing the lower the subsequent metal extraction costs and environmental implications of iron disposal, particularly in hydrometallurgical processes. Iron rejection has been a contributing target to periodic attempts to apply mineral processing to nickel laterites and bauxites but the prime application is control of pyrite and pyrrhotite (iron sulphides) in the treatment of sulphide ores by flotation. In this paper some new concepts and innovations introduced in sulphide flotation plants over the past ten years or so (i.e., since a previous review [1]) will be outlined with examples of how they have contributed to improved “iron control”.To increase rejection of iron minerals, first the recovery mechanism should be understood. There are four principal ones, two physical in origin: 1, via locked particles (i.e., flotation of composite particles due to insufficient size reduction to liberate the minerals) and 2, through entrainment in the water reporting to the float product (an unselective process); and two originating from a response to the system chemistry: 1, true flotation (i.e., iron sulphides becoming hydrophobic) and 2, as a result of iron sulphides forming aggregates with hydrophobic particles (e.g., ”slime” coatings). There has been considerable effort to diagnose which of these dominates iron sulphide recovery; in many cases it is due to “chemistry”, in particular true flotation. The flotation effect often appears related to contamination by metal ions [1]. This can reduce selectivity in two ways: 1, metal ion species may activate iron sulphides, or 2, cause general depression which demands more vigorous flotation conditions (e.g., additional collector) with consequent loss of selectivity. This is where the review will start, by considering ways to control contaminant ions."

Jan 1, 2007

By Larsen D. F

Minor iron formation related base metal sulphide mineralization occurs in granulite facies metamorphic rocks of the early Proterozoic Willyama Complex. Rock sequences hosting three iron formation related Cu, Zn, Pb prospects from the Thackaringa Group (Suite 3) are described. A caparison of host rock sequences, style of mineralization and facies of iron formations suggests major differences in terms of the overall depositional environment. However, significant similarities are present with respect to the nature and distribution of iron formation facies and the occurrence of chlorite 'alteration' zones in close proximity to mineralization in all cases. The chlorite within these zones occurs in a number of diverse forms in a range of rock types. A comparison of the prospects shows that there is no evidence to indicate that the chlorite in the zones is a retrograde alteration product of former higher grade prograde mineralogies - the chlorite appears to have survived granulite facies metamorphism. The mode of occurence of the chlorite in the 'alteration' zones together with the fact that the association quartz + chlorite + magnetite + pyrite + base metals is cx rmn to all areas suggests that the chlorite is specifically related to the processes which deposited the stratiform iron formations and related sulphides. It is considered that the chlorite precursor was a prenetanorphic alteration product or chemical sediment closely related to submarine hot spring activity which was also the source for chemical sediment precursors of the iron formations, associated lode rocks and Sulphides.

Jan 1, 1983

By F. McCarthy, R. McDonald, G. Woodbridge, G. Brock, D. Robinson

"The Direct Nickel process is a hydrometallurgical technology being developed to treat nickel laterite ores by leaching at atmospheric pressure. The leaching process uses nitric acid in a relatively large excess, is thus non-selective, and much of the soluble iron goes into solution. The first stage of solution purification is iron hydrolysis and the Direct Nickel process utilises the colligative properties of the pregnant leach solution (PLS) to enable the removal nitric acid of varying concentrations via distillation. Once sufficient acid has been removed, the boiling point of the solution is increased allowing high temperatures (up to ~170°C) to be achieved under atmospheric pressure. The higher temperatures initiate the precipitation of the iron primarily as hematite and allow the removal of the acid generated by the hydrolysis reaction. The rejection of the iron is near complete with solution tenors typically falling from 65 g/L Fe, or more, to less than 50 mg/L Fe. The separation of clean nitric acid from the PLS at this stage allows for relatively simple acid recycling. A hematite product with iron content above 60% could also provide an extra revenue stream.INTRODUCTION The Direct Nickel (DNi) Process is a novel hydrometallurgical processing route designed to treat all types of nickel laterite ores in a single flow sheet using nitric acid under atmospheric conditions. A simplified flow sheet is shown in Figure 1.Between 2007 and 2012 the process was developed and refined at Direct Nickel’s laboratory within the CSIRO Minerals’ facilities in Perth, Australia, and in 2013 a series of pilot plant trials were run under continuous operating conditions. The process is designed to treat both limonite and saprolite in the same flow sheet, and after comminution, the blended ore is mixed with nitric acid and leached just below boiling point in agitated atmospheric leach tanks. The acid is added in excess, so typically for a blend of limonite and saprolite the acid addition can be in the order of 1.8-2.0 t acid/t dry ore. After a residence time of between 4-6 hours the majority of the soluble metals have leached into solution and the insoluble leach residue is separated from the pregnant leach solution (PLS) via counter-current decantation."

Jan 1, 2016

By M. Arvola, A. Mäkinen, N. Isomäki

Arsenic is a compound that has no significant market value. However, it needs to be removed from ores, concentrates and other process streams because of environmental or technical processing concerns. A wide range of arsenic containing minerals exists in nature, and in many instances these minerals are also associated with the ones that have commercial value. For example, sulfide copper ores are normally closely associated with minerals like enargite, Cu3AsS4 and tennantite Cu12As4S13. After mineral processing these arsenic sources can report to the waste waters and these effluents need to be treated before discharge or recycling. Ferric arsenate precipitation is a well-established method for stabilizing arsenic in effluents. Electrochemical arsenic removal utilizes the same adsorption/precipitation ideology as ferric arsenate precipitation. Electrochemical arsenic removal, even though it is a simple process in terms of equipment, is a complex system involving chemical and physical mechanisms taking place simultaneously to remove dissolved and/or solid arsenic components from wastewaters. The whole process can be described by the following three steps: 1) electrolytic oxidation at a sacrificial anode (dissolving electrode metal, iron for example), 2) chemical reaction between dissolved iron and arsenic to form a solid precipitate and 3) aggregation of the particles to form flocs, which can be removed by known solid/liquid separation methods. Electrochemical arsenic removal is a very efficient way to remove arsenic from different waters to very low residual concentrations.

Jan 1, 2016

By Campbell Brown GA

IN 1904-5 diamond drilling operations in the Mount Morgan mine proved the presence of some inillioils of tons of rich, copper-gold ore, averaging about 45% to 50% silica and 22%Fe as sulphide. To smelt this ore in blast furnaces, without previous concentration, large quantities of basic flux.were required. Unlimited quantities of cheap, limestone, were available at Marmor, on the GladstoneRockhampton railway, 50 miles from Mount Morgan, but the supply of iron flux was a more difficult problem. Smelting operations started, with one' furnace in January, 1906, using as flux low-grade sulphide ore fro:m. the mine, containing very little silica. When the second, furnace was blown in this was supplemented by ironstone from, small aeposits in the immediate district. It was recognized that these sources of supply would be insufficient to keep the full plant going after the third furnace had been blown in. Accordingly, the deposits at Eabra and Mount Etna were opened, neither of which proved capable of supplying the quantity required viz, 1000 tons per week. Negotiations were meanwhile being conducted with the Marble Island Iron and Limestone Co. to obtain the right to mine at Iron Island, where a sufficiently large deposit was known to exist. Shipments from this source commenced in January, 1907, and ceased at the end of July of this year, when the metallic flux from...

Jan 1, 1912

By Campbell Brown G A

IN 1904-5 diamond drilling operations in the Mount Morgan mine proved the presence of some millions of tons of rich copper-gold ore, averaging about 45%to 50%silica and 22%Fe as sulphide. To smelt this ore in blast furnaces, without previous concentration, large quantities of basic flux were required. Unlimited quantities of cheap limestone were available at Marmor, on the GladstoneRockhampton railway, 50 miles from Mount Morgan, but the supply of iron flux was a more difficult problem. Smelting Operations started with one furnace in January, 1906, using as flux low-grade sulphide ore from the mine, containing very little silica. When the second furnace was blown in this was supplemented by ironstone from small deposits in the immediate district. It was recognized that these sources of supply would be insufficient to keep the full plant going after the third furnace had been blown in. Accordingly, the deposits at Kabra and Mount Etna were opened, neither of which proved capable of supplying the quantity required-viz., 1000 tons per week. Negotiations were meanwhile being conducted with the Marble Island Iron and Limestone Co. to obtain the right to mine at Iron Island, where a sufficiently large deposit was known to exist. Shipments from this source commenced in January, 1907, and ceased at the end of July of this year, when the metallic flux from...

Jan 1, 1911

By C M. Wawryk, S L. Garwin, J D. Foden

"An EXTENDED ABSTRACT is available for download. A full-length paper was not prepared for this presentation. The Batu Hijau porphyry Cu-Au deposit in south-western Sumbawa, Indonesia is an ideal natural laboratory to study the fractionation of iron isotopes in magmatic rocks that range in composition from basaltic andesite to tonalite. Intrusive rocks are associated with a porphyry system that contains well-preserved early hypogene copper mineralisation. We analysed pre-, syn- and post-mineralisation igneous intrusive rocks. We also separated magnetite, chalcopyrite and bornite from hypogene porphyry-style quartz veins, and measured the Fe-isotope ratios of samples by solution multi-collector ICP-MS. Iron isotopic composition of samples from the magmatic suite show an increasing d57Fe with increasing SiO2, supporting geochemical and textural evidence that the Batu Hijau Tonalites underwent closed system fractionation. Equilibrium and co-existing mineral textures allow the calculation of the following preliminary empirical mineral-mineral fractionation factors at 500°C for certain mineral pairs.Iron isotopes have the potential to provide geothermometric data to complement fluid inclusion data, especially where heating stages have operational limitations and where fluid boiling results in a wide variety of inclusion types that may make analysis difficult.CITATION:Wawryk, C M, Foden, J D and Garwin, S L, 2015. Iron isotope fractionation in magmatic-hydrothermal minerals – a porphyry copper case study from the Batu Hijau deposit, Sumbawa, Indonesia, in Proceedings PACRIM 2015 Congress, pp 389–396 (The Australasian Institute of Mining and Metallurgy: Melbourne)."

Mar 18, 2015

Iron Ore - Mineral Processing Overview Several years of iron ore price increases, coupled with a period of strong global demand for raw materials, presented iron and steel producers with unprecedented costs and difficulty procuring the demanded high quantities of iron ore. These conditions spurred many companies to investigate new ore bodies and also reassess past decisions (such as divestment of captive iron ore mines that ensured dedicated supply or a move to reliance on the 'spot market' instead of long term contracts with suppliers) and revisit alternative sources of iron units, including low grade deposits, tailings reprocessing, Ti-rich ores, and iron sands. To properly upgrade these iron sources requires a complete battery of mineral processing techniques. Within different regions around the world, operations and technology have developed to specifically beneficiate the local ore bodies. This paper attempts to bring these different general processing techniques together to allow insight into various common and proven methods of iron ore beneficiation. This paper further explores the current trend to develop global iron ore reserves, and discusses the methods to beneficiate and successfully reduce and smelt iron ore using Outotec's physical separation, direct reduction and smelting technologies for final production of pig iron and slag. Use of these various technologies may allow treatment of what was typically considered a tailings stream into a profitable product.

Sep 13, 2010