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By Shianny Cruz Vasquez

Peru is a country with a complex physiography due to the Andes uplift that expose the different ore deposits. Actually Peruvian mining produces a variety of metal commodities and has one of the world’s largest mining. It is the third-largest global producer of copper, silver, zinc and tin. Within Latin America is the largest producer of gold, zinc, tin and lead. The importance of this research was to determine the toxic elements source and the current state of surface water and groundwater all the way from the top until it empties into the Tambo River and assess their, that impact have the toxic contaminants on the environment and the human health of the surrounding Communities and provide a management and decision-making tool to prevent socioenvironmental conflicts.

Sep 1, 2017

By Ivo Dreiseitl

Bottom sediment sampling by means of a box corer, as a direct method of deep seabed exploration for polymetallic nodules, is the most comprehensive way to obtain various types of geological information on points forming a network of stations. However, direct information is lacking from areas separating those stations and has to be approximated by interpolation or extrapolation, which leads to uncertainties. Sediment sampling with a gravity or piston corer can provide information on the superficial, up to 4 m thick, part of the sedimentary cover. As opposed to box coring, gravity or piston coring provides no information on nodule abundance. Information for unsampled areas can be gained by application of remote techniques of exploration. The techniques of choice in visualising nodule-rich fields, nodule-free areas, hard rock outcrops and other obstacles for seafloor mining involve using sonar and continuous deep sea (CDS) camera. Seafloor mapping can be rendered with two major sonar types: the side scan sonar used to obtain seafloor imagery and multibeam sonar for bathymetric data; the two types are usually combined and work with an intermediate frequency profiler. Photo-profiling by means of a deep sea towed camera provides a series of seafloor photographs, each supplemented with information on the area covered by each frame, including the nodule abundance. Remote techniques have been quite frequently applied by the Interoceanmetal Joint Organization (IOM) in nodule field exploration. Recently, geoacoustic techniques (side scan sonar + profiler) and CDS were applied for exploration of IOM?s first prime area H11 (5372 km2) on 6 transects. During the IOM-2009 cruise, a total of 295 km of geoacoustic transects and 344 km of photo-transects were surveyed. The data obtained were processed with the aid of earlier information produced by multibeam sonar surveys. The aim of this paper is to demonstrate the advantages of remote techniques, particularly with regard to application of the towfish device, for geological and geotechnical applications in exploration for polymetallic nodules.

Sep 14, 2011

By William Hanco Mamani

El presente trabajo describe la implementación del GEOCATMIN en el Instituto Geológico Minero y Metalúrgico (INGEMMET). La labor del INGEMMET estriba en otorgar información de manera fácil, rápida y sobre los trabajos técnicos de INEM, MTC, MINAM, INEI, COFOPRI, SERNANP, geología y minería, productos geológicos entre mapas y boletines, etc. De forma, que esta información contribuye a una serie de procesos de cambio que el Gobierno impulsa, con el objetivo de mejorar la calidad de vida de los peruanos, promoviendo las inversiones, la inclusión social, el ordenamiento territorial, la zonificación ecológica económica, identificación de zonas de riesgo para la prevención de desastres, información geológica y minera, etc.

Sep 21, 2013

By A. Philipp, A. S. Middleton, G. A. Harron, A. B. Durham

"Basal till sampling techniques were used to search for gold mineralization in the Timmins, Ontario area. During 1978 and 1979, approximately 90 overburden sampling drill holes were completed in Murphy and Hoyle Townships to test specific geophysically defined target areas. A conventional tricone dual tube drill system, and a unique retractable tricone/rock coring system were used to various advantages.First pass till sampling at 800 to 1200 ft intervals perpendicular to ice transport direction yielded anomalous gold values in till and carbonatized quartz pyrite-rich bedrock chips, and lateritic soil. Subsequent induced polarization-resistivity surveys defined the areal extent of a pyritic carbonate alteration zone. A second pass till sampling/limited rock coring program evaluated the gold mineralization potential of the alteration zone. Diamond drilling has substantiated the till and bedrock gold anomalies. Further evaluation of this mineralization is currently in progress. IntroductionThis paper describes an integrated geochemical/geophysical gold mineralization discovery case history in Hoyle Township. This discovery is on a property jointly owned (I983) by Canamax Resources Inc. and Du Pont of Canada Exploration Limited. Exploration of the property began in 1978 by Rosario Resources Canada Ltd. and in 1979 a joint venture agreement was signed with Du Pont of Canada Exploration Limited. Rosario Resources Canada Ltd. was taken over by Amax Minerals Exploration in 1981, which became Canamax Resources Inc. in 1982.The work described in this paper deals with a gold mineralization discovery located three-quarters of a mile northwest of the gold deposit currently being readied for underground exploration and development. Further drilling is required to investigate the economic potential of the gold mineralization herein described."

Jan 1, 1987

By S Henderson

The Thames gold-silver deposits are part of the Hauraki goldfield, situated within the Miocene to Pliocene calc-alkaline Coromandel Volcanic Zone (CVZ). The Waitangi vein system is one of the mineralised ore shoots in the Thames district. The Thames gold deposits are characterised by shallow level epithermal vein mineralisation with phyllic to advanced argillic alteration assemblages and abundant sulphide minerals including pyrite, arsenopyrite, chalcopyrite, galena and sphalerite. Gold occurs as electrum in association with sulphide minerals. Microprobe analyses.of sphalerite grains from the Waitangi deposit mostly range from 0.8 to 1.5 mole % FeS, although one sample contains 9.5 mole % FeS. Arsenopyrite from Waitangi yields a range from 33.1 to 34.6 atomic As (%). There is no discernible correlation between the FeS content of sphalerite and gold grade in the Waitangi deposit suggesting that gold deposition is probably not controlled by changes in temperature and activity of sulphur aS2 that control the FeS content of sphalerite. The possible causes for gold deposition are thought to be boiling, mixing and changes in pH. Sulphur isotope analyses of mixed sphalerite-galena and sphalerite-galena-ehalcopyrite samples yield a narrow range of d34SCDT values (-1.0 to 0.9 ë;n=5), whereas late spongy pyrite gives unusually light sulphur isotope values (-16.7 to -27.9 ë; n=4). The sulphur isotopic values of base metal sulphides from Waitangi suggest that the sulphur was derived from a magmatic source. However, the source of light sulphur in the late pyrite grains is not known. Preliminary fluid inclusion+studies indicate homogenisation temperatures between 173¦ and 284¦C and salinities of 0.23.0 NaCI equiv. wt % (uncorrected for C02). Vein quartz at Waitangi yields d18OSMOW values from 6.8 to 12.7 ë (n=23). The calculated oxygen isotopic composition of ore fluids is between -2.1 to 3.8 ë at 250¦C and -0.1-5.8 ë at 300¦C. Oxygen isotope analyses have revealed significant variations in d18O values with elevation and gold grades. Zones of gold enrichment coincide with a zone of variable oxygen isotope values at the top of the vein system, where boiling and/or fluid mixing most likely occurred. Oxygen isotope values varying with gold grades within the Waitangi conduits suggest that d18O values may be useful in targeting bonanza grade gold mineralisation in epithermal vein systems.

Jan 1, 1993

By Jeffrey A. Holcomb

INTRODUCTION The passage of Comprehensive Environmental Response Compensation and Liability Act (CERCLA/Superfund) as well as the Resource Conservation and Recovery Act (RCRA) and state laws, have placed added regulatory pressures on the mining industry. These laws which focus on the regulation of hazardous substances and wastes for the protection of the public health and welfare and the environment, present the potential for tremendous financial impacts and liabilities on existing mine operators and owners and/or potential mine operators/owners. This paper takes a brief look at these laws and presents an environmental audit procedure to identify environmental liabilities prior to mine land transactions. The environmental audit approach presented is an overview of the procedures that could be used to document, evaluate and inventory existing and/or potential environmental concerns. This audit procedure can be applied to developed or undeveloped properties and at active or inactive mining sites. REGULATORY OVERVIEW Mining environmental liabilities have been addressed in RCRA, Superfund, the Clean Air Act (CAA) and the Clean Water Act (CWA). Even though the U.S. Environmental Protection Agency (EPA) has determined that mining wastes will be treated as solid wastes under RCRA and not as hazardous wastes, these wastes could still bring about a great deal of financial liability under Superfund. The catch is if the mine wastes generated contain hazardous substances such as the heavy metals arsenic, beryllium, cadmium, chromium, copper, lead, mercury, nickel, selenium, silver, thallium, zinc and others as well as cyanide. Thus, it is not only important for a mine operator/owner or a potential mine operator/owner to know if the mine wastes generated are hazardous, but it is important to know if the wastes contain hazardous substances. Following is a brief overview of RCRA and Superfund and their potential implications. RCRA RCRA, which provides the basis for the regulation of solid and hazardous wastes, is applicable to active mining and milling sites. Within RCRA the definition of a hazardous waste is provided. This definition applies to owners and operators of mining and milling sites if the operator has stored, disposed or treated hazardous wastes on-site. If this is the case and if strict process control and waste management activities are not adhered to, environmental liabilities may be associated with the site. Superfund The 1980 Superfund law can be applicable to inactive mining sites or to inactive sections of an active facility. The provisions of Superfund call for the regulation of hazardous wastes and hazardous sub- stances disposal and release not only by the existing owner, but also for any previous owner. This concept of joint and several liability means that one party, as among many, can be held totally responsible for the costs of hazardous waste cleanup (Haller, 1987). Furthermore, liabilities under Superfund have also been applied back to past acts; thus, several mining properties, active or inactive prior to the 1980 Superfund law, are at risk of being placed on the EPA's National Priority List (NPL) for cleanup. Last years amendments to Superfund, known as the Superfund Reauthorization Act of 1986 (SARA), provided some significant developments for the mining industry. The major requirement of the amendments as it pertains to owners or operators of mining sites is that the EPA must revise its present Hazard Ranking System (HRS). This is important be- cause in most cases the primary reason for several mining sites having been included on the NPL was due to the large volume of wastes generated. As is typical at most mining sites, large volumes of low toxicity wastes are generated and the current HRS model prejudices against this. It should be noted that this provision only applies to sites that are not already on the NPL or have not been proposed for inclusion on the list.

Jan 1, 1987

By Andrea Koschinsky, Sophie Paul

"INTRODUCTIONOnce again deep-sea mining has been receiving a lot of attention in recent years. Industrial and political advancements also call for environmental baseline studies and analyses to aid the development of standards and monitoring protocols. As part of the EU research project “JPI Oceans: Ecological Aspects of Deep-Sea Mining”, the RV Sonne cruise SO242 to the Peru Basin revisited the DISCOL area that had been artificially disturbed in 1989. This offered the unique opportunity to study a deep-sea site 26 years after a disturbance similar to manganese nodule mining had been carried out (Figure 1). A comparison of a variety of undisturbed and disturbed sites shed light on the re-establishment of a geochemical equilibrium and a range of baseline values. This information can help to inform standard development for monitoring and mining purposes.Heavy metal data and its applicationResearch findingsDuring the cruise, disturbed and undisturbed surface sediment was sampled. The pore water analyses show that the 26 years old disturbance is not visible in the metal profiles and that the pore water reaches equilibrium through diffusive fluxes relatively quickly. The sediment, however, shows some differences between disturbed and undisturbed sites in the upper 20 cm, even after 26 years. Lower concentrations in the usually manganese-oxide rich top layer, variations and “unnatural” peaks in the manganese profiles, for example, suggest removal or mixing of the top layer (Figure 2)."

Jan 1, 2017

By Catharine E. G. Farrow, David H. Watkinson

Abstract-The Ni-rich Epidote Zone of the Fraser Mine at Sudbury is characterized by alteration assemblages rich in epidote, actinolite and magnetite which are roughly concentrically zoned and up to hundreds of meters in length. These zones form discrete areas within the igneous Footwall Breccia below the Sudbury Igneous Complex. The assemblages grade from epidotized Footwall Breccia matrix, through actinolite-bearing rocks with few vestiges of original Footwall Breccia textures, into the most intensely altered rock, a magnetite-rich facies. Pentlandite, pyrrhotite and pyrite are the dominant sulfide minerals; chalcopyrite is minor. The strongest geochemical differences compared to original Footwall Breccia occur where epidote and actinolite dominate the alteration assemblage (EPDZact facies). The most intense alteration facies are typified by low Cu/(Cu+Ni) values of <0.1. Strong positive correlations exist between Ni and Co, Cu and Au, and among Ir, Os, Ru and Rh. Chondrite-normalized Ni - PGE - Au - Cu plots display an overall increase in all elements from the least to the most intensely altered facies except for Au and Cu. As the proportion of actinolite increases in the EPDZact facies, the chondrite-normalized profiles flatten considerably due to low Au and Cu contents. Abundances of Ni, Ir, Ru and Rh almost ubiquitously increase with degree of alteration. In contrast, Cu, Zn, Ag and Au contents are low in almost all facies. It is suggested that saline hydrothermal fluids moved through the Epidote Zone formation and became more oxidized as they reacted with the Footwall Breccia and with footwall units, including ultramafic rocks. As this trend continued, magnetite-rich zones eventually developed. The occurrence of calcite locally in these magnetite-rich zones suggests that the pH of the fluid increased, causing Cu solubility to drop as activity in the hydrothermal system waned. Sudden changes in fluid composition such as this may have been due to an influx of fluid from bounding ultramafic rocks. Hydrothermal activity was focused along the margins of footwall ultramafic units. Individual hydrothermal cells may have formed in the Footwall Breccia along pre-existing structures or sulfide concentrations. Metals may have been scavenged from sulfide-bearing Footwall Breccia and possibly Sublayer rocks. Nickel and some PGE were deposited in the Epidote Zone, whereas Cu, Au and Ag continued outward into the footwall where they were deposited as Cu-rich footwall veins.

Jan 1, 1996

By Catharine E. G. Farrow, David H. Watkinson

The Ni-rich Epidote Zone of the Fraser Mine at Sudbury is characterized by alteration assemblages rich in epidote, actinolite and magnetite which are roughly concentrically zoned and up to hundreds of meters in length. These zones form discrete areas within the igneous Footwall Breccia below the Sudbury Igneous Complex. The assemblages grade from epidotized Footwall Breccia matrix,through actinolite-bearing rocks with few vestiges of original Footwall Breccia textures, into the most intensely altered rock, a magnetite-rich facies. Pentlandite, pyrrhotite and pyrite are the dominant sulfdeminerals; chalcopyrite is minor. The strongest geochemical differences compared to original Footwall Breccia occur where epidote and actinolite dominate the alteration assemblage (EPDZact facies). The most intense alteration facies are typifed by low Cu/(Cu+Ni) values of <0.1. Strong positive correlations exist between Ni and Co, Cu and Au, and among Ir, Os, Ru and Rh. Chondrite-normalized Ni - PGE -Au - Cu plots display an overall increase in all elements from the least to the most intensely altered facies except for Au and Cu. As the proportion of actinolite increases in the EPDZact facies, the chondrite-normalized profles fatten considerably due to low Au and Cu contents. Abundances of Ni, Ir, Ru and Rhalmost ubiquitously increase with degree of alteration. In contrast, Cu, Zn, Ag and Au contents are low in almost all facies. It is suggested that saline hydrothermal fluids moved through the Epidote Zone formation and became more oxidized as they reacted with the Footwall Breccia and with footwall units, including ultramafic rocks. As this trend continued, magnetite-rich zones eventually developed. The occurrence of calcite locally in these magnetite-rich zones suggests that the pH of the fluid increased, causing Cu solubility to drop as activity in the hydrothermal system waned. Sudden changes in fluid composition such as this may have been due to an influx of fluid from bounding ultramafic rocks. Hydrothermal activity was focused along the margins of footwall ultramafic units. Individual hydrother-mal cells may have formed in the Footwall Breccia along pre-existing structures or sulfde concentrations. Metals may have been scavenged from sulfide-bearing Footwall Breccia and possibly Sublayer rocks. Nickel and some PGE were deposited in the Epidote Zone, whereas Cu, Au and Ag continued out-ward into the footwall where they were deposited as Cu-rich footwall veins. Copyright © 1996 Canadian Institute of Mining, Metallurgy and Petroleum.

Jan 1, 1996

By E. O. Afreh, R. J. Bowell, E. Hanssen, D. Pohl, S. Abe, R. K. Yao, N. d'A. Laffoley

In the largely preserved laterite profiles at Syama mine, in the savanna region of southern Mali, element geochemistry in the mottled-clay horizon and below can be related directly back to the protolith, but above this, in the ferricrete and cuirasse horizons, the hypogene signature is much modified by pedogenic processes. In tropical rainforest terrains extensive remobilisation can result in wide but weak geochemical targets for gold and pathfinder elements. At the Hire concession in central Ivory Coast, intense recent alteration of the largely intact laterite sequences has modified soil-geochemical dispersion patterns extensively, producing Fe-rich nodular stone lines and obliterating previous patterns and features. Where the upper horizons of the laterite profile have been removed or reworked, as at the Senoufo concession in northern Ivory Coast (savanna) or the Kubi prospect in Ghana (rainforest), all soil horizons can be related directly to hypogene geochemistry. In these truncated profiles, gold and base metal anomalies are essentially those of the lower weathering profile and form narrow but strong dispersion haloes. A good understanding of the geochemical processes active in deeply weathered profiles is required if targets are to be recognised effectively

Apr 1, 1996

By L. W. Ashton

Geochemical exploration guidelines were developed from a study of 460 rock chip samples collected at nine disseminated gold deposits in Nevada. Obtaining high grade Au samples is difficult because gold content is extremely variable, even over 8 m (25 ft) distances. For reconnaissance sampling, pathfinder elements are reliable indicators with threshold values of 100 ppm As, 1 ppm Hg, and 50 ppm Sb. Arsenic is the most reliable of the three elements, being significantly enriched in all deposits. If the pathfinder threshold levels are reached with low Au content, more samples should be collected. Successful disseminated gold exploration requires large numbers of samples.

Jan 1, 1990

By A. D. Thomas, V. N. Rampton, S. Paradis, C. F. Gleeson

"A shallow till sampling program was completed on a 1 km grid over the St . George Batholith in southern New Brunswick. The ""B"" soil horizon was analyzed for Cu, Pb, Zn, Ag, Co, Mo, U and Sb and the heavy minerals from the ""C"" soil horizon were analyzed for W, Sn and A u. The results delineated four of five recorded W occurrences, three of four recorded Mo occurrences, all recorded Cu occurrences and one recorded Au occurrence. The results indicate that shallow till sampling in conjunction with bedrock and Quaternary mapping can inexpensively define exploration targets in terrain similar to that underlain by the St. George Batholith.A similar program was carried out in eastern Ontario involving the analysis of four separates from the till, the ""8"" soil horizon, the -50 mesh fraction, the -250 mesh and the heavy mineral fraction of the ""C"" soil horizon and humus. Also sampling was carried out near known gold occurrences at closer spacings. Regionally, anomalous results from all sample media clearly defined a large auriferous shear zone and associated splays. Over one known showing all media clearly defined the showing and a secondary zone. On the regional scale the heavy mineral fraction gave the best anomaly definition and contrast, but the -250 mesh fraction was found to be the most cost effective for defining exploration targets. For detailed surveys, humus was found to be cost-effective."

Jan 1, 1986

By J. Smolensky, M. Paul

The Nordhalde is a waste rock pile resulting from uranium mining near Ronneburg, Germany. The pile contains over 27 million m3 of waste rock. Typical seepage water has a pH of 2.7 and a sulfate concentration of 10,000 mg/L. Geochemical investigations of the Nordhalde from 1993 to 1996 included drillholes, test pits, ABA and metals analyses, column tests, and a detailed review of the construction history of the pile. In 1996, eight drillholes were instrumented for monitoring oxygen and temperature. Monitoring continued for a fill year. Hourly temperature and pressure readings were taken by automated data recorder. Oxygen concentrations were measured three times per week, and periodic gas samples were obtained for complete analysis. The resulting data set is believed to be one of the most comprehensive of its kind. Effects noted elsewhere, such as thermal convection, are evident. However, unlike other data in the literature, the NordhaIde data shows a strong seasonal effect, with convection dominating oxygen transport only in the winter months. Analysis of the data allowed the amount of contaminants associated with ongoing and historical oxidation to be compared, and results were used to assess the potential effectiveness of proposed remediation measures.

Jan 1, 2000

By T. Lenarcic, R. Svrkota, J. M. McNeal, E. Prohic, S. Pirc

Paper presented at the 28th International Geological Congress held in Washington DC, July 1989 (International geochemical mapping sessions). Surface drainage samples, the usual media employed in mapping national territories, cannot be used for the geochemical mapping of carbonate terrains because there is no regular surface-drainage pattern on karst. Suitable sampling media have been studied in Yugoslavia, one-third of which consists of karst terrain. Sampling designs for the work were based on analysis of variance techniques. During initial investigations of various sampling materials in NW Yugoslavia sediment and aquatic moss from karst springs, along with soil, were established as the most appropriate media. Modified sampling procedures were then carefully applied along the entire Yugoslav karst belt, which includes terrains of contrasting topography, climate, pedology and vegetation. The studies indicate that climate and relief do not systematically influence the geochemical composition of soil. Regional and local variability was assessed for 21 chemical elements and the feasibility of producing stable regional geochemical maps was determined for a number of elements on the basis of sampling aquatic moss and sediment from karst springs and soil

Jul 1, 1991

By V P. Elpatyevskaya, V S. Arzhanova

Main geochemical problems concerning the environment and mining industry interrelation are connected with the transformation of natural water chemistry by mining wastes. The investigation of many mines in Primorye, the southern part of the Russian Far East, showed that their mining waters have high concentrations of heavy metals and aluminium. Water acidity is primarily connected with the amount of acid-forming sulphide minerals in ores and also depends on the neutralising capacity of rocks. Considerable quantity of metals occur in the waters in dissolved form. Metal concentrations in mining waters exceeds the natural levels by two to five orders of magnitude and can&apos;t be reduced to the background levels even after multiple dilution. It is necessary to develop and put into practice new technologies so that to reduce the geochemical impact upon the environment.

Jan 1, 1995

By Regina N. Tempel, Laurie S. Balistrieri, Lisa L. Stillings, Lisa A. Shevenell, Maggy F. Lengke

Dexter pit lake, within the townsite of Tuscarora, Nevada, has been in existence since 1990 and provides a natural laboratory for the study of cycles of trace elements associated with ore deposits (e.g. As, Cu, Pb, and Se). Our goal in this study is to develop and calibrate methods of geochemical modeling that may be applied to estimating the concentrations and fluxes of trace elements in pit lake systems. Our initial modeling work considers limnology, hydrology, wall rock mineralogy and geochemistry, benthic fluxes, and colloid composition. Results from our work may be useful in evaluating water quality in the arid West.

Jan 1, 2000

Geochemical data on Australian granites and pegmatites, and the mineral components of these rocks, are compared with that obtained in similar studies in the U.S.S.R. and elsewhere.The geochemical character of tin granites and the trace chemistry of their component minerals, particularly biotites, have some significance as ore guides in prospecting for tin.The primary geochemical dispersion of tin can be readily tested both in the laboratory and field by colourimetric methods, after volatilization with ammonium iodide, using modifications of the method described by Wood (1958).Secondary dispersions of tin in residual soils or alluvia can likewise be readly tested by rapid colourimetric methods in the field, but simple hydraulic methods, handling larger sample volumes, give reliable outlines of dispersion patterns.INTRODUCTIONThe search for tin ores, whether lode or placer in type, is usually directed on genetic grounds to country within or adjoining acid intrusives.A long established means of prospecting is to test samples for cassiterite by panning or other hydraulic separation.These methods can be used on crushed lode material or the natural materials from placers.With the advent of new techniques for extraction and for colourimetric analysis for tin (Wood, 1958 and Ross and White, 1961) a means is available for rapid analysis of materials not susceptible to quantitative testing by hydraulic methods because of the fine sizings of cassiterite or the occurrence of tin structurally held in minerals. The new methods thus opened up the field of tin prospecting by extending the search for ore guides to genetically associated rocks and minerals, wall ror-ks of veins and a wider range of superficial deposits.

Jan 1, 1963

By S. Litke

Elemental sulfur was stockpiled at the Mount Polley Mine for use as a source of sulfuric acid as part of research into leaching copper from oxide ores, but the project did not proceed beyond an initial pilot- scale evaluation. Since placement, the sulfur has oxidized and some sulfuric acid leached into the underlying rock. The reaction of the acid with these underlying materials has been studied as part of an evaluation of the effects of leachate from the pile. The rock underneath the sulfur pile is composed dominantly of primary and secondary alumino-silicates with less than 1% carbonate (calcite) and iron sulfide (pyrite). In its unaltered condition, the rock is classified as non-acid generating. Conceptually, it was expected the sulfuric acid would be neutralized by the rock to varying degrees resulting in a series of pH-controlled weathering fronts progressing from leached near the contact with the sulfur pile (pH <3), to active neutralization by silicates (pH 4–5), to active neutralization by carbonates (pH >7). The rocks underneath the pile were sampled to determine the extent to which the rocks had reacted and their long-term stability after removal of the acid source. INTRODUCTION When rock is blasted and excavated to facilitate mining ore, it is typically placed and stored on the surface in piles. The resulting drainage may have a neutral to basic pH (i.e., non-acidic drainage) or a low pH (i.e., acid rock drainage, ARD) depending on the mineralogy of the rock being stored in the piles. Acid- base accounting (ABA) can be used to characterise the two types of rock: potentially acidic drainage generating (PAG) and not potentially acidic drainage generating (NAG) (Price, 2009). According to Price (2009), NAG is defined as having an excess of neutralization potential (NP) in the rock in the form of calcium carbonate-like minerals when compared to acid potential (AP), i.e., a Neutralization Potential Ratio (NP/AP = NPR) greater than 2.0, whereas PAG is classified as having an excess of AP (i.e., an NPR less than 1.0). This is a conservative estimate and may be slightly modified depending on the mineralogy at specific mine sites. Rock with an NPR of 1–2 is also capable of generating acid (Price, 2009) and, depending on the mineralogy, may also be classified as PAG. Drainage from PAG material can generate acid immediately, or many years after it has been exposed to surface conditions. Disposal techniques depend on the category (i.e., NAG or PAG) and reactivity of the rock stored in the piles.

Jan 1, 2019

By William W. Shilts

"In carrying out a geotechnical survey of a proposed gas pipeline route from the Arctic Islands south to Longlac, Ontario, the Polar Gas Consortium contracted the drilling of several hundred 2- to 2D-m-deep boreholes in drift and bedrock. Samples from these holes were made available to the Geological Survey of Canada, where they were subjected to stratigraphic and trace-element geochemical analyses. The geochemical characteristics of the clay and sand-sized heavy mineral fractions of till samples from these boreholes have been summarized in a series of geochemical profiles.From the proposed pipeline terminus at Longlac northward to the vicinity of God&apos;s River in Manitoba, tills contain significant amounts of Paleozoic carbonate rocks and Proterozoic sedimentary rocks derived from the Hudson Bay basin and lowlands. Within this section, two sites were enriched in base metals, indicating the possibility of local mineralization of possible economic interest.From God&apos;s River northward to Seal River, Manitoba, no evidence of local mineralization was noted. The heavy mineral fractions of the tills are universally enriched in Mn-rich siderite thought to originate on or in the Paleozoic section of the Hudson Bay lowlands.From Seal River northward to Thelon River, near Baker Lake, tills contain only components originating west of the Hudson Bay sedimentary basin. Near the Keewatin-Manitoba border, all till is enriched in uranium, which probably originates in the ""young"" porphyritic granites underlying much of the region, and produces a distinctive airborne radiometric anomaly.At the Thelon River, multiple till sections are variously enriched in Cr, Ni, U, Cu and Mo in the vicinity of a distinctive aeromagnetic anomaly.From Thelon River northward, several coincident zones of chromium and uranium enrichment are found where the line of boreholes crosses east-west-striking belts of volcanic, ultramafic and sedimentary rocks of the Prince Albert Group.The results of this study indicate that till tends to have characteristic element associations or concentrations over each of several broad regions along the pipeline route. These are related both to large-scale bedrock associations and to largescale effects of glacial dispersal. In addition, the samples, collected more or less at random with respect to local bedrock geology, have intersected several small-scale geochemical anomalies that appear to be related to zones of mineralization of possible economic interest."

Jan 1, 1980

By S. M. Flaherty, R. E. Scheffel, A. Guzman

Geochemical conditions within a leaching operation are heterogeneous. This variability arises mainly from hydrological controls imparted by physical characteristics of the ore and by heterogeneous metallurgical properties at the rock-fragment and industrial heap scale. The resulting chemical conditions are responsible for stratified mineral recovery, non-uniform extraction and prolonged leach cycles. This paper presents field data from a sulfide-leaching operation which clearly demonstrate the impact of chemical heterogeneity on metal recovery and the potential use of modern measuring techniques to facilitate operational monitoring and decision making for optimization of leaching operations.

Jan 1, 2006