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By Murat Alkan

In this study, a self-propagating high-temperature synthesis (SHS) and following acid leaching techniques were carried out to produce boron carbide (B4C) powder. First, B2O3 was obtained through calcinations of H3BO3 at 1073 K for 2 hours. Then, the glassy B2O3 obtained was crushed and sieved. In the SHS experiments, different amounts of B2O3, Mg and C black were used. The SHS product was obtained in the form of black, spongy solid. In the leaching step, the SHS product was leached in a HCl solution to eliminate the MgO and Mg3B2O6. The effect of acid concentration on the selective leaching was studied at different concentration range, solid/liquid (S/L) ratio, and temperature. The products obtained were characterized by using X-ray diffraction, chemical analysis and SEM techniques.

Jan 1, 2009

By Don Kay

A two year study into the effects of coal mining induced subsidence on cliff lines was undertaken by the Department of Mineral Resources with the support of a grant under the National Energy Research, Development and Demonstration Program. A new monitoring technique, using an Electronic Distance Meter and acrylic reflectors attached to the cliffs, provided safety for the surveyors and extensive and accurate three dimensional displacement data on the movement of the cliffs as they were being undermined. The study report included many graphs showing the measured vertical and horizontal displacements, differential subsidence, tilts and strains and included analysis of these movements with various parameters, such as, seam thickness, depth of cover and distances between the reflectors, longwall face and the edge of the chain pillar. Some of these graphs are presented in this paper and could be used, with caution, to predict subsidence movements around other cliff lines, after allowing for differences in geology and mining layout. A mechanism is suggested as an explanation for the observed high horizontal movements around the cliff lines. Sixteen percent of the overall lengths of cliffs that were undermined during the monitoring study fell and the contributions of various factors that appeared to influence the cliff falls are discussed. It is concluded that no single factor dominated as the major cause of the cliff falls and, often, many factors combined to cause cliff face instability.

Jan 1, 1992

By Carter J. P

A two year study into the effects of coal mining induced subsidence on cliff lines was undertaken by the Department of Mineral Resources with the support of a grant under the National Energy Research, Development and Demonstration Program. A new monitoring technique, using an Electronic Distance Meter and acrylic reflectors attached to the cliffs, provided safety for the surveyors and extensive and accurate three dimensional displacement data on the movement of the cliffs as they were being undermined. The study report included many graphs showing the measured vertical and horizontal displacements, differential subsidence, tilts and strains and included analysis of these movements with various parameters, such as, seam thickness, depth of cover and distances between the reflectors, longwall face and the edge of the chain pillar. Some of these graphs are presented in this paper and could be used, with caution, to predict subsidence movements around other cliff lines, after allowing for differences in geology and mining layout. A mechanism is suggested as an explanation for the observed high horizontal movements around the cliff lines. Sixteen percent of the overall lengths of cliffs that were undermined during the monitoring study fell and the contributions of various factors that appeared to influence the cliff falls are discussed. It is concluded that no single factor dominated as the major cause of the cliff falls and, often, many factors combined to cause cliff face instability.

Jan 1, 1992

Basic parameters affecting the stability of foams have been studied. We used the thin film pressure balance (TFPB) technique of Scheludko and Exerowa (1959) to measure the surface forces in foam films stabilized with various frothers such as pentanol, octanol, MIBC, and PPG. The results were compared with the froth stabilities measured using the shake tests and the film elasticity calculated using the model developed by Wang and Yoon (2006). It was found that the froth stability is controlled by both film elasticity and surface forces (or disjoining pressure), the relative contributions from each changing with frother concentration and type.

Jan 1, 2006

By G. S. S. Raman, M. S. Klima

Coal refuse slurries stored in tailings impoundments can potentially lead to environmental concerns such as effluent seepage, property devaluation, and in extreme cases, dam failures. Pressure filtration offers an opportunity to reduce the impoundment requirements by providing significantly drier solids. A full-factorial design was used to study the effects of temperature and pH on dewatering a refuse slurry obtained from a coal preparation facility in Pennsylvania, USA. The experimental results indicated a strong effect of temperature on cake moisture as the cake moisture after about 2800 s was 22% at 43 °C and only 36% at 10 °C for tests conducted at pH 3. ANOVA results confirmed the statistical significance of pH, temperature, and their interaction effect. Also, the results showed no significant differences between the tests conducted near neutral and alkaline pH values at low and ambient temperatures. On the other hand, Tukey's test indicated higher reductions in cake moisture at higher temperatures for lower pH values. This study affirms the need to monitor and control the pressure filtration process as throughput could significantly vary with changes in temperature and slurry conditions.

Jun 17, 2019

By Sutham Niyomwas

The Fe-TiC composite powder was synthesized in situ by carbothermal reduction of ilmenite. The standard Gibbs energy minimization method was used to calculate the equilibrium composition of the reacting species. The effects of the reaction temperature (1300 °C - 1500°C) and milling time of precursors on the Fe-TiC conversion and powder morphologies were investigated using XRD and SEM method. The synthesized products showed that composite with iron matrix and titanium carbide as a reinforced phase was formed.

Jan 1, 2006

By Charles Austin

IN an earlier series of studies on 18-8 stainless steel at 600°, 700°, and 800°C.1 one pretreatment was used throughout; viz., 15 min. in hydrogen at 950°C., followed by an air quench. Several manufacturers of this alloy since have expressed doubt as to the suitability of the temperature employed, recommending instead the more customary Strauss treatment as promising superior results. In this subsequent investigation on the effects of the temperature of pretreatment several interesting points have arisen, which are described in this paper. Previous work on our equipment had shown a marked difference between alloys of "similar chemical composition" that had been manu-factured by different companies. Accordingly, one mill-bar length was selected from which to prepare all specimens. It could then be assumed that any marked differences in creep characteristics would be due to effects resulting from variations in the pretreatment of the alloy. The material was furnished by the Allegheny-Ludlum Steel Co. in the form of 5/16-in, dia. rod, finished by air cooling from a mill anneal at 1950°F. (1066°C.). It was analyzed only for the elements shown: carbon, 0,07 per cent; chromium, 18.73; nickel, 9.46; manganese, 0.40. Three pretreating temperatures were chosen, the specimens being held for 15 min. in hydrogen at either: (1) 1150°C., to conform to the recom-mended Strauss treatment; (2) 950°C., to compare with the results of previous tests; or (3) 750°C., to initiate precipitation of carbides in the material before testing. As the test cross sections were only 1/8 -in. dia., air cooling followed the annealing treatment. These treatments per-mitted two direct comparisons: (1) between the 1150° and 950°C. treat-ments to indicate the effect of grain size when all carbides were probably in solution at the start of the test; and (2) between the 950° and 750°C. treatments to indicate the effect of carbide "nucleation" for similar grain sizes.

Jan 1, 1940

By Lijuan Chen

During the detoxification of chromium-containing slag by Achromobacter sp. CH-1, anionic surfactant Sodium Dodecyl Sulphate(SDS) and its mixed systems with different Tween surfactants(Tween 20, Tween 60 and Tween 80) were used to promote the interaction between the bacteria and the chromiumcontaining slag and the rate of acid-soluble Cr( ? ) leached from the slag. The effects were evaluated by the surface tension, the pH of the leaching solution and the leaching rate of total Cr( ? ) from the slag. The results showed that the surfactants systems improved Cr(VI) leaching and its detoxification of chromium-containing slag. The mixed surfactants of SDS combined with Tween surfactant revealed better effectiveness of detoxification than SDS only. When the mass ratio of SDS to Tween 80 was 1:1, the rate of Cr( ? ) leached from the slag increased by 12%.

Jan 1, 2009

By E. Esponosa-Gomez, J. A. Finch, A. R. Laplante

"Water quality plays an important role in oxide flotation. The effects on selective flotation of fine (1-16 um) pyrochlore of two types of water used at the Niobec concentrator, potable and plant recycle, were assessed. Several pyrochlore collectors and silicate depressants were tested. Water effects were different for each mineral-reagents) combination. In general plant recycle water decreased selectivity and increased reagent consumption. Interpretation of results is given in terms of electrokinetic effects, hydrolysis of cations, and mineral-collector interactions. Two techniques of treatment for plant recycle water, cation precipitation and zeolite adsorption were assessed. The former was found to be more effective under the tested conditions but recycle water continued to give poorer selectivity than the potable.INTRODUCTIONWater quality plays an important role in selective flotation. Specific effects have been reported by many workers (1-6) and in general the better the water quality the more selective is flotation. Water composition depends on origin and the minerals being processed. For example pulp containing salt-type minerals (calcite, apatite, dolomite) will contain more Ca and Mg cations than that from a sulphide deposit. Another source of water contamination is the flotation reagents added to the pulp, particularly if water recycling is practiced."

Jan 1, 1986

By W. J. Birch, L. Bermingham

Air overpressure is becoming an increasingly problematic issue within the quarrying industry. With blasting operations moving ever closer to residential properties, the number of complaints about air overpressure is beginning to increase. It is therefore important for operators not only to have a greater understanding of the blasting parameters that give rise to air overpressure but also the factors which have an effect on air overpressure levels as it attenuates with increasing distance from the location of the blast.

Jan 1, 2013

By Anastasia M. Suchowerska

The design of effective ground support requires a sound understanding of the pre-mining state of stress in the stratum to be mined. Irregularities in the stress field encountered during multiseam mining are governed primarily by the previous mining in the surrounding strata. The aim of this study is to quantify the effects of rock mass transverse isotropy on the vertical stress redistribution in the rock strata beneath supercritical longwall panels. Wilson?s equations for determining the stress distribution induced in and beyond a single longwall panel after it has been mined have been adopted, and a plane strain finite element analysis of an elastic medium, together with the stress changes predicted by Wilson, was used to calculate the final pre-mining stresses in the underlying strata. Values of the independent shear modulus (G¢) of the rock strata, ranging from 0.1 to 1 times the isotropic shear modulus (Giso) in the plane of the strata, and a Poisson?s ratio (?) of 0.25 have been investigated. The key finding of this study is that the predicted magnitude of vertical stress in the transversely isotropic strata beneath a mined supercritical longwall panel is larger and changes more quickly with horizontal distance than is the case for an isotropic rock mass. This finding is of significance for the design of ground support measures in multi-seam mining operations.

Jan 1, 2012

By X. B. Zhao, J. G. Cai

When stress wave propagates through fractured rock masses, the wave will be slowed and attenuated due to the presence of these fractures. If the amplitude of stress wave is large enough to mobilize nonlinear deformation of these fractures, they will present different effects on one-dimensional P-wave propagation compared with those of linear deformational fractures. The static BB model is adopted to describe the nonlinear deformational behavior. Method of characteristics combined with displacement discontinuity theory is used to build analytical solutions of wave particle velocities and wave stresses. These equations are numerically solved with sufficient accuracy.

Jan 1, 2003

By Wenbo Luo, Kang Liu, Jilai Xue

"Coal fly-ash(CFA) from thermal power plants is rich in Al2O3, which has great potential as an alternative resource for alumina production. In this work, Alz03 contained in the coal fly-ash was extracted using an acid sintering-leaching process. This process was enhanced by aid of power ultrasound during the leaching. The recovery rate of Al2O3 was increased with ultrasound, compared with the similar process without ultrasound under the identical operation conditions. Leaching temperature can be lowered by about 10-l5°C and the processing time reduced by about 50%. The process kinetics were investigated in details for a better understanding of the fundamentals on the effects of power ultrasound. The obtained results demonstrate the potential application in reducing processing energy and increasing production rate.Introduction Coal fly ash is a typical solid waste generated from coal combustion in thermal power station. Vast amount of CF A accumulation lead to serious environmental problems such as air and water pollution, cropland occupation, radioactive contamination, etc. However, CFA is rich in Al2O3 and SiO2 content, so that it has a potential use as recourses for alumina and silica production [1]. Aluminum industry, especially in China, has made a rapid expansion in recent years accompanying with a large amount of bauxite consumption, resulting a urgent demand to develop secondary alumina resources like CF A to maintain a sustainable development of aluminum industry that faces grim challenge [2].Acid leaching is an efficient technology to use in alumina extraction from CF A. Since the particle of CF A is not naturally existed mineral but was formed in molten state at high temperature, the internal Al-O-Si bonds are so strong to separate alumina from the ash particle. Because of this reason, the direct acid leaching [3-6] operated at ambient temperature has low extraction efficiency, approximate 30% to 40%, which is attributed to self inhibition effect from CaS04 generated by reaction between CaO and H2S04 [7-8]. High pressure leaching can efficiently decompose mullite to release A12O 3 content in the fly ash particles, but this requires autoclave material having strong acid corrosion resistance, high temperature (100°C-300°C) and pressure (1.0MPa-2.SMPa) resistance while its operating security is low and its acid consumption is large [9]. Concentrated acid boil process is conducted at near acid boiling point (200 °C - 300 °C) in 4 mouth flask wrapped by electric heating jacket with high mass ratio of acid and ash to achieve high Al203 recovery rate from CFA. Its disadvantages are similar to the high pressure leaching technology except no-pressure, and also the operating solution at nearly boiling point acid may easily spill and splash with additional acid loss and potential safety hazard [10]."

Jan 1, 2014

By B. C. Qi

"In water treatment, flocculation or coagulation with aluminium or ferric salts has been widely used for many years to remove natural organic matter (NOM), including humic acids. However, the adsorption of NOM to aluminium hydroxide flocs during conventional coagulation/flocculation processes is very complex, with the flocculation of aluminium hydroxide particles and the adsorption of NOM molecules on flocs occurring simultaneously. Any effect on the surface characteristics and micro-structures of the humic acids and aluminium hydroxides could affect the adsorption efficiency.It has been widely observed that if a reaction system (liquid-liquid or liquid-solid) is exposed to an ultrasound field, under appropriate conditions, a variety of physical (emulsification, aggregation/flocculation) or chemical (the production of radical and exited species; single electrotransfer) actions may be activated. Though the ultrasound effects have been used in biological and chemical decontamination in many conventional environmental protection practices, the idea to explore the ultrasound effects in the removal of humic acids by preformed aluminium hydroxide flocs is relatively new. In this paper, the effect of an in-situ ultrasonication on removal of the humic acids extracted from the acidification fermentation of lignocellulosic residues, by a preformed aluminium hydroxide, was evaluated; the effect of ultrasonication on the surface complexation of the humic acids with the preformed aluminium hydroxides was investigated."

Jan 1, 2003

By L. Yuan

In the U.S. coal mining industry, most spontaneous combustion fires occur in longwall or worked-out gob areas. In order to reduce the fire hazard caused by spontaneous combustion, it is important to understand how ventilation and gob characteristics affect the spontaneous heating process. Given the difficulty to conduct field tests in such an environment, a computational fluid dynamics (CFD) study was conducted to investigate the effects of ventilation and gob characteristics on the spontaneous heating process in longwall gob areas. Two longwall panels with a bleeder ventilation system were simulated. The spontaneous heating is modeled as the low-temperature oxidation of coal in the gob using the Arrhenius rate law and kinetic data obtained from previous laboratory-scale studies. The heat generated from the spontaneous heating is transported by convection and conduction, and oxygen and the oxidation products are transported by convection and diffusion. Unsteady state simulations were conducted with different ventilation conditions and gob permeability distributions. The ventilation parameters varied in the simulations are the pressure at the bottom of the bleeder shaft and regulator resistance in the second entry inby the longwall face.

Jan 1, 2009

By S. K. Kawatra, S. J. Ripke, T. C. Eisele

"An estimated 600,000 tons of bentonite clay are used annually in the U. S. as binder for production of iron ore concentrate pellets. Since this is a significant cost item for the plants, and the addition of bentonite to the pellets contributes undesirable silica into the finished pellets, there is considerable incentive for finding methods to reduce bentonite use. One way to reduce bentonite levels is to selectively use those bentonites that are most effective in this application, so that a lower dosage will still produce a sufficiently strong pellet. Unfortunately, there are no satisfactory methods available for accurately predicting which bentonites are actually most effective, short of using them to actually make pellets. One of the popular methods for attempting to evaluate bentonites is the “Plate Water Absorption” (PWA) test. While some plant operators accept the PWA results as indicating the relative quality of bentonites, others disagree and claim that, over a fairly broad range of values, PWA does not correlate with bentonite performance.Since both Ca+2 and Mg+2 ions are known to reduce the swelling and water absorption capacity of bentonite, it was believed that the presence of these ions in plant recycle water could be changing the bentonite performance. Since the standard PWA test uses only distilled water for its measurements, it could not detect these effects. Experiments were therefore carried out on a number of different bentonites using a modified PWA tests, with plant recycle water replacing the distilled water. These experiments showed little effect of the plant water on the PWA value, and chemical analysis of the water showed that the levels of dissolved salts were quite low.Water and accompanying salts were then extracted from a magnetite concentrate filter cake by rinsing with distilled water. Analysis of this water showed an extremely high level of dissolved salts, particularly salts of calcium and magnesium. When concentrations were compared with the recycle water from the plant filters, it was determined that levels of Ca+2 and Mg+2 retained in the filter cake were over 500 times higher than levels in the recycle water. This extreme elevation of soluble salts in the filter cake is believed to be due to adsorption of these ions into the electrical double layer of the magnetite particles."

Jan 1, 2003

By Ch. D. Taylor

Past studies with blowing face ventilation systems have shown that using a machine-mounted scrubber and water sprays can reduced methane levels at the face. The current research was conducted to determine how the sprays and scrubber interact to reduce methane levels, and what spray configurations provide the best face ventilation when used with a scrubber. Testing was conducted in a ventilation test gallery designed to simulate a full-scale mine entry. In the entry, a model mining machine, equipped with a simulated dust scrubber and water spray systems, was located at the face of a 6.1 m (20 ft) box cut. Face ventilation was provided by a blowing curtain located 12.2 m (40 ft) from the face. Methane released from a manifold at the face was measured at six locations near the face to compare the ventilation effectiveness of the spray systems while operating with and without the scrubber. Airflow movement across the face was affected by the spray configuration and scrubber operation. Average face concentrations were lowest when directed sprays were used with the scrubber. Varying the direction of the scrubber exhaust affected face methane levels.

This study was conducted to determine the effects of a machine-mounted scrubber and water sprays on face methane levels. Testing was conducted in the NIOSH ventilation test gallery which was designed to simulate a full-scale mine entry. In the test entry, a model mining machine, equipped with water sprays and a simulated dust scrubber, was located at the face of a 20-ft box cut. Blowing ventilation was provided using a curtain with a 40-ft setback distance. Methane released from a pipe manifold located inby the mining machine was monitored at six locations that were 1 ft outby the pipe manifold. Tests were first conducted to evaluate the effects of using sprays and scrubber separately on face methane levels. Additional tests were conducted to determine how a scrubber used with various water spray systems would affect face methane levels. The use of either sprays or scrubber reduced face methane levels significantly. The combined use of sprays with the scrubber further reduced face methane levels a small amount. Primarily the sprays affected methane levels by changing airflow distribution close to the face.

This study was conducted to determine the effects of a machine-mounted scrubber and water sprays on face methane levels. Testing was conducted in the NIOSH ventilation test gallery which was designed to simulate a full-scale mine entry. In the test entry, a model mining machine, equipped with water sprays and a simulated dust scrubber, was located at the face of a 20-ft box cut. Blowing ventilation was provided using a curtain with a 40-ft setback distance. Methane released from a pipe manifold located inby the mining machine was monitored at six locations that were 1 ft outby the pipe manifold. Tests were first conducted to evaluate the effects of using sprays and scrubber separately on face methane levels. Additional tests were conducted to determine how a scrubber used with various water spray systems would affect face methane levels. The use of either sprays or scrubber reduced face methane levels significantly. The combined use of sprays with the scrubber further reduced face methane levels a small amount. Primarily the sprays affected methane levels by changing airflow distribution close to the face.

Jan 1, 2001

By John L. Ellenberger, Gabriel S. Esterhuizen

Observations of pillar conditions in limestone mines showed that the presence of weak bands in the limestone can result in pillar damage at stresses that are lower than one would otherwise expect. The objective of this National Institute for Occupational Safety and Health study was to investigate the mechanism of failure caused by the presence of weak bands by using a series of numerical models based on realistic physical properties. The effect of the weak bands on pillar strength was also investigated by developing a series of pillar models with different width-to-height ratios and determining their strength by simulating a servo-controlled loading condition. The material properties of the bands and the limestone were varied and their effects on pillar strength were determined. Model results demonstrated failure development similar to the pillars observed in the field. The weak bands were seen to develop tensile stresses in the limestone as they extrude under increasing stress. The limestone fails in tension at a much lower stress than its expected uniaxial compressive strength. The results showed the load bearing capacity of the pillars can be reduced significantly by the presence of multiple thin weak bands. The degree of strength reduction is largely dependent on the compressive strength, the frictional resistance and the thickness of the weak bands. Single weak bands do not affect pillars as severely as multiple bands. However, the model results show that a single thick weak band, which comprises more than about 2 percent of the pillar height, can cause a significant reduction in pillar strength. The weakening effect of the bands become less severe as the pillar width-to-height ratio is increased. Field observation of spalling and failure associated with weak bands in limestone pillars show that the failure mechanism in the models resembles the observed failure. The model results provide insight into the important factors affecting pillar strength in the presence of weak banded materials.