Search Documents

By E. H. Smith

"The El Indio mine treats a complex mixture of copper and gold/silver ores at its plant located in the high Andes in Chile. The plant utilizes conventional crushing, grinding and flotation to produce a copper/gold/silver concentrate. Due to high levels of arsenic and antimony, the flotation concentrate must be roasted prior to custom smelting. The flotation tailings is leached and additional gold recovered from a CIP circuit. Present and future metallurgical developments are discussed in this paper. INTRODUCTIONIn late 1989, LAC Minerals purchased 65 % of Bond International Gold and as a result became controlling shareholder of the El Indio Mine through Bond and San Jose.El Indio is a world class, complex sulphide gold deposit located in the hydrothermal alteration belt of the Andes mountains in the 4th Region of Chile. The mine is located in the high Andes about 185 km east of La Serena at an elevation of 4000 meters. The 1450 workers at El Indio live in the mine camp at 3200 m and on days off are bussed to La Serena.The El Indio mine was started in 1979 by St. Joe Minerals Corp., bought by Bond in 1987 and subsequently by LAC in 1989. The mine has produced 2.7 million oz. of gold, 9.5 million oz. of silver and 170,000 t of copper since start of operation. The mill is currently operating at a rate of 2850 t/d and producing a copper/gold concentrate which is roasted to produce a copper/gold calcine and high quality, saleable crude AS2O3 . A small proportion of the precious metals are also produced as bullion from the leach circuit.Total production during 1989 was 224,197 ounces of gold, 1,309,342 ounces of silver and 26,968 tonnes of copper. The average cash cost of production for the period was U.S. $96 per ounce of gold, net of by-product credits. The average realized price was $5. 30 per ounce of silver and $1.14 per pound of copper."

Jan 1, 1991

By Antonio A. Cristóvão, Alexandre Pinto

"Abstract Deep foundations of buildings using driven ductile iron micropiles TRIM solutions, leads to recognized advantages, from technical, schedule and economic points of view. High production rates together with the possibility of using conventional equipment, duly adapted, confer this solution a high versatility.The aim of this paper is to describe the main design criteria adopted for the foundations of the Church ""Nossa Senhora dos Navegantes"" building in Lisbon - Portugal. In addition, results of a full scale load test carried out at site are presented, confirming the adequacy of the solution to the geological and geotechnical scenario, which is characterized by the proximity of the Tagus River Basin as well as the presence of heterogeneous landfill material and alluvial layers of soft clay (muds).1. INTRODUCTION Located on the right bank of the Tagus River, in Lisbon, the new Church building of ""Nossa Senhora dos Navegantes"", patroness of fisherman and navigators, with three or four upper floors, is surrounded by a school and by new residential buildings.The Tagus River basin is known by its alluvial soft soils, achieving, in certain areas, more than 50m meters depth, challenging the construction of new facilities due to the significant unfavorable geotechnical conditions.With a modern an unusual architecture, allusive to the ships used by the Portuguese navigators, the building has a reinforced concrete structure, with one basement and three upper floors. A bell tower with about 40m high, emerging from the structure, marks the landscape with the presence of this religious building (figure 2).For all the reasons previously described, geotechnical engineers play a crucial role on the design of valid foundation solutions, from both technical and economic point of view. Ideally, the solutions adopted should be supported by full scale load tests, performed at site, so that design assumptions could be verified and adjusted on time."

Jan 1, 2014

By S. K. Mitterecker, T. Hofbauer, F. Baerhold

"Acid regeneration is a very important process step in each acid leach circuit. It is required to recover dissolved metals and HCl from spent leaching acid. Andritz Metals presents its recently commissioned spray roast pilot plant. The facility is now available for testing and demonstrating acid recovery or metal oxide production which is a requirement in several flow sheets under development for the mining and specialized oxides industries. Results from pilot test campaigns are reported here. We are currently focusing on a nickel ore leaching process, which requires both a feasible iron control and acid regeneration step. In addition, we disclose the results of a magnesium ore and aluminium recycling test campaign conducted in our pilot plant facility.INTRODUCTION Hydrochloric acid regeneration is widely used in the steel industry to regenerate spent pickle liquors into hydrochloric acid at a typical concentration of 18 wt.%. Andritz Metals (formerly known as Ruthner) has built more than 200 acid regeneration plants worldwide (Andritz Metals brochure). As technology leaders Andritz also has vast experience with specialty metal oxide plants, producing metal oxides such as aluminium oxide (Al2O3), magnesium oxide (MgO), nickel oxide (NiO), cobalt oxide (Co3O4) and mixed oxides from metal chloride solutions (Baerhold F., Lebl A., Starcevic J., 2006), (Jedlicka, H., n.d.), (Ruthner M.J., Krischner H., 1973), (Ruthner Ind. Planungs AG, 1967). Hydrochloric acid leach circuits have been developed and proven in the industry for many years. Examples of industrial applications are: synthetic rutile production (TiO2) (Walpole E.A., Winter J.D., 2002), Quebec Iron and Titanium’s UGS process (Patoine M.-C., De Mori A., Borowiec K., Coscia C., 2002), magnesium and potassium production (Priemer H., 1973) and Goro Nickel (Vahed A., Colton D.F., Duterque J.P., Karner W., Baerhold F., 2004), (Taylor A., 2013). One of the critical process steps in developing a hydrometallurgical process is acid regeneration, as it is an economic requirement to recover both the dissolved metals and acid (commonly HCl) from the spent leaching solution."

Jan 1, 2016

By Dorsey Lyon

I. INTRODUCTION. In presenting, this paper the writers wish to call attention first of all to the fact that the electric furnace was not developed as a competitor of the combustion furnace, but: 1. For the purpose of doing high-temperature work which it is not possible to do in the combustion furnace; and 2. For the treatment of ores from deposits which. are located in regions where fuel is scarce and costly, and where hydro-electric power is comparatively cheap, as is the case in Chili, in Canada, in certain parts of this country and Mexico.. This paper is not presented with the idea of trying to. prove that the electric furnace should replace the reverberatory or the blast furnace as used at present in the smelting of copper ores, but that it may be substituted for their in those localities which are not favorable to them,) and where either of the two following conditions may exist: (a) A district remote from railway transportation. facilities, and where there is a deposit, or deposits, containing sufficient values to warrant their being worked, but which, due to the cost of getting coke in for operating a smelter and of getting ore out to a smelter, have to remain unworked.. And where, on the other hand, there is plenty of water power which call he developed at reasonable cost for the production of electric power, by the use of which for. smelting the ores in an electric furnace, with subsequent Bessermerization if necessary, a concentrated product may be obtained, which can easily stand the necessary transportation charges. (b) Or,. comparatively speaking, the transportation facilities may be all right, but the cost of fuel be too great to permit of the ordinary methods of smelting, whereas,- on the other hand, hydro-electric power can he developed: in the district at a, low cost,, and the ores could be smelted by the electric furnace at a cost. that would make their treatment possible. With these possibilities in mind we have attempted to make a brief comparative study of the problem for the purpose of aiding those interested in the subject, in determining whether it would be possible metallurgically, and feasible commercially; to use the electric furnace-in those localities where, by reason: of excessive fuel costs, the cost, of operating the furnaces for smelting copper-ores. is either excessive or prohibitive. Although the smelting of copper ores in the electric furnace has received considerable attention and more or less experimental work has been done, so far as: we lire: aware there ate no electric furnaces in the United States which are' being worked on copper ores. In Norway, however, trial smeltings of copper ores with an electric furnace of 1,000 h. p. and an estimated producing' capacity of 2,000 tons per annum, have been

Jan 8, 1913

By David K. Hylbert

This study investigated roof falls in room-and-pillar drift coal mines in eastern Kentucky and utilized geologic methods for predicting roof conditions in advance of mining. In the Highsplint mine, the roof was classified in four categories or conditions: Condition A and B (Laminated Shale), Condition C (Rolling Sandstone with Shale in Pockets) and Condition D (Zone of Major Sandstone Roll(s)). Structure contour and isopach maps of the Darby coal bed and associated immediate roof rocks were used to project axial trends of the sandstone roof. Trend mapping in the mine and on outcrop provided more detailed control for roof projections.

Jan 1, 1978

By R. C. Earlougher

Jan 1, 1970

By C. G. Buttleman, W. C. Brice

In Minnesota, reclamation of active aggregate mining sites is primarily regulated through local permits issued at the county, township, or municipality. However, for abandoned or depleted aggregate mining sites, a responsible party for reclamation is often no longer available. Since 1995, the Minnesota Department of Natural Resources has reclaimed several abandoned aggregate sites using innovative public/private partnerships and emphasizing native plant materials. The purpose of these projects is to demonstrate cost effective reclamation methods that can be utilized by both aggregate operators and local government and to promote mine planning and resource identification as it relates to reclamation.

Jan 1, 2000

By A. L. Service

Idaho has nearly 6 billion tons of potential sources of phosphorite, 10 to 31 percent P2O5' above and within 100 feet below entry level, the largest potential of any State in the United States. In 1963 Idaho ranked third after Florida and Tennessee in total mine and marketable production of phosphate rock; Montana ranked fourth. This report describes phosphate deposits, mines, and prospects in 10 districts covering most of the Idaho phosphate field. All mine production of phosphate rock in Idaho comes from surface mines and is processed to phosphate fertilizers, phosphoric acid, and elemental phosphorus. Producing districts are Fort Hall (Gay mine), Trail Creek (Conda and Ballard mines), and Crow Creek (Georgetown Canyon mine). FMC Corp. and J. R. Simplot Co. at Pocatello have the largest elemental phosphorus and fertilizer production facilities, respectively, in the State, followed by Monsanto Co. and El Paso Natural Gas Products Co. (formerly Central Farmers Fertilizer Co.). The only other major phosphate processing plant in the State is the phosphoric acid and phosphate fertilizer complex at Kellogg operated by the Bunker Hill Co. In 1963 a plant was constructed and put on line at Monsanto, Idaho, to recover vanadium from ferrophosphorus produced by electric furnace operations in the area. El Paso Natural Gas Products Co. completed construction of a fertilizer and phosphoric acid plant near Conda in 1965. There is a small fertilizer plant producing phosphate fertilizers for local consumption in Soda Springs.

Jan 1, 1966

By T. P. Mucho

Strata behavior and support performance were evaluated in a longwall tailgate test area at the Eagle Nest Mine near Van, WV. The mine operates in the Eagle coalbed which ranges in height from 4 to 6 ft (1.2 to 1.8 m) on the mine property. Rugged topography results in rapid changes in overburden which ranges from 200 to 1200 ft (61 to 366 m). The immediate roof at this mine transitions from sandstone to shale. In some areas the sandstone appears to be massive while in many locations it is highly laminated, fossilized, and interspersed with coal streaks. Horizontal stress levels appear to be sufficient to create instabilities in the roof in some locations, especially where the roof is thinly laminated. Traditionally, hardwood cribs have been used at the mine to provide secondary support for longwall tailgates; Strata Products' Hercules cribs are installed on 8 ft (2.4 m) centers staggered left and right in the tailgate entry. In a 250 ft (75 m) tailgate test area, however, cable bolts were installed in lieu of cribs. The bolts were 12 ft (3.6 m) long tensionable cables anchored with 5 ft (1.5 m) of resin. Four cables were installed across the entry and rows were spaced on 6 ft (1.8 m) centers. Primary roof support was maintained in the vicinity of the test area using 42 in (1.1 m), grade 60, No. 6 (19 mm diameter) resin bolts installed on 4 ft (1.2 m) centers through T-2 channels. The cable test area was located under a stream valley in an area of relatively shallow overburden. Strata instabilities consistently had been associated with the stream valley in both the Eagle and the overlying Powellton coalbeds. In an effort to further expose the cables to the most difficult stress conditions available at the time of the test, the specific site chosen was directly beneath a barrier pillar remaining in the upper Powellton mine (approximately 150 ft (45 m) of interburden separates the two coalbeds).

Jan 1, 1996

By D Frost, G Harbort, T Lipiec, N Deonarain

"The use of flotation columns has remained a contentious issue among mill operators. There are those who consider them an essential part of any mineral processing operation, while others consider them a necessary evil, which should only be installed if there is no alternative. Lastly, there are those who believe they should not be installed, no matter how great the perceived benefit.This paper provides an analysis of over 4000 installed flotation columns, contained in the Amec Foster Wheeler flotation database. Changing trends in column flotation use by type, commodity and geographical region are discussed. The effect of changing commodity prices and the China ‘phenomenon’ are reviewed. Special reference is made to the changing face of column flotation in Australia.Of note is the fact that after falling to a 20 year low in installed flotation column capacity in 2014, flotation columns during 2015 went through a resurgence in popularity. This resurgence was in direct contradiction to depressed metal prices and was driven by brownfield optimisations to reduce off-site costs, particularly in base metals. A case study is presented comparing the benefits of column flotation at high commodity prices with low commodity prices.Citation:Harbort, G, Deonarain, N, Frost, D, Lipiec, T and David, D, 2016. Changing Trends in Column Flotation Use - Their Impact for Australian Mill Operators, in Proceedings 13th AusIMM Mill Operators’ Conference 2016, pp 93–104 (The Australasian Institute of Mining and Metallurgy: Melbourne)."

Oct 10, 2016

By D. A. Greenwood

Dr David Greenwood opened the first technical session of the conference by highlighting the diverse nature of the papers in this session but drawing attention to the common theme that each solved a particular problem. PAPER 1.1 Tony Elliott introduced his paper on deep mix-in-place soil/cement stabilisation by stressing its simplicity. The engineering solution adopted at Elland was detailed in his paper and had formed the key to success of the project. The process itself is not widely used or known in the UK, although it has the potential to achieve significant benefits, subject to proper engineering control being exercised. It was explained that although the concept was not new, development of the technique for soil modification was relatively recent. The alternatives to mechanical mixing are injection, which is very dependent on soil type, site geometry, etc, and jet grouting; both processes are soil-responsive, and not easily monitored or programmed, difficulties which can largely be overcome by mixing. To achieve this at depths to say 30m requires high-powered, high torque machines and has resulted in significant equipment development.

Jan 1, 1991

By D. I. Bleiwas

Bureau of Mines personnel evaluated the potential availability of nickel from 151 deposits in 18 market economy countries and selected 126 for detailed analyses. An evaluation was made of tonnage-cost relationships indicating the quantity of nickel available at various total costs of production expressed in dollars per pound nickel, including a 15-pct rate of return on the invested capital. The 126 deposits studied contain approximately 73 million metric tons (t) of nickel. An estimated 52 million t is available from laterite deposits, of which less than 2 pct could be produced at $3.50/lb Ni, about equal to the average published price of nickel in 1981. Approximately 21 million t of nickel is available from sulfide deposits, of which about 10.0 million t can be produced at $3.50/lb. Sensitivity studies performed for both laterite deposits and sulfide deposits indicate that the total cost of nickel from laterites is most sensitive to increases in energy costs, and that sulfides are most sensitive to increases in labor costs; sulfides are also sensitive to changes in byproduct revenues. In 1983 the Nickel Mountain mine in Oregon was the only U.S. producer, though development continued on the Gasquet property in California. Of the total 5.1 million t of recoverable nickel in the United States, about 20 pct is available at or below $3.50/lb.

Jan 1, 1984

By M. Lu, E. Broch

Abstract: The formation and mechanism of rock cavern roof arches are studied and effects of rockbolts reinforcement are evaluated. It is concluded that a self-supported roof arch may be formed by the excavation. To stabilize such a roof arch, fully grouted rockbolts are effective. Tensioned cable anchors may have a negative influence on the arch stability. Zusammenfassung: Die Formation und der Mechanismus von Deckenbögen in Bergkavernen wird studiert und der Effekt von Verstärkung mit Bergbolzen wird bewertet. Es wird festgestellt, dass die Exkavation einen selbst-stützenden / freitragenden Deckenbogen formen kann. Eingegossene Bergbolzen sind effektiv um einen solchen Deckenbogen zu stabilisieren. Spannkabel können unter Umständen eine negative Einwirkung auf die Stabilität des Bogens haben. Résumé: Le mécanisme et la formation de voûtes dans les cavernes rocheures sont étudiés et l'effet du renforcement par boulonnage est évalué. Nous arrivons à la conclusion qu'une voûte autosupportêe peut être formée par excavation. Des boulons entièrement scellés par coulis de bêton s'avèrent efficaces pour stabiliser de telles voûtes. Les tirants d'ancrage peuvent quant à eux nuire à la stabilité de la voûte.

Jan 1, 2003

By Hidenori Hatta, Takero Watanabe, Hideo Yoshida

"The effect of the quenching rate on age hardening in an Al-6.0mass%Zn-0.75mass%Mg alloy sheet was investigated. The quenching rates and aging conditions were as follows: water quenching (WQ) or furnace cooling (FC) followed by pre-aging at 20°C,then artificial aging at 120, 160 or 200°Cwere performed. The peak strength of the FC and the WQ are very similarat120°C aging. It is important high strength was obtained even at the extremely slow quenching rate. On the other hand, the strength of the WQ significantly decreased compared to the FCat200°C aging. GP(I) zones were formed during the pre-aging at 20°C even if the cooling rate was very slow like the FC, and were transformed into the GP(II) ones at 70°C or higher and then into the ?’ phase. However, these zones were dissolved by reversion during heating to 200°C. Thus the strength of the WQ decreased. On the other hand, it is considered that an unknown cluster or GP zone with a thermal stability formed during the FC was not dissolved up to 200°C and was transformed into the ?’ phase. Therefore, a higher strength was obtained in the FC for the200°Caging.INTRODUCTIONAl-Zn-Mg alloys are widely available in commercial production because these alloy have lower quench sensitivity and can be produced by air cooling (AC). Heat treatable aluminum alloys are usually produced by water quenching (WQ) to increase their strength because a high cooling rate inhibits the precipitation of the stable phase during cooling and increases supersaturated solute atoms. However, Baba(1967)reported the strength of an Al-6%Zn-1.8%Mg(mass%) alloy without additional elements quenched by very slow cooling (15°C/min) was 96% of that quenched by WQ. Furthermore,the age hardening at room temperature (RT) occurs after annealing at 410°C followed by furnace cooling (FC, 0.5ºC/min or less)in these alloys. Therefore, the process of annealing at 410 to 430°C for 120 min followed by AC, and reheating at 230°C for 240 min, then cooling is recommended in the specifications (Japan Aluminum Association, 2011). Matsuda and Yoshida(1996)also recommended annealing at 300°C for Al-Zn-Mg alloy extruded products to inhibit age hardening at RT by precipitating the solute atoms and decreasing them in the matrix. It has been considered that the higher the content of excess quenched-in vacancy becomes by WQ, the higher aging rate at RT is obtained. Therefore,it is theoretically and commercially important to clarify the reason why the age hardening occurs relatively quickly in almost no excess quenched-in vacancies such as the FC, and why the same strength as the WQ can be obtained in the FC"

Jan 1, 2018

By R. Katzenbach, M. Vogler, U. Adamietz

Abstract The design of deep excavation pits in rock mass is dependent as well on the mechanical properties of the rock mass as for example the orientation and the type of discontinuities like bedding planes, joints and fissures, the length of the discontinuities (persistence), the grade of weathering, the strength of rock mass, and the shear strength in the discontinuities, etc., and also on the respective boundary conditions specific for the project, and here especially the geometrical boundary conditions. The basic mutual influences and interactions between these boundary conditions are explained and exemplary presented at an excavation pit with a depth of 18,5 m, situated at a slope with a surface near groundwater table. Résumé La planification des excavations profondes dépend aussi bien de la qualité mécanique du roc, par exemple la location de la texture de la surface de moindre résistance, le degré de rupture, le degré de décomposition, la dureté du roc et la résistance limitée au cisaillement de la texture de la surface de moindre résistance que des conditions limitées spécifiques pour le projet, ici en particulier des conditions limitées géométriques. Les influences et interactions essentielles et mutuelles entre les conditions limitées isolées seront expliquées et présentées à l’aide d’une excavation 18,5 m de profondeur, située sur une pente où le niveau des eaux souterraines est près de la surface. Kurzfassung Die Planung tiefer Baugruben im Fels hängt sowohl von den mechanischen Eigenschaften des Fels wie z.B. der räumlichen Lage des Trennflächengefüges, dem Durchtrennungsgrad, dem Verwitterungsgrad, der Gesteinsfestigkeit sowie der Scherfestigkeit des Trennflächengefüges als auch von den projektspezifischen Randbedingungen hier insbesondere von den geometrischen Randbedingungen ab. Die wesentlichen gegenseitigen Einflüsse und Interaktionen zwischen den einzelnen Randbedingungen werden aufgezeigt und an einer 18,5 m tiefen Baugrube in Hanglage mit oberflächennahem Grundwasser vorgestellt.

Jan 1, 2003

By Sachihiko Tokunaga, Hirofumi Taguchi, Kenji Maruyama, Hidenori Takahashi, Yoshiyuki Morikawa

"Abstract The present study proposed a new liquefaction countermeasure to improve sandy ground and conducted a trial execution. The new method is a floating-type and lattice-shaped cement treatment method, where cement-treated soil is not fixed to a non-liquefiable stratum. A fixed structure such as treated soil should be formed at the side of the floating-type treated soil to reduce its lateral displacement. In the study, one-dimensional dynamic response analyses were first conducted to confirm the mechanism of the new method. Then, a series of centrifuge model tests were performed to demonstrate the effect under a stress condition at the prototype scale. The analyses and model tests confirmed the effect of the liquefaction countermeasure. Finally, trial executions were carried out to confirm high-quality vertical execution.INTRODUCTIONLiquefaction induced by an earthquake generates sand boiling and ground settlement. Other problems have also been reported, including a decrease in bearing capacity and an increase in the horizontal earth pressure against retaining walls. To prevent these problems caused by liquefaction of the ground, various countermeasures have been proposed, such as cement deep mixing and high-pressure jet mixing methods. These methods have the big advantage of being applicable to ground that contains soil with a fine-grain fraction. Furthermore, the unnecessary displacement caused by the construction can be reduced. In Japan, a lattice-shaped cement-treatment method has frequently been used at many construction sites to prevent liquefaction, where cement-treated piles are intersected to form a lattice, as shown in Fig. 1. The lattice-shaped walls can reduce the shear stress generated by an earthquake, restricting the liquefaction at that location. However, the construction cost of the cement treatment is relatively high compared to other methods such as the sand compaction pile (SCP) method, and needs to be reduced. In particular, the cost of the high-pressure jet mixing method, which can be applied to the liquefiable ground under existing structures, is significantly high. Therefore, decreasing the total volume of the cement treatment is necessary to reduce the construction cost."

Jan 1, 2014

By Bruce Vandenberg, R. Frank Chiappetta, John Foley

Recent advances in solid-state, field portable, fast framing compact video camera systems and PC based frame capture hardware now allow blast imaging up to 1000 frames per second. Up to 4.1 seconds of data can be captured directly into the unit, downloaded to a PC or archived to a standard VCR without data compression. Since no film processing is involved, motion analysis can be performed instantly and on-site within a few minutes. This paper will describe the design features and applications of the MotionMeter system and compare these with the analogous aspects of film-based cameras and other systems. Of all blast monitoring systems and techniques available today, high-speed motion picture photography and videography still remain as the most valuable, stand alone, diagnostic techniques for troubleshooting and evaluating full scale blasts in the mining and explosives industries. High-speed image data, coupled with information obtained from other instrumentation systems, such as continuous velocity of detonation recorders, laser surveying systems, refraction and ground vibration recording seismographs, etc., can eliminate many assumptions about what actually took place in a blast. Thus, diagnostic confidence in evaluating both excellent and poorly designed blasts is increased, and optimum blast results, (which are application dependent), are achieved considerably faster when compared to the trial and error approach of relying on strictly the experience factor. Applications include developing site-specific blast designs, decay equations relating burden, burden velocity and explosive energy, determining ground response times, reducing coal damage, quantifying backbreak, evaluating the effectiveness of sternming, checking delay detonator firing times, evaluating air decks and for studying general dynamics. Motion analysis is performed with a 2D and 3D software package developed specifically for video analysis, but is also directly applicable to film analysis when using a digitizer. Dimensional controls, lens aberration, field set-ups and camera orientation are all automatically corrected for with matrix analysis.

Jan 1, 2000

By David A. Neudorf

Known resources of nickel laterites considerably exceed nickel sulfide resources and there is a growing consensus that most new nickel production will be sourced from laterites. The development of nickel laterite projects is very capital intensive due to inherently low grades, inability to concentrate ore prior to processing, complex processing technology and typically large infrastructure requirements. This has resulted in most recently proposed projects being "mega-projects," to achieve economics of scale. However, this may result in unacceptable project risk in many cases. Furthermore, many known laterite resources are not large enough to support a mega-project. This paper describes an alternative model for nickel laterite project development that allows, smaller scale and reduces capital exposure. The requirements of this model in terms of process technology, infrastructure and commercial innovation are described. Keywords: Nickel, Laterite, Project, Economics

Jan 1, 2004

We report the studies of Proton-Exchange Membrane Fuel Cells (PEM FC) and hydrogen storage materials at McMaster University for the last 14 years. From the initial investigation of ionic conduction mechanism to the revelation of the origin of non-Arrhenius temperature dependence, as well as the synthesis and characterization of high temperature polymer electrolytes, both experimental and theoretical works have been compiled for the fuel cell membranes. In addition to the discovery of suppressed ionic conduction in Electrode-Membrane Assembly (EMA) and novel hydrocarbon PEMs based on micro-emulsion, the first evidence of hydrogen adsorption saturation by carbon nano-tubes was also achieved, which has been the bottleneck for the application of PEM FC. Prior to our study, a number of controversial publications have claimed the hydrogen capacity of these materials to be between 0.1 to 10.0 wt.%, and none demonstrated a plateau of adsorption with pressure that is consistent with monolayer saturation. Others suggested that the tube bundle structure is opened under high pressure to enable higher adsorption on newly uncovered surfaces, but received no confirmation. Using our home made high-pressure instrument with in-situ electrical probes, we found that a plateau is nearly achieved at about 300 atm in the room temperature isotherm, and that nanotube bundles actually compress with pressure instead of splitting, using in-situ electrical measurements.

Jan 1, 2005

By I. Demers

Doyon mine, Quebec, Canada evaluates the possibility of desulphurizing their tailings to produce material to be used in as cover over the acid generating tailings disposal site. Laboratory tests were conducted and showed that a single-layer cover made of desulphurized tailings placed over reactive tailings can prevent the generation of acid mine drainage. Modelling with the software Vadose/W was undertaken to optimize the design parameters, namely cover thickness, water table position, and residual sulphide content of desulphurized tailings following laboratory work. It was found that the optimal configuration includes a 1 m desulphurized tailings cover containing 0.8%S, with the water table kept at the interface between the reactive tailings and the cover. To maintain the cover performance to reduce oxygen flux towards acid-generating tailings even in the event of a long dry period, a sand layer is suggested to protect the cover from excessive evaporation. It is possible to reach the environmental objective chosen for Doyon mine (10 mol/m2/year) with the protective sand layer, even in extremely dry conditions.

Jan 1, 2008