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By Pengfu Tan

Electric arc furnace (EAF) dust from the steel industries is listed by the United Sates EPA as a hazardous waste under the regulations of the Resource Conservation and Recovery Act due to the presence of lead, cadmium and chromium. The disposal of the approximately 650,000 tons of EAF dust per year in the U.S. and Canada is an expensive and unresolved problem for the majority of steel companies. The Waelz process has been considered as the best process for treating EAF dust. A process model, combined thermodynamic modeling with heat transfer calculations, has been developed to simulate the chemical reactions, mass and heat transfer and heat balance in the kiln. The injection of air into the slag and the temperature profile along the kiln has been modeled. The effect of (CaO+MgO)/SiO2 on the solidus temperature of slag has been modeled also and discussed. Some optimizing results have been presented in this paper.

Jan 1, 2005

By Heikki Jalkanen

The mineralogical composition and morphology of solidified copper smelting and converting slags are of some interest from slag cleaning (by froth flotation), impurity elimination, and environmental points of view. Properties result from both the state of molten slag before solidification and processes taking place during solidification and cooling. In solidification and cooling, copper and sulfur dissolved in molten slag are .precipitating substantially from the silicate phase. Even in water quenching of slag, dissolved copper is pushed out of the solution in the form of finely divided precipitate. Elements present in the raw materials are distributed in a distinct manner between the solidified slag and non-silicate solidification products. Arsenic, antimony, and tin are strongly accumulated in copper precipitate, but not the other metallic constituents common in copper concentrates. Smelting and converting slags differ remarkably on their mineralogical composition and morphology although resulting principally of same chemical processes. Converter slags are more inhomogenous; they often contain solid particles and copper content is .as a rule higher than in matte smelting slags. The final copper content of converter slags was observed to be in a distinct manner dependent on iron oxide - silica ratio. Slag forming, solidification, and precipitation phenomena are discussed on the basis of mineralogical and morphology analysis of smelter slags and laboratory scale experiments.

Jan 1, 2002

By Guomin Jiang

Potassium ferrate is an excellent multifunctional reagent for wastewater treatment, but its preparation is crucial. The improved hypochlorite oxidation method was used to prepare potassium ferrate in this study. Iron nitrate, the preferred iron source, was added into hypochlorite solution and then the stabilization agent was added during the purification process of product. The influence of available chlorine content, iron molecular proportion, reaction temperature and reaction time on potassium ferrate preparation was investigated. The optimal condition for potassium ferrate preparation is 15% of available chlorine content , 0.6 of iron molecular proportion , 30i of reaction temperature , 45min of reaction time. The yield of potassium ferrate is about 67% with high purity (> 99%). The structure and performances of the product was characterized by XRD, EDX, SEM, TG and IR and the results show that the prepared product is consistent with the properties of potassium ferrate(VI).

Jan 1, 2010

By Zhouhua Jinag

The attempt has been made to manufacture high nitrogen austenitic stainless steels by pressurized electro-slag remelting furnace with maximum nitrogen pressure of 7MPa. To obtain high nitrogen content in steels, the compound electrodes with different nitrogen sources (FeCrN, Si3N4) were prepared. Using the Si3N4 as the nitrogen alloying source, the silicon contents in ingots were prone to be out of the specification range, and the electric current fluctuated greatly and the surface qualities of the ingots were poor. The surface qualities of the ingots were improved using FeCrN as nitrogen alloying source. The sound and compact macrostructure ingot with the maximum nitrogen above 1.0wt% could be obtained. A series of high nitrogen austenitic stainless steels have been successfully developed by this method. The mechanical and pitting corrosion resistance properties of high nitrogen austenitic stainless steels were investigated. The results show that the steels exhibit excellent mechanical and pitting corrosion resistance properties.

Jan 1, 2009

By Alicia Esther Ares

The family of Zn-Al (ZA), Zn-Ag and Zn-Al-Ag (ZINAG) alloys offers high mechanical properties, ease of finishing, the advantage of low energy and pollution-free melting. Also, present alternatives to the well developed alloy systems, such as brasses, bronzes, cast irons and aluminum alloys. The main objective of this paper is to measure thermal parameters in ZA, Zn-Ag and ZINAG hypoeutectic and hypereutectic alloys directionally solidified which present columnar, equiaxed and columnar to equiaxed transition structures (CET). Also, estimate the mechanical properties, such as microhardness and tensile parameters and correlate these with the thermal (cooling rate) and structural parameters (grain size and dendritic spacing). The different types of structures were analyzed with optical and scanning electron microscopy. The results showed the influence of concentration, microstructural arrangement and thermal conditions during solidification on the mechanical properties. The results of the present investigation are compared with previous experiments.

Jan 1, 2010

By Xiao Caimei

The method of Substance Flow Analysis (SFA) provides a helpful tool for the study of the industrial metabolism of a certain metal within a regional level, such as copper, lead etc. In this paper the flows and inventory of cobalt in China, 2008, were traced with the STAF model, and the situations of production, fabrication and manufacturing, use and waste management in China were introduced. The result revealed that the resource of cobalt in China was so poor that a large amount of cobalt material or cobalt products needed to be imported, and there was lack of recycling of cobalt resources.0

Jan 1, 2010

By P. A. Olubambi1

Representative samples of the hydrothermal vein deposits of the bulk complex sulphide ore deposit, 10 km south of Ishiagu, in Ebonyin State, South Eastern part of Nigeria were collected from two small scale mining companies. The samples were mixed and successively crushed in a jaw crusher and cone crusher, and ground in a rod mill. Characterization was carried out with SEM, EDX, XRD, XRF and ICP-OES. Mineralogical analysis revealed the presence of sphalerite, galena, siderite, pyrite, quartz and chalcopyrite. X-ray Diffractometry showed that sphalerite mineral in the ore occurs as sphalerite ferrous with varied percentage of Zn and Fe within the various sizes while chalcopyrite occurs as a chalcopyrite group mineral with chemical formula Cu2MnSnS4. Results of the elemental analysis showed variations in elemental composition within the different sizes.

Jan 1, 2006

By Thomas Prietl

The use of gas stirring systems through the furnace bottom is common for anode and holding furnaces in the copper industry The first implementation of a gas stirring COP KIN® system in a Peirce-Smith converter was performed at the New Boliden smelter, Rönnskar, Sweden. In addition to other benefits, a decrease in process time and a decrease of the oxygen content in the blister copper were observed. To determine the effects of the gas stirring system and the process endpoint, an optical production control ?Semtech OPC system? was used. The light emission of the converter flame as an optical process parameter provides qualitative on-line process information, and is also used for endpoint determination of the slag making process, on-line control of iron content in white metal, quality control of slag etc. The results, benefits and risks of using the COP KIN® and OPC system for a Peirce-Smith converter are reported.

Jan 1, 2005

By Hamed Mirzadeh

The hot working behavior of 17-4 PH stainless steel was studied using the hot compression test at temperatures of 950-1150 °C with strain rates of 0.001-10 s-1. A step by step procedure for data analysis in hot compression test was given. The work hardening rate versus stress curves were used to reveal whether or not dynamic recrystallization (DRX) occurred. At low Zener- Hollomon (Z) parameter, this material showed a new DRX flow behavior, which was called Multiple Transient Steady State (MTSS). At high Z, as a result of adiabatic deformation heating, a drop in flow stress was observed. The general constitutive equations were used to determine the hot working constants of this material. Moreover, after a critical discussion, the deformation activation energy of 17-4 PH stainless steel was determined as 337 kJ/mol.

Jan 1, 2010

By David B. George

Kennecott Utah Copper adopted Outokumpu Flash Smelting and Kennecott-Outokumpu Flash Converting in 1995, a process based on granulating high grade copper matte. While nickel mattes and very small quantities of copper matte had been commercially granulated for years, no large scale copper matte granulation system had been built. This paper summarizes the history and benefits of copper matte granulation, the Kennecott design basis, the successful operation for over 10 years and potential problems inherent in some matte granulation approaches.

Jan 1, 2006

By Dongok Kim

Regardless of the advantages of the Friction Stir Process (FSP), for age-hardened aluminum alloys, the mechanical properties such as hardness in the stir zone decreased after FSP due to the growth or dissolution of strengthening precipitates. Here, as a new technique, FSP was introduced to alloy copper nanopowders in Al7075 T651. Mechanical properties of copper nanopowder- alloyed Al7075 T651 together with micro and nanostructures were compared with those of as-FSPed Al7075 T651 using SEM, TEM, and Vickers hardness testing to understand structure-property relationships. It was observed that Vickers hardness of the stir zone in copper nanopowder alloyed Al7075 T651 increased by 20% compared to that of the heat affected zone, while the as-FSPed samples did not show a noticeable increase in hardness in the same zone. Xray mapping showed traces of copper nanopowder after the process. TEM is being used to verify if there was CuAl2 formed in the copper alloyed sample.

Jan 1, 2006

By David R. Jessey

An ore microscopic and geochemical study of the nickel-cobalt occurrence in the Southeast Missouri Mining District has revealed several significant relationships. Siegenite [(Ni,Co)3S4] is the dominant nickel-cobalt sulfide in the ores, however, several other members of the thiospi¬nel group (AB2S4) occur: carrollite (CuCo2S4), nickelean carrollite [(Co,Ni,Cu)3S4], fletcherite [Cu(Ni,Co)2S4] and polydymite (Ni 3S4). In addition, bravoite [(Ni,Fe)S2], vaesite (NiS2), millerite (NiS) and gersdorffite (NiAsS) are present. Thiospinel composition varies dramatically within the district. Paragenetic studies have shown that the stratigraphically lowest thiospinels are the most cobalt-copper-rich. A detailed ore microscopic study of the AMAX Lead Company Buick mine has also shown significant changes in mineralogical association, texture and grain size of the siegenite along the north-south strike of the major ore bodies. Siegenite commonly replaces and veins chalcopyrite and is subsequently replaced by sphalerite. Less commonly, siegenite and chalcopyrite are observed to form linear replacements along sphalerite grain boundaries. The grain size of the siegenite varies markedly, but in a predictable north-south pattern that is consistent with a genetic model formulated from geo-chemical data. The compositional as well as textural trends displayed by the thiospinel mineralization could be exploited to optimize recovery of any or all thiospinels of economic interest.

Jan 1, 1981

By S. Prasad

The effectiveness of ultrasonic velocity measurements and attenuation of the propagating pulse was evaluated as a means of Non-Destructive characterization of cold worked and annealed copper. Commercial copper is subjected to mechanical working such as forging, rolling and thermal treatment to induce re-crystallization. The microstructural changes that occur in copper and a variation in its mechanical properties are subjected to analysis using the ultrasonic technique. The signal processing is carried out using the wavelet analysis technique. The features of wavelet analysis namely, localization in space and the presence of an infinite set of basis functions allows removing noise from the time series and components of a non-stationary signal to be analyzed. This is seen to improve the accuracy of the results obtained from the ultrasonic technique in the case of copper, which has distinct coarse grains that are difficult to inspect due to backscattering from the grain boundaries.

Jan 1, 2010

By P. A. Mahanwar

Flyash were melt mixed with nylon 6 at a 30wt% concentration. TYZOR® TPT, a coupling agent, was used to facilitate the link between filler and matrix. The morphological characterization, using SEM, revealed sufficient matrix residue on the filler surfaces thus confirming the strong interfacial bonding between the filler and the matrix on treating. Tensile, impact and the flexural properties of the composites were also improved with the incorporation of coupling agent. As flyash particles tend to impart a grayish color to the plastic, TiO2 pigment was employed to make the formulations aesthetic. The pigment was added to the filled system in 0.1, 0.5, 1.0, 1.5, 2.0 wt/wt ratios. Scattering of incident light and spectral reflectance was higher for smaller particle size flyash. Moreover an increase in the scattering with increase in pigment concentration indicates better dispersion of the pigment, which again is due to the presence of coupling agent.

Jan 1, 2006

By Varadarajan Seshadri

Geometallurgical characterization of iron ore which is a raw material for Iron making as in the case of charcoal blast furnaces operating in Brazil or for production of agglomerates such as iron ore sinter which serves as burden material for blast furnces of high productivity or pellets extensively used in the direct reduction processes all over the world in the iron and steel industry. Selection of proper raw material after due characterization should lead to an improvement of the productivity of the respective processes The usual classification of quality of iron ore is uniquely based on chemical analysis, granulometric and physical parameters. However not much emphasis has been given to the structural characteristics which also are important in the processes. Different typological categories of Brazilian iron ores have been used in the characterization . For instance, several kinds of hematite crystals like specularite, martite and microgranular hematite, etc with variable crystal sizes are found in the different ore types. They are also composed of different of fabrics and types of accessorial mineralogical constituents and have different porosities, pore diameters, etc which influence the cold and the hot agglomeration stages of the ore fines, and also chracteristics such as reducibility, decrepitation etc, important for assessment of quality of iron ores. . The first step for attaining a good characterization of ores is to know in detail about the structure of the deposit, shape of the body, types of iron ores and their distribution. This requires a geological-structural study and the mapping of the bodies using mineralogical criteria for typological classification of ores. followed by structural characterization of materials in stages of mining, comminution, screening and concentration processes. In this contribution a geometallurgical approach for quality control of Brazilian iron ores for sintering and pelletizing processes is highligted.

Jan 1, 2006

By Sutham Niyomwas

The Fe-TiC composite powder was synthesized in situ by carbothermal reduction of ilmenite. The standard Gibbs energy minimization method was used to calculate the equilibrium composition of the reacting species. The effects of the reaction temperature (1300 °C - 1500°C) and milling time of precursors on the Fe-TiC conversion and powder morphologies were investigated using XRD and SEM method. The synthesized products showed that composite with iron matrix and titanium carbide as a reinforced phase was formed.

Jan 1, 2006

By P. N. Anyalebechi

The effects of solidification rate on the cast microstructures of aluminum alloys 6009 and 6016 have been investigated with directionally cooled laboratory-size ingots, at 0.2-10.1 K/s and 0.4- 23.1 K/s, respectively. These ranges of solidification rate are within those observed in commercial-size ingots. In both alloys, the average dendrite cell size and second phase particle size decreased with increase in average solidification rate and with a decrease in average local solidification time. However, at comparable solidification rates, the dendrite cells and second phase particles are finer in the shorter freezing range alloy 6009 than in the longer freezing range alloy 6016. This is provisionally attributed to the earlier formation of second phase intermetallics at higher temperatures during solidification and to the formation of greater amount of the relatively coarse plate-like ß -phase (Al9Fe2Si4) phases in alloy 6016. In general, in both alloys, the types and relative amounts of the second phase particles in both alloys are independent of solidification rate.

Jan 1, 2006

By F. A. Guo

Ultrafine-grained surface layers were obtained by surface mechanical attrition treatment (SMAT) in copper and titanium samples. The thermal properties of the deformed layers were characterized using a scanning thermal microscopy (SThM) that allows thermal conductivity to be mapped down to the submicrometer scale. A theoretical approach, based on this investigation, was used to calculate the heat flow from the probe tip to the sample and then estimate the thermal conductivities at different scanning positions. Experimental results and theoretical calculation demonstrate that SThM can be used as a powerful tool for the thermal property and microstructural analysis of ultrafine-grained microstructures.

Jan 1, 2006

By Y. Zhoa

The surface morphology of materials is of fundamental importance to many surface related applications, such as wetting, friction, reflection, drag, and adhesion. Various approaches for micro/nano patterning atop polymer surfaces have been proposed in recent years. However, a cost effective technique is still highly in demand. In this paper, we demonstrate a novel but rather simple and generic approach for surface micro/nano patterning using shape memory polymers (SMPs). Different types of novel patterns are realized and their 3-D surface features are quantitatively analyzed by a PLµ Confocal imaging profiler.

Jan 1, 2010

By Omid Lashkari

Keywords: SEED, SSM materials, Microstructural evolution, Rheology, Swirling Speed SEED (Swirled Enthalpy Equilibration Device) is established itself as a new technology amongst the many Semi-Solid Metal (SSM) processes, where swirling of the mush plays an important role in modifying the dendritic structure of as-cast parts. A range of semi solid metal structures, dendritic, rosette and/or globular morphology of primary phase, can be prepared using SEED. The current article reports on the application of rheological tests in characterizing microstructural evolution during SSM processing of 356 Al-Si foundry alloy. A simple parallel plate test machine, designed and constructed at our labs, was used to determine viscosity values for each structure and identify the optimum structure with superior die filling characteristics. Such findings have important technological and economical implications during high pressure die casting of semi- solid metals. The strain-time graphs for 356 Al-Si foundry alloy indicated lower viscosity values for globular microstructure, i.e. improved die filling.

Jan 1, 2005