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By K. -I. Higuchi, M. Mizutani, K. Haga, A. Shibayama, A. Batnasan

In recent years, the quality of iron ores has decreased due to the increase in the content of impurities, namely quartz, aluminum, phosphorus, and sulfur. It indicates that the removal of impurities from iron ore is an extremely challenging task. In particular, the high amount of phosphorus in iron ore could be a problem for energy consumption and CO2 emission in the steelmaking process. To reduce the impact of phosphorus, mainly two approaches: the utilisation of low-phosphorus iron ore, or dephosphorisation of high-phosphorus iron ore using mineral processing technology, have been suggested. In this paper, the removal of phosphorus from a low-grade high-phosphorus iron ore containing 0.1 mass% P and 57.5% Fe by alkaline roasting and wet grinding is discussed. The iron ore consists mainly of hematite, goethite, and quartz. Effects of sodium hydroxide concentration used as an alkaline source, roasting temperature, grinding time, and particle size on the dephosphorisation of highphosphorus iron ore were investigated. The dephosphorisation efficiency, iron loss, and mineralogical components of low-grade high-phosphorus iron ore under various experimental conditions were characterised by using XRD, SEM-EDS, and particle size distribution analysis. Results showed that the phosphorus content was lowered from 0.1 mass% to 0.034 mass%, while the iron grade reached 59.8 mass% from 57.5 mass% by alkaline roasting with 0.05 w/w NaOH at 300 °C for 2 h, followed by wet grinding in an attritor with water for 30 seconds at room temperature. Under the experimental conditions, the dephosphorisation rate was about 54.7%, and the solution obtained by wet grinding contained 22.7 mg/L of phosphorus and 21.5 mg/L of iron. The recovery rate of iron by this process reached 99.9%. Keywords: Iron ore, phosphorus, dephosphoriszation, alkaline roasting, wet grinding

Jan 1, 2020

1. Book review Economics of mineral exploration in Australia, by Brian W. Mackenzie and Michel L. Bilodeau. Australian Mineral Foundation (Private Bag 97, Glenside, South Australia 5065). 198pp. $A58. $A45 for students. Reviewer: D.G. Krige 2. Recent publications Combustion of coal liquid mixtures, by G.F. Morrison. London, lEA Coal Research, 1983, 52 pp. Hafnium: physico-chemical properties of its compounds and alloys. Vienna, International Atomic Energy Agency, 1981. 408 pp. 620 Austrian schillings. Canadian mines handbook 1984-85, edited by CD. Gardiner. Toronto, The Northern Miner, 1984. 500 pp. $24. Drilling equipment in Canadian mining and exploration- opportunities for the industry, by AJ. Jakubek. Toronto, Micromedia Limited (144 Front Street, Toronto M5J IG2, Canada), 1984. Research report 1984. Port Melbourne, Division Mineral Chemistry, Commonwealth Scientific and Industrial Research Organization, 1984. 190 pp. Surface engineering Wear is an unavoidable problem in virtually all products of the engineering industry, from the minute bearings of instruments to the cutting surfaces of earth-moving plant. Safety in mines About 50 papers will be presented at the 21st International Conference of Safety in Mines Research Institutes at Sydney from 21st to 25th October, 1985. Some 250 delegates from 30 nations are expected to attend. Professional development seminars March 18th-21st, 1985 Underground Blast-hole Mining May Ist-3rd, 1985 Mineral Processing of Gold Ores May 6th-10th, 1985 Mineral Comminution Systems May 13th-15th, 1985 Processing of Metallurgical Residues Analytical chemistry The Second Symposium on Analytical Chemistry in the Mining, Exploration and Processing of Materials is to be held in Pretoria from 15th to 19th April, 1985.

Jan 1, 1985

1. Reviews Extraction metallurgy, by J.D. Gilchrist. 3rd ed. Oxford, Pergamon, 1989. 431 pp. £50.00 (hard cover), £14.95 (soft cover). Reviewer. Prof. M.D. Brayshaw. Reviewer. Prof. M.D. Brayshaw This third edition bears testimony to a work that contains much of value for lecturers, students, and practising metallurgists. Mineral processing in the United Kingdom, edited by P.A. Dowd. London, Institution of Mining and Metallurgy, 1988. 223 pp. £25.00. Reviewer: Prof. M.D. Brayshaw It came as both a pleasure and a challenge for a resident of South Africa (with its volume and diversity of minerals) to review a book focusing on the beneficiation of ores from the sparsely endowed mineral chests of the United Kingdom. 2. Recent issues Rock mechanics. Theory and applications with case histories, by W. Wittke. Translated from German by R. Sykes. Berlin, Springer-Verlag, 1990. 1076pp. DM248. McGregor's quick reference to the JSE. Pretoria, Juta & Co., 1990. R39,95. McGregor's economic alternatives. Pretoria, Juta & Co., 1990. 400 pp. R34,95. 3. New journals Journal of Materials Chemistry, edited by A.R. West and J. Leader, and published two-monthly by The Royal Society of Chemistry (Blackhorse Road, Letchworth, Herts SG6 IHN, OK). £195 per year, starting in 1991. New Materials World, published monthly by Lawrence Cooklin (15 Selvage Lane, Mill Hill, London NW? 3SS, OK). £180 per year. Mendeleev Communications 4. Books from The Institute of Metals The following were published recently, or are to be published soon, by The Institute of Metals, 1 Carlton House Terrace, London SWl Y SOB, OK. Illustrated case histories of marine corrosion. 1990. Modern steelmaking methods, by C. Moore and R.I. Marshall. 2nd ed. 1990. Grain boundary fractures, by S.F. Pugh. 1991. 160 pp.

Jan 1, 1991

By J. T. Nel

The Kroll process is the traditional method of producing zirconium metal by reduction of zirconium tetrachloride with magnesium metal. This paper discusses the production of zirconium metal in a plasma reactor. Anhydrous low-hafnium ZrCl4 and Mg metal were fed continuously to a 30 kW non-transfer plasma reactor at a rate of 0.31 kg.h-1. Due to losses in the system the recovery of crude product was 77.5 %. After purification to remove unreacted feed material and MgCl2 by leaching, >98 % pure zirconium metal powder was obtained. The overall recovery of purified Zr was 74 %. The conversion efficiency of the process was 95 %.

Jan 1, 2012

By N. B. Strydom, P. L. Jooste, H. F. Kotze, W. H. Van Der Walt

Note: A revised method of heat acclimatization by N. B. STRYDOM, W. H. VAN DER WALT, P. L. JOOSTE, and H. F. KOTZE INTRODUCTION Climatic-room acclimatization was introduced in the gold-mining industry in 1965 and was rapidly adopted by all mines because it reduced the number of days required for heat acclimatization from 12 to 8. The method has been adequately described in previous papers1, 2 but, briefly, requires four hours of heat exposure per day while the work rate is progessively increased from 35 W on Day 1 to 70 W on Days 7 and 8. Several attempts to shorten

Jan 6, 1976

By S. Maluadzi, D. Rocchi, S. Luyckx, S. S. Potgieter-Vermaak, C. Machio, J. H. Potgieter

The aim of this work was to compare the corrosion behaviour of thermal spray WC ? based coatings before and after annealing. X-ray diffraction (XRD) was used to determine the phases present in the coatings at various stages. The corrosion resistance of the coatings was measured using electrochemical and immersion corrosion tests. The results obtained from electrochemical corrosion (quantified by corrosion current density) and immersion corrosion tests showed that annealing appears to decrease the corrosion resistance of the coatings. From the XRD results it was determined that the phases that corroded preferentially were cobalt (Co), eta (Co6W6C) and W2C. Keywords: Corrosion, thermal spray, coatings, hardmetals.

Jan 1, 2006

1. OPLEIDING IN INGENIEURSWERK VIR IN G ENIEURS- IN -OPLEID IN G 1.1 llegistrasie as Ingenieur-in-opleiding 'n Gegradueerde ingenieur wat in 'n eksamen geslaag het wat die Raad erkenl, is registreerpaar as 'n ingenieur-in-opleiding kragtens die Wet op Professionele Ingenieurs2. Aansoekvorms kan van die Registrateur verkry word. Mineral processing congress The XIIIth International Mineral Processing Congress is to be held in Warsaw from 4th to 9th June, 1979. Seeing that by products and co-products are becoming of increasing importance in mineral processing operations, the theme of the Congress is to be the 'Treatment of Raw Materials with Total Utilization of All Constituents'.

Jan 1, 1979

1. Journals Marine Geotechnology, edited by R.C. Chaney. London, Taylor & Francis (Rankine Road, Basingstoke, Hants RG 24 OPR, OK), 1988. vol. 8, $50. Published quarterly. Mineral Resources Engineering, edited by C.T. Shaw. London, Taylor & Francis (address as above), 1988. vol. 1, $99. Published quarterly. 2. New publication World mining map of non-ferous metals (with 4 regional maps and a booklet). Reinhard Ryborsch (Postfach 2105, D-6053 Obertshausen bei Frankfurt am Main, West Germany). International edition: bilingual, English and German. 7 colour-print: Size (unfolded) 138 X 100 cm. US$ 19 (excl. mailing) for folded map with hard cover (Order No. 61-4); US$ 25 (excl. mailing) for unfolded (flat) map with hanging strip (Order No. 62-2). 3. Mintek reports Report M326 Crevice corosion and other localized corosion behaviour of 3CR12 corosion-resisting steel in synthetic minewaters, by D. Howarth. May 1988. 28 pp.Report M332 The carbon-regeneration furnaces at Mintek, by P.M. Cole and P.J. van Staden. Nov. 1987. 31 pp. Report M344 The flotation of pyrite with amine colectors, by R.D. Hil, E.W. Giesekke, and P.J. Haris. Mar.'1988. 25 pp.Report M345 The substitution for chromium in steels: Progress and trends, by M.B. Cortie. Mar. 1988. 14 pp.Report M346 The direct reduction of sulphur dioxide to elementalsulphur, by I. Henderson. Mar. 1988. 30 pp.Report M349 The optimization of a process using weak-base resin for the recovery of gold from plant solutions and pulps, by A. Mehmet. Apr. 1988. 17 pp. Report M353 The determination, by ion-interaction chromatography, of sulphur species in cyanide solutions, by Pohlandt-Watson, M.J. Hemmings, D.E. Barnes, and a.w. PansL Jun. 1988. 7 pp. Report M355 A laboratory-scale continuous-feed resistance furnace, by K.P.D. Pery, A.S.E. Kleyenstiber, andC.T. Logan. May 1988. 9 pp. Report M357 The determination of minor and trace elements in activated charcoal, by RT. Eddy and G.J. Wal. Jun. 1988. 14 pp. Report M358 The sensitive determination of germanium by atomicabsorption spectrophotometry using electrothermal atomization, by G.D. Marshal. Jun. 1988. 11 pp. Report M92D The recovery of tin and tungsten from various zones of the Van Roois Vley deposit, including setling and filtration, by C.F.B. Coetzee. First issued Apr. 1983; reissued Apr. 1988. 40 pp. World Environment Day Symposium* Mintek auditorium in Randburg was the venue on Thursday, 2nd June, 1988, for more than 200 interested delegates at the annual World Environment Day Symposium, organized jointly by the Federation of Societies of Professional Engineers (FSPE), The Environmental Planning Professions Inter-disciplinary Committee (EPPIC), The Habitat Council, and The Associated Scientific and Technical Societies of South Africa (AS&TS). The theme 'Cultural and Historical Conservation' was adapted from the theme of the Department of Environment Affairs for the 1988 Environment Week.

Jan 1, 1988

By M. Timucin

High-temperature phase relations in the Pb-PbS system were established by the quenching of samples equilibrated in evacuated and sealed silica capsules. The liquid-miscibility gap seen in some previously published phase diagrams was not observed. The thermodynamic activities of PbS in liquid solutions of this system were derived at 1473 K from the isopiestic equilibration of samples belonging to this solution series with Cu2S-PbS melts of known PbS activities. The behaviour of Pb-PbS melts was found to be compatible with a subregular solution model. This model also made it possible to obtain an analytical liquidus for PbS that was in excelent agreement with the experimental determination.

Jan 1, 1988

By R. P. King, L. C. Woollacott

To date developments in the simulation of carbon-in-pulp (CIP) adsorption circuits have focused primarily on the modeling of adsorption. This series of three papers describes a development in a direction that has received less attention, i.e. the need for a detailed description of the movement of carbon and slurry in continuous CIP and carbon-in-leach (CIL) plants. A new simulator has been developed based on the population-balance approach for modeling the movement of carbon and slurry. Existing adsorption and leaching models are evaluated in this paper in order to establish which are appropriate for use in the new simulator. The details of the simulator are given in Part 2 of this series.

Jan 1, 1990

By P. J. D. Lloyd

The Federation of Societies of Professional Engineers (FSPE) recently conducted a survey of professional engineering manpower in South Africa. This article presents the data relevant to mining and metallurgical engineering. FSPE in their survey attempted to determine the supply of engineers in South Africa both from local universities and by immigration. The immigrants gave some problems in that it is difficult to know whether a man who claims to be professionally qualified really is. However, it was estimated that the ratio of immigrants who claimed to be qualified to those who really are the equivalent of our local graduates was between 1,0 and 1,9 for mining engineers, and between 2,0 and 4,1 for metallurgical engineers.

Jan 1, 1980

By J. P. G. Pretorius, T. C. Partridge

The analysis of angular atypicality of lineaments as an aid to mineral exploration by J. P. G. PRETORI USc, M.Sc. (Pret.) (Visitor) and T. C. PARTRIDGE, Ph.D. (Natal) (Visitor) In an exploration project, data pertaining to 84000 lineaments in an area of 25 000 km2 were recorded. The total length of lineaments in intervals of one degree was determined. Angular intervals with Iow length densities were regarded as atypical. The proportion (by length) of lineaments with such atypical orientation was calculated for 5 km X 5 km grid squares. This index of angular atypicality was contoured and, used in conjunction with conventional photogeological techniques, contributed in a large measure to the success of the investigation.

Jan 5, 1974

By S. J. Webber

This paper reports on the use of the MINSIM-D stress-analysis program for the modeling of two large seismic events that occurred on the same fault eleven years apart. It was found that the first event (magnitude 5,2) could not be ascribed to purely mining-induced stresses, indicating that the largest seismic events probably result from the interaction of mining-induced stresses with large scale tectonic stresses. However, the stress changes induced during eleven years of mining were found to be capable of generating sufficient excess shear stress (ESS) to be responsible for the second event (magnitude 4,3), The upper limit for the magnitude of purely mining-induced events was found to be approximately 4,3.

Jan 1, 1990

By J. O. Roux

The Impala Platinum Limited Base Metals Refinery in Springs, South Africa, refines convertor matte containing base metals and PGM?s (platinum group metals) using a hydrometallurgical process. In addition to a PGM-rich concentrate that is further refined, the Base Metals Refinery produces nickel (in powder or briquette form), copper cathodes and cobalt powder. Five leaching stages are utilized to remove the base metals and impurities from the PGM concentrate. The project described in this paper involves a radical redesign of the second stage leach autoclave with the aim of reducing maintenance costs and downtime, increasing throughput and ensuring a safer working environment. The second stage leach process at the Base Metals Refinery, produces a PGM-rich residue through the extraction of copper and any remaining base metals from the first stage leach solid residue material. Leaching is performed in an autoclave operating at a pressure of 600 kPaG and a temperature of 140°C to 150°C. Concentrated H2SO4 is added to the feed to produce a solution with a free acid content between 10 and 30 g/L and a pH of less than 2. Oxygen is passed into the 1st and 2nd compartments of the autoclave. As a result of the aggressive, highly oxidizing conditions within the autoclave, the original design utilized a heavy wall carbon steel shell with lead lining and two layers of acid bricks. The bricks acted as a wear resistant material and ensured a low surface temperature at the skin of the lead lining, whereas the lead lining acted as a corrosion barrier to protect the steel shell. These brick lined autoclaves were heavy, maintenance intensive and prone to catastrophic failure. A radical autoclave redesign was needed to reduce the high costs of manufacturing, installation and operation. Finite element modelling was used to optimize the design and various high alloy materials were investigated for the application. Based on extensive test work, the carbon steel shell was replaced with duplex SAF 2205 stainless steel in the new design. The use of this highly corrosion resistant material, eliminates the need for the lead and brick linings and reduces the wall thickness requirements substantially, resulting in an increase in the available volume for the same external shell dimensions. The vessel is welded in circular sections to form an elongated, impermeable, cylindrical body, with several agitator nozzles and compartments. The first new duplex stainless steel unit has been in continuous operation for more than 24 months and its performance has exceeded the highest expectations. The design was so successful that a patent has been registered. The major benefits of the new stainless steel design include increased throughput, improved performance, less downtime and a safer working environment. Lead has been eliminated and replaced with a more environmentally safe material, and the total lifespan of the vessel has been extended. In addition, the autoclave project has made significant developments in advancing the field of welding and optimizing the integrity of welding quality standards in South Africa.

Jan 1, 2009

By C. M. Rule

High pressure grinding rolls (HPGR) technology has come a long way in its application for comminution duty in hard rock mineral processing in the last three years. Several major projects in copper, nickel, gold, molybdenum, platinum, and iron ore have opted for this technology. Advances in wear abatement technology have established the HPGR as a reliable machine with the required high utilization and availability. The HPGR captures the imagination as the next step change improvement in ore processing, based on the following benefits: ?Energy efficiency (potentially 10?30% more efficient)?very topical in an increasingly ?green? society, and in times of rapidly increasing energy costs and availability concerns. 2008 has shown this to be especially important in Southern Africa ?High (and stable) throughput with a relatively small footprint ?Lower operation cost ?Liberation benefits ?Creative ?mine-to-metal? system improvements made possible by HPGR. The platinum industry, renowned for its historically conservative approach, has not been left behind with two significant new HPGR installations, one in Platreef application and one in UG2 application, commissioned in 2008. While the decision for the Platreef application was driven primarily by comminution circuit capacity and design imperatives, the UG2 application seeks to develop a flowsheet that will have a significant recovery benefit in addition to capacity increase and reduced operating cost. The Platreef application of HPGR also provides the opportunity to introduce a novel comminution flowsheet and to demonstrate exceptionally low wear rates treating very hard, abrasive and variable ore types. The HPGR lends itself for inclusion in existing SABC circuits to increase the capacity of the plant and mills. With current PGM prices many operations are attracted to the HPGR technology benefits. The HPGR clearly has the potential to transform entrenched opinion and provide decision makers with significant alternative comminution options. This paper aims to provide an overview of the current applications and to speculate on the transforming stimulus that the HPGR exerts on industry.

Jan 1, 2009

By M. R. Khalesi, S. Arfania

"Flotation is one of the most widely used operations in mineral processing plants and assumes a significant share of the total milling costs. The purpose of this paper is to introduce a new set of capital and operating cost models for major flotation machines based on the application of single (SRA) and multiple regression analysis (MRA). Thirty-seven major flotation machines were analysed for this purpose. Depending on the machinery type, different technical variables such as diameter, required air flow rate, required floor space, cell volume, required air pressure, and power were considered as predictor variables, individually (in SRA) or simultaneously (in MRA). Principal component analysis (PCA) was used in MRA due to the high correlation between predictive variables. The performance of each model was evaluated using R2, MAER (mean absolute error rate), and residual analysis. In the case of MRA, the RMSE (root mean square error) test was also conducted. Maximum obtained MAER of 13.5% and minimum R2 of 0.86 indicated that these models could be applied as credible tools in estimation of capital and operating costs of flotation machines for design and feasibility studies.IntroductionMineral processing is a vital part of mining projects and mainly involves comminution, sizing, concentration, extractive metallurgical processes, and dewatering. Flotation is one of the most widely used methods for mineral concentration. Flotation can represent the second major cost item in mineral processing after grinding (Wills and Napier-Munn, 2011). Accordingly, it is a main concern of mining project managers to select and optimize flotation circuits in order to decrease costs and increase productivity. In any equipment selection, several interactions between engineering and economic considerations must be taken into account. Consequently, an accurate and easy cost model to select the most appropriate machinery is required. Moreover, cost models could be used in flow sheet simulations applied in design and optimization. Models of unit operations built into the simulators could be improved by linking the equipment cost models (Khalesi et al., 2015)."

Jan 1, 2017

By A. Fouchee, N. Naudé, K. Schommarz

"This article presents laboratory test work conducted on an African haematite ore to determine the influence of the flotation pulp pH on the final iron grade and recovery. Results show that a combination of an isodecyl ether propylene amine/amino acetate and 1,3-propanediamine, N-(3-(C10-C16-alkyloxy)propyl)-derivatives collector is suitable for separating haematite from quartz. Higher iron grades were obtained at pH levels between neutral and pH 9. This underlines the importance of the surface charge effect of the ore on its flotation characteristics. The results serve as good baseline conditions for further optimization. IntroductionBeneficiation of iron ore by flotation is widely used in Brazil, India and China. In Africa, however, this practice is not yet commercially developed.The aim of this test work is to serve as a starting point by establishing suitable pH conditions for the development of a practically implementable reagent suite, which will then be included in a larger beneficiation circuit for producing high-grade iron ore sinter feed.In the literature, African iron ore types are graded as low-grade (60.0–62.9% Fe; 8.6– 12.5% SiO2 and insolubles), high-grade (66.0– 69.9% Fe; 0.8–4.5% SiO2 and insolubles), and meduim-grade as the remaining portion (Astrup et al., 1998). The low-grade ore used in this work contains less than 60% Fe.For Brazilian ores consisting of a combination of haematite and quartz, it is common to use corn starch as a depressant and ether amine blends as collectors with additional frothing characteristic (Araujo et al., 2005). Work by Turrer and Peres (2010) shows the possibility of using other depressants successfully as well.The main mechanism of the reverse flotation of quartz from iron ore is based on the electrostatic theory of flotation. This is due to the strong pH dependence of the zeta potential of the mineral edge planes on silicate particles (Fuerstenau and Pradip. 2005)."

Jan 1, 2016

By O. S. Tinkler, K. C. Sole

"Although the first large-scale application of copper recovery by solvent extraction took place in Zambia in the early 1970s, it is only in the last decade that this technology has become widely employed in this part of the world and is now a mainstay unit operation in copper hydrometallurgical flow sheets. The mineralogy of the ores of the African Copperbelt, and hence the characteristics of African leach liquors, differs significantly from those in Chile and the southwestern USA, where copper solvent extraction has had a long and successful history. These differences provide operators, metallurgists, reagent vendors, and engineers with many challenges: new approaches are needed to adapt solvent-extraction technology for successful implementation in this region. This paper examines typical operating practice in the African Copperbelt, discusses differences compared with other parts of the world, and looks at some of the challenges and opportunities presented by these flow sheets. IntroductionFollowing the success of the Rancher’s Bluebird and Bagdad solvent extraction and electrowinning (SX–EW) operations in Arizona in the late 1960s, the Tailings Leach Plant at Chingola, Zambia, became the first large-scale copper SX plant in the world, commissioned in 1974. Despite the equipment design now being outdated, this plant still continues to operate successfully, indicating the versatility and adaptability of this technology. Today, there are some 75 copper SX operations worldwide with cathode production above 10 kt/a. The top ten producers currently account for about 40% of the global 4.3 Mt/a SX–EW copper production. South America (predominantly Chile and Peru) is the largest copper cathodeproducing region, with annual production of some 2 Mt. The Central African Copperbelt (Zambia and the Democratic Republic of Congo (DRC)) is second, with cathode production of 1.2 Mt/a, and North America (USA and Mexico) third, producing close to 0.8 Mt/a Cu (Solvay Cytec data, 2014). The remaining 0.35 Mt/a comes from all other regions combined (referred to as ‘Rest-of-World’)."

Jan 1, 2016

By C. A. Young, J. L. Bowden

"Cyclic voltammetry experiments were conducted on copper and chalcopyrite (CuFeS2) in the absence and presence of ethyl xanthate, and compared to mass-balanced EH–pH diagrams. The results for copper duplicate those found in the literature and confirm xanthate chemisorption. However, the, results indicate that chalcopyrite oxidizes to chalcocite (Cu2S) and only afterwards is chemisorption observed due to small currents appearing with xanthate. This phenomenon suggests that the mineral's hydrophobicity is induced by more than dixanthogen and copper xanthate. Hydrophobicity was found to be pH-dependent over a range of alkaline conditions (pH 7–11) at narrow potentials (0 to –200 mV). An EH–pH diagram for chalcopyrite with xanthate is presented to illustrate the conditions under which chalcopyrite would be hydrophobic and thereby more thoroughly explain the results in the literature. IntroductionSulphide minerals are generally concentrated from ores by froth flotation, a physiochemical process that induces separation based on differences in hydrophobicity. In this process, a gas is bubbled into a slurry and the minerals that are hydrophobic (water-repelling) adhere to the bubbles and float to the surface while the hydrophilic (water-loving) minerals remain in the slurry. With sulphide minerals, the hydrophobicity is generally established in two ways. The first is by the addition of a collector, which is a heteropolar molecule with a reactive inorganic head group and an inert organic tail. Typically, the head group bonds with the sulphide mineral surface by adsorbtion either chemically (chemisorption) or physically (physisorption) or by complexing with atoms that solubilize somewhat at the surface (surface precipitation). These interactions leave the organic tail protruding from the mineral surface, thereby inducing hydrophobicity. The second method is by oxidation of the mineral surface to form a layer that is metal-deficient/sulphide-rich or comprised of elemental sulphur. Because the layer mimics naturally hydrophobic sulphur, this enables ‘collectorless’ flotation. Furthermore, this oxidation phenomenon adds an electrochemical dimension to the understanding of sulphide mineral flotation."

Jan 1, 2016

By A. F. Lee

Dr E. C. Hanekom (Visitor): Two years ago we used the bubble pick-up technique as developed at Anglo American Corporation for screening candidate flotation agents prepared in our laboratories. It was obviously necessary to know to what extent the technique gave reproducible results and a statistical evaluation of the test method was made using a mineral sample provided by Anglo American Corporation. A bubble of 2.0 mm diameter was used and the measuring graticule was divided into squares (units) with sides of 5.0 mm at 25 X magnification. The mineral granules had diameters from 53 to 74 mm. The bubble was loaded by depressing it against a layer of mineral grains to give an arbitrary but constant compression of 0.4-0.5 mm. It was rolled five times through 2 mm horizontal displacement. The bubble was then lifted, its load compacted by gently stirring and the projected area measured in squares (units) on the grid. Each substance was tested at 5 ppm concentration in distilled water at five points in the pH range 3-6. With these standardized conditions of operation the reproducibility of the test was studied. Four materials were tested and at each pH value the procedure of forming a bubble, picking up granules and counting the units was repeated ten times. From these results the standard deviation for a single count at any pH value was calculated for each material (Table 1. The coefficient of variation of approximately 3 per cent was relatively low and it was decided that further refinements in the counting procedure would be of doubtful benefit with the present apparatus. Similar experiments were carried out with 12 sample materials. In this case the bubble formation and pick-up were repeated four times at each pH value, the mean value was calculated for each set of four observations and final pick-up values for the materials were obtained by selecting the highest mean count. Each test was completely repeated a number of times as indicated in Table 2 and the standard deviation calculated. The results allowed the selection of the more promising materials and the rejection of poor performers at the 95 per cent confidence level. All tests were carried out by one operator. Some evidence was obtained that the method is sensitive to operator bias. In conclusion it can be said that from all the results analyzed it would appear that once operation conditions are fixed (viz operator, pH control) the precision of the method is adequate. The author wishes to thank Messrs African Explosives and Chemical Industries Limited for permission to publish these data. G. S. Stander and C. J. Kooij (Visitors): We must congratulate Mr Lee for this most interesting and useful development of the pick-up experimental method. It certainly provides research workers with an instrument which makes flotation more of a science and less of an art. We visited Mr Lee at his laboratory where he gave us a demonstration of the bubble pick-up instrument and technique as developed and improved by him.

Jan 12, 1969