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By Michael A. Evanto, George J. Karabin

The Mine Safety and Health Administration, Pittsburgh Safety and Health Technology Center, Roof Control Division, is routinely involved in the evaluation of ground conditions in underground coal mines. Assessing the stability of mined areas and the compatibility of mining plans with existing conditions is essential to ensuring a safe working environment for mine workers at a given site. Since 1985, the Roof Control Division has successfully used the boundary-element method of numerical modeling to aid in the resolution of complex ground control problems. This paper presents an overview of the modeling methodology and details of techniques currently used to generate coal seam, rock mass, and gob backfill input data. A summary of coal and rock properties used in numerous successful evaluations throughout the United States is included, and a set of deterioration indices that can aid in the quantification of in-mine ground conditions and verification of model accuracy is introduced. Finally, a case study is detailed that typifies the complexity of mining situations analyzed and illustrates various techniques that can be used to evaluate prospective design alternatives.

Jan 5, 1999

By E. G. King

This report contains experimentally determined heat-content values for cerium dioxide and Columbium (niobium) dioxide in the temperature range from 298° to 1,800° K. There are no previous similar data for Columbium dioxide, and those for cerium dioxide have an upper limit of 373° K. The heat-content and corresponding entropy-increment data are presented in tabular form. Equations were derived to represent the heat contents and heat capacities. The data for cerium dioxide are entirely regular, but those for columbium dioxide show two previously unreported anomalies at 1,090° and 1,200° K.

Jan 1, 1961

By G. F. Friel

A series of experiments in the U.S. Bureau of Mines Safety Research Coal Mine at the Pittsburgh Research Center evaluated the effects of crosscuts on the travel time of carbon monoxide (CO) along an entry to improve the accuracy of a mine-fire locator program. Three entries, ten single crosscuts, and three double crosscuts were instrumented with CO sensors. One-percent CO in nitrogen was released and monitored as it traveled the entries. In addition to dispersion of CO at the front of the CO wave, CO was entrained from the entry into the crosscuts. It was determined for an entry and single-crosscut configuration that the measured travel time for a concentration change of 5 ppm was 27% greater than the predicted time based upon entry volume only, but 13% less than the predicted time based upon entry and crosscut volumes. For an entry and double-crosscut configuration, the measured travel time for the same concentration change was 25% greater than the predicted time based upon entry volume only, but 10% less than the predicted time based upon entry and crosscut volumes. An effective dispersion coefficient for CO dispersion along one of the entries was estimated to be 1.5 m2/ s.

Jan 1, 2010

By O. P. Hood

The smoke problem means different things in different places . In the neighborhood of industrial plants , especially smelting plants and cement plants , the term " smoke " is applied to material discharged from these plants , consisting of a mixture of solid particles ( dust ) , fume which has condensed from vapors , and gases of various kinds that are produced in the operations . In the ordinary use of the word , however , " smoke" refers to the visible material which escapes from the burning of coal . White smoke usually owes its color to small drops of water which have condensed from the water vapor that it formed in the burning of coal . When smoke is black, the color is due to unconsumed particles of carbon and usually when the smoke problem is spoken of , it is this black smoke produced in the burning of coal that is referred to , Many inquiries in regard to smoke are addressed to the Bureau of Mines , and the following brief summary has been prepared as covering the usual questions . For references to the smoke problem in England , I am indebted to a recent interesting paper on this topic by David Brownlie .

Feb 1, 1922

By W. H. Eddy

The Bureau of Mines made small-scale continuous tests and large-scale commercial plant tests of a calcareous fluorspar ore near Cave-In-Rock, Ill., to determine if the application of the lignin-fluoride process of fluorspar flotation would be industrially feasible for treatment of fluorspar ores, and also to compare the lignin-fluoride process with the quebracho process, which is the method currently used for concentrating calcareous fluorspar ores. The small-scale continuous tests yielded fluorspar concentrates analyzing 93.6 percent CaF2 with a recovery of 87.6 percent of the total fluorspar in the ore. In large-scale commercial plant tests, a fluorspar concentrate analyzing 93.3 percent CaF2 with a recovery of 78.0 percent was produced by the quebracho method. About 86.0 percent of the fluorspar was recovered in a metallurgical-grade fluorspar concentrate from the lignin-fluoride circuit which analyzed 89.9 percent CaF2? with a much simpler flowsheet than that in the current commercial application.

Jan 1, 1967

By H. B. Humphrey

The solvents used most widely in industry may be divided into groups according to their chemical and toxicological properties. These groups, with representative members, follow: Petroleum distillates (aliphatic hydrocarbons) Examples: Gasoline, benzine, Stoddard's specification solvents. Alcohols, esters, ketones, ethers, and ether alcohols Examples: Denatured alcohol (ethyl alcohol to which various denaturants may be added), methanol (methyl alcohol), ethyl acetate, amyl acetate (banana oil), acetone.

Jan 1, 1956

By M. J. Ackerman

This study was undertaken to make a comparison between the cost of mining coal under roof bolt and under conventional timber methods of roof support. Studies were made at 14 mines in Pennsylvania, eastern Ohio, and northern and southern West Virginia. At each mine data were obtained for sections of the mine where the physical conditions, mining equipment, and mining systems were similar. Coal, recognized as one of the basic industrial fuels, is very competitive with other fuels, and management, in order to protect and enlarge its market, must be continually alert to find more efficient methods of production. Continuous production of coal is desired by all operators but never obtained. In mechanized mining the performance and production vary with operating time, which can be interrupted by many variable factors, such as condition of the roof, method of roof support, condition of equipment, water, ventilation, power, transportation, efficiency of operating crew, and supervision.

Jan 1, 1961

By H. C. Ko

Calorimetric determinations of low-temperature heat capacities and standard enthalpy of formation were made by the Federal Bureau of Mines for basic aluminum sulfite, A1203?2.0S02?5.3H20. The standard values of entropy (S°), enthalpy of formation (?Hf°), and calculated Gibbs energy of formation (?Gf°) at 298.15 K are 85.2±0.1 cal/deg-mole, -943.1±1.2 kcal/mole, and -820.7±1.2 kcal/mole, respectively.

Jan 1, 1976

By Stephen Krickovic

Air quantity-pressure and methane concentration surveys were conducted by the Bureau of Mines in accessible portions of an area being pillared in a Pittsburgh coalbed mine in West Virginia. These included two mined-out and three active butt headings and a bleeder system. The particular mine workings were started in virgin coal directly from a set of main headings; the main reason for the study was the difficulty usually encountered in adequately bleeding the gobs under such conditions. Although the two separate return airways in each active butt heading and the North and 1 Left bleeders contained acceptable methane concentrations (0.01 to 0.78 percent in the butts and 0.73 to 1.0 percent in the bleeders) with significant total methane removal (109 cfm in butts and 631 cfm in bleeders), there were relatively large areas in the gobs with possible minimal airflows. This condition appears to have developed from lack of systematic regulation of the airflow across the gobs and appears to indicate the existence of considerably more methane in the probably low flow areas in the gob.

Jan 1, 1973

By Henry Kreisinger, WALTER T. RAY

The investigation of the transmission of heat into steam boilers is one of several researches now being carried on by the Bureau of Mines that have for their object the testing of methods by which the mineral fuels in this country may be used more efficiently. A better understanding of the laws governing heat transmission into boilers will result in the design of more efficient boilers, and more efficient boilers will reduce waste in the use of fuel. The results of the investigations described in this report indicate that the conductivity of the heating plates of steam boilers is so high that the present steaming capacities can be tripled or quadrupled by forcing over the heating surfaces three or four times the weight of gases now passed over them. With well-designed mechanical-draft apparatus this greater weight of gases can be forced through the boilers at a small operating cost. It is possible to increase the capacity of many of the present boilers in this way without reducing their efficiency much; in fact by a proper arrangement of the heating surfaces the efficiency can be made higher than the present rating. The efficiency of any boiler can be increased by arranging its heating surfaces in series with respect to the path of hot gases. New boilers of high efficiency can be constructed by making the cross section of the gas passages small in comparison with the length. In Bryan Donkin's book, entitled "The Practical Physics of the Modern Steam Boiler," it is stated that James Watt obtained nearly as good an evaporation per pound of coal and per square foot of heating surface as is obtained now. The remark is probably true. At any rate, about the only decided superiority of the modern steam boilers over older types is in mechanical construction, and for this superiority credit should be given to the designers of machine tools quite as much as to the boiler engineer. The main reason for tardi- ness in boiler improvement probably lies in the reluctance of educated engineers to do the dirty and disagreeable work involved in boiler tests.

Jan 1, 1912

By W. M. Deaton

The Keyes Helium Plant of the Federal Bureau of Mines was constructed under an expedited schedule, to supply the urgent and growing demand for helium in atomic energy, missiles, aerology, space exploration, shielded-arc welding, and low-temperature research. Construction began in December 1958 and ended in August 1959. The plant, near Keyes, Okla., processes 2 percent helium-bearing natural gas from the Keyes gasfield. In 1960 the plant produced and shipped 263 million cubic feet of helium (equivalent to an annual rate of 290 million cubic feet). Production cost was $9.11 a thousand cubic feet of helium. A low-temperature process involving two steps is used; the first separates a crude-helium product from the natural gas at about -250° F. and 225 pounds per square inch gage (p.s.i.g.); and the second purifies the crude helium to a high-purity product (Grade-A helium, 99.995 percent helium) at about -320° F. and 2,750 p.s.i.g.

Jan 1, 1961

By C. E. Armantrout, H. Kato, M. I. Copeland

The data collected during this investigation indicate that the chromiumgadolinium system has extensive liquid immiscibility and one eutectic point . Liquid immiscibility occurred at temperatures above the monotectic isotherm , 1,830 ° C , which extended from less than 0.25 to about 85 weight - percent gadolinium . The eutectic was at 96 percent gadolinium and 1,170 ° C. Gadolinium and chromium were the only phases in this system . There was a solid solubility of less than 0.25 percent gadolinium in chromium at 1,730 ° C and less than 0.10 percent chromium in gadolinium at 1,160 ° C. The alloys were prepared by nonconsumable - electrode arc - melting , and the alloy system was investigated by heat treatment , metallography , thermal analysis , and X- ray diffraction . All the melting , heat treatments , and thermal analyses were conducted in a vacuum or in helium because of the reactivity of chromium and gadolinium with the components present in the atmosphere at elevated temperatures .

Jan 1, 1964

By J. M. Stuve

Low temperature and high-temperature calorimetric measurements were made by the Federal Bureau of Mines on high-purity samples of Re02(s) and Re03(s) to determine heat capacities and enthalpies. The temperature range of heat capacity measurements was 5 to 310 K for Re02 and 8 to 309 K for Re03. High-temperature enthalpy measurements alone were determined for pure Re207(s,1). The derived standard entropies are S°298 = 11.43±0.01 cal/deg mole for Re02(s) and S298 = 16.55±0.02 cal/deg mole for Re03(s). High-temperature enthalpy equations expressed in calories per mole are as follows: Re02 (s) , H-H298.15 = 16.002T + 1.600 X 10-3T2 + 3.522 X 105T-1 - 6,095 (298 to 1,400 K); Re03 (s) , H-H298.15 = 20.293T + 3.238 X 10-3T2 + 3.950 X 105 T-1 - 7,664 (298 to 1,000 K); Re207 (s) , H-H298.15 = 38.437T + 10.309 X 10-3T2 + 4.315 X 105 T-1 - 13,824 (298 to 413 K); Re207 (s) , H-H298.15 = 30.181 + 17.713 X 10-3T2 - 10,612 (413 to 600 K) ; Re207 (1) , H-H298.19 = 66.101T - 10,092 (600 to 700 K). Gibbs energy of formation (?Gf°) data and related functions over the temperature ranges investigated are tabulated for the three oxides.

Jan 1, 1976

By D. Harrington

Notwithstanding all the effort maa.e to introduce wet drills to prevent dustiness of air of metal-mine workint;s pl2.ces, there has during the pa.st few years arisen in Australia and South Africa an impression that wet drills, in­cluding the Leyner typa, actuali"y cause und..ue quantities of finely divided ore and rock to rise into the air, these fine particles being chiefly attached to · P=i-rticles of fog or spray escc:.ping frow holes using water drills. This fs saia. to have created consternation in the ranks of the min operators who have com­piiei With drastic wet dri llin rf,ubtions, 2nc:i. purchased and operateC1. various types of wet drills at no inconsiderable expeniiture in both money and effort.

Mar 1, 1922

By S. J. Pearce

The Bureau of Mines has prepared, as circumstances have dictated, a series of Schedules setting forth the minimum requirements that various types of equipment should meet to be considered safe and satisfactory for use in certain hazardous or unhealthful conditions. These Schedules cover a wide variety of devices ranging from explosives to electrically operated mine locomotives. This paper deals with those Bureau of Mines Schedules under which respiratory protective devices are tested and approved, and its purpose is to explain the function and operation of these Schedules. Provisions have been made for testing and approval of the following types of respiratory protective devices: Self-contained breathing apparatus,2/ supplied-air respirators,3/ gas masks,4/ dispersoid respirators,5/ and chemical cartridge respirators.6 These devices are tested at the Central Experiment Station of the Bureau of Mines in Pittsburgh, Pa. Self-contained breathing apparatus is tested by the Safety Branch, and the other types of respirators are tested by the Health Branch.

Jan 1, 1951

By Sean Gallagher, Rhys Llewellyn, Jay Mattos

This paper contains the results of an examination of accident, injury, employment, and production information reported to the U.S. Department of Labor's Mine Safety and Health Administration (MSHA) and provides information on some of the measures longwall mine operators are using to prevent accidents In all industries, technological advances play a key role in determining those who will survive as competitive participants in an increasingly global marketplace. While mining is among the most basic of industries, technological change is neither unfamiliar nor unwelcome to miners. Historically, technological advances in mining, particularly coal mining, have tracked closely with fluctuations in demand. In the early 1900's, coal accounted for more than three quarters of all the fuel consumed in the U.S. To meet this tremendous demand, underground cuffing machines were introduced, resulting in faster, more efficient coal extraction. Transporting coal to the surface, however, remained labor intensive. In the 1920's, nearly all underground coal was still being hand loaded. Demand for coal then declined as the price of oil, natural gas, and electricity became competitive. In the late 1930's and throughout the duration of World War II, coal demand and production was high. By 1940, more than half the coal mined was being mechanically conveyed to the surface. In 1948, the continuous mining method was introduced in the U.S., further accelerating the extraction process. By the 1950's and 1960's, however, coal production again declined as railroads converted to diesel fuel and gas and oil provided a larger share of the home heating market. Underground coal mines required even more mechanization to remain competitive as an energy source. The first longwall system was introduced in 1960. By 1995, longwalls were producing more than 189 million tons of clean coal annually, surpassing continuous mining production for the second straight year. The mining of coal and other materials has not come without a huge loss of life and considerable human suffering. More than 103,000 workers died from injuries in U.S. mines in the last 85 years. Between two and three thousand miners died each year from the turn of the century until 1931, many from underground fires and explosions. The U.S. has witnessed a tremendous drop in fatalities in underground coal mines. Credit for that is due to safety inspections and enforcement activities, better safety awareness and practices among management and labor, improved ventilation, the use of safer equipment, and increased mechanization which removed many miners from the hazards at the face and also reduced the size of the mining work force. There is little doubt that longwall mining has greatly increased underground coal mine productivity. The degree to which longwall mining has contributed to a safer work environment for underground miners is more difficult to ascertain.

By Ludwig Schmidt

The policy of buying crude oil on a gravity basis , recently instituted by the major crude oil purchasing agencies in the Mid- Continent field , has caused a new and vital interest to be taken in the work of the U. S. Bureau of Mines for preventing evaporation of crude . From the early years of the industry oil men have recognized that the gravity of crude oil is usually an index of the gasoline content , but it has not been so generally known that the gravity of the crude oil decreases if evaporation is permitted . In 1919 the Bureau of Mines began a survey to determine the evaporation losses of crude petroleum in its various stages of handling from the well to the refinery , The results of this study are presented in Bulletin 200 ( Wiggins , J.H. , Evaporation losses of petroleum in the Mid- Continent Field , Bulletin 200 , U. s . Bureau of Mines , 1922. ) and Bulletin 225 ( Wiggins , J.H. , Methods of decreasing evaporation losses of petroleum , Bulletin 225 , U. S. Bureau of Mines , ( In press ) The findings of this survey were so startling that soon after the preliminary report had been published , several tank companies began manufacturing vapor- tight tanks for the purpose of reducing these important losses . Since that time the development of this type of apparatus has been so rapid that today , every oil trade journal carries numerous advertisements of vapor- tight tanks and equipment as well as technical articles dealing with various problems in connection with the elimination of evaporation losses , whereas three or four years ago the subject was scarcely even thought of. The present report has been prepared in response to numerous requests for information on the apparatus actually being used to prevent evaporation losses . At this time oil operators are also extremely interested in holding the lighter fractions in the crude oil in order to prevent a lowering in gravity . The practice of removing the vapors from crude- oil tanks by means of a slight vacuum and extracting the gasoline from them is not discussed here .

Feb 1, 1923

By Maria I. De Rosa

Combustible materials, when burned, produce toxic gases and smoke, which may vary dramatically from one material to another, with resultant different total toxicity and smoke obscuration levels. This U.S. Bureau of Mines report presents smoke property data acquired for a variety of mine combustibles and shows that there exists a correlation between the smoke properties, the relative toxicity, and the smoke obscuration levels of those combustibles tested. These correlations can be used to devise simple, standard tests for determining the toxic and smoke obscuration hazards of mine materials during fire.

Jan 1, 1989

By Martin H. Stanezyk

The Bureau of Mines investigated leaching of selected copper sulfide minerals and a composite of impure flotation concentrates at elevated temperatures and pressures with ammoniacal solutions. Copper 1 (tractions of 96 percent were obtained by leaching chalcopyrite at 75° C under oxidizing conditions for 60 minutes. An extraction of 99 percent of the copper contained in the composite concentrate was obtained by leaching the product for 90 minutes at 75° C. In tests of bornite, chalcocite, and covellite, 90 to 97 percent of the copper was extracted at 20° C provided an 8-hour reaction period was used. At 75° C essentially complete dissolution of the copper from these three minerals was accomplished in 60 minutes. Additions of ammonium sulfate to the leach solutions were required to obtain high-percentage extractions of the copper from bornite, chalcocite, and covellite. Although ammonium sulfate was not required when digesting chalcopyrite, copper extraction was enhanced and less free ammonia was required when ammonium sulfate was added to the leach pulps. The chemistry of leaching copper minerals was studied. It was C, termined that chalcocite altered to covellite as one step in the dissolution When leaching iron-bearing copper sulfides, hydrated iron oxide formed on the mineral surfaces, indicating that a diffusion process prevailed. No evidence of covellite was detected.

Jan 1, 1966

By Jerome J. Hoeppner, Walter W. Fowkes

The Federal Bureau of Mines has determined the distribution of forms of sulfur for several lignites and gasification chars and noted the changes induced by the gasification process . A method was adopted for quantitatively determining sulfide sulfur that was found to be present in the chars , although absent in the lignites . Changes in the behavior and distribution of sulfur forms were further investigated concerning the ashing of lignites and chars under standard conditions , as well as at various temperatures , and the determination of volatile matter applied to both chars and lignites . The authors concluded that the first and greatest change in the form of sulfur present in natural lignite , upon heat treatment , resulted from the reduction of pyritic and sulfate sulfur to sulfide . Organically - bound sulfur originally present is less reactive , but largely disappears on strong ignition . An appreciable part of the sulfur content of natural lignite is fixed in the char as sulfide and in the ash as water - soluble sulfate and will affect the summation of constituents , to a greater or lesser degree , in reporting the ultimate analysis of a lignite or char .

Jul 1, 1960