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By L. M. Chan, D. H. Carlson, J. B. Johnson

"Abstract — Concentrations of tailpipe pollutants from diesel-powered. underground mine vehicles change over time due to engine wear and the need for maintenance. Since this deterioration in pollutant emissions may adversely affect the air quality in an underground mine, it should be monitored and controlled. This paper presents decision criteria concerning when to service a mine vehicle diesel engine. These criteria, based on mine air and tailpipe concentration measurements, are designed to maintain the tailpipe concentrations within limits that assure satisfactory mine air quality.Application of the deterioration criteria to mine vehicle emissions involves:establishing, for each pollutant, the allowable deterioration factor, anddetermining the deterioration factor, from the mine air and tailpipe diesel pollutant measurements, and the mine air threshold limit values (TLVs).If the deterioration factor is greater than or equal to the allowable deterioration factor the vehicle is removed from service for maintenance.An analysis applying the criteria to measurements made in an underground coal mine is presented. The tailpipe pollutant concentration data were collected using the Emissions Mea-surement Apparatus (EMA) developed by Michigan Techno-logical University. Since the TLV for diesel particulate matter (DPM) has not yet been established assumed mine air DPMTLVs of 15 and 1.0 mg/m3 were used in the analysis. For all of the diesel haulage vehicles included in the analysis. DPM was found to be the critical pollutant (the one most in need of control). For an assumed mine air DPM TLV of 15 mg/m3 none of the diesel haulage vehicles would he removed from service. However reducing the DPM TLV to 1.0 mg/m3 would make it necessary to remove two of the three vehicles tested from service."

Mar 1, 1992

By Jr. Karr

The Bureau of Mines studied the influence of carbonization method, temperature, and carrier gas on the composition of eight different low-temperature tars produced from a Colorado subbituminous coal. A fluidized bed was compared with an entrained bed, temperature was varied from 500° C to 650° C, and external heating using recycle gas as the carrier gas was compared with internal heating using oxygen-containing gas. The entrained bed yielded significantly more m-cresol and m-ethylphenol, indicating that thermodynamic equilibrium was more nearly approached in the system. Increasing the temperature greatly increased the yield of benzenes and naphthalenes, while paraffins, olefins, and total tar acids were reduced. Using oxygen in the carrier gas decreased the yield of low-boiling phenols and increased that of paraffins and olefins at 650° C.

Jan 1, 1966

By Jalna R. Zatko

The Bureau of Mines has developed and constructed an apparatus that is capable of measuring concentrations of high-molecular-weight polymers in solution at 10 ppm and less. A means for determining low concentrations of polymeric solutions was devised that was independent of slight fluctuations in solvent quality in order to measure polymers in effluent prior to recycling of the recovered solution. The concentrations of polymers ore related to a measured pressure drop observed during turbulent flow of the solution. Low concentrations of polymers of ethylene oxide and acrylamide (frequently used as flocculants for clay waste systems) in aqueous and salt solutions have been successfully measured on the apparatus constructed by the Bureau.

Jan 1, 1981

By R. V. Ramani, A. S. C. Owili-eger

List of Numbers

Jan 1, 1974

By Thomas L. McVay

Laboratory batch and pilot plant flotation tests were made to determine the feasibility of recovering commercial grade kyanite from a quartzite- kyanite rock from the Graves Mountain, Ga., deposit. Best results in laboratory and continuous tests were obtained using sodium carbonate for pH control, citric acid for quartz depression, and oleic acid as the kyanite collector. Over 80 percent of the kyanite was recovered in a concentrate analyzing 56.8 percent Al203 and 3.8 percent hydrochloric acid soluble Fe203. Subsequent treatment of the flotation concentrate by magnetic separation reduced the acid soluble Fe2O3 to 0.6 percent and increased the alumina content to 59.2 percent. Acid leaching of the concentrate gave a product analyzing 59.7 percent Al203 and about 0.1 percent Fe203. As a result of the beneficiation research, a commercial kyanite flotation plant was completed in September 1962 by private industry.

Jan 1, 1963

By L. T. MCELVENNY, Robert B. McElwaine, M. Clair Smith

Production of mercury from the cinnabar deposits of the southwestern Arkansas mercury district began in 1931 , reached its peak in 1942 , and ended in 1944. The mines are now idle . Virtually all the cinnabar was obtained from deposits in a belt , about a mile wide , of steeply dipping sandstone beds in the overriding blocks of three thrust faults . The belt was productive for a length of about 27 miles eastward from eastern Howard County, through Pike County, into Clark County . During the early life of the district, Federal agencies watched and recorded its progress as a contributor of a strategic metal, and later, during the war, conducted investigations designed to advance its development . In 1941 , the Bureau of Mines and the U. S. Geological Survey cooperated in investigations on eight mineralized areas in the western part of the district , to wit : Hales mine , U. S. mine , Lulu Bell property, Hopkins Hill , East Gap Ridge , Gap Ridge , Parnell Hill , and Section 17 mine area . U. S. Geological Survey prepared both surface and mine maps and designated the areas to be investigated ; the Bureau did the drilling , trenching, and sampling involved in the investigations . Twelve holes , aggregating 3,539 feet of bore , were diamond drilled on six properties ; 5,309 linear feet of surface trenches were bulldozed in six areas and 19 samples taken from them ; and 86 underground channel samples were cut in two adits on one property . In 1944 , the Bureau of Mines measured mine dumps and calcine dumps in the district in an investigation of their mercury content . Two mine dumps and one calcine dump were sampled . The data pertinent to the work done by the Bureau are included in this report .

Oct 1, 1950

By Michael R. Yenchek

The U.S. Bureau of Mines investigated the operational characteristics of spliced portable power cables. This research had a dual purpose: (1) to determine the thermal and mechanical performance of repaired trailing cables and compare them with undamaged cables and (2) to gauge the impact of long-term, localized heating on the insulating and jacketing materials contained in cable splice kits accepted or approved by the Mine Safety and Health Administration. The ranges of splice joint resistance and tensile breaking strength were determined from laboratory measurements. The choice of crimping tools affected the strength of the splice under tension. Thermal profiles of energized spliced cables were constructed, which showed that spliced conductor joints operated 5 to 20°C hotter than the intact cable at rated currents. Accelerated life tests of thermally aged samples of splice kit insulation and jacket materials confirmed a deficiency in the thermal rating of the insulating tape. The recommendations in this report may be utilized to revise splice kit design, splice kit approval criteria, and trailing cable loading guidelines. Characterizing the thermal operating limits of spliced trailing cables may help to minimize the associated risks from explosions, fires, personnel burns, and shock.

Jan 1, 2010

By George L. Gates

The Bureau of Mines developed a rapid instrumental method of analyzing oil well scales containing primarily barium sulfate. After removal of oil and water by carbon disulfide) the scale was dissolved in strong hydrochloric acid. The cations, barium, calcium, strontium, magnesium, and iron, were determined with the flame photometer using the method of additions. Sulfate was deter-mined colorimetrically after separation by selective adsorption on an alumina column. Phosphate was determined colorimetrically and carbonate titrimetrically. The method was reasonably accurate, although iron and magnesium were found to have mutual interference.

Jan 1, 1965

By Alex C. Smith

This report describes laboratory studies conducted by the Bureau of Mines to evaluate the effectiveness of 10 additives to inhibit the self-heating of coal. Aqueous additive solutions were applied to a bituminous coal with a high spontaneous combustion potential, and the minimum self-heating temperatures (SHT's) of the dried coal-additive mixtures were determined in the Bureau's adiabatic heating oven. The relative effectiveness of the additives was determined by the observed changes in the minimum SHT's of the mixtures, or by the time required for the sample temperature to reach 150" C, compared with the untreated coal and a coal-water blank. Sodium nitrate, sodium chloride, and calcium carbonate were found to be the most effective inhibitors, followed by ammonium dihydrogen phosphate, calcium chloride, ammonium chloride, sodium acetate, and potassium chloride. Two additives, sodium formate and sodium phosphate, promoted the self-heating process. Differential scanning calorimetry experiments on the coal-additive mixtures showed that reactions occurred between the coal and some of the additives, but these reactions did not influence the self-heating process.

Jan 1, 1988

By Neil B. Young

Carbonate minerals constitute a major fraction of the oil shale in Colorado's Green River Formation. Quantification of carbonate minerals is important for the characterization of oil shale, particularly because of their thermal activity in production of oil from shale. The carbonate minerals found in this oil shale are nahcolite (NaHCO3), dawsonite [NaA1(OH)2CO3], dolomite [(Mg1-xFx)Ca(CO3)2], calcite (CaCO3), and ferroan [(Mg1-xFex)CO3]. Although carbonate minerals can be removed by acid extraction from the balance of the oil shale, direct determination of carbonate minerals is complicated by the occurrence of the same cations in more than one mineral. A method for assigning the acid-soluble cations to the individual carbonate minerals was developed from two assumptions based on oil shale geochemistry: (1) Calcite and ferroan do not occur together, and (2) the ratio of iron and magnesium is the same in dolomite and ferroan. These assumptions were tested by the Bureau of Mines by applying the technique for assigning cations to 219 samples from the saline section of the formation. The reported carbonate mineral amounts were compared statistically with X-ray diffraction peak heights, verifying the cation assignment method.

Jan 1, 1975

By D. Harrington

Advocates of health and safety in mining have found themselves confronted in recent years with what might appear to be contradictory procedures with regard to dust occurrence in mines and what appear to be suitable methods or measures to give the mines and mine workers a maximum measure of protection against dust. A concerted and relatively effective drive has been made to introduce rock dust into bituminous and lignitic coal mines to prevent or limit explosion and fire disasters, while an equally determined effort has been and is now being made to curb rock dust or to eliminate it from air in metal mines to prevent or at least limit the occurrence of miners' consumption and other diseases. Both procedures are logical even though the efforts appear to be of an opposing nature. While rock dusting has not been applied in coal mines nearly as universally or as effectively as could and should be done, nevertheless a careful analysis of the record of the past 10 years indicates that the amount of rock dusting that has been done has resulted in the saving of a minimum? of 200 lives annually certainly no small achievement. Largely but by no means wholly due to the use of rock dusting, the number of fatalities from explosions and fires in our coal mines in the last 4 years haw been reduced more than 75 percent as compared with the 4-year period 1911-15, the first years of the existence of the United States Bureau of Mines, which was brought into existence in 1910 largely to try to do something about reducing the disgracefully high fatality occurrence from explosion disasters in our coal mines. Hence, rock dusting has been given at least a. trial and has proved its effectiveness definitely.

Jan 1, 1937

By D. W. Frommer, L. Bonicatto, M. M. Fine

A mineral - dressing investigation was conducted to demonstrate the ability of an anionic silica - flotation process to produce high- grade concentrates from submarginal iron ores of the western Mesabi and Menominee ranges . Commercially available equipment and reagents were used . Samples from the Menominee range were exclusively from the Groveland , Mich . , mine and contained hematite as the chief iron - bearing mineral . Bench- scale investigations established that the anionic silica flotation method can function effectively on a variety of undeslimed ores . Continuous tests completed on one Mesabi semitaconite ore and on Groveland mill feed , have verified the validity of the bench research . The Mesabi samples yielded a concentrate containing 60.3 percent Fe and 6.0 percent Sio with an accompanying iron unit recovery at 90.5 percent . Iron recoveries from the mill feed ranged from 79.0 to 87.4 percent .

Jan 1, 1964

By John A. Organiscak

The Bureau of Mines conducted a survey of eight shearer longwall operations to identify factors that affect respirable dust generation from longwall roof supports. The longwalls surveyed were in coal seams located in different geographic regions of the United States. Data were collected on mining (geologic) conditions, support design, operational characteristics, and amount of respirable dust generated from roof supports. Analysis indicated that mining conditions are the main factors that affect the generation of dust during roof support movement. Both roof strength and depth of cover above the coal seam showed relationships with the amount of support dust generated. Several practices are currently employed to effectively control roof support dust; however, some of these controls are limited. More research and development is needed to improve dust control technology for longwall roof supports.

Jan 1, 1985

By d&apos, Kathleen J. Amico

THIS summary appears in Minerals Yearbook volumes I and III, which cover mineral production in the United States, its island possessions, the Canal Zone, and the Commonwealth of Puerto Rico, as well as the principal minerals imported into and exported from the United States. The several commodity and area chapters contain further details on production. A summary table comparing world and U.S mineral production also is included.

Jan 1, 1964

By George S. Koch

Several methods of calculating ore grades by diamond-drill sampling in the Homestake mine, Lead, S. Dak., have been evaluated by statistical analyses of assay data. The natural distribution of gold particles, partly masked through sampling and assaying procedures, is probably lognormal. As a consequence of the gold particles being clustered rather than randomly distributed within the ore bodies, (1) more mine samples are needed to obtain a specified precision of mean grade than the number predicted by the standard-error-of-the-mean law; (2) the variance of gold values is not inversely proportional to sample volume, and, therefore, small-diameter drill core yields samples nearly as good as larger diameter core; and (3) sampling at 5-foot intervals provides nearly as good results as sampling at shorter intervals.

Jan 1, 1971

By Bernard Porter

The solubility of UO2 was determined at 1,250° C. in ternary melts of UF4 and BaF2 with CaF2, LiF, and SrF2. The solubility of Ce02 was measured at 800° and 850° C. in a solution of CeF3, BaF2, and LiF. The amount of La203 which dissolves at 950° C. in a binary mixture of LiF and LaF3 and a ternary of LiF, LaF3, and BaF2 was also measured. In each case, the amount of soluble oxide was mound to be less than 5 weight-percent. A procedure was developed for filtering fused, oxide-saturated fluoride melts in order to obtain a representative sample for chemical analysis. The oxide content of the samples was determined by an inert-gas fusion procedure.

Jan 1, 1961

By H. E. Perlee

Mathematical expressions are derived for the histories of the pressure, flame radius, mass fraction burned, and burned and unburned gas temperatures associated with a spherical flame propagating concentrically in a spherical vessel. The equations are solved numerically for a 9.5 pct CH4/air mixture using the best available information for the burning velocity, expansion ratio, and specific heat ratio. Calculated histories are in complete accord with experimental measurements. The accuracy of calculated histories is determined relative to errors in the system parameters, and it is found that 10 pct errors in either the burning velocity or the expansion ratio results in a 40-pct error in the pressure history. A 10-pct error in either burned or unburned specific heat ratio results in a 22-pct error &apos;in the pressure history. It was further established that the usual assumption of constant specific heat ratio is unacceptable, but equating the burned and unburned specific heat ratios result in no apparent error in the histories. The cubic law (P = Kt3 + Po) is derived and discussed, and it is found that the law is valid only during the early period (P<2 atm) of flame growth.

Jan 1, 1974

By W. J. Fene

Ventilation is undoubtedly the greatest single safety factor in the operation of a coal mine. Any condition or occurrence that interrupts the ventilating current or changes its normal course through the mine workings is a distinct hazard and should be considered as such by every coal-mine owner, operator, and worker. The hazard, of course, is much greater in a mine that is emitting gas, as an explosive mixture can accumulate in a very short period if the ventilating current is interrupted. It is common to find one or more entries producing 600 cubic feet or more of methane per hour. If the ventilating current were short-circuited from these entries for 15 minutes, there would be an accumulation of 150 cubic feet of methane, which, when mixed with enough air to dilute it to the lowest explosive point, would make about 3,000 cubic feet of explosive mixture; this gas could be ignited in almost any normally operated mine by a cutting machine or other electrical equipment. The ignition of this quantity of an explosive gas-air mixture can readily cause an explosion of coal dust that would completely wreck the underground workings and possibly some of the surface structures. In fact, the ignition of one-tenth of the above quantity of an explosive mixture of gas and air might readily start an explosion that would, extend through every part of a large mine. The possibility of occurrence of interruptions to the ventilating current has received comparatively little consideration from mine owners, operators, and workers in many parts of the United States. Such a possibility should be considered in connection with every mine that gives off explosive gas, and steps should be taken to prevent it.

Jan 1, 1943

By Rudolf E. Greuer, Linneas W. Laage, Xinton Chang

UNIT OF MEASURE ABBREVIATIONS USED IN MFIRE FT foot FT3/MIN cubic foot per minute LBM•MIN2/FT4 pound mass times minutes squared over feet to the fourth FT2/HR square feet per hour BTU/HR*FT*F British thermal unit divided by hours times fimes feet times degree Fahrenheit IN W G inches water gage FT3/MIN cubic feet per minute FT2 square feet FT3 cubic feet LBM, pound mass F Fahrenheit IN W G /CFM2 inches water gage per cubic foot per minute squared PERCENTAGE percent BTU/MIN British thermal unit per minute MFIRE BAT PROGRAM cls echo off echo MFIRE activated mfire0 echo Wait a moment for loading the program if EXIST zheng chg mfirel if EXIST zheng chg mfire2 if EXIST zheng chg mfire1 if EXIST zheng chg erase zheng chg if EXIST hang chg erase hang chg if EXIST yunzhi fan copy yaodong.ion+yunzhi fan yaodong ion if EXIST yunzhi fan erase yunzhi fan if EXIST xintan chg copy yaodong xin+xintan chg yaodong ion if EXIST xintan chg erase xintan chg if EXIST yaodong xin copy yaodong.xin mfire out if EXIST yaodong.xin erase yaodong.xin if EXIST net erase net echo Your output is saved in file MFIRE OUT MFIRE0 FOR PROGRAM CHARACTER•50 A OPEN (10,FILE=&apos;NET&apos;,STATUS=&apos;UNKNOWN&apos;,FORM=&apos;UNFORMATTED&apos;) NETWW=0 WRITE (10) NETWW OPEN (21,FILE=&apos;ZHENG CHG&apos;,STATUS=&apos;UNKNOWN&apos;,FORM=&apos;UNFORMATTED&apos;) A=) &apos; B=0.0 WRITE (21) A WRITE (21) A,B

Jan 1, 1990

By Donald P. Blasko

The first well that produced commercial quantities of oil in the Cook Inlet Basin of Alaska was completed in 1957. Since that time oil production in the basin has increased rapidly and by the end of 1969 had reached an annual rate of 74 million barrels. Five major oilfields had been developed, and two additional discoveries awaited development. Estimated amounts of recoverable oil by primary and secondary recovery methods total 2.7 billion barrels, or 36 percent of the estimated oil originally in place. Repressurization by injecting gas or water in formations containing undersaturated oil has significantly increased the volume of recoverable oil. All production has been from formations of the Tertiary age; that much of it is from depths of 10,000 feet or more is unusual for Tertiary formations. The oils are low in sulfur and contain low to moderate amounts of asphalt.

Jan 1, 1972