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By Robert F. Randolph

Research on improving haulage truck safety, started by the U.S. Bureau of Mines, is being continued by its successors. This two-part article reports the orientation of the renewed research efforts, beginning with an update on accident data analysis, the role of multiple causes in these accidents, and the search for practical methods for addressing the most important causes. Fatal haulage accidents most often involve loss of control or collisions caused by a variety of factors. Lost-time injuries most often involve sprains or strains to the back or multiple body areas, which can often be attributed to rough roads and the shocks of loading and unloading. Part II will describe research to reduce these accidents, including improved warning systems, shock isolation for drivers, encouraging seatbelt usage, and general improvements to system and task design.

Jan 1, 1997

By L. N. Plein, J. W. Paul

"The United States Bureau of Mines, in the interest of the prevention of injuries and fatalities in coal mines, has engaged in a study of the circumstances and conditions under which falls of roof and coal contribute to coal-mine accidents, and this publication is devoted to the result of a study conducted in mince developed in the Pittsburgh or No. 8 coal in eastern Ohio.To emphasize the need of this study a statement of the fatalities which have resulted from falls of roof is presented, followed by a brief description of the field and its geology. The mining methods, regulations, and timbering practices are presented and discuss, as well as supervision and discipline, all of which are important factors in the control of the roof and the prevention of falls of roof material that are liable to result in injury to the underground workmen.During the five-year period, 1924 to 1928, there were 10,820 fatalities in the cool mines of the United States, of which number 5,573 or 51.5 per cent resulted from fells of roof material, such as draw slate or roof coal, and of coal from the fact or sides. These fatalities generally occur singly, consequently they are given little publicity compared with major disasters consulting from explosions which, during the same five-year period, amounted to only 17.8 per cent of the total fatalities.Seven,mines in eastern Ohio, each typical, of mines in its locality, have been carefully studied, and the result of this study is herein presented so the information may be and beneficial to all who may be operating mines having,similar natural or physical conditions.In general, it will be found that measures taken to prevent injuries or fatalities from falls of roof as well as other safety measures, will have the effect of increasing the efficiency and economy in mining operation. The result of the study so far made on the falls of roof problem indicates that such features as mine management, supervision, inspection, discipline, character of roof, timbering methods, and blasting have a direct bearing on any scheme that may be evolved to prevent injury or loss of life by falls of roof."

Mar 1, 1931

[1.1. The provisions of this code are minimum provisions and are designed to minimize hazards to life and property in and about underground coal mines where electrical equipment and circuits installed used. They indicate the Steps necessary in the selection, installation, operation, inspection, and maintenance of electrical equipment and circuits to obtain proper safeguards in reducing electric shock, fire, explosion and other hazards. Surface as well as underground installations were considered in formulating the code and, unless otherwise stated, each provision applies equal to both underground and surface installations. This code does not apply to buildings and installations not directly connected with mining operations, nor does apply to strip-mining operations.]

Jan 1, 1952

By Joe B. Rosenbaum

New applications and concepts of solvent extraction as a unit operation in extractive metallurgy have been developed in the last decade. Wider use is being made of established solvent extraction techniques in processing spent nuclear fuel elements and in winning columbium-tantalum, hafnium-zirconium, thorium, tungsten, uranium, and vanadium. Commercial application has been extended to recovery of beryllium, boron, bromine, copper, molybdenum, phosphorus, rare-earth metals, and rhenium. Systems in use and proposed typically extract metals or salts as anion, cation, or neutral species from aqueous media by reaction with a recycleable organic reagent.

Jan 1, 1971

By G. B. Atkinson

The Bureau of Mines investigated a method for increasing the leaching rate of bulk superalloy scrap to facilitate recycling and recovery of critical metals such as Ni, Co, and Cr. Three superalloys were investi- gated, the cast-nickel-base superalloy IN-738, the wrought-nickel-base superalloy Rene-41, and the cast-cobalt-base superalloy Mar-M-509. Superalloys melted with 20, 30, 40, and 50 pct Al metal to form inter- metallic compounds were easily crushed to a convenient particle size and reacted rapidly with acid solutions which dissolved the metals. For example, leaching 1/2-in pieces of unalloyed IN-738 with excess 6N HC1 at 95° C for 2 h dissolved about 0.5 pct, while leaching 10 g of minus 20-mesh 30 pct Al-70 pct IN-738 with excess 6N HC1 at 95° C for 2 h dis- solved 96.2 pct.

Jan 1, 1983

By N. E. Hanna

As part of a program for improving, the safety of permissible explosives, the Federal Bureau of Mines has undertaken an investigation to establish the ability of sodium chloride to reduce the incendivity of permissible explosives to firedamp atmospheres. A motivating influence for this investigation has been the comparatively extensive experience of British and other European investigators, who used sodium chloride as a component of their permitted explosives (1, 5, 6 7).5/ In the United States research and development work of this type has been less extensive, although sodium chloride has been added to permissible explosives as a cooling agent (9) for many years. The results of the first phase of this investigation were presented in a previous paper (8), which established that adding up to 10 percent sodium chloride to permissible explosives reduces the likelihood of ignition of firedamp in the gallery test; however, the results were somewhat inconsistent, and the conclusions were qualified. Accordingly, the investigation was continued with a study of the effect of added sodium chloride as a function of the quantity added and of the particle size of the salt.

Jan 1, 1960

By C. H. Fisher

Sulphuric acid of various concentrations has long been used as a reagent in the determination of olefins and aromatics in hydrocarbon oils4 such as gasoline, kerosene, and neutral oils from coal-tar distillates. Despite its long use, however, there is no general agreement as to optimum conditions and concentration of acid, and numerous methods and modifications have been recommended. In most cases, treatment of the neutral oil with 80 to 90 percent sulphuric acid, followed by distillation to the original endpoint to remove olefin polymers, is recommended for the estimation of unsaturated hydrocarbons. The distillate thus obtained is taken as olefin-free oil and used in later stages of the anlysis. Aromatic hydrocarbons generally are determined in the olefin-free oil by suphonation with more concentrated acid (96 to 100 percent and fuming sulphuric acid are recommended), the hydrocarbons not attacked and removed as water-soluble sulphoric acids being considered as saturated hydrocarbons. In some cases the saturates are examined further by differentiating between cyclic (naphthenes) and acyclic hydrocarbons (paraffins), Generally this is achieved by physical methods, although strong sulphuric acid is known to react preferentially with some types of saturated hydrocarbons. It was the purpose of the present work to make a general study of this type of analysis and to investigate the reactions of hydrocarbons under conditions often used in analyses that employ sulphuric acid reagents. Since previous work is not in good agreement, the optimum concentrations of acid for the different stages of the analysis were determined. Several sulphuric acid methods previously recommended and new modifications were compared, two synthetic solutions being used as the reference oil. The results obtained are presented below under separate headings.

Jan 1, 1937

By C. H. Fisher

Sulphuric acid of various concentrations has long been used as a reagent in the determination of olefins and aromatics in hydrocarbon oils4 such as gasoline, kerosene, and neutral oils from coal-tar distillates. Despite its long use, however, there is no general agreement as to optimum conditions and concentration of acid, and numerous methods and modifications have been recommended. In most cases, treatment of the neutral oil with 80 to 90 percent sulphuric acid, followed by distillation to the original endpoint to remove olefin polymers, is recommended for the estimation of unsaturated hydrocarbons. The distillate thus obtained is taken as olefin-free oil and used in later stages of the anlysis. Aromatic hydrocarbons generally are determined in the olefin-free oil by suphonation with more concentrated acid (96 to 100 percent and fuming sulphuric acid are recommended), the hydrocarbons not attacked and removed as water-soluble sulphonic acids being considered as saturated hydrocarbons. In some cases the saturates are examined further by differentiating between cyclic (naphthenes) and acyclic hydrocarbons (paraffins), Generally this is achieved by physical methods, although strong sulphuric acid is known to react preferentially with some types of saturated hydrocarbons. It was the purpose of the present work to make a general study of this type of analysis and to investigate the reactions of hydrocarbons under conditions often used in analyses that employ sulphuric acid reagents. Since previous work is not in good agreement, the optimum concentrations of acid for the different stages of the analysis were determined. Several sulphuric acid methods previously recommended and new modifications were compared, two synthetic solutions being used as the reference oil. The results obtained are presented below under separate headings.

Jan 1, 1937

By Martin Hertzberg

In this Bureau of Mines study, an equation is derived for the limit burning velocity for divergent, spherical propagation from an ignition kernel of radius, r: (Su)e = ( ) . For flame propagation into a preexisting, stretching velocity gradient of magnitude dv/dx, the limit velocity is (Su)e = (a dv/dx)1/2. These formulations are shown to be equivalent to the fluid dynamic concepts of Damkoh1er, Kar10-vitz, and Markstein. Existing data for the b10woff limits of flames are shown to give excellent agreement with those concepts provided that proper account is taken of two dilution effects: composition dilution caused by entrainment and velocity gradient dilution caused by flow expansion. Approximate flow-field solutions are also derived for the unburned gas motion above an upward propagating, spherical flame kernel in buoyancy-induced flows. It is shown that;, the upward hemisphere propagates toward a stagnation plane in a counterflow configuration involving the balance between the combustion force, which accelerates the cold gas upward, and the buoyancy force that accelerates the cold gas downward. The position of the stagnation plane above the upward propagating hemisphere is related to the ratio of the buoyant velocity, vb, to the burning velocity, Suo Extinction of the upward propagating wave occurs by flame stretch in that counterflow configuration when n = Vb/Su begins to exceed the expansion ratio, Pu/Pb' and the wave is blown off by its own buoyancy-induced flow field.

Jan 1, 1984

By E. Robert Ruhlman

["Phosphate rock" is a broad term applied to natural deposits of minerals valued chiefly for their phosphorus content. More specifically, phosphate rock may be defined as a natural rock containing one or more phosphate minerals, usually calcium phosphate, of sufficient purity and in sufficient quantity to permit its use directly, or after beneficiation, in the manufacture of phosphorus-bearing products. The grade or quality of phosphate rock is expressed either in terms of its phosphorus oxide (P20S) content or the equivalent in tricalcium phosphate (Ca3(P04)2). The trade name for tricalcium phosphate is bone phosphate of lime (B. P. L.).]

Jan 1, 1958

By K. E. Stanfield

The Bureau of Mines oil-shale program, initiated in April 1944, is concerned with the future utilization of oil shale in the United States as a source of liquid fuel. One phase of this program is the accumulation of information on the location, extent, and richness of oil-shale deposits that may be suitable for processing to oil and related products. A previous publication5/ presented, by means of logs, the oil yields of sections of the largest known oil-shale deposit in this country -the shales of the Green River formation occurring in adjoining portions of the states of Colorado, Utah, and Wyoming. This present supplementary report presents the oil yields of cores from 48 holes drilled during 1952 to 1954 in the Green River formation of Colorado, which is distributed over an area of more than 1,000 square miles. The oil yields of the 48 oil-shale sections, involving the assay of 9,651 samples, representing 22,451 feet of core, are presented by means of logs. In addition, the oil yields of samples comprising the maximum sections of 15 gallon-per-ton shale are tabulated for these cores and for the 28 cores from Colorado which were logged in the previous report.

Jan 1, 1957

By Albert L. Toenges, Louis A. Turnbull, Henry E. Dekay, James N. Scudder

A preliminary survey of coke and steel plants conducted by the Bureau of Mines in cooperation with the Office of Solid Fuels Coordinator and under the auspices of the Coke Production Committee indicated that a very appreciable increase in pig-iron production would be obtained if pres- ent blast furnaces were supplied with a more uniform coke. Control of the sulfur and ash content of coal used for making coke is an important factor in producing uniform coke and thus increasing blast- furnace efficiency. In some mines producing metallurgical coal, the analysis of the coal bed shows a wide range of sulfur and ash content. To obtain production of coal with minimum deviation in sulfur content sampling, grading, selective mining, blending, and surface preparation are practiced at some mines with satisfactory results. The mines selected for this study have developed these methods and are successfully producing coal of uniform sulfur and ash content. The systems employed at different mines vary according to the physical character- istics of the coal bed, the manner of occurrence of impuritites in the coal, the development plan and mining system, surface preparation and the acceptable impurity content of the prepared coal. The ash content of the coal can be controlled by face preparation and in the cleaning plant. The introduction of some method or practice at other mines might make possible the use of coal for inetallurgical purposes that otherwise could not be used for making coke because of the wide variation of sulfur and ash content.

Dec 1, 1943

By Sam Friedman

The Bureau of Mines conducted experiments using bench-scale apparatus to explore the effect of large changes in process variables on the yield and composition of the gases produced by passing 800° C steam through a fixed bed of Pittsburgh seam (hvab) coal. The total yield of combustible gases increased throughout the given range for the following variables: Superficial steam velocity increasing from 0.02 to 0.12 fps, pressure increasing from 1,000 to 6,000 psig, residence time increasing from 0 to 60 minutes, and temperature increasing from 800° to 900° C; however, a greater increase in the yield of hydrogen in comparison with the increase in yield of methane reduced the gross heating value of the gas to around 470 Btu per scf at conditions giving the maximum yield. Pressures of 1,000, 3,000, and 6,000 psig at 0.09 fps steam velocity, 800° C, and 60 minutes residence time, respectively, produced methane yields of 20, 24, and 22 percent, based on maf coal, with the gross heating value of the CO2-free gas decreasing from 552 to 520 and to 470 Btu per scf. Methane concentrations in the CO2-free gas were 26, 22, and 14 percent, respectively. Based on the gross heating value of the coal, the percentage of the heating value recovered in the gas was 60, 71, and 87 percent, respectively. The use of tungsten sulfide as a catalyst for converting carbon oxides and hydrogen into methane was explored briefly using both a sulfur-free gas rich in methane and a sulfur-bearing synthesis gas (3H2:1CO).

Jan 1, 1968

By L. J. Froisland

Water classification and heavy-media sink-float methods were investigated for concentrating metallic junk automobile shredder rejects initially upgraded to about 75-percent metal content in an air elutriation system. An 8-inch-diameter water elutriation column with a feed capacity of 2.7 tons per hour was constructed and operated. The results obtained were compared with those produced by sink-float methods. Tests made on duplicate samples of an intermediate-grade metal product were successful in upgrading the metal con-tent from 75 percent to 98.7 and 99.1 percent with respective recoveries of 95.5 and 98.9 percent for the water classification and sink-float procedures. Tentative flowsheets for treating junk auto shredder rejects are outlined.

Jan 1, 1972

By T. T. Campbell

This report traces the development of techniques for the preparation of high-purity rare-earth metals. Rare-earth metals, excepting samarium, europium, and ytterbium, were prepared by converting their oxides to anhydrous chlorides or fluorides and reducing the rare-earth halides with active metals such as lithium or calcium. High-purity, anhydrous rare-earth chlorides were prepared by dissolving the rare-earth oxides in hydrochloric acid to form hydrated chlorides and by subsequently dehydrating the hydrated salts in the presence of ammonium chloride at temperatures ranging from 70° to 360° C. while under reduced pressure (50 microns to 1 inch Hg). The chlorides were also prepared by direct chlorination of rare-earth oxide-carbon mixtures. Reaction efficiencies in excess of 95 percent were obtained by either method; however, purer chlorides were prepared by the aqueous ammonium chloride conversion method. Purification of yttrium chloride by high-temperature vacuum distillation proved to be an effective method of separating, oxygen-bearing compounds from the chloride. Yttrium metal prepared from purified chloride contained significantly smaller amounts of oxygen (990 p.p.m. oxygen in yttrium metal prepared from raw chloride and 200 p.p.m. in that prepared from distilled chloride).

Jan 1, 1961

By E. J. Gleim

[THE ORGANIC act under which Federal Bureau of Mines was established provided for the investigation of the safe use of electricity in mines. Each Congress appropriates funds for conducting this investigation. As part of this investigation, electrical apparatus used in mines is studied to determine if its operation and use might introduce a hazard. From this study, certain safety standards have been developed. These standards, established with the aid of both the manufacturer and user of such apparatus, are published in schedules, and apparatus that complies with the requirements set forth these schedules is classified as "permissible." This term is defined to designate apparatus as "completely assembled and conforming in every respect with the design formally approved by the Bureau of Mines." In the judgment of the Bureau, the manufacturers of such apparatus have adhered to certain minimum standards of safety in supplying a product that when properly used and maintained is safe for operation in mines where flammable gas or coal dust may accumulate. This work of the Bureau of Mines for increasing safety does not make it obligatory for manufacturers of mine equipment to produce only that of permissible classification. Before the effective date of the Federal Mine Safety Code,5 the Bureau sought to promote safety by recommending that mine operators install permissible equipment in gassy mines as a preventive measure against gas and dust explosions initiated by electrical equipment. For some years, the mining laws of several States have prescribed the conditions under which permissible equipment must be used. The Federal Mine Safety Code requires that ?all new electric face equipment and replacements of equipment purchased for mines where nonpermissible equipment is now being used shall be of a permissible type approved by the United States Bureau of Mines,]

Jan 1, 1955

By James W. Townsend

The Vicksburg mining property lies in the southeastern foothills of the Star mining district, Beaver County, Utah (fig. 1). Within a few miles of the Vicksburg mine, lying in a semicircle from south to northwest, are such past producers of lead-silver ores as the Moscow, Hoosier Boy, Red Warrior, Wild. Bill, Harrington-Hickory, and many others. Farther to the north, in the San Francisco district, are the famous Horn Silver and Cactus mines. The formation at the Vicksburg property consists of interbedded limestone, shale, and dolomitic limestone. These beds have been metamorphosed by the intrusion of irregular masses of porphyritic igneous rocks grading from quartz-monzonite to granodiorite. Ore deposition is in north-trending fissures of sheeted zones, contact metamorphic in type. These depositions were subsequently altered to gossan. A preliminary investigation of the Vicksburg property involving surveying, mapping, and sampling was made by W. A. Young and F. H. Gunnell, engineers of the Bureau of Mines, in the fall of 1946. As a result of the investigation, a project was set up to investigate the possibility of ore occurrence at greater depth on the fissures under the mineralized zone by diamond drilling.

Jan 1, 1950

By J. F. McIlwain

As part of its goal to minimize the requirements for critical materials, the Federal Bureau of Mines has investigated the consolidation of an iron-base superalloy (20 pct Cr, 5 pct each Ni and Mn, 1 pct each C, W, Mo, and Cb, and the balance Fe) and its modifications by powder metallurgy (P/M) techniques. Vacuum-atomized, prealloyed powder was used. Consolidation was by sintering of cold-pressed alloy powder, or by forging plus rolling or extrusion of canned powder. Several commercial lubricants were evaluated in the pressing operation. At 50-tsi compacting pressure with up to 3 wt-pct lubricant, green strengths did not exceed 1,000 psi. Powder sintered just below the solidus temperature attained a tensile strength of 69,000 psi and 4 pct elongation. Liquid-phase sintering produced higher densities, lower tensile strengths, and nil ductility. Canned powder was forged and rolled at 1,200° C, yielding a 100-hr rup¬ture strength of 9,800 psi at 815° C and a room-temperature tensile strength of >130,000 psi at 6 pct elongation. Heat treatment of modified P/M iron-base alloy containing 0.63 pct C resulted in a 100-hr rupture strength of 17,000 psi. Oxidation resistance at 805° to 815° C of the forged and rolled P/M iron-base alloy was similar to that of the cast iron-base alloy and supe¬rior to conventional stainless steels.

Jan 1, 1981

By Dean H. Ambrose

This Bureau of Mines publication summarizes the status of mine electrical equipment reliability research. Failure rate data were estimated from theoretical, laboratory, and field studies. Tables are presented listing reliability characteristics of molded-case circuit breakers, undervoltage relays, ground check monitors, cables, motors, and control circuitry. Application of failure rate data is shown in tables listing maintenance scheduling intervals of components and components that are most sensitive to the probability of hazardous voltages on power distribution systems in the mines. Complete, accurate, and appropriate failure rates on mine equipment are of the utmost importance for reliability evaluations.

Jan 1, 1985

By W. B. Tarpley

This program was conducted to demonstrate the unique advantages of suppressing methane ignition in underground mines by use of Energy & Minerals Research Company's thixogel fire extinguishing system, which stably suspends dry powder extinguishing agent in thixotropically gelled liquefied gas extinguishant. As anticipated, the project demonstrated thixogel system advantages of: 1) capability to disperse state-of-the-art powders in thixogelled Halons; 2) non-agglomerating stability for dependable expulsion; 3) stability in storage for long shelf life; 4) virtually in¬stantaneous dispersion; 5) expansive cloud formation; 6) reach and re-forming around obstacles; 7) at least twice the extinguishant effectiveness; and 8) compatibility of use with Fenwal bottles and MSHA canisters. Thus, it should prove a superior explosion/fire suppressant for coal face cutters and triggered barriers, as well as for motorized equipment, electrical equipment and the like.

Jan 1, 1981