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By K. O. Bennington

The thermodynamic properties of hedenbergite, of composition [(Ca0,9516) (Mg0,0583Fe2+0.7134 Fe3+0.0934 Mn0,1366) (Si206)], were experimentally determined at the Bureau of Mines. The standard enthalpy of formation determined by hydrofluoric acid solution calorimetry is AHf298 = -680.96±0.855 kcal/mol. The standard enthalpy of formation from the oxides is AR-96 = -24.55±0.485 kcal/mol. Low-temperature heat capacities were determined by adiabatic calorimetry from 12.3 to 300.1 K. The derived standard entropy is S-98 - 41.218±0.148 cal/mol-K. High-temperature heat capacities were measured with a differential scanning calorim¬eter from 397 to 1,147 K. These experimentally determined data were combined with data from the literature to calculate the Gibbs energies of formation and equilibrium constants of formation over the temperature range of measurements. Standard enthalpies of formation are given as a function of temperature. The standard Gibbs energy of formation at 298.15 K is AGf298 = -641.90±0.86 kcal/mol.

Jan 1, 1984

By M. A. Elliott, F. W. Brown

"INTRODUCTION During the recent war the Bureau of Mines, at the request of one of the armed services, investigated the hazards that night be encountered 5n handling perchloric acid, particularly if spilled on certain materials. The hazardous nature of perchloric acid when mixed with reducing agents had been known qualitatively, but it was desired to obtain quantitative data on the explosion hazards of such materials. Accordingly, tests were made to determine the sensitivity of mixtures of perchloric acid and oxidizable materials to initiation by heat, impact, sparks, flame, and explosive impulses. This report summarizes the results of those tests.PROPERTIES OF PERCELORIC ACIDAnhydrous perchloric acid is a colorless,hygroscopic, volatile, mobile liquid that fumes in the air. The anhydrous acid is unstable at ordinary temperatures, and therefore the commercial acid is a water solution containing either 60 percent or 70 percent by weight of the anhydrous acid. The commercial acid is widely used in chemical analysis, frequently to oxidize organic material. If proper precautions are not observed, such an oxidixation may become exceedingly rapid and result in an explosion. Several such explosions involving the acid are mentioned in the literature. 4, 5, 6/"

Jan 1, 1948

By K. J. Liles

The Federal Bureau of Mines conducts a comprehensive test program on clay and shale at the Tuscaloosa Metallurgy Research Center. All samples are subjected to standard preliminary ceramic tests, which include firing formed briquets at temperatures ranging from 1,000° to 1,250° C to identify firing range and colors, and quick-firing to determine bloating characteristics. Materials that shop potential as structural products are further tested after either extrusion or dry-pressing. If the quick-fire test is positive, bulk samples can be fired in a rotary kiln to evaluate their potential as light- weight aggregate A number of miscellaneous tests also can be conducted if requested. These tests determine properties such as refractoriness (pyrometric cone equivalency), oil-bleaching characteristics, oil absorbency, viscosity for drilling-mud applications, sand-bonding properties for foundry usage, and pelletizing characteristics.

Jan 1, 1977

By Sidney Katell

The present report, a continuation of the series of Bibliography of Investment and Operating Costs for Chemical and Petroleum Plants, is concerned with articles published from January 1958 through December 1958. The periods covered in previous reports are as follows: January 1930 - August 1948 I. C. 7516 September 1948 - June 1952 I. C. 7705 July 1952 - June 1954 1. C. 7751 July 1954 - December 1956 I. C. 7847 January 1957 - December 1957 I. C. The following sources were used to obtain the references to and the abstracts of the published articles included in this report: 1. Bureau of Mines Information Circulars. 2. Bureau of Mines Reports of Investigations. 3. Chemical Engineering. 4. Chemical Engineering Progress. 5. Coal Age. 6. Coal Utilization. 7. Cost Engineering. 8. Industrial and Engineering Chemistry. 9. Nucleonics. 10. Oil and Gas Journal. 11. Petroleum Engineering. 12. Petroleum Refiner. 13. World Oil.

Jan 1, 1959

By R. S. Dean

The function of the Metallurgical Division is to conduct investigations relating to the treatment of mineral products from the state in which they are mined to the refined metal or other unfabricated product. These investigations include scientific and practical studies of ore dressing, covering the crushing and grinding of ores, separation by gravity, flotation. and magnetic methods; the hydrometallurgical treatment of ores, including cyanidation and amalgamation of the precious metals; the smelting and refining of copper, lead, and zinc, as well as the rare metals; and steel-melting practices from the raw ore to the finished steel. The object of this work is to conserve natural resources and eliminate waste by furnishing information on current methods of metallurgical practice. making fundamental studies of metallurgical processes, and developing new processes to the point of demonstrating their practicability. The Division is made up of sections devoted to the several phases of this work, each section being headed by an investigator capable of supervising his particular work. The work is carried on at the experiment stations and field offices or in the field, whichever seems best suited for the work in hand. The following, projects should be mentioned as particularly outstanding among those consummated successfully during the year: 1. Application of the type of chemicals known in the textile industry as wetting-out agents to flotation and agglomeration of ores, particulary soluble salts such as sodium and potassium chloride which must be treated in saturated brine. 2. Demonstration or a linear relation between surface and coercive force in magnetic minerals and Its application to magnetic separation and to the determination of grinding efficiencies and other metallurgical data which require surface determination at very fine sizes. 3. Pilot-plant demonstration of the practicability of the reduction of iron ore by natural gas and conversion of this direct iron into steel by direct melting and by forging and rolling before melting. The structure and properties of the iron so produced were studied in detail. This report covers the fiscal year July 1. 1934, to June 30, 1935.

Jan 1, 1936

By Oliver Bowles

Limestone is the most widely used of all racks and is essential to a great many industries, including tae building trades, highway construction, metallurgy, agriculture, end many chemical and manufacturing enterprises. It occurs in some form in every State and is produced in thousands of quarries. Production in 1930 exceeded 134,000,000 tons. It has more numerous and more diversified uses than any other rock. This paper is designed to furnish general information on the various branches of limestone quarrying and their economic importance. Brief reference is made to dimension stone, and a more complete discussion follows of the uses, requisite qualities, quarry methods, grid processes of preparation of crushed and broken limestone. Footnote references serve to guide the reader to more detailed information.

Jan 1, 1933

By Irving Hartmann

Rock-dusting of coal mines is a most important safety measure for preventing or limiting the propagation of explosions. The Bureau of Mines has recommended for many years that rock dust be distributed on the top, ribs, and floor of mine entries and other workings of all bituminous coal and lignite mines in sufficient quantities to maintain the incombustible content of the dust above the minimum requirements. Rock-dust barriers constitute a secondary safeguard used occasionally to complement generalized rock dusting at entrances to panels and side entries or at other locations. In general, rock dust can be applied effectively with modern rock-dusting machines. However, in thin coal beds, in certain back entries, and in some other areas, rock-dusting machines cannot be used conveniently. Furthermore, many small mines find the purchase of machines costly. In such cases, rock dust is not used at all, or else it is distributed by hand, a relatively slow and costly procedure. In recent years some coal mines have started applying rock dust with the aid of permissible explosives. This may be done in various ways. One method consists in placing a stick of explosive on the floor of a room or entry midway between the ribs and covering the stick with two bags of rock dust that are slit on top and set crosswise one above the other. The explosive is then fired, causing the rock dust to be distributed on the nearby roof, rib, and floor surfaces. The procedure is repeated at desired intervals until the entire area is rock dusted. The method is claimed to be rapid, safe, and inexpensive.

Jan 1, 1950

By Raymond L. Lowrie

Coal deposits in the Boulder-Weld County coalfield in Colorado are analyzed in relation to economic factors governing the growth, stability, and competitive potential of the coal industry. Recoverable reserves, estimated to be 571 million tons, are discussed in detail, particularly those in the Erie and Frederick Quadrangles. Geology of the coal measures, quantity and quality of water resources, and chemical and physical properties of the coal are described. Coal production factors, including mining techniques and equipment, labor requirements, transportation facilities and rates, and markets, are considered for coal's position in competition with alternate fuels. Growth of the fuels market, through increasing thermal-electric power generation in the Denver Metropolitan Area, will stimulate coal production in Colorado. Reserves of the contiguous Boulder-Weld coalfield, if mined in a sustained, year-round, high-tonnage operation, could be used to supply much of that fuel demand.

Jan 1, 1966

By Oliver C. Ralston

[The NOJ'l..metals Division deals wi tt mi:leral n t inte .ded to be used a ra\o,f materials for extraction of metals. ~ _ ereas, a. materinl containing a chromite, if used' for production of c~1r()rrti1..1r.'l ::tetE' .. l or fcrrochromiu"1, 1,oJould be a chromi te ore, if used as 8. rcfrn.cto~J or for prod .1.ction of chromium chemicals, it is a chromi te-beari [. ~?oCl... Li;{eHise, a r:1a&neti te used for production of iron is a metallifero"'..ls ~in8re..i; if used 8.S a water-filtration granule in .:l magne.tically cleaned filter bed, it 'ould be a nonmetallic in-dustrial mineral.]

Jan 1, 1940

By R. L. Grant

[Detonators are used to explode permissible explosives, dynamites, or other high explosives. This explosion or detonation is brought about by the energy which is liberated as a combination of concussion and heat when the detonator is fired. In Other words; "The detonator is the key which unlocks the energy of a high explosive" (8)4. Being sensitive and latently dangerous, detonators must meet two primary requirements: They must be safe to handle and must detonate when desired, thereby imparting detonation to the explosive charge.]

Jan 1, 1941

By R. S. Dean

The function of the Metallurgical Division is to conduct investigations relating to the treatment of mineral products from the state in which they are mined to the refined metal or other unfabricated product. These investigations include scientific and practical studies of ore dressing, covering the crushing and grinding of ores, separation by gravity, flotation, and magnetic methods; the hydrometallurgical treatment of ores, including cyanidation and amalgamation of the precious metals; the smelting and refining of copper, lead, and zinc, as well as the rare metals; and steel-melting practices from the raw ore to the finished steel. The object of this work is to conserve natural resources and eliminate waste by furnishing information on current methods of metallurgical practice, making fundamental studies of metallurgical processes, and developing new processes to the point of demonstrating their practicability. The Division is made up of sections devoted to the several phases of this work, each section being beaded by an investigator capable of supervising his particular work. The work is carried on at the experiment stations and field offices or in the field, whichever seems test suited for the work in hand. The following projects should be mentioned as particularly outstanding among those consummated successfully during the year: 1. Application of the type of chemicals known in the textile industry as wetting-out agents to flotation and agglomeration of ores, particulary soluble salts such as sodium and potassium chloride which must be treated in saturated brine. 2. Demonstration of a linear relation between surface and coercive force in magnetic minerals and its application to magnetic separation and to the determination of grinding efficiencies and other metallurgical data which require surface determination at very fine sizes. 3. Pilot-plant demonstration of the practicability of the reduction of iron ore by natural gas and conversion of this direct iron into steel by direct melting and by forging and rolling before melting. The structure and properties of the iron so produced were studied in detail. This report covers the fiscal year July 1, 1934, to June 30, 193b.

Jan 1, 1936

By Clyde E. Williams

[As a results of work conducted during the past three years, the Northwest Experiment Station of the Bureau of Mines, in cooperation with the University of Washington at Seattle, Washington, has developed a process for the production of sponge iron. Commercial operation of this process in a 3 to 4-ton scale has been so satisfactory that its use on a large scale (20 to 100 tons per day) can be safely considered. Description of Process. The process consists in passing a mixture of iron ore and coal through a rotating kiln heated at one end to a temperature sufficient to convert iron oxide to metallic iron, discharging, cooling, and separating the sponge iron from the residual coke and silicious material on a magnetic separator. Both the coal and the ore should be crushed to peso as 6-meth scream, tans producing particles finer then 1/12 of an inch. Seventy-five parts of coal or other carbonaceous material arc charged with every 100 parts of ore), This large amount of coal is required in order to supply sufficient carbon to maintain a strongly reducing atmosphere in the charge, but may be reduced to about 65 parts per 100 parts of ore by recovering and using tae carbon that remains in the discharge product. Large-scale operation and refinements in furnace design should lower this ratio to perhaps 56 or 60 parts of coal to 100 parts of ore.]

Jan 1, 1924

By R. S. Nutter

The results of designing, constructing, and laboratory testing of a modular, distributed, microprocessor-based mine monitoring and control system are presented. A standard computer communications protocol (DDCMP) was utilized throughout the system. Tests were performed on the utilization of a high-level language for programming mine monitoring and control systems. Laboratory tests were run on a combined air velocity/methane sensor.

Jan 1, 1980

By Mayer G. Hansen

A series of papers dealing with diamond drilling practices, compiled in accordance with an outline prepared by engineers of the United States Bureau of Mines, is to be published as information circulars by the bureau. This paper, the first of the series, describes the general practice at the United Verde mine during the last ten years; specific instances cited in the paper refer to 1930, the last year of full operation. The United Verde copper mine is located at the town of Jerome, Yavapai County, north central Arizona.

Jan 1, 1933

By Stephen P. Holt

During the spring and summer of 1946, the Bureau of Mines put down 8 churn-drill holes and 9 diamond-drill holes, totaling 3,535 feet of bore, at the Blewett zinc-lead deposit in Jo Daviess County, Ill. Attention of the Bureau of Mines was first directed to this deposit by the Illinois State Geological Survey, which had investigated the Blewett mine. In the opinion of the Survey and the Bureau of Mines, the record of production and results of drilling previously done on the property were considered sufficient justification for continuing investigation to the north and south along a projection of the trend. This report describes the work done by the Bureau on this, property and presents the data obtained.

Jan 1, 1948

By Nan C. Jensen

Modern high-temperature metallurgical processes have created a demand for raw material for furnace parts and lining that not only will with-stand high temperatures is but will not react with the substance being melted in the furnace. Spark-plug insulators, laboratory ware, tanks for the glassmaking making industry, and saggers and kiln furniture for the chinaware and pottery trades also must be made of materials hat have high melting points. Among the minerals that can be employed for such refractory uses ore those commonly known as the "sillimanite group' -kyanite, andaluste, sillimanite, and dumortierite - and the allied minerals topaz and pinite. Consideration of the occurrence, properties, qualities, uses, and sources of supply of these commodities and the markets for them constitute the subject of this paper. General Features of Kyanite and Related Minerals Kyanite, andalusite, and sillimanite ire composed of three elements - aluminum, silicon, and oxygen ? and are called aluminum silicates. The have

Jan 1, 1943

By W. H. Oppelt

A lignite from west-central North Dakota (Mercer County) was dried by the Bureau of Mines by the Fleissner process at saturated steam pressures to 1,500 pounds per square inch absolute (p.s.i.a.). Normally, the process is operated at pressures of 200 to 370 p.s.i.a. At the highest pressure the temperature of the saturated stearn is 596° F. The purpose of the investigation was to evaluate the influence of very high stearn pressure and temperature on moisture removal, steam consumption, and physical and chemical characteristics of the dried lignite. Two drying cycles were used: A normal cycle, corresponding to previously established standard time requirements, and an accelerated cycle, wherein time requirements were determined by boiler capacity and handling speed. Blank tests to determine stearn requirements for heating the empty autoclave were performed for each cycle and each test condition. Moisture removal, final moisture content, net steam consumption, and size stability of the dried lignite were determined.

Jan 1, 1959

By W. D. Dietzman

This Bureau of Mines report presents a profitability analysis of producing crude oil by waterflooding. Included are the estimated costs of installation of water injection and producing equipment for waterfloods at 2,000 and 4,000 feet and the estimated annual operational expenses for each in west Texas. Using these cost estimates as a base for selecting a range of costs that are indicative of producing crude oil by waterflooding, a simulation technique was derived for determining the profitability under various conditions. Because of the large number of combinations of variables used in this study, a high-speed digital computer was utilized for the calculations. The variables include operational expenses, capitalized costs, price of the oil, annual production, and leasehold acquisition cost. The results obtained from the simulations are presented Fn the appendix. In addition, a nomographical approach was chosen for presentation of the profitability. Five nomographs are presented that can be used for fast estimation of the discounted cash flow (DCF) rate of return that might be expected from a prospective or active operation under various sets of assumed conditions.

Jan 1, 1974

By Walter D. Holland

This is one of a series of instruction guides developed to help instructors present health and safety training courses to workers in the coal mining industry. This course is intended for training those, usually the safety officers, who perform surveys fur inhalation contaminants in above ground work areas. The handbook entitled ?Handbook for Surveys of Inhalation Contaminants in Above Ground Coal Mining and Processing Work Areas? (NTIS #PB-243-35";) is used as a manual for the course and as a prime reference when performing the actual surveys or interpreting the sampling results. There are six experiments for the students to perform during the course to familiarize them with the sampling devices routinely used during the surveys.

Jan 1, 1976

By Thomas P. Mucho

Retreat or pillar recovery mining redistributes the overburden weight onto the adjacent coal pillars in a room-and-pillar section. The additional stress and the resultant energy stored in the remaining pillars can become so great that pillars may bump or violently fail. An investigation at the Gary No.2 Mine was conducted to examine the effectiveness of the thin pillar mining method for mitigating bump occurrences. Field observations were made and instruments were installed to monitor pillar behavior during extraction. Stress monitoring instruments and roof-to-floor convergence stations were installed in pillars and entries and crosscuts, respectively. Results indicated that high pillar stress concentrations occurred in these bump-prone geologic conditions. The thin pillar mechanism, the creation and progressive outby movement of an expanded yield zone, was also monitored through the instruments. The expanded yield zone, a result of using thin pillars in a highly stressed pillar line area, mitigates bump risk.

Jan 1, 2010