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By G. B. Shea

"In 1928, there were 47 fatal accidents in the California petroleum industry, 14.6 per cent more than occurred in 1927 when 41 men lost their lives in the drilling, producing, manufacturing, and marketing divisions of the industry. This increase in the number of fatal accidents for 1928 has caused the first upward trend in the fatality curve of the California petroleum industry since 1923. In no other year during the 6-year period have the fatalities in any one year been greater than those for the preceding year. This fact should be given serious consideration and study by the petroleum industry, and an endeavor should be made to cause the number of fatalities again to decrease and conform to the previous gradual declining trend of the fatality curve.The following chart shows the trend of fatal accidents during the past six years:Of the 47 fatalities in 1928, 30 occurred in the drilling and producing division, 1 in the pipe line and transportation division, 14 in the refining division, and 2 in the sales and marketing division. A comparison of the number of fatalities in each division for 1927, and 1928, is given in the following table:3"

Sep 1, 1929

By L. G. Marshall

This report is one of a series published by the Federal Bureau of Mines describing mining methods and performance at individual operations throughout the United States. The objective of these papers is to promote development and conservation of our mineral resources by disseminating reliable technological information on mining methods, practices, and results that may be applied to the engineering analysis and solution of mining problems. SUMMARY Operation of a limestone quarry producing flux for the steel industry and crushed stone for production of concrete is described in this report. The deposit being mined is a flat-lying limestone formation under a thin overburden 2 to 25 feet thick. The height of the quarry face varies from 9 to 60 feet, averaging 40 feet. Production rate ranges from 4.5 to 5 million long tons per year.

Jan 1, 1959

By N. A. C. Smith, A. C. Fieldner, R. R. Sayers

Gases and vapors given off by petroleum and its products have long been recognized as somewhat injurious, when inhaled in high enough concentrations. The petroleum industry has recognized these effects and has tried to minimize the possibility of employees encountering dangerous concentrations of the vapors. Petroleum gases and vapors have not, however, been considered as actively poisonous, in the sense that hydrocyanic (prussic) acid and phosgene are poisonous; men have been exposed to them repeatedly, and for long periods, without any marked ill effects. Light Mexican crude oil when first introduced into the United States for refining was handled in much the same way as was customary with other apparently similar crudes; but experience soon showed that some toxic substance escaped from the crude during production and transportation and in most of the refinery operations. After a preliminary investigation several of the larger companies decided that the gases from the petroleum were the source of trouble, and therefore took precautions, wherever possible, to protect the men from exposure to these gases. With the increasing use of Mexican crude, this problem has become important. The present report covers the work done on the subject by the Bureau of Mines and the Public Health Service under a cooperative agreement with the American Petroleum Institute.

Jan 1, 1925

By W. E. Wallace, V. Castranova, F. Saus, D. Bates, C. A. Hill, V. Vallyathan, M. J. Keane

"Two in vitro systems are being developed to model initial stages in the interaction of respired dusts with the acinar region of the lung. Incubation of quartz and kaolin with dipalmitoyl glycerophosphorylcholine, a major component of pulmonary surfactant, suppresses the prompt C)1otoxicity of both dusts as measured by in vitro enzyme release from pulmonary macrophages or assay by erythrocyte hemolysis. Additional data is presented to quantitate the detoxification of quartz and kaolin by dipalmitoyl lecithin. Subsequent incubation of lecithin treated dusts with phospholipase enzymes results in partial to complete restoration of the assayed cytotoxic potentials, dependent on the lipase activity applied, the incubation time, and the mineral. Restored cytotoxic potential is due to removal of the prophylactic lecithin surface coating and/or due to residual lysolecithin which is produced by the partial enzymatic digestion of lecithin. Data is presented on the contribution of each mechanism to the restored toxicity. Again, this is dependent on the mineral used, the lipase activity applied, and digestion time. Additionally, a system is under development to challenge pulmonary macrophages in culture with native and surfactant treated dusts. A preliminary test of the dipalmitoyl lecithin - quartz rabbit pulmonary macrophage system is presented to illustrate the method.IntroductionRespirable quartz dust exposure is known to cause librotic lung disease; respirable clay dust exposure is less likely to do so as indicated by epidemiologic data on occupational exposures and by animal model studiesP·7) The hypothesis that damage to pulmonary macrophages in the acinar region of the lung by respired dusts is an early event in the disease process requires consideration because kaolin clay and quartz dusts are comparably cytotoxic to pulmonary macrophages in vitro.(3•9)"

Mar 1, 1989

By R. O. Dannenberg

The Bureau of Mines conducted laboratory investigations with the objective of developing an alternative process for recovering cobalt and copper from complex sulfide concentrates. Processes currently used depend largely upon precipitation techniques to remove impurities and recover cobalt from sulfate liquors prepared by oxidative pressure leaching of the sulfide concentrates. The Bureau conducted bench-scale research on a process for treating cobaltite concentrates, comprising (1) oxidative pressure leaching, (2) jarosite precipitation followed by H202 oxidation and pH control to remove iron and arsenic, (3) copper solvent extraction with a mixed hydroxyoxime-amine extractant, (4) copper electrowinning from recirculating acidic strip liquor, (5) selective cobalt extraction from copper solvent extraction raffinate with a phosphinic acid extractant, and (6) electrowinning of cobalt from a recirculating weak acid strip liquor. Overall cobalt and copper recoveries were 91.7 and 84.1 pct, respectively. Electrowon products assayed 99.8 pct Co and 99.89 pct Cu.

Jan 1, 1987

By J. B. Rosenbaum

This report presents new findings and consolidates previously published data to provide a single reference containing a concise and comprehensive description of the Bureau's work on electrolytic chromium. Two separate systems for electrolytic-chromium recovery were developed, one designated as the oxidized system the other as the reduced system. The electrowinning of chromium metal follows the dissolution of chromium from the ore or from ferrochrome and its separation from gangue and metallic impurities. Chromite was first solubilized by pressure digestion at slightly elevated temperatures in an oxidized acid solution using Na2Cr2O7 as an oxidizing agent. Later it was found that a sodium-free electrolyte was preferable, using return-cell anolyte containing H2SO4 and Cr03 as the oxidizing agent. Gangue materials were separated from the soluble metallics by filtration; and, after the Cr+3 had been stabilized, the metallic impurities were separated as crystalline ammonium salts by vacuum crystallization.

Jan 1, 1957

By E. P. Carman

In this report, the Federal Bureau of Mines presents a summary of the occurrence, properties, and uses of some natural bitumens, using the layman's or dictionary definition of bitumens - that is, naturally occurring hydro-carbons. Emphasis is on the less common solid and semisolid bitumens, particularly those occurring or used to some extent in the United States. This comprises data from many sources and references to these sources for more detail than is given in this summary. This paper was prepared primarily to answer questions about some of the less known bituminous materials. The word hydrocarbons could just as well have been substituted in the title for bitumens, but bitumens was used, since an abstract of the paper was presented at a meeting where the major emphasis was on bituminous materials. The reader will realize that coals, of which only the more unusual such as the cannel coals and torbanites are discussed in this paper, are primarily mixtures of bituminous materials and carbon. The amount of bituminous material, or volatile matter, in coals is greatest in the lower rank coals and the unusual types described in this paper, and decreases as coal rank increases. However, since no method other than destruction of the original coal substance by heat is known that will separate the volatile matter from the carbon, it appears reasonable to classify the coals with other bituminous materials, particularly since bituminous coal - the most widely used coal - by its name indicates the combination of bituminous materials and carbon.

Jan 1, 1961

By Donald R. Corson

The Bureau of Mines is conducting research on the effects of various established and potential soil-stabilization additives to hydraulic backfill. This initial phase is an evaluation of the effect of inclusion of varying amounts of Portland cement and combinations of cement and a dispersant on the bearing strength of backfill. Results of unconfined compression tests are given for over 200 sample cylinders incorporating a fill material with cement or cement and dispersant. Inclusion of a minor amount of dispersant (0.2 percent by weight) is found to yield a significant increase in strength for 20-to-1 and leaner sand-cement mixes. An apparent optimum concentration of dispersant exists beyond which no further increase in strength is achieved. A dispersant-cement ratio of l.8- to-1 yielded a strength increase of 515 percent over the strength of untreated 40-to-l sand-cement mixes.

Jan 1, 1966

By R. Lindsay Mundell

In the first half of 1990, lessening of cold war tensions was welcome. But Iraq's invasion of Kuwait in August led to the Persian Gulf War in January and February 1991. The subsequent oil shock contributed to a dampening of the U.S. economy, and the U.S. gross national product rose only 0.9 % to $5,463 billion (U.S. billion = 109). The buildup of military forces in the Persian Gulf area focused greater attention not only on petroleum but also on other strategic materials. The U.S. Department of Defense continued to review stockpile goals and upgrade several mineral materials. In addition, the U.S. Bureau of Mines continued to maintain the standby Emergency Minerals Administration. After the Defense Production Act, which authorizes priorities, allocations, and supply expansion, lapsed on October 20, 1990, the Selective Service Act of 1967 became the authority to ensure that orders of the Armed Forces and defense atomic energy programs were given priority treatment.

Jan 1, 1993

By N. L. Wimmler

The Metaline mining district was examined in 1942 by Bureau of Mines engineers with the cooperation of geologists of the Federal Geological Survey. Because the demands of war production were rapidly depleting reserves in some of the older zinc-lead producing districts of the United States, it was decided that an attempt should be made to increase the proved or indicated ore reserves of the Metaline district. With this objective, certain areas to be explored by diamond drilling were selected. The Bureau of Mines began work on this program. January 15, 1943; work terminated September 8, 1945. Forty-five holes were drilled in seven areas, The holes ranged from 154 feet to 2,050 feet in length. Their combined length was 38,150 feet. Thirty-three of the holes were drilled in. the North Pend Oreille and the West Bella May areas.

Jan 1, 1949

Auger operations produced 14 million tons of coal in 1974, or approximately 5% of all surface mined coal. It was the most efficient of all coal mining methods, producing 40.0 tons per man-day. Exhibit 1.1 gives a breakdown of productivity of all coal mining methods. Exhibit 161 PRODUCTIVITY OF COAL MINING METHODS (Short tons per man-day) [Method - 1971 1972 1973 1974 Conventional 11.00 10.00 9.75 9.30 Continuous 13.00 12.50 12.25 11.90 Strip Mines 35.69 35.95 36.00 36.00 Auger Mines 39.00 43.00 45.33 40.00 ] Unlike other surface mining methods, augering produces clean coal, largely uncontaminated by foreign materials, other than those existing in the coal seam itself. However, compared to other methods, the coal recovery rate is relatively low. For example, a triple-headed auger in a 35-inch seam would recover approximately 50% of the coal in the seam as compared to a 90 to 95% recovery rate for strip mining and a 55 to 65% recovery rate for deep-mining. The low auger recovery rate is due to the circular cuts and pillars left in the seam.

Jan 1, 1975

By B. J. Moore

This publication contains routine analyses and related source data for 528 natural gas samples from 21 States collected during calendar year 1965 as part of a continuous survey of the United States for occurrences of helium in natural gas. This survey has been conducted by the' Bureau of Mines since 1917. The analysis published herein were made by mass spectrometer and a special helium analysis apparatus, which are described in Bureau of Mines Bulletins 4863 and 576.4

Jan 1, 1966

By B. J. Moore

This publication contains routine analyses and related source data for 528 natural gas samples from 21 States collected during calendar year 1965 as part of a continuous survey of the United States for occurrences of helium in natural gas. This survey has been conducted by the Bureau of Mines since 1917. The analyses published herein were made by mass spectrometer and a special helium analysis apparatus, which are described in Bureau of Mines Bulletins 4863 and 576.4

Jan 1, 1966

By B. M. Stewart

Researchers at the U.S. Bureau of Mines conducted a long-term groundwater monitoring and site characterization program at an abandoned 10-ha, acid-producing, copper-gold tailings impoundment in north-central Washington State. The purpose was to investigate contaminant release and transport, and attenuation mechanisms in the tailings, sediments below the tailings, and gravels downgradient of the impoundment. This report summarizes the monitoring results and physical properties of the tailings, the sediments below the tailings, and the groundwater system associated with the tailings. Water samples from the vadose and saturated zones of the impoundment were analyzed for 15 constituents. Concentrations of the same constituents were determined in water samples up to 3 m beneath the impoundment and in the shallow colluvium and deep bedrock at 76, 335, and 550 m downgradient and 168 m upgradient. Constituent concentrations within the tailings are quite variable and are influenced by pH, depth of oxidation, grain-size differential (surface area), hydraulic gradient, groundwater mixing, and the presence of hardpan layers, carbonaceous material, and organic matter. Most of the metal constituents decreased to background or near-background concentrations in the farthest downgradient well.

Jan 1, 2010

By M. C. Irani

This study is a survey of supply and demand for minerals, metals, alloys, and compounds used by the chemical industries in the Ohio River Basin (ORB) area of Ohio, Pennsylvania, and West Virginia during 1967. Data for the study were obtained from completed questionnaires received from chemical manufacturers and from interviews with officials of chemical companies and mineral producers and distributors. The information includes kind, quality, quantity, values, sources, specifications, uses, and methods of transportation. Results of the study show that of the total value of mineral materials consumed by the chemical industry, manufacture of inorganic chemicals consumed 46 percent; fertilizers, 22 percent; and soaps and detergents, 19 percent. Fifteen commodities accounted for 91 percent of the total value of mineral materials consumed. Five of these--phosphates, potash, salt, sulfur, and titanium dioxide--accounted for 59 percent of the total.

Jan 1, 1970

By David E. Kaslow

In sampling dust laden air by drawing the medium into an inlet, some larger particles fail to follow the air and a true sample is not obtained. Inertia prevents particles from accelerating with the air as well as from turning sharp bends; also the particles' weight causes them to fall relative to the air. An analytic solution to the sampling efficiency calculation by Levin gives particle paths and sampling efficiencies for various particle sizes when the inlet can be treated as a point sink. However, the flow field in the neighborhood of an aspirating tube is quite different from a point sink flow. Employing Levin's solution in the outer field, trajectories in actual flow fields have been calculated by computer to locate the critical trajectories separating the entering particles I paths from those paths where the particles hit the tube wall or escape. Sampling efficiencies are presented in terms of 3 variables--a dimensionless particle size coefficient, a dimensionless orifice size coefficient and the tube orientation--for the no-wind case. Over most of the range of sampling conditions, the Stokes drag law can be used and dependence on the variable--particle Reynolds number--can be ignored. A procedure for achieving maximum efficiency in design of a sampler is proposed. Whether these results apply when typical room-sized eddies constitute the ?calm air? environment is not known.

Jan 1, 1974

By Edwin C. Reeder

This paper, describing milling methods and costs at the Hillside Fluorspar Mines at Rosiclare, Ill., is one of a series being prepared for and published by the United States Bureau of Mines on non-metallic milling methods. The milling practice described is that of one of the large mines in the Kentucky-Illinois fluorspar field in southern Illinois and western Kentucky, on the Ohio River. Milling methods throughout the district are similar in their general principles, although details vary considerably in different plants.

Jan 1, 1932

By Zsuzsanna Zborovszky

Investigation of the discharge duration power and current relation required for ignition. The current and power amplitude-discharge time curve was found to flatten out over 3 ms. It is concluded that discharges having at least 3 ms power maximum are required for reliable testing of the ignition limit for resistive circuits. Investigation of the effect of molten cathode on the discharge duration and igniting ability of the discharge. The surface tension of the liquid metal causes a very fast separation and consequently a much shorter discharge duration than the solid electrode would have. The minimum discharge voltage effect overrides the effects of the temperature of electrode, material, or atmosphere. Investigation of the effect of different surface layers on the discharge duration. Oxides and sulfates were found to give significantly longer duration than the "clean" metal itself in most cases. The lowest ignition current was obtained with CdS04 coatings. Ignition was obtained with 0.7A at 30V, which is below the corresponding minimum igniting current obtained from the BASEEFA curve for circuits containing Cd, Zn or Mg.

Jan 1, 1977

By W. H. Ode

Because trade increased among various nations after World War II, the Coal Committee of the Economic Commission for Europe established a Classification Working Party in 1949 to develop an International system for classifying coal. Although national classification systems existed, they had been developed in accordance with characteristics of domestic coals without reference to coals of other countries. Terms for describing similar or identical coals differed in each nation. This caused confusion in evaluating coals shipped in international trade and also hampered exchange of technical information on problems of coal utilization. Experts4/ participating in the classification project early in their work agreed that two systems should be formulated, one for the higher rank coals or so-called "hard" coals in European terminology and the other one for the lower rank coals, the latter designated mainly as brown coals and lignites in the various countries. Rank refers to the degree of metamorphism (progressive alteration) in the natural coalification series from lignite and brown coal to anthracite. The system for classification of hard coals was published late in 1956 as a document of the United Nations.5/ Results of a study for applying this system to American coals were published in 1958.6/

Jan 1, 1960

By W. J. Kroll

Despite the fact that barium minerals are plentiful and widely distributed in nature, this element is one that we do not yet know how to prepare cheaply in metallic form. This is due to its chemical activity, as evidenced by its great affinity for fluorine, chlorine, oxygen, nitrogen, hydrogen, and sulfur. Furthermore, it forms a very stable subchloride and subfluoride, which prevents isolation of the metal by fusion electrolysis from a halide bath. A good survey of the metallurgy of barium calcium, arid strontium has been made recently in Light Metals (54,55).3/ Metallic magnesium (46), calcium (83), barium, and strontium (27) reduce each other's oxides. Proof of this can be found in the activation of BaO after reduction with Mg, which leads to the formation of so-called "Maquenne" mixtures (58) used for absorbing gases. However, it is impossible to extract the reduced metal- from the residue, a fact that Guntz (25) attributed to the formation of barium suboxide. There is no necessity for presuming the formation of such a compound, as it has boon established that in the reduction there is always formed an alloy of the alkaline-earth metal with the magnesium, which is capable of producing hydrogen when brought into contact with water. The reduction of alkaline earth-metal oxides with aluminum was observed by Mallet (57) in 1877, but recent investigations have shown that the end product of the reaction is an alloy of aluminum with the alkaline earth metal (1,2). Silicon also has been suggested as a reducing agent, and the results obtained are the same (84,85).

Jan 1, 1945