Search Documents

By S Durucan, A Korre

The application of simple methods of statistical analysis, coupled with geostatistical analysis and geographic information systems, can only summarise and give an outline of the spatial distribution of the parameters measured. Spatial analysis of the components or factors calculated, through principal component analysis or factor analysis, allows assessment of the geographical distribution of the dominant processes contributing to soil composition and/or contamination. Neither of these tools, however, distinguishes between the different sources of pollution. The application of canonical correlation to the data, driven by expert appraisal of the potential pollution sources, allows their quantitative and spatial assessment while GIS provides the environment in which to organise and present the results. The methodology is illustrated by its application to soil-contamination data from the Lavrio area in Greece, where silver-bearing orebodies have been mined for more than 25 centuries

Jun 21, 1905

By G. M. Steed, A. O. Oyinloye

The deposit lies in amphibolite-facies biotite granite-gneisses of Proterozoic age, 4 km east of a major crustal break known as the Ifewara-Zungeru fault. Gold mineralisation is contained in a zone of quartz-carbonate (mainly calcite) veins and hydrothermally altered gneisses with associated small-scale intrusions along a steeply dipping second-order fault zone that roughly parallels the main fault. Gold is present mainly at grain boundaries between quartz and carbonate as discrete particles up to 100 micrometres in size, in general association with sparse, scattered pyrite, pyrrhotite and some base metal sulphides. Adjacent to the gold-bearing zone the granite-gneisses have been hydrothermally altered with minor volume increase, most notable enrichment being in K2O, S, Pb and Cu (and Au). High concentrations of Th, Y, Ce and Zr in the granite-gneisses imply derivation from S-type granites. It is likely that their high heat production capacity maintained the high temperatures needed to transport gold in the hydrothermal systems. It is most probable that the mineralisation dates from the Pan-African orogeny (650-450 Ma)

Apr 1, 1996

By J Hadijigeorgiou, R. W. Lawrence, R Pouling

The layered co-mingling method involves the disposal of waste rock with the addition, at predefined construction stages, of layers of dewatered mine tailings. The resulting waste structure displays bulk properties that are more favourable to acid rock drainage (ARD) control than the constituent materials alone. A laboratory test programme was conducted to examine the potential of this method. Columns containing different configurations of waste rock and tailings were percolation leached for 40 weeks and the leachates examined for various parameters. In the short term the chemical reactions that result from the introduction of dewatered tailings into rock waste can significantly improve the quality of the drainage. Columns with co-mingled material produced leachate with pH levels of 8, whereas leachate from the control column containing waste rock alone had a pH of 4. Larger-scale field tests are planned to determine the effect of the disposal method over the longer term

Apr 1, 1996

By Seong-Taek Yun, Chil-Sup So, Seung-Jun Youm

The greisen-bordered quartz veins are spatially, temporally and genetically associated with a late Cretaceous granite intruding an early Palaeozoic, limestone-rich formation. Paragenetic data indicate three stages of hydrothermal mineralisation, the first typically in or within 500 m of the granite stock and showing vertical zoning between deeper Mo and higher W, the other two more abundant in the upper and outer parts of the mineralised area. Fluid inclusion and stable isotope data indicate that hydrothermal veins formed over a temperature range of 120-395 degrees C from low-salinity fluids. Early wolframite and molybdenite deposition in stage I occurred at temperatures of 300-395 degrees C from magma-derived, low-salinity, CO2-rich fluid, mainly as a result of fluid boiling and associated CO2 effervescence. Progressively larger volumes of local meteoric water entering the system led to the successive deposition of scheelite in stage I vugs, stage II base-metal sulphides and stage III fluorite-carbonates. Remobilisation of W and its later deposition of scheelite in the outer and shallower portions of the system occurred at 215-275 degrees C and stage II and III mineralisation from lower-temperature fluids that became progressively lighter in stable isotopes. It is concluded that the influx of meteoric water increased with distance from the cooling pluton

Jun 18, 1905

By G. G. Roy, R Shekhar

Pachuca tanks are extensively used for the cyanide leaching of gold and the carbonate leaching of uranium, processes in which oxygen mass transfer plays a very important role. Experiments were carried out to clarify the effect of design and operating parameters on oxygen mass transfer. Parameters such as the ratio of tank height to tank diameter, the ratio of draught-tube diameter to tank diameter and the tank design were found not to influence oxygen mass transfer. Results also showed that equal superficial gas velocities may be used as a criterion for scaling up oxygen mass transfer in both full-centre-column and free-air-lift Pachuca tanks with clear water. A volume-averaged, volumetric gas-liquid mass-transfer coefficient (k'av) was used to characterise oxygen mass transfer in full-centre-column tanks. The axial dispersion model was used to determine k'av. The resulting model used only tank geometry and air flow rate as inputs for the prediction of k'av in industrial-scale tanks. Predictions from the model show clearly that "local" mass-transfer coefficients, measured at one or two locations, may not adequately represent gas-liquid mass transfer in industrial tanks. It is therefore necessary to obtain an estimate of k'av

Jun 18, 1905

By O. Dojcar

The results of a laboratory investigation of rock fragmentation conducted with a model material were partially verified under field conditions. The object of the investigation was to study the qualitative and quantitative relations between the parameters of the primary blast and fragmentation to enable the planning of an economically efficient degree of disintegration with optimum utilisation of the blast energy. The three blast parameters that were considered were burden, specific charge and the ratio of spacing to burden

Jan 1, 1991

Two concentrates from Palabora, in South Africa, containing 0.056-0.068% undesirable Cu and 0.8 or 2.2% Ti, were chlorinated with air:chlorine ratios of 10:1, 15:1 and 20:1 at temperatures between 1 200 and 1 329 K. The resulting volatile chlorides were condensed and the solutions analysed for Cu, Fe and Ti. Recovery of Cu was less than 25% at low temperatures and short reaction times, but at 1 258 K almost all Cu was removed from the magnetite at all ratios of chlorine to air. At higher temperatures, the increased carrying over of iron as FeCl3 could be minimised by decreasing the partial pressure of chlorine. No titanium was detected in the volatile products and the percentage of Cu recovered was independent of Ti concentration in the concentrates, though as a function of Cl2 vol%, more Cu was recovered at 1 200 K from the low-Ti than from the high-Ti concentrate. In a fluidised-bed reactor, Cu recovery was 58-90% and iron carry-over less than 10 ppm

Jun 21, 1905

By W. E. Stephens, A. J. Boyce, D. Lowry

Paper presented at Mineralisation in the Caledonides, the Mike Gallagher memorial meeting held in Edinburgh, 27-28 June 1996. An integration of S isotopic, fluid and mineralogical data for granitoid-related mineralisation showed that the porphyry systems had a predominantly subcrustal magma source, but the inner magma pulse of two-mica granite in the Fleet pluton was derived mainly from reduced sediments. The porphyry-style mineralisation formed from boiling fluids at high crustal levels, with a moderately saline fluid percolating down to the upper veins as they cooled but not penetrating the deeper Talnotry deposit. Veins in peripheral greywackes have a significant magmatic component but also incorporated CO2-rich components and metals released by dewatering of host sediments in response to granitoid intrusion. The low grade of regional metamorphism resulted in the significant fluid input from country rocks which led to the more exotic mineral compositions, especially where argillaceous sediments were involved

Jun 19, 1905

By J. S. Duval

Paper presented at the 28th International Geological Congress held in Washington DC, July 1989 (International geochemical mapping sessions). The compilation of the National Uranium Resource Evaluation aerial gamma-ray data to produce maps of the apparent surface concentrations of potassium, uranium and thorium for the conterminous USA has resulted in a reasonably accurate representation of the distribution of these elements in the surface rocks and soils. This claim is supported by the general agreement between the mapped geology and the patterns seen in the data

Jul 1, 1991

By R. J. Gochin, M. A. Diaz

A modified Hallimond tube is described which allows the determination of the ultimate recovery R and the flotation rate constant k in a single, continuous experiment. The range of fine particles which can be satisfactorily floated with the modified apparatus can be extended by increasing the length of the bottom part of the tube. Findings suggest that pyrite and arsenopyrite can be separated in alkaline suspension using the so-called F series of collectors. Lime was found to act as a depressant. The collectors operate under pH and dosage control and do not require other depressants. Collectors used in the study were thio-amine (a cationic surfactant) and alkyl propionamide (a non-ionic surfactant)

Apr 1, 1995

By G. B. Harris, A. R. Laplante

Fine tungsten was used to mimic gold and fine and coarse silica and magnetite to mimic gangue. The optimum flow rate of fluidisation water varied from 1.7 l/min for fine silica to 5.6 l/min for coarse magnetite. Overloading at optimum flow rate was then investigated. With fine silica gangue no overload occurred under any of the conditions studied, and there was very little overload with fine magnetite. Coarse silica caused appreciable overload, but only after a significant bed of tungsten had been formed; with fine magnetite gangue the onset of overloading occurred earlier. Finally, with coarse magnetite severe overloading occurred almost immediately. Overloading was modelled using a first-order kinetic rate constant for erosion of the concentrate bed and a critical mass of constant above which it takes place. The results clearly demonstrate the importance of removing oversize to maximise recovery, particularly with a high-density gangue

Jun 18, 1905

By R. G. Kidel, S. C. Doming

The project has shown that it is feasible for a junior company to reopen a narrow vein-style gold mine and successfully take it into production. An intimate understanding of the mineralisation and a flexible approach to mining are crucial, as are stringent cost control and efforts to keep overheads low. The project has confirmed the geological complexity of the Main Lodes, which consist of highly sheared quartz-sulphide infill in strongly sericitised granodiorite. The existence of discrete high-grade zones within the Hangingwall Lodes has also been confirmed. Broad low-grade zones continue to be recognised and require the local application of bulk longhole mining methods. The initial mine plan called for predominantly longhole stoping, but adverse ground conditions have meant that a switch to air-leg mining has produced higher run-of-mine grades. The excess capacity at the processing plant can best be used by batch processing, with its reduced maintenance requirements

Jun 21, 1905

By P. H. Davenport, L. W. Nolan

Paper presented at the 28th International Geological Congress held in Washington DC, July 1989 (International geochemical mapping sessions). Geochemical mapping provides a direct approach to delineating areas of epigenetic mineralisation and for relating the regional distribution of this mineralisation to an overall tectonostratigraphic and structural framework, as well as to extensive areas of hydrothermal alteration. Organic lake sediment is a widely available and effective sampling medium for regional geochemical mapping in Newfoundland, that has proved to be valuable in Au, Sb and W exploration

Jul 1, 1991

By P. J. Baguley

The model has been developed on the basis of the observation that the partitioning behaviour of a particle is related to its calculated terminal velocity. It utilises a theoretical calculation of the terminal velocity of each particle class. This is then correlated with the observed partition data for a plant separator using empirically-derived functions of operating conditions which take into account effects such as bath turbulence, holes in drum lifters and feed arrangements. The model successfully decouples the effects of medium density and viscosity and is appropriate for any bath-type separator. The correlation between calculated terminal velocity and actual partitioning behaviour was established and modelled using data obtained from two Wemco drums treating Fe and Mn ores. The model can be used to predict the prevailing size-by-size partition curves and the separation (product grades/recoveries) given the washability of the feed and operating conditions. Simulations are used to show that, for the treatment of Fe ore, there is a maximum medium density beyond which product grades fall and that this maximum decreases as the proportion of magnetite in the medium increases. This is attributed to the dominant effect of viscosity at higher medium solids concentrations

Jun 18, 1905

By Boorder De, B. S. Panov, A. B. Westerhof, V. A. Korcemagin

Paper presented at the conference on Economic geology in Europe and beyond II, models for <mineral deposits> in sedimentary <basins>, held in Keyworth, UK, 13-14 April 1994. The Hg and Sb deposits of the Mediterranean and Circum-Pacific Belts are often found at elevated structural levels, suggesting that their preferential occurrence in young orogenic belts is not a fundamental metallogenic feature but merely reflects their chances of surviving post-orogenic peneplanation. In western Europe their emplacement appears often to be related to late orogenic extensional events accompanied by a notable increase in heat flow. Although Nikitovka and Almaden have quite different settings, both appear to be related to deep-reaching shears. Together with brittle fault zones at higher levels, these provided pathways for fluid phases that originated at least partially within the mantle. The Nikitovka deposits are located in the Donets segment of the 2 000 km Pripyat-Dniepr-Donets palaeorift in the East European Platform. Initiated in the mid-Devonian with a possible Precambrian precursor, its listric boundary faults displace the Moho from a depth of about 50 km north and south of the rift to 35 km along the axes of the Pripyat and Dniepr segments. The steep central anticline of the Donets segment, within which the main Hg-Sb district is located, is interpreted to be associated with a reactivated fault reaching into the upper mantle. The Almaden syncline, formed during the Variscan Orogeny, may be an older pull-apart basin or half-graben associated with the collapse of the Cadomian Orogenic Belt. It is situated on a major ENE-WSW-striking shear zone which may represent a Late Cadomian transfer zone reaching into the mantle

Apr 1, 1995

By A. K. Tripathy, P. K. Pattnayak, H. S. Ray

The effects of water addition on the solid-state reaction between Cr2O3 and Na2CO3 at low temperatures (up to 873 K) were investigated to determine its possible influence on the reaction rate and the degree of conversion to soluble chromate. Experiments at high temperatures were conducted for comparison. It was found that adding water to the mixture before roasting enhanced both reaction rate and yield significantly. The reactions followed the Lesokhin-Tempelman equation at low temperature and the Ginstling-Brounshtein equation at above 973 K; the respective activation energies were 95 and 22 kJ/mol

Jun 19, 1905

By S. G. Beattie, N. Mojtabai

A study was carried out which aimed to: determine the effects of blasting on excavation perimeters and nearby slopes; establish a low-cost blast monitoring and field observation programme to determine peak particle velocities and blast damage; and to develop criteria for observable blast damage that are based on the peak particle velocity. Full-scale production blasts in a large open pit copper mine were monitored and studied to develop damage criteria for various rock types. Better blast designs can be achieved by correlating the results of blast monitoring with field observations of damage at the pit walls and on benches. Back-break and damage are related to blast-induced ground vibration. Peak particle velocity is accepted as a reliable measure for the prediction of ground vibration levels. Empirical models for the estimation of rock damage can be developed and used for blast design. The models are used to determine the zones of damage within the rock face. Rock damage models can also be used to design trim shots to achieve further reduction of back-break in more critical areas

Apr 1, 1996

By P. H. Carr, G. G. Marino, K. A. Patel

Extensions to a correctional institution at Wabash Valley, Indiana, required development over abandoned coal-mine workings, at 90 m depth, where subsidence was possible at surface. Backfilling of the flooded mine in critical areas was determined to be the most cost-effective method of limiting the risk of damage to the buildings. Containment grout was first placed in selected entries and cross-cuts of each mine area; the remaining volume was then filled with a readily flowing infill grout. Where a high proportion of an area was taken up by rubble, calcium lignosulphonate was used as a retarder and plasticiser to increase penetration. Grout movement was monitored from adjacent boreholes with an electrical resistivity probe during grouting, while after the work was finished core samples were obtained from verification holes drilled in the backfilled areas

Jun 19, 1905

By C. A. Pickles, J. M. Toguri

The refining of two molten Ag-Cu alloys, containing 7.5 and 11.2 mass% Cu, with a borosilicate slag was investigated using both air and pure O2 to determine the effects of the following variables: flow rate of oxidising gas; injection time; mass of sodium borosilicate flux; and injection of the oxidising gas into either the slag or the metal. The results demonstrate that more than 90% of the Cu can be removed with Ag losses of less than 5% and that refined metal with a Cu content of less than 0.5 mass% can be produced. Ag losses to the slag increased with the amount of Cu removed, and a mechanism is proposed to account for this

Dec 1, 1995

By R. Venugopal, T. C. Rao, N. Suresh

Experiments were carried out using the cyclone to treat coal in the size range -2.0+0 mm. The diameters of the cyclone outlets (vortex finder and spigot) were varied to study their effects on cyclone performance. The cyclone products were deslimed over a screen with an aperture of 0.075 mm. The performance of the separator was studied for washing coarse coal (-2.0+0.075 mm) and fines (-0.075 mm). Performance curves were plotted for the separation of -2.0+0.075 mm coal. The concept of a generalised distribution curve was adopted to predict cyclone performance. A mathematical representation was derived from the generalised distribution curve. The specific gravity of separation for individual size fractions showed a decreasing trend with decreasing particle size down to 0.85 mm, beyond which a reverse trend was noted. It was also found that the fine size fraction (-0.075 mm) does not separate on the basis of size or specific gravity but follows the water distribution

Apr 1, 1995