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By Jan J. Cilliers, Nicolas Barbian, Esther Ventura-Medina

"Mineral froth flotation is one of the most widely used processes to separate particles of valuable mineral from its associated gangue. It involves the selective separation of the hydrophobic particles from the slurry into the froth. The hydrophobic particles attach to the air bubbles and rise up to the froth phase on top of the slurry. The valuable mineral is collected when the froth overflows the cell wall. The separation performance of the process can be linked to the amount of solids and valuable material loaded on the bubble shells. In addition, it is well known that in most mineral systems, the presence of solids can enhance the stability of the froths. How the solids get to be distributed and what proportion is actually attached and stabilising the bubbles is not well known.This study aims to establish the relationship between operational variables, solids loading on bubbles and flotation performance. For this purpose, a series of industrial experiments to sample the solids in the bubble films under different operational conditions were carried out in two copper concentrators under steady state conditions. Samples of the lamellae were taken by touching the top surface of the bubbles with a glass slide. The amount of solids and liquid per unit area in the bubble lamellae can subsequently be estimated gravimetrically and by image analysis. The grade of the attached particles was also measured by adequate sampling. This gives an indication of the maximum grade that could be achieved from the process under the operating conditions."

Jan 1, 2003

By Jochen Petersen, Harro von Blottnitz

"The landfill disposal of slags is common practice in the metallurgical industry. Chromium may be a minor constituent in many cases. It is present mostly in the form of chromites, which are considered environmentally benign and hence safe for disposal. Wastewaters from metal finishing operations are most commonly treated by reduction and precipitation of dissolved metals, including chromium, by lime addition, and subsequent landfill disposal of the resulting sludge. The metals contained in such sludges are mostly in the form of hydroxides, and as such considered environmentally stable.Thermodynamically, trivalent chromium, which is the predominant form in these waste materials, can be oxidised to the hexavalent form by atmospheric oxygen. Detailed research work on both slags and sludges has shown that a gradual emergence of hexavalent chromium can indeed be observed. The mechanism is governed by close physical contact between chromium oxide (or hydroxide) phases on the one side and calcium oxide (or hydroxide), which is present as flux in slags and residual lime in sludges, on the other. If oxygen can migrate to the points of contact, gradual formation of calcium chromate ensues.Hexavalent chromium is associated with high environmental toxicity, and hence undesirable in landfilled materials. Moisture migrating through landfill deposits can mobilise the highly soluble chromates and thus potentially transport them into natural waterways. Such gradual release from stainless steel and ferrochromium slag deposits has been demonstrated in a column experiment."

Jan 1, 2003

By A. V. Nozhkina

"Transformation of diamond into graphite was investigated in the region of diamond metastability under the action of media chemically active relative to carbon in the temperature range from 770 K up to 2200 K and pressure range from 10-3 Pa up to 3 GPa/IV VIII group metals of periodic system and oxygen were used as media chemically active relative to diamond.Methods of electron diffraction, chemical analyses, emission spectroscopy and X-ray phase analyses were used for determination of the reaction products.It was found that in the region of diamond metastability the stage of catalytic phase transformation of diamond into graphite took place during the interaction between diamond and metal. Metal reduce activation energy for transition of diamond into graphite from 109,4 kcal/mole to 77,4 kcal/mole.Kinetic of phase transformation of diamond into graphite was investigated.Pressure does not considerably influence on the rate of phase transformation of diamond into graphite in the presence of transition metals."

Jan 1, 2003

By Konstantin Fedotov, Victor Beloborodov, Anatoly Potyomkin

"There are areas in Russia, which cover huge territories and they are north, and Siberia. These difficult to access regions with cold climate are rich in a great number of distant deposits of valuable and rare metals, gold and platinum. The development of such deposits requires highly effective technologies of mineral processing which could be realized in modular and quick-built processing plants.The work presented includes the results of long term research in the development of new technologies of processing of zirconium (in the form of rare mineral Baddeleyite – natural zirconium dioxide) bearing ore of the Kovdor deposit which is located in the Polar region of the Kola peninsular and also in Siberia deposits of of ledge ores of gold."

Jan 1, 2003

By Roberto C. G. Oliveira, Scott C. Brown, Brij M. Moudgil

"The wettability or surface energy of particle surfaces dictates a number of multiphase ensemble interactions that have a significant impact in mineral processing. Dispersion, bulk powder handling and flotation are just a few of the processes that are largely influenced by the degree of hydrophillicity or hydrophobicity on particulate surfaces. Because of the importance of surface wettability, a number of simple, precise and accurate techniques for accessing surface wettability or contact angle on macroscopic flat surfaces have been developed. However, these techniques cannot be directly applied to the particulate surfaces that are often in query. Though a number of techniques are available for accessing the wettability of particulate surfaces, these methods are either relative, application specific or prohibitively tedious. In the present study, key features of existing techniques are combined to formulate an improved method to delineate particle wettability that is simple, versatile and capable of providing reproducible measurements in an industrial environment.Through the use of an inert adhesive and an inert macroscopic surface as a support, it is illustrated that precise measurements of particle wettability are obtainable under suboptimal or ‘shop floor’ conditions. The measurement of the maximum external meniscus height formed between a test liquid and a particlecoated rod is employed to estimate phenomenological contact angles on particles ranging form a few nanometers to several hundred microns in size."

Jan 1, 2003

By Chris A. Bennett, Glenn S. Dobby, David A. Bulled

Establishing reagent dosing strategies for new ore bodies has traditionally involved a combination of experience and empirical experimentation using standard laboratory tests. The grade and recovery data resulting from these lab tests have historically been used as direct indicators of plant performance despite the obvious differences between the flotation environments. A reagent scheme selected in this way would subsequently be employed to generate the grade and recovery information for the geometallurgical model which in turn was used for metal production and cash flow forecasts. If the reagent scheme was sub-optimal then so too would be the forecasts and the resulting cash flow.

Jan 1, 2003

The introduction and subsequent ascendancy of autogenous and semi-autogenous milling for comminution circuits has undoubtedly lead to many economic advantages. From a process viewpoint, however, at least one downside has been the sensitivity of these machines to process input variations. Foremost among these is ore competence, though feed size comes a close second. This sensitivity is due to the reliance of ag/sag mills on the feed ore for their grinding media competence and size. Autogenous (ag) mills are the most sensitive in this respect with semi-autogenous (sag) mills being increasingly less so as the ball charge is increased. Increasingly designers and operators are recognising the importance of feed size and the benefits of manipulating it to improve performance. This has been achieved by installing additional crushing/screening capacity ahead of the ag/sag, better operation of the primary crusher, better control of segregation cased by stockpiles and bins and by changing blast design/practices to modify the ROM size distribution. This paper describes the influence of feed size distribution on ag/sag mill performance with reference to a range of plant data. It particularly concentrates on how changing blasting practice to modify ag/sag feed size can have a considerable overall benefit.

Jan 1, 2003

By P. Huang, D. W. Fuerstenau

Various factors that control the natural flotability of talc, including differences due to crystal face and edge effects, were delineated. For study of talc depression phenomena, dextrin was used as a model depressant. For the enhancement of talc flotation, dodecylammonium acetate (DDAA) was used as the collector. The interaction of DDAA with talc was assessed by flotation experiments and electrokinetic (zeta potential) measurements, from which the role of hydrophobic bonding can be demonstrated. The results presented in this paper provide useful information on how the crystal chemistry and surface chemistry control the electrical double layer, adsorption phenomena, wettability, and flotation behavior of talc in aqueous media.

Jan 1, 2003

By Scott C. Brown, Ivan U. Vakarelski

The particles commonly encountered in mineral benefication schemes have irregularites that are expressed at many different length scales. In part, this originates from preceding processes (e.g. makedown, comminution, handling and storage), which are known to chemically and physically modify the bulk particle and its surface. Interparticle tribology, dissolution and reprecipitation events along with large-scale mechanical stresses are just a handful of the interactions encountered during processing of particles prior to separation. It is feasible to imagine that each one of these events may impose a fingerprint of characteristic nanoscale, microscale, and macroscale morphological changes that can modify the overall interaction of these particles within a system. Suprisingly there are just a few works on how these resulting features can alter the performance of benefication schemes, and especially flotation.

Jan 1, 2003

By Yuhe Tang, Jun Zhang, Jianguo Liu

"The nature high carbon graphite with fine particle size has low commercial value because of its narrow application range. In order to improve its value, this paper has studied the methods for nature spherical graphite. The nature spherical graphite can be used as the battery material in the field of electronic product battery and new energy automobile battery, basis on the physicochemical characteristics and particle feature of graphite. In this research, the Fixed Carbon (FC) grade of the graphite sample is more than 95.0% and the particle size of the graphite sample is from +325 mesh to -100 mesh. There are many methods for nature spherical graphite, including the fluidized bed airflow mill, the hydro-spheroidization mill and micropowder mill. The testing results indicate that the method of ACM micropowder mill is the best because the spherical shaping ratio and production yield of spherical graphite are both the best.According to the testing results of the ACM micropowder mill, the best process includes two stages of coarse crushing, four stages of fine crushing and twelve stages of shaping. And two kinds of spherical graphite products can be got, which are the product of D50=22.85 µm and the product of D50=15.43µm, and the whole yield of them is up to 54.43%. So, it lays a foundation for the high value utilization of this kind of graphite resources.INTRODUCTION Graphite is isomer of the diamond. Graphite ore resources are mainly concentrated in China, Brazil, India, followed by Czech, Korea, Mexico, Canada and other countries. Graphite ore has lots of characteristics by itself crystal structure, such as good resistance to high temperature, electrical conductivity, thermal conductivity, thermal shock resistance, good lubricity, plasticity, chemical stability and so on. So, Graphite is widely used in metallurgy, machinery, electrical, chemical, petroleum, nuclear industry, defense industry and other areas. [1,2,3] Natural graphite ore has low geological Fixed Carbon (FC) grade. FC grade should be enriched to more than 94.0% by mineral processing. [1,2] The particle size composition of this high carbon graphite affects its application value. The part of +100 mesh particle size has high application value. The part of -100 mesh particle size has low value because of its limited application field. In order to improve the value of-100 mesh particle size, this part high carbon graphite can be made into spherical graphite. And the value of the spherical graphite is great, it is more than 8 times of the feed. This paper has lots of tests for spherical graphite preparing with the fine particle size natural high carbon graphite. And it lays a foundation for the high value of this kind of resource."

Jan 1, 2018

By K. Takahashi

Generally speaking, wastewater coming from the metallurgical process for recovering precious metal contains precious metals such as gold (Au), platinum (Pt), palladium (Pd), Silver (Ag), etc., which concentration is about 10 mg/L. In addition, there are other metals such as copper (Cu), iron (Fe), which concentration varies from several mg/L to more than 10,000 mg/L. It should be noted that the concentration of metals in wastewater is relatively high, considering the fact that these metals of similar concentration can be found in ores. However, most of these valuable metals are not treated, due to the high processing cost and technical problems. Within this frame, the authors put forward a new process that includes neutralization/reduction, precipitation and fusion. The idea is to recover and recycle Au, Ag, and Pd metals as well as protecting the environment by saving the resources. It was found that this new process was able to recover more than 90% of Au, Ag and Pd.

Jan 1, 2014

By Behzad Vaziri Hassas, Firat Karakas, Mehmet Celik, Onur Guven

Since dewatering is a costly process, removal of moisture from relatively fine size lignites is an important industrial problem. As the lignite gets finer, the presence of micropores and relatively low hydrophobic nature of lignite lead to trapping of large quantities of water in the coal matrix. Lignites used in power stations need to be dried to a certain degree of humidity before it is transferred to the combustion chamber. It is generally wise to dewater coal as much as possible by physical means before it is dried. However, dewatering cost in some cases may be prohibitive. Thus, sometimes removal of even little percent moisture may be of great help in such operations. Surfactants have been used to increase the efficiency of coal dewatering. It is crucial to select appropriate type and amount of surfactants in order to get higher efficiency. Since the hydrophobic characteristic of coals increases with increasing the coal rank, dewatering of bituminous and anthracite can be accomplished using low HLB surfactants (Oily), however, these surfactants are not efficient in the case of low rank coals like lignites and brown coals. It is suggested that adsorption of low HLB surfactants on high rank coals is governed by Acid-Base interactions rather than electrostatic and van der Waals forces. Since this characteristic in lignites is not strong enough, low HLB surfactants could not be effectively adsorbed on low rank coals to make surface more hydrophobic. In this paper, a special set-up has been designed to study the effect of high HLB surfactants on dewatering of fine lignite particles. It is shown that high HLB surfactants function more efficiently on low rank coals than low HLB ones.

Jan 1, 2014

By H. Z. Kuyumcu

Associated with the development of a novel microbiological oxidation process for the conditioning of iron hydroxide slurries from ferrous mine waters, there is a realistic chance to make the contained iron available for a material utilization. The transformation of ferrous into ferric compounds is coupled with the precipitation of iron hydroxisulphate mostly in terms of the mineral Schwert-mannite. The further treatment of the iron hydroxisulphate has to be aimed on the processing for product recovery and product refinement. For many potential applications, e.g. in the ceramic industry, the pigment industry or for metallurgical applications, the removal of sulphate is essential. For the dehydration of the iron hydroxisulphate and the sulphate removal, microwave heating technology is a beneficial method. In contrast to conventional thermal heating processes the supply of energy in microwave application takes place directly within the material through the dissipation of electromagnetic energy, i.e. no heating medium is needed. It is a volumetric heating process regardless of the surface of the material. The rapid and targeted energy supply and the good controllability of microwave heating systems are advantages which have led to a wide variety of applications in industrial processes. Among the diverse use for heating of temperature-sensitive, chemical and pharmaceutical products as well as foodstuffs the number of applications also in mineral and solid processing increases. At the Department for Mechanical Process Engineering and Solids Processing of the Technical University Berlin the use of microwave technology for the treatment of iron hydroxisulphates has been investigated systematically within the framework of a cooperative research project. The paper at hand shows results from material conversion tests subject to a variation of the relevant process parameters. The reaction products are characterized and the process is compared with the conventional heating in a rotary kiln.

Jan 1, 2014

By M. Rehor

The importance of brown coal as a raw material is currently given by growing energy needs of Czech Republic. More than 70% of mined brown coal comes from North Bohemian Basin these days. Mining of brown coal is run in four mining locations. They are geologically different and the parameters of mining coal are quite different too. This requires a little bit different methodology of both extraction and reclamation. Methods of reclamation works in the region are given mainly by the characteristics of overburden rocks appearing in the upper horizon of recuperated localities. The difficulties of the North Bohemian mine dumps reclamation works are caused by extremely unfavourable properties of rocks poured down to the majority of mine dumps. These are mainly rocks of the overlaying strata and the rocks strata of brown coal bed. Main materials poured down to the mine dumps are sands, clayey sands and kaolin ? illitic clays. Admixtures in filled rocks consist of organic (coal) mass, siderite and pyrite. These rocks are mechanically instable with respect to the wind and water erosion and during weathering they are getting unfavourable, acid (phytotoxic) nature, due to the influence of SO3 and Al ions. External and internal dumps of open pit mines are significant part of the North ? Bohemian landscape sustained by excavation. Their as fast as possible preparation and gradual integration into ecosystem of the area is interest of both citizens of region and mining companies. The paper briefly summarizes the methodology of restoration of the largest dumps of the North Bohemian Brown Coal Basin and the results of analyses and evaluation of samples taken on restored localities Rado-vesice dump, Strimice dump, Ru?odol dum pand internal dump of Bilina mine. An example of modern non-tradicional restoration methods is the restoration of internal dump of Bilina mine (application of power plant stabilizer). According to observations and results of sample analyses the methods of restoration were selected to limit the erosion influence, adjust the chemical and physical composition of surface of Radovesice and Strimice dumps. The application of marlites and bentonite prevent the unfavourable weathering processes on dump surface. Compensation of Quaternary sediments was artifically formed here. The need of marlite ploughing in, application of organical substrates and vegetation preparation was proved on Radovesice dump. The conception of landscape reclamation of the largest dumps after finishing of mining, methodology of technical reclamation and well considered using of fertilizable soils are main results presented in this article.

Jan 1, 2014

By Olgac Kangal, Ali Guney, Gulay Bulut, Guven Onal, Ayhan A. Sirkeci

This paper presents the results of pilot scale column flotation applications in the two different copper concentrators in Turkey. The Kure Copper Plant is located in the Black Sea Region of Turkey. In Kure, a very fine grinding requirement for an adequate level of liberation makes a successful flotation difficult and consequently the final concentrate can hardly assay above 16% Cu Column flotation tests were conducted at the plant site using two different column types The experiments proved that the grade of the concentrate could be increased from about 14% Cu to 25-26% Cu. Murgul Cakmakkaya Copper Concentrator is the largest copper concentrator in Turkey. Although concentrate production capacity is around 170,000 tons annually with 22-23% Cu content, this figure tends to be much lower than that. In Murgul a Turbo Column of Multotec Company of South Africa was employed. As a result of systematic column flotation tests, the grade of the concentrate was increased from 20.3% Cu to 28.7% Cu.

Jan 1, 2003

By Ralph J. Holmes, Victor Sharp, Steven J. Spencer, Kevin J. Davey, Jonathan J. Campbell, Peter L. Phillips, David G. Barker

"Improved measurement tools for monitoring and control of AG/SAG mill performance have a high level of interest in industry. Historically, acoustic emission monitoring has been widely used on SAG/AG/ball mills and hydrocyclones to provide new information on the conditions inside these devices affecting their performance. The current work was focused on a new technique using surface vibration monitoring of a number of pilot-scale and production-scale AG/SAG mills to yield insights into the events occurring in the mills. The development of relationships between signal analysis outputs and mill operating conditions can be used for soft-sensor measurement of mill process variables. The technique used an array of accelerometers mounted on the mill lifter bolts linked to a fast data acquisition system which monitored the surface waves generated during operation. Details of the system are presented. Mill operating variables were adjusted systematically to provide a wide range of operating conditions for surface vibration signal collection. The experimental approach is discussed.The signals acquired during the experiments were analysed using a range of techniques. The results show that strong relationships exist between measured vibration power (both total power and within certain frequency bands) and mill load level/power and mill speed. A new method for extraction of power spectral density and band power information on features of interest in a mill rotation cycle is also presented.These results show that single sensor analysis information from the surface vibration system can be used as soft sensor inputs for monitoring process variables such as mill load that until now, have not been reliably measured. System outputs also show considerable promise in the area of condition monitoring. An example of the signal analysis output is presented showing elevated vibration levels in an area with higher resultant wear. Eventually, it is considered that outputs from this system for process variable and wear condition monitoring will be key new inputs to an online AG/SAG mill monitoring and control system."

Jan 1, 2003

By M. Taheri

Multiple Attribute Decision Making (MADM) method is applied to select tailings site of the Gol-e-Gohar Iron Ore Processing Plant in the Kerman province, south-eastern of Iran. To select tailings site, screening is applied on eight location proposed by Binnie and Granges. Consequently three sites identified for further studies. Evaluation factors include only the most important factors such as efficiency ratio, elevation and distance to processing facilities, occurrence of faults and fractures. Crisp values such as efficiency ratio, elevation and distance can be determined by measurements and calculations, but some factors such as occurrence of faults and fractures are presented as linguistic values that can be described with triangular fuzzy numbers. Based on evaluation values obtained an optimal tailings site can be selected using a modified Technique of ranking Preferences by Similarity to the Ideal Solution (TOPSIS) given crisp data and linguistic variables as the alternatives of attributes. Each attribute?s weight is assigned using the analytic hierarchy process. The final ranking order aids in the selection of tailings site. Finally, the stages of modified TOPSIS method were applied and site No.2 situated in 5400m to the mill was selected as the best alternative.

Jan 1, 2014

By W. Z. Yin

It is investigated systemically in this paper that the granularity of the precursor, ZnC2O4?2H2O, is influenced by synthetic conditions. Instantaneously adding of precipitation agent is able to control the mean size of precursor ZnC2O4?2H2O under 300nm, which has great function to obtain well-dispersed ZnO nanoparticles in the next step, pyrolysis. The pyrolysis kinetics model of ZnC2O4?2H2O powder is obtained. Two steps take place during the pyrolysis. The first is dehydration, which the pyrolysis kinetic model is 2(1-a)2/3(chemical reaction), A=8.3×108s-1, E=(75.82±3.00) KJ/mol. The second is formation of ZnO, which the pyrolysis kinetic model is (1-a) (random nucleation and latter growth), A=8.45×1028s-1, E=(360.54±12.00)KJ/mol. ZnO nanoparticles obtained by pyrolysis take on self-growth behavior. It is resulted that for precursor ZnC2O4?2H2O pyrolysis time takes obvious influence on the partilces size under 420?, 500? and 600?. Finally, a new flow sheet for synthesis of ZnO nanoparticles is investigated, in which blendes is used as raw material and hydrometallurgy is introduced into it. The whole flow sheet has no industrial wastes, that is all byproducts can be used in the flow sheet recycled, resulted in the de-crease of productive cost and industrial wastes.

Jan 1, 2014

"The most common comminution testing methods and the associated analytical procedures provide average values and do not capture the variability in breakage behaviour of ore particles. Therefore, plant designs and process performance predictions use only average values; hence, the inherent variability that exists within an ore domain translates into variation in process performance. This paper discusses the drawbacks of using the average approach to impact comminution testing and plant design. It considers breakage intensity from a single-particle testing perspective. To clearly delineate breakage behaviour of each broken particle, an experimental technique using the JK Drop Weight Tester (JKDWT) has been developed by which actual comminution energy per particle and breakage intensities were measured directly. Four different ore types in ranges of -45+37.5mm and -22.4+19mm were tested at three energy levels of 0.1, 0.25, 0.5 kWh/t and six energy levels of 0.5, 1.0, 2.0, 2.5, 3.0 and 4.0 kWh/t, respectively. Sieved results of individual particles, notionally, t5, t10 and t50 showed the presence of large variability in their breakage behaviour, which was not captured by the standard JK impact breakage testing approach. In addition, the original JKMRC model is modified by introducing a third parameter, ‘Emint10’ which describes the minimum energy required to produce the minimum percent t10 for a given ore type and its significance is tested statistically. These results suggest that the analysis of breakage variability may lead to more robust plant designs. Perhaps, the most useful insight from this work is to extend single particle breakage model developed by JKMRC to a comminution percentile envelope which may provide a more detailed picture of ore breakage variability. INTRODUCTION Rock consists of mineral grains, pores, voids and cracks that may differ markedly in size/density which make rock a heterogeneous material by nature. The degree of heterogeneity in rock affects its breakage characteristics where these variations increase local differential strain and stress within a stressed rock (Scholz, 1968) and it depends on many factors such as rock genesis, alterations, etc. One important aspect of this heterogeneous feature is presence of a large amount of experimental scatter in rock breakage results when considered from a quantitative perspective (Bieniawski, 1967; Liu, Roquete, Kou, & Lindqvist, 2004)."

Jan 1, 2018

By Peter Kondos

The need for a sustainable development of ore deposits makes it imperative to be innovative and mindful in creating an economically and environmentally viable operation, while maintaining a good working relationship with the various stakeholders involved in developing and operating a large and complex mining project. This is becoming immensely important as gold ore deposits are becoming more mineralogically complex along with lower grades presenting both metallurgical and environmental challenges that need to be addressed in mitigating risks and improving project economics. This paper presents Barrick?s approach to development of strategic technologies for our long-term sustainable growth through conversion of valuable resources into reserves for both our green-field development projects and the expansion of our existing mining operations. Some of the key strategic solutions, including mineral processing, metallurgical and energy technologies, developed by Barrick and their impact on some of our complex gold and copper-gold ores will also be discussed in this paper. Keywords: gold ores, copper-gold ores, processing, breakthrough technologies

Sep 1, 2012