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By Max W. Ball

YOU have been kind enough to ask me to speak to you on "The War and Anglo-American Relations." A speaker always takes the liberty of putting his own interpretation on the scope of his subject. I am going to exercise that privilege, and try to look back over a generation of Anglo-American relationships and forward beyond the present war. I should like particularly to consider responsibilities as well as relationships. A more accurate caption for what I am going to say would be "Anglo-American Responsibilities.?? THE WAR WILL BE WON I am assuming that sooner or later we shall win this war. History and economics point to the same conclusion, that Germany has attempted the impossible and that the seeds of defeat are already sown. As to one ecof1:omic factor, I am already on public record as believing that Germany's oil supply is inadequate for the war she has launched. That opinion is unchanged. Aside from such tangible factors, moreover, I am convinced that the spirit of freedom is unquenchable, and that no combination of powers will be able to rout it from the British Commonwealth of Nations and the United States. Stronger even than this conviction is my faith in a God who will not suffer the defeat of man's aspiration to be master of his own soul. I am sure that all of you share that faith, and that we need not argue it. We can start with the assumption that the war will end in victory. The subject we are to consider, then, is the relationship of the English-thinking peoples during the conflict, and their joint responsibilities in the difficult days that will follow it. A CANADIAN-AMERICAN No talk on such a subject is worth listening to unless the audience knows the background and fundamental beliefs of the speaker. No human statement stands alone; behind and beside and within it are the ideals and the bias of the man who makes it. Because I am a stranger to most of you, I am constrained to talk about myself before I talk about more important matters. The review may be profitable, not because of the subject, but because it may illustrate the evolution of an attitude toward England.

Jan 1, 1941

By José J. Suárez

Abstract: Globally, the mining industry is expected to face the following challenges through 2020: 1. Sustaining growth amidst fierce competition 2. Containing cost increases and managing through the cycle 3. Attracting and retaining talent 4. Managing environmental concerns and improving sustainability 5. Managing volatility risks in commodity markets Our experience and research reveals that the higher performing global miners are adopting many of the following strategies: (1) Adopt a Global, Agile Operating Model (2) Be the Developer of Choice (3) Drive Capital Efficiency (4) Be the Employer of Choice (5) Integrate the End-to-End Business Model (6) Move to the Virtual Mining Value Chain This paper/presentation will provide data obtained through research on five (5) challenges facing the mining industry, and on the six (6) strategies that high performing global miners are adopting.

May 1, 2013

By Eva Surová, Molák. Bohumil, Márta Polgári

The Úrkút rhodochrosite deposit and Branisko Mn showings (rancieite, manganiferous calcite), located in Lower Jurassic marine sedimentary rocks with black shale, were studied by organicgeochemical methods. Both depositional localities were affected by the Lower Jurassic Toarcian anoxic event. UrkUt shales are rich in organic matter (av. 2.94 wtOJo total organic carbon), the composition of which indicates derivation mainly from marine sources, with some terrigenous component. The shales matured in a bacterially active environment under reducing conditions of diagenesis-catagenesis. Branisko shales (~0.2 wt % TOC) with lenses of Mn oxide ore were weakly metamorphosed and their organic matter thermally degraded. The model for Mn carbonate ore formation envisages reaction of Mn derived from sediments, with carbonate generated by a bacterially mediated process of decomposition of organic matter that also involved Mn reduction.

Jan 1, 1992

By Marta Polgari, Eva Surova, Bohumil Molak

Abstract -The Ûrkút rhodochrosite deposit and Branisko Mn showings (rancieite, manganiferous calcite), located in Lower Jurassic marine sedimentary rocks with black shale, were studied by organic­ geochemical methods. Both depositionallocalities were affected by the Lower Jurassic Toarcian anoxic event. Ûrkút shales are rich in organic matter (av. 2.94 wt% total organic carbon), the composition of which indicates derivation mainly from marine sources, with some terrigenous component. The shales matured in a bacterially active environment under reducing conditions of diagenesis-catagenesis. Branisko shales (?0.2 wt% TOC) with lenses of Mn oxide ore were weakly metamorphosed and their organic matter thermally degraded. The model for Mn carbonate ore formation envisages reaction of Mn derived from sediments, with carbonate generated by a bacterially mediated process of decom­ position of organic matter that also involved Mn reduction.

Jan 1, 1992

By A. Saigal

The effect of temperature on the cutting forces during machining of alumina reinforced aluminum composites was investigated, Aluminum 6061, 10% Al2O3 reinforced composite and 20% Al2O3 reinforced composite were tested, A 5/8-inch diameter high-speed steel end mill, a Micro 100 TiN coated single edge endmill cutter and a two-fluted solid carbide insert cutter were used for tooling, The results, in general, showed an increase in the cutting forces as the temperature of the material increased, From the raw data, there are temperatures ranges in which the force data did decrease but they were insignificant with regards to predicting a downward trend. A regression analysis was used to understand which variables had the greatest affect on the forces being generated, The correlation and regression analysis showed that at 600 rpm (velocity: HSS- 98,2 sfpm, Micro 100 cutter - 78,5 sfpm, solid carbide cutter - 192,4 sfpm) the tooling, the workpiece material, built up edge, and temperature were statistically significant factors in the test, Tooling was a significant variable in all testing, The smallest forces recorded during machining were generated with the solid carbide two-fluted endmill cutter, Visually, the solid carbide tooling produced a better surface finish during the testing which made it the tool of choice, In addition, the force data proved that as the cutting speeds were increased, the cutting forces decreased.

Jan 1, 2005

By P. B. Demarsh

"Location: - On highway 59, 17 miles east of Val d 10r near junction of Montreal highway in Northwestern Quebec.Life; - Started production 1952, ceased 1965.Ore: - Pyrite, chalcopyrite and small amounts of free gold and goldsilver tellurides in narrow quartz-carbonate-tourmaline veins in granodiorite. Specific gravity 2, 70.Capacity: - 700 tons daily Bevcon ore supply, l 000 tons daily when custom ore available.Assay: - Heads 0 .140 oz. per ton; tails 0. 009 per ton; extraction 92.5%.Grind: - 75% minus 200 mesh at 700 tons; 68% minus 200 mesh at 1000 tons. Detention time 28 hours and 21 hours respectively.Treatment: - Cyanidation process.Reagents: - Per ton. Aero Cyanide (NaCn) 0, 50; crushed unslaked lime 1. 75; zinc 0. 03; litharge 0. 10; steel consumption 2. 25.Water: - Pumped from land-lock spring fed lake l 1/2 miles distant.Cost: - Per ton. Crushing 0. 13; grinding 0 .32; filtration 0. 07; cyanidation 0.14; miscellaneous 0.29; total 0.95.Power: - Hydro-electric, 25 cycle, 12, 000 volts reduced to 550 volts.Labour: - Predominantly French Canadian, nucleus English Canadians.Tailings: - Impounded low lying pond.Personnel: - 15 including supervision.Flow sheet: - Canadian Mining Manual l 9 5 6 .Building: - Wood truss construction: 3/ 4 in. siding, ten test and 1/ 4 in. transite outside. Corrugated galvanized iron roof. Ground level foundations. Internal self induced heating. Wood stave tank equipment."

Jan 1, 1966

By D. Madsen, B. Salamondra, A. Moss, D. Etienne

"Raise mining at the Namew Lake Nickel Mine in Manitoba uses 3 m diameter bored raises driven at 45 to 50 degrees dip for stope access and drilling. These raises are developed within the orebody on 20 m centres to accommodate electric-hydraulic longhole jumbos and charging wagons. Critical elements of stope development include delineation of are contacts, control of deviation during raise development, optimal stope sequencing to permit a high extraction rate, drill anchorage installation, production drilling and blasting, and ground control. Procedures to deal with these elements are described, with emphasis on the geotechnical investigation for design of open stopes and pillars.Although mining with drilled raises does not have the flexibility to follow large variations in orebody dip, results to date indicate that it can be used successfully in the thicker ore zones. Thinner zones are currently mined using a modified Avoca method. Some flexibility to accommodate variations in orebody dip in thin are zones may be obtained by using alimack raise climbers to drive access raises, and carry longhole drills and charging equipment. Rock quality has been sufficiently good to maintain stable stope walls for full-height mining of primary stapes at 20 m strike length.IntroductionThe Namew nickel deposit is located 60 km south of Flin Flon, Manitoba. It is a moderately dipping (45 to 50 degrees) pipe-like ultramafic intrusion with a sulphide halo enrichment. The diluted recoverable ore reserves at January I, 1990 are 2.2 million tonnes grading 2.05% Ni and 0.7% Cu. The operation is a joint venture between Hudson Bay Mining and Smelting (60%) and Outokornpu Mines Ltd. of Toronto (40%). The mine is budgeted to produce 530 000 tonnes in 1990. The deposit was discovered in 1984 and mine development commenced in 1987.In the raise mining area, primary stopes will be filled with a high quality backfill consisting of cement and quarried limestone. Secondary stopes will be mined out between the primaries in the second pass of mining. The design extraction rate is 94% over all.The orebody above 120 level has an average mining width of 2.4 m, so is too narrow for raise mining. A modified form of Avoca stoping is used."

Jan 1, 1991

By Jean-Yve Tremblay, Michel Prud'homme

"IntroductionIndustrial minerals include a group of more than fifty minerals which are marketed into almost all the sectors of industry; they are the backbone of many manufacturing industries. Table I shows major end-uses for industrial minerals in manufacturing sectors.At Energy, Mines and Resources, industrial minerals are divided in three major categories: (I) agro chemicals and chemicals, (2) construction mineral s, and (3) ceramics and specialty minerals. A listing of the major groups of minerals is shown in Table 2.Agro-chemicals and chemicals are sold on the basis of their chemical content and purity. Construction minerals or structural minerals are distinguished by their performance as low cost and bulky commodities. Ceramics and specialty minerals are performance-specific and are sold for their property on imparting functions on end-products. Industrial minerals have unique characteristics that are useful in many stages of processing; from crushed size to micronized fillers a single mineral ca n serve a broad range of industries because of its intrinsic properties.The Industrial Minerals Industry in CanadaCanada has a large industrial minerals base and is a world leader in the production of some of them. The total value of product ion of these minerals has grown by 115% over the last 10 years despite the misfortune of asbestos.Industrial minerals have shown remarkable growth in the past 20 years at an average annual rate of 9.2%, compared to 7.8% for metallic minerals. In 1986, the value of industrial minerals rose to $4.9 billion, or 14% share of the Canadian mineral production. Figure I shows the value of production of the mineral industry for the period 1966-1986.The leading segment in industrial minerals segment since 1976 is the chemicals and agro-chemicals sector which has an average annual growth rate of 5.75 % in terms of value of production. During the same period, the growth rate for the whole Canadian mining industry was 1.37% per annum. The chemicals and agro-chemical s sector increased its contribution to the total value of production of 2% to 6070 despite the growing share of fuel minerals with 59%."

Jan 1, 1988

By Howard J. Handewith

"Tunnel boring machines have been tried in underground mining applications as early as 1957. Although tunneling machines hardly threaten to supplant traditional drill-blast-muck operations for drifting, the latest modern machines offer substantial improvements in progress rates over traditional methods under certain conditions.An evaluation guide is offered which identifies conditions that favour machine boring. Different types of costs related to the use of a tunnel machine are discussed. The advantages of the tunnel machine over the traditional method are reviewed. IntroductionThe first tunnel boring machine ever used in a mine was in Quebec in the year 1957. Although less than successful at the time, this experiment served to illustrate the mining industry' s willingness to try new ideas. Since 1957, the manufacture of tunnel boring machines has developed into a full-size industry. Most contractors in Europe and North America will now consider the use of a tunnel boring machine first on any long tunnel that can have a circular section.The modern tunneling machine offers a great potential to the mining industry. Just as the blasthole and raise drill machines have revolutionized mining in the last decade, it is expected that tunnel boring machines will make an equal impact in the future.This is not to suggest that tunnel boring machines will replace explosives in the foreseeable future, but they can supplement drill-and-blast operations. In areas where long drifts, inclines, declines or cross-cuts are needed in a hurry, the tunnel boring machines offer the fastest way to a production return on investment. Figure 1 shows the range of production that two types of tunnel machines have produced as compared with conventional excavation methods in various ground conditions.Rotary hard-rock tunnel boring machines (Fig. 2) commonly produce progress rates in excess of 20 metres per day in uniform ground from 300 to over 2,000 kgl cm2 in unconfined compression strength . These averages are for the completed tunnels. One 7. I6-metre-diameter tunnel boring machine just completed a 1O.7-km tunnel in hard rock of 700 to 2,800 kg/cm>, The last eight months of production averaged 30 metres per day."

Jan 1, 1980

By D. Y. Li, C. D. Ma, T. Zhou, T. J. Cheng

In this paper, a number of experimental tests are carried out to study the strength difference on rectangular prismatic marble specimens with different height-to-width (H/W) rations. The specimens have a nominal size of 45×15 mm in the compressive cross-section (W×T) and different heights (H = 22.5 mm, 45 mm, 60 mm and 90 mm). It is to say that the height-to-width ratios are equal to 0.5, 1.0, 1.33 and 2.0, respectively. The quasi-static uniaxial compressive tests are finished by a servo-controlled INSTRON machine (the strain rate at about 10-5/s), and the dynamic compressive tests are finished by a diameter of 50 mm cylindrical SHPB apparatus (the strain rate reaching about 101/s). The rock failure process of marble specimens is captured by a high speed camera in order to distinguish the fracture propagation behaviour. It is found that the compressive strengths increase when the H/W ratio of marble specimen changes from 2.0 to 1.0 due to the end clamping effect both for quasi-static and dynamic loads. However, when the H/W ratio changes from 1.0 to 0.5, the apparent compressive strengths decrease both for the two loading conditions. The strength decrease of short marble specimens may be attributed to the change of failure mode from shear to slabbing, which can be identified by the fracture patterns of the specimens. Based on the uniaxial compressive tests, the slabbing strength of the marble was found to be about 40% of its UCS for the specimens with a nominal height-to-width ratio of 2.0. In addition, it is found that the dynamic increase factors (DIF) are affected by the specimen’s aspect ratios. It implies that the same aspect ratios should be used to compare the dynamic and static compressive strength of rocks. Meanwhile, both the static and dynamic tensile strengths of the marble are obtained by the Brazilian disc tests. The ratio of the dynamic tensile strength to the static tensile strength of the marble is about 2.68.

Jan 1, 2015

By T. Robson

"A multi-seam underground mining operation employing mechanized room-and-pillar methods provides 35 per cent of Smoky River's annual ROM coal production (2 million tonnes) from the Smoky River coal field. Surface mines provide the balance. Tectonic activity, which has resulted in deformed coal seams and a rugged relief to the area, has provided natural boundaries to discrete mining areas. Coal transportation to the central preparation plant incorporates a 3 km long underground conveying system. The company is committed to efficient resource recovery and a safe and healthy working environment. Introduction The Smoky River Coal operations (SRC) are centered in the Smoky River coal field located in west central Alberta, some 360 km west of Edmonton and 20 km from the Town of Grande Cache (Fig. 1). Combined mining operations produce 2 million tonnes per year run-of-mine coal from which 1.65 million tonnes of high quality, low volatile, coking coal are obtained. The underground mining operation, employing mechanized room-and-pillar methods, provides 35 per cent of SRC's annual ROM coal production (2 million tonnes). Surface mines provide the balance. Tectonic activity has resulted in deformed coal seams and a rugged relief in the area. This has provided natural boundaries to discrete mining areas. Background Exploration of the Smoky River coal field took place over four decades commencing in 1926. McIntyre Mines Limited (parent to Smoky River Coal Ltd.}, commenced development of the property in 1968 having secured a long-term contract for the delivery of coal to Japan. Production of underground coal at Smoky River commenced toward the end of 1969 and has been continuous on the property since that time. Originally, two underground mines were opened. Original planning envisaged the use of room-and-pillar techniques to develop blocks of coal for subsequent extraction by longwall retreat mining. Following initial development, two longwall units were established, the first in November 1970 in No. 5 Mine and the second in February 1971 in No. 2 Mine. Difficulties were experienced on both units, and production commitments could not be achieved. The longwalls were discontinued, and mechanized room-and-pillar was subsequently used for all underground mining."

Jan 1, 1985

By W. Grell

"In this paper, two methods of standardizing mill language are proposed; one is based on metric units and the other on English units. Tentative procedures for chemical and screen analysis based on published methods are proposed.Standard procedures for determining work index, and for leaching, flotation, and classification tests are outlined.Objects of Standardization:(1) to improve communication -(a) among gold metallurgists(b) with other branches of mineral dressing(c) with mineral dressing in other countries(d) with general scientific procedure(2) to improve mill control by -(a) standard methods of analysis (i)(ii)(iii)(b) standard methods of calcula tiort(c) standard accounting proceduresin the plantin the mill laboratoryin the assay office(3) to improve mill test work and investigationAreas of Standardization(1) Nomenclature or terminology(2) Measuring techniques(3) Test procedures(4) Accounting procedures"

Jan 1, 1966

By M. K. Aly

"ABSTRACTThis paper briefly describes the mining method proposed for the iron ore deposits in Wadi Shatti, western Libya. The iron ore produced will be used in the steel plant at Misurata on the Mediterranean coast. GeologyThe Wadi Shatti is located in the central part of western Libya. Flat iron-bearing sedimentary rocks are exposed with remarkable regularity in this valley. It occupies an area 200 km long by approximately 20 km wide trending in an eastnortheast direction between Jabal Fazzan in the north and Zel1af Sand Dunes in the south (Fig. I). Only a part of this valley has been ful1y explored by drilling on a 400- by 200-m pattern in an area of 18 km2 south of the town of Taroot. Farther to the south, no exploration by drilling can be done due to the presence of sand dunes .The iron-bearing bed is about 10to 15m thick, with a dip of 2 to 4 degrees in a southerly direction . The overburden consists mainly of clayey sandstones, 4 to 5 m thick, in the northern part, increasing to 35 m in the southern part. The iron ore bed consists of three different layers, from the floor upward: (1) Lower Reduced Ore (LRO), having a varying thickness of 1 to 7 m; (2) Magnetic Ore (MO), with a thickness varying from 4 to 12 m mainly in the central part of the area; and(3) Upper Reduced Ore (URO), with a bed thickness varying from 0 to 7 m."

Jan 1, 1980

By Kadir Sariiz

Abstract - The Akçayir-Yürükakçayir Miocene-Pliocene basin in the Central Anatolia hosts ancient lacustrine sepiolite deposits. The succession in this basin consists of conglomerate (Yürükakçayir conglomerate), clayey and silty limestone, dolomitic marl, sepiolite beds and lenses, and dolomitic limestone (Kepeztepe formation). The main impurities within the sepiolite rock are dolomite, opal-CT, calcite, smectite and feldspar as sepiolite + dolomite and sepiolite + opal-CT are the main mineral assemblages. Smectite and feldspar are thought to be of detrital origin. Calcite is found as a secondary filling in root tubes and casts. Sepiolite samples studied display root-marks and root tubes, soapy and massive structure indicating direct precipitation. Sepiolite deposits probably formed at a pH of 8 to 9, and Mg+2 and SiO2 concentrations in moderately saline environments of internal facies of an alkaline lake.

Jan 1, 2000

By V. C. Pandolfelli, P. Bonadia, F. A. O. Valenzuela, L. R. Bittencourt

Refractories for aluminum cells, if not properly selected, can lead to increased energy consumption and even shorten the pot life. Based on recent advances in understanding the deterioration mechanism of cathode materials, several commercial bricks in the SiO2-Al2O3 system were compared to the one used by an Alcoa smelter. Both physical and chemical properties were considered in the selection of the refractories. A more reliable method of permeability measurement, which takes into account inertial and viscous effects during the fluid flow, was applied. Additionally, the traditional cup test and other characterization techniques, such as thermal conductivity, X-ray diffraction, and mercury porosimetry, indicated that a brick with a relatively low alumina/silica ratio, presenting low open porosity and low permeability, far exceeded the performance of the brick currently in use.

Jan 1, 2004

By Gordon. I. M., J. Blackshaw

"The wet part of the Hollinger mill is housed in two buildings, the grinding plant and the treatment plant. In the grinding plant there are four 7xl5 ball mills which grind the ore to 60 per cent through 200 mesh. There is also one 7xl5 ball mill which grinds table concentrate to 9 5 per cent through 200 mesh.The primary classifier overflow is pumped to the treatment plant where it passes over shaking tables, producing a concentrate and a tail. The concentrate pulp is pumped to the grinding plant for secondary grinding. The secondary classifier overflow is pumped back to the treatment plant where it is thickened in two 40xl 5 tray thickeners and agitated in four 20x24 mechanical agitators arranged in series of two (with 2 spares).The table tail pulp is thickened in nine primary 40xl5 tray thickeners (with 2 spares). The thickened table tail pulp and the concentrate agitator discharge pulp are mixed and pumped to four rows of 15x45 pachuca agitators, arranged in series of five tanks.The pachuca discharge pulp is divided. The smaller part goes to two rows of 3-step decantation using 40xl5 tray thickeners (with 2 spare rows). The larger part goes to six 14xl6 drum filters. The repulped primary filter cake and the thickened pulp discharged from the decantation rows are fed to eight 14xl6 drum filters. The secondary filter cake is mixed with water and pumped to the tailing line."

Jan 1, 1968

By D. McFadgen

"THE Dominion Steel & Coal Corporation, through its subsidiaries, the Old Sydney Collieries and the Dominion Coal Company Limited, produces 4% million tons of coal annually from eight submarine collieries situated on the eastern coast of Cape Breton Island. The present workings have a frontage of 20 miles and extend 31/2 miles under the Atlantic ocean on gradients varying from 4 deg. to 24 deg. To date, some of the workings have reached .a depth of cover up to 2,800 feet.The pitching seams, the annual seaward advance, the resulting depth of cover and the rdatively soft roof and floor have necessitated the adoption of extensive longwall mining, with room-and-pillar mining con-fined to areas above the 1,000 foot cover line, where 60 per cent of the -coal is left standing in pillars to support the ocean floor. Longwall mining accounts for 87 per cent of the total production with the remaining outputs obtained from room-and-pillar work and the narrow work development. Seventy-four per cent of the longwall production and 41 per -cent of the room and development production is completely mechanized.Although 2 tons of water is pumped from the collieries for each ton of coal mined, the working sections are relatively dry as the heavy make of water is essentially surface drain-age from the land crop areas. The dry workings and the long haulage distances, which in many cases exceed 4 miles, have resulted in a continuing programme to combat the dust hazard, both at the working face and along the mine roadways."

Jan 1, 1960

By M. K. Walter

"The underground operations of Kidd Creek Mines uses an average of 450 U.S. gpm water during regular operations, and discharges an average of 800 U.S. gpm through consecutive staged pumping lifts of 1200f t.Water is used as a flushing medium for the drilling operations and as a dust suppressant for drawpoint mucking. The water retains an average of 5% suspended solids by weight which is removed underground before being pumped to the surface. This paper outlines the treatment of the mine water for the removal of suspended solids which are chemically treated to settle out as a sludge product of 60% solids by weight. This process reduces the sludge handling operation by 50%. The sludge is systematically disposed into the ore passes.IntroductionThe Kidd Creek minesite, located 27 km north of Timmins, Ontario, produces 4.5 million tonne s of copper, lead, zinc and silver ores annually from its No. I and No.2 underground mining operations. Both mines use a sublevel blasthole stoping method of extraction.Water from the underground operation passes through a series of surface settling ponds, where it is treated to remove heavy metal ions from solution. A blend of the pond effluent with fresh water from Kidd Creek, supply the underground with water at an average rate of 450 U.S. gpm. Water flows from the production zones through coarse sumps and into a main pumping station. There are five main pumping stations underground, three in No. I Mine and two in the No.2 Mine.The No. 2 Mine pumping stations are located on the 4800 level and the 3600 level. All water below the 3600 level to the shaft bottom is controlled from the 4800 pumping station. The water from the 4800 pumping section is combined with water from the remaining levels of the No.2 Mine at the 3600 pumping station. Water from the 3600 pumping station is pumped to the 2400 pumping station in No. I Mine.The No. I Mine pumping stations are located on 2800, 2400, and 1200 levels. All water below the 2400 level to the shaft bottom is controlled through the 2800 pumping station. This water is pumped to the 2400 pumping station. The 2400 pumping station also controls the water below 1600level to 2400 level."

Jan 1, 1988

By Ata Akcil, Z. B. Karshigina, Ye. G. Bochevskaya, Z. S. Abisheva

"Phosphorus slag is the most heavy-tonnage waste of yellow phosphorus production, which is stored in the dump fields for many years creating ecological problems in the regions. Despite of the actions taken to utilize the slags, most of them remain in the slag disposal area. One of the relevant and priority directions is rare-earth metals production (REMs), presence of which in the phosphorus slags allows considering the latter as an acceptable raw material source. Phosphorus slags contain about 30–40 wt% of silicon dioxide, therefore they can serve as a source of production of precipitated silicon dioxide highly required in different industries.The purpose of this work is the most complete REMs recovery in the solution while leaching and subsequent processing of siliceous cake. The work shows results of researches on establishment of the chemical and phase compositions of phosphorus slags, determination of the forms of presence therein of REMs compounds, processes of phosphorus slag leaching by nitric acid and processing of produced siliceous cake by NaOH solution.Based on the data of the instrumental and chemical methods of phosphorus slag analysis, it was established that it consists of pseudowollastonite a-CaSiO3 for 90–92%. It was found out that REMs are present in it in the form of carbonate apatite Ca10(PO4)6CO3 or rare earth apatite, and La2S3 compound inclusions.Optimum parameters of phosphorus slag leaching process were selected: HNO3 concentration 7- 7.5 mol/L; L/S ratio = 2.6–3 mL/g; temperature – 50–80o?; duration – 1 h; pulp stirring – 500 rpm. Recovery of SREMs, CaO, Al2O3 and Fe2O3 into the solution were achieved at 98.0, 99.1, 99.0 and 18.8%, respectively. Presence of 10 elements of the rare earths group in the phosphorus slag was established. It was found out that recovery of almost all REMs is within ~92–99%, except for Sc and Lu – ~39% and ~28%, respectively.For the purpose of optimization of siliceous cake leaching by NaOH solution, influence of some physical and chemical parameters was studied: N?O? concentration, L/S ratio, temperature, and duration. Results of the experimental data will serve as a basis for development of the technology of complex processing of the technological waste of phosphorus industry with production of REMs concentrate and precipitated silicon dioxide."

Jan 1, 2016

By Xiaoqi Sun

"Rare earth elements (REEs) have a series of specific properties making them invaluable in products including lighting, electronics and magnetism. The elements have been used in many commercial products, for example, turbines, electric vehicles, batteries, lighting, computers, cell phones and lasers. Heavy REEs are attracting the interests of scientists from many countries, and these elements have become critical to develop high-tech materials. Ion-adsorbed rare earth deposits were first discovered in China. The minerals are also called weathered crust elution-deposited rare earths. The particular types of deposits are distributed throughout southern China. The ion-adsorbed deposits are rich in medium and heavy REEs, accounting for more than 80% of the world’s total medium and heavy REEs production. However, the separation of heavy REEs from ion-adsorbed deposit is difficult owing to their similar chemical properties. The conventional separating technologies have caused serious pollution. A novel extraction strategy has been developed in this laboratory and is presented herein.INTRODUCTIONThe unique properties of rare earth elements (REEs) render them important in high-strength magnets, lighting phosphors, polishing compounds, and ceramics. Especially for applications that take advantage of the f-orbital electrons, substitutions outside the REE family are often difficult to impossible (Nassar, Du, & Graedel, 2015). Extracting and separating individual elements from mined ore is not easy, requiring lengthy operations to separate them, and this results in high costs and adverse effects on the environment. The low concentration of REE in the earth’s crust makes economic exploitation difficult (de Boer & Lammertsma, 2013) and the sustainability of the REEs separation industry has aroused considerable attention (McLellan, Corder, Golev, & Ali, 2014). To eliminate protons and break the dimmers in organic phosphonic acids or carboxylic acids, the saponification of acidic extractants by acid-base neutralization reactions are widely used in industrial REEs separation (Sun, Luo, & Dai, 2012a). The saponification procedure contributes to increased extractability and selectivity of acidic extractants to a considerable extent. The common industrial saponification mechanisms and technological processes are shown in Figure 1 and include ammonium saponification (saponified by NH3·H2O), sodium saponification (saponified by NaOH), calcium saponification (saponified by Ca(OH)2), and magnesium saponification (saponified by MgO). These inevitably result in wastewaters containing NH4 +, Na+, Ca2+ or Mg2+ because of the cation-exchange extraction mechanisms (Xiao, Long, Huang, Feng, Cui, & Wang, 2013; Song, Fu, Wang, Liu, Zhou, & Li, 2014; Sun & Waters, 2014)."

Jan 1, 2016