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By S. A. Briggs

Bioremediation has been accepted as a treatment technique for groundwater contamination in subsurface soils and shows promise for contaminated fractured rock environments. Biological growth in fractured rock is expected to occur predominantly as biofilms attach to the fracture surfaces. Biofilms in rock fractures are subject to a complex system of forces and other phenomenon due to the dynamics of the bulk fluid in which they grow. In this paper, through the applications of computational fluid dynamics (CFD) to rock fractures, where the boundaries are rough and the flow is complex, a precise analysis was conducted of the interaction of a fluid flow and the rock fracture. Specifically, hydraulic parameters and velocity profiles of an actual rock fracture were calculated and compared to a fracture of equivalent aperture. From the analysis it is clear that it is important to use more complex models such as the Lattice Boltzmann Method used is this paper to describe fracture flow.

May 1, 2009

By G. S. Headley

At the Sullivan Mine, recent experience with sulphide fires, locally referred to as " hot muck", has necessitated extensive modifications to pillar mining design and operating procedures. Potentially hot pillars are now being designed and mined to prevent fires. Unusual safety hazards and difficulties are encountered in working with, and adjacent. to, existing pillar fires. Operating procedures developed for these conditions have proved successful for safe and continuing production. These changes have minimized the impact of hot ore on current operations and have promise for an improved future.

Jan 1, 1977

By E. Asselin, P. Sauve, H. Salomon-de-Friedberg

"Residues from the CESL Copper process were leached using the CESL Gold process. The kinetics of reaction were confirmed to be fast with over 50% of the gold consistently extracted within 2 minutes of leaching. Final gold extractions under the conditions tested here were between 80-90% obtained within 90 minutes. A model for the CESL Gold process was developed. This model is slightly different based on whether the copper concentrate leach residue was ground or unground prior to leaching: the gold leaching rate constant is approximately twice as fast for the ground samples. Unground residues had a P80 of 13 ?m whereas ground residues had a P80 of 10 ?m. The model predicts a 43% decrease in leaching time for ground residue versus unground residue to achieve the same extraction under otherwise identical conditions. The model was more accurate for the ground samples. INTRODUCTIONTeck's CESL Process (Jones, 1996) was developed to provide an economically attractive alternative to traditional copper smelting. It has since evolved to also deal with copper concentrates containing valuable impurities such as nickel and undesirable ones, such as arsenic, while reducing downstream costs. Effective recovery of gold and silver is essential to the economics of the CESL Process. The Brook Hunt 2007 copper concentrate assay data (Wood-Mackenzie, 2007) were examined to determine the ratio of gold plus silver value relative to the contained copper. As indicated in Figure 1 below, nearly two-thirds of concentrates have 10% or more of their total value tied up in their precious metals content.CESL has extensively examined the recovery of gold and silver at bench, pilot and demonstration scale, which has culminated in the present CESL Gold Process (Barr et al., 2007). The process targets the precious metal contained in the leach residues produced in the copper portion of the flowsheet. This residue has two primary components which influence downstream processing. The major iron-rich fraction (-75 wt%) of the residue is a mixture of various forms of iron oxide precipitates including hematite and jarosite (Sahu and Asselin, 2011). The iron fraction ranges from amorphous to crystalline in nature depending on the compound precipitated, upstream operating conditions and feed material composition. The lesser, but by no means less important, fraction is a mixture of elemental sulphur and unreacted sulphides (principally pyrite).Elemental sulphur formed during the oxidative leach of the copper concentrate reacts with cyanide to form thiocyanate (SCN-) making a traditional cyanide leach approach too costly. Since the SCN formation reaction strongly depends on contact time with the CESL residues (Po, 2007) short contact times were preferred. This factor guided the development work towards the eventual room temperature, pressure cyanidation process which results in near complete gold dissolution in 90 minutes. A recent CESL gold demonstration campaign treating 1.5 t/d of residue from the copper oxidation step achieved an average gold extraction of 91% (96% maximum)."

Jan 1, 2012

By S. McPherson, M. Chalkley, R. Ellenwood, W. Nicot

"The Moa JV was formed in December 1994 as a 50/50 joint venture between Sherritt Inc. and General Nickel Company S.A. of Cuba. The joint venture consists of the mine and Pedro Sotto Alba processing plant in Moa, Cuba and the Corefco refinery in Fort Saskatchewan, Alberta, Canada. Throughout its now nearly 23-year history, the Moa Joint Venture has faced a number of global, operational and process challenges. Global challenges have included high input costs such as for fuel oil and sulphur, as well as low nickel prices. Operational and process challenges have included increasing ore haulage distances, decreasing ore Ni + Co grades, and increasing ore impurity contents. For example, increases in impurities such as Mg and SiO2 in the ore result in increasing acid demand in leaching and decreasing solids content of preheated leach feed slurry, respectively. In spite of these challenges, the mixed sulphide production capacity from the Moa Joint Venture has increased from 12,500 to 37,000 t/y Ni + Co since 1994 by judiciously targeting expansion projects and by continuously performing process and operational improvements.INTRODUCTION The Pedro Sotto Alba high pressure acid leach (HPAL) plant at Moa Bay, Cuba has a long history (Maslenitzkiy, 1969; Chalkley, 1996; Carlson, 1960; Roy, 1961; Carlson 1961). The plant was constructed by Moa Bay Mining Company and started up in late 1959 after several years of process development by Freeport Nickel Company, including operation of a 10 t/d plant in Hoskins Mound, Texas and a 50 t/d plant in Port Nickel, Louisiana (Southwick, 2004), as well as development work by Chemical Construction Company (Chemico) to precipitate metal sulphides (Roy, 1955a; Roy, 1955b). The Moa plant had an original reserve of 50,000,000 t of ore, graded at 1.35 wt% Ni, 0.146 wt% Co, 3.70 wt% Si, 1.00 wt% Mg and 4.5 wt% Al. At original design rates of 2,000 kt/y of ore, the design capacity of the plant was around 25,000 t/y Ni + Co as a mixed sulphide product, which would be shipped to the Port Nickel Refinery in Louisiana for processing. In 1960, the plant changed ownership and was restarted in 1961 under Cuban management. Between 1961 and 1989, the plant was also supported by involvement from the former USSR, supplying spare parts and consumables. In 1994, Sherritt Inc. partnered with the General Nickel Co. S.A. of Cuba and formed the Moa Joint Venture. This joint venture includes the mine and Pedro Sotto Alba HPAL processing plant in Cuba and the Corefco refinery in Fort Saskatchewan, Alberta, Canada. Under this partnership, ore is processed in Cuba to produce a nominally 55 wt% Ni and 5 wt% Co mixed sulphide product that is shipped to Canada and processed by Corefco to produce class 1 nickel, high grade cobalt and byproduct ammonium sulphate fertilizer."

Jan 1, 2017

By W. E. Selnes

Introduction In 1938, a survey conducted by the Ontario Mining Association revealed a rather startling fact. Injuries incurred in chute pulling were more numerous than those from any other single cause. This report prompted Mr. W. B. Paton, then Inspector of Mines for Manitoba, to make a similar survey of the mines of his Province. It indicated that, in Manitoba mines, chute accidents ranked second only to those from falls off roofs and sides. Why has the mining industry been so slow to recognize the dangers of chute pulling? A partial answer may be the lack of any systematic classification of accidents according to their real cause. The result has been to attribute to other causes injuries which were a direct outcome of chute pulling, and, indeed, has made it difficult to analyze accidents in the industry as a whole. Perhaps, too, because chutes are generally located in the comparative safety? of the drifts, there has been a tendency to consider the occupation as not very hazardous. Not until enough statistics were obtained on this particular task could it be appraised correctly. The Mining Association's survey has been most helpful, and latterly the industry has done a great deal toward analyzing the causes of chute accidents and toward determining an effective means of overcoming them. Much, however, remains to be done. An effort will be made in this paper to outline methods which have been found successful in materially reducing the number of injuries. Qualifications of the Chute Puller First of all it must be realized that chute-pulling is a specialized occupation. The men require proper training for the job, just as in other mining operations. Care must, therefore, be taken to choose persons whose qualifications fit them for the job. Chute-pulling is an integral part of the general mining operation and cannot be considered as isolated from the tasks of other workers. One of the essential qualifications of a chute-puller is a sufficient knowledge of mining operations to appreciate the effect his work will have on the safety of others in the vicinity. He must take the necessary precautions, by verbal warnings, by placing barricades and signs, or by personally guarding the chutes, to prevent accidents to fellow workers.

Jan 1, 1947

By K. J. Daun, C. J. Shi

UsiborThrough the second step heating at 900 °C, the spectral emissivity shows a gradually decreasing trend with increasing soak time, caused by the surface phase transformation from Al® 1500P coupons are austenitized in a Gleeble 3500 thermomechanical simulator using a two-step heating procedure in an argon atmosphere. Variations in spectral emissivity are measured in-situ using a near infrared spectrometer and ex-situ with a Fourier transform infrared reflectometer. Microstructural evolution and surface roughness are investigated using optical microscopy, FE-scanning electron microscopy, and a surface profilometer. A series of phase transformations of Al-Fe-Si intermetallic phases at the coating/steel substrate interface cause the surface phase and surface roughness to change, which in turn influences the spectral emissivity. At the beginning of the first heating step, the coupons have very low spectral emissivity, due to the molten Al-Si coating. Spectral emissivity increases significantly with increasing soak time from 5 to 12 minutes, associated with the surface phase transformation of the coating into Al7Fe2Si intermetallic phase and an increase in surface roughness. 5Fe2 into AlFe intermetallic phase with a decrease in surface roughness.

Jan 1, 2015

By Christopher Boys

"Abstract -Many water inflows in Saskatchewan potash mines are linked to salt anomalies. Potash ore and three anomalies in the PCS Cory potash mine in the Patience Lake Member of the Prairie Evaporite Formation were studied to understand the processes involved in their formation. Another goal was to find geological indicators of the proximity of anomalies. A geological model that relates the potash to the salt anomalies has been developed.Up to five post-burial facies may be recognized . These range from carbonate-mud collapse breccias to bedded sylvinite, and probably result from post-burial leaching. ln this model, the same fluids that caused widespread recrystallization and possibly enrichment of the potash salts, started by dis­ solving huge cavities in the evaporites . The effects of the leaching were highly variable, indicated by selectively preserved delicate laminae and chevron textures, to deformed and totally dissolved salt beds . ln at least two major events, Late Devonian and Cretaceous, collapse structures may have acted as conduits for overlying formation waters to cause pervasive leaching and recrystallization of the Prairie Evaporite Formation .Geological indicators of the proximity of an anomaly may include: a change in Insoluble seam color from greenish-gray to mottled brown and greenish-gray, unusual local increases in ore grade, large patches (e.g., >200 cm2) of sylvite-poor potash crosscutting units near the top of the ore zone, and drops in topography >10 m of the marker seams. Anhydrite was more common in an anomaly than in ore. The local abundance of anhydrite in ore may indicate the proximity of some salt anomalies.Once an anomaly has been encountered, indicators of a major collapse feature may include: stretched clay seams, folded beds, small collapse features (1 m to 20 m), numerous washouts, or split clay seams with injected salt. Any number, or none, of these indicators may be found close to a major collapse feature."

Jan 1, 1993

By D. S. Evans

Major Project Blues Over the last two decades, almost every major project has suffered significant cost overruns, significant schedule delays, and/or poor quality work. Exceptions are rare and most projects that tout being ?On Time and Under Budget? have re-cast schedules, significantly modified scope or revised base estimates. The problem isn?t new. In the late 1980?s the Rand Corporation published a study showing that 80% of all major projects had significant cost and schedule overruns. The problem is not restricted to the Canadian environment, or to a specific industry. It is a global problem.

May 1, 2013

By Yihan Liu, Jintao Zhang, Chen Xiao, Xiaomeng Zhao, Guanglei Song

To estimate the performance of the inert anode materials based on NiFe2O4 spinel ceramic during it used for aluminum electrolysis, we investigated the wetting process of cryolite molten salt which is in composition of industrial aluminum electrolysis with carbon anode and NiFe2O4 based cermet materials, by means of determination the interface wetting angle between the molten cryolite electrolyte and the solid anodes interface. The results show that the wetting angle between the electrolyte and carbon anode is larger than 90 angulation, this means that they basically can not wetting; however the nickel ferrate spinel ceramics behaves much better. In regard to the NiFe2O4 matrix materials, their initial wetting angles is 76.9. The initial wetting angles for 1.0wt%MnO2, 2.5wt%TiO2 and 0.5wt%V2O5-doped samples are respectively 56.86°, 52.98° and 51.93°. However, after 50s later, all the wetting angles came down below 15°.

Jan 1, 2015

By Hiroyuki Sano, Hiroshi Chida, Katsuya Toda, Takafumi Sasaki

Saganoseki Smelter & Refinery is one of the largest copper producers in Japan to produce 450,000 tons of new copper annually. Saganoseki used to operate six PS converters with "4 Hot-2 Blow" scheme, but managed to change its operation to "3 Hot-2 Blow" scheme with four PS converters, while maintaining the same production capacity. To achieve the operational change, the following improvements have been carried out; 1) Extending service life from 220 to 350 batches, 2) Shortening cycle time by increasing the blowing rate and the matte grade, 3) Reducing environmental impact by applying sophisticated fugitive gas collection system and 4) Saving energy by waste heat boiler’s modifications. The operational change has been successfully executed, and results in drastic productivity increase and cost reduction. Currently, Saganoseki is maintaining the efficient and consistent operation with 4 PS converters. This paper describes the above-mentioned improvements for increasing productivity and the recent operational conditions of the PS converters.

Jan 1, 2015

By A. Scheltema Beduin, H. Oterdoom, A. Haaks, C. Kempe, A. Liedtke

"For the Kazchrome DC Ferrochrome plant, SMS-group specifically designed an electrode column that would minimize downtime. Special features include the possibility for on load electrode jointing, on load slipping, and back-slipping. Electrode consumption is strongly related to furnace load and impedance, and is very low at high loads, which makes the graphite electrode an alternative to consider even in AC applications. The electrode could also be applied in other DC applications, as for example TiO2 slag, the novel Conroast process, or (twin) DC FeNi furnaces, and could possibly be installed during bigger shut downs. This paper will describe some of the design considerations and operational performance data on this novel column in the FeCr industry that could also be of interest for the FeNi or PGM industry if these would continue to develop towards DC technology.INTRODUCTION Every DC furnace has a cathode and an anode. The anode applied is commonly known as the Concast design, though the original design was by ABB who handed it over to Concast, subsidiary of the SMS-group. Some well-known DC furnaces outside the steel industry where the Concast bottom has been installed are listed in Table 1 as well as a few other key design features.Sidewall cooling and some other data have been left out for reasons of space, and being a lesser relevant design feature to this paper. HES stands for Hollow Electrode System, in which feed is charged through an electrode. Table 1 is built up chronologically according to first start-up date. Below comments are given to briefly explain some of the columns in Table 1: •,“Arm” in the “Cathode” column means that the design of the cathode holding and regulating mechanism consists of an electrode arm as depicted in Figure 1. •,Charging is relevant as some operations started with HES charging, whereas recently most new operations have started without HES but only charging chutes, of which at least some are close to the electrode and possibly others installed closer to the sidewall. •,“Dome” in the “Roof” column means that the design of the roof involves a center piece that can be exchanged if worn. •,The optimal roof design still seems to be a topic of debate, where no design is without problems."

Jan 1, 2017

By E. L. Bruce

EUROPEAN Russia is mainly a great plain, the average elevation of which is only 600 feet above sea level and the maximum elevation less than 1,200 feet (Figure 1). The main divide between the Arctic ocean and the Black sea and Caspian sea is an indistinguishable topographic feature from which the Dneiper and Don rivers flow southward to the Black sea and the Volga river to the Caspian. The valleys of these rivers are but little below the general level (Figure 2). To the south, this great, rolling plain is broken by a low ridge of Precambrian gneisses and intrusive rocks. The Crimea is an upland from which the descent to the Black Sea coast is precipitous (Figure 3). The Ukrainian Soviet Socialist Republic occupies the southern part of the plain. It is the southwestern unit of the Union, bordered by Rumania and Poland on the west and by the Crimean Soviet Socialist Republic on the south.

Jan 1, 1938

By A. Anderko, V. G. Papangelakis, G. Moldoveanu, G. Azimi, M. Carlos

"OLI Analyzer is a software package that uses the powerful Mixed Solvent Electrolyte (MSE) model to simulate the behavior of multicomponent electrolyte solutions from infinite dilution to the limit of fused salt, and from temperatures below the freezing point up to near critical temperature of the mixture. The software also allows the creation of thermodynamic parameters for new chemical systems unavailable yet in public-domain or commercial software databanks. This communication reviews the basics of the model and provides some examples of modeling hydrometallurgical applications with emphasis on high temperature applications, including calcium sulfate scale formation in autoclaves, high temperature pH inference and iron control. INTRODUCTIONModeling of electrolyte systems has been of particular interest to various industrial processes, such as separation processes (e.g., solution crystallization, extractive distillation, seawater desalination or bio-separations), environmental applications (e.g., gas treatment, wastewater treatment or chemical waste disposal) and hydrometallurgy (e.g., pH control and neutralization, iron control, scaling and fouling of equipment). Using a chemical model, time-effective predictions of various properties of electrolytes can be obtained, which is beneficial not only during process monitoring, but also during process optimization and process scale up. As a result, pilot scale studies can sometimes be eliminated where budgetary constraints exist. Development of such a powerful model requires the use of a speciation-based model, in which solution chemistry is explicitly addressed (as compared with some models that treat electrolytes either as undissociated or fully dissociated systems), despite being computationally challenging. In addition, as a feature of electrolyte systems, speciation equilibria inherently influence the phase equilibria due to complex formation, ion pairing, and acid-base reactions. Therefore, how the electrolyte solutions behave at various conditions may differ significantly due to the non-ideality, which must be carefully addressed to obtain a model that is applicable to a wide range of conditions such as concentration, temperature, pressure and solvent system."

Jan 1, 2012

By C. Blawert

The corrosion properties of the skin and the bulk of semi-solid processed and high pressure die cast AZ91 alloy were studied in 5% NaCI solution by (a) analysing the corrosion morphology, (b) measuring electrochemical polarization curves, (c) performing electrochemical impedance spectroscopic measurements, and (d) immersion tests at constant pH-values. Using XRD, LM, SEM and EDX to evaluate the microstructure of skin and bulk specimens, the corrosion results were related to the microstructures of the particular alloys. However, microstructure and corrosion performance were found to be similar for both production processes, and only slight but distinct differences were found. Generally, the skin corrosion properties are inferior to those of the bulk, with the exception of the high pressure die cast AZ91 alloy, where the finer microstructure of the skin layer exhibits a better performance as showed by impedance studies and confirmed in long term immersion tests.

Jan 1, 2004

By Eric Barnard, Andreas Nashitati, John Tero, Guy Deschênes, Setta Mbalamba, John Rajala

The Otjikoto Mine, owned at 90% by B2Gold Corporation, is located 300 km north of Namibia’s capital city of Windhoek. The reserves from the open pit mine, estimated at 25.9 million tons with an average grade of 1.28 g/t Au, contain gangue minerals, pyrite and pyrrhotite, and have an estimated 10 year mine life. The feasibility study included an optimisation of gold leaching using CSTR for the original design. The results of the test work were used to establish the design criteria. Gravity tails from three composites (drill cores), representing the major ore types, were used. The XR3 sample (gravity tails) contained 0.32 g/t Au, while the XR2 and XR1 gravity tails samples (used for variability) contained, respectively, 0.30 g/t Au, and 0.47 g/t Au. The optimum leaching conditions were: a pre-treatment of 7 h at pH 10.5 with 100 g/t lead nitrate, DO > 5 ppm followed by cyanidation at 300 ppm NaCN, pH 10.0, DO > 5 ppm for 48 h. The gold extraction was 91.5% (97.2% overall extraction gravity/leach) and the cyanide addition was 0.57 kg/t NaCN. Increasing the DO to 16 ppm did not show any economic benefits. No pre-treatment or a 4-h pre-treatment reduced the gold leaching kinetics. The XR2 and XR1 gravity tails samples had gold extractions of 92.9% and 92.3%, respectively. At the plant scale, an 11 h pre-treatment is used followed by 42 h cyanidation with 250 ppm NaCN and an average DO of 8 ppm and 230 g/t lead nitrate in 2016. The cyanide addition was 0.49 kg/t NaCN. The commercial operation started on February 28th, 2015. The overall gold recovery and production were 98.4% and 145,696 ounces for 2015 and 98.1% and 166,286 ounces for 2016. It was found that retention times, gold content of leach residues and cyanide addition are comparable for the lab and the plant. Details of the Otjikoto process flowsheet are discussed in this paper along with the results of the lab leach optimisation test program and the plant leach circuit performance and improvements.

Jan 1, 2017

By Y. Tanaka, M. Maeda, S. Suzuki, C. Tokoro, T. Kato, K. Muto

Boron (B) co-precipitation was investigated with ettringite to establish a cost efficient method of removing B from acid mine drainage. For 25 mg/L of B solution, most appropriate pH for B removal was pH 11.5. The most appropriate amount of reagent for B removal within Japanese effluent standard (10 mg/L) was B:Al:Ca:SO4 = 1:3:9:4.5, which corresponds to the composition of Ettringite (Al:Ca:SO4 = 2:6:3). The effect of silicate, carbonate and temperature on efficiency of B removal is important as groundwater and hot spring water are often contaminated. When silicate and carbonate are present, more Al and Ca salts are needed for B removal since some aluminum and calcium precipitate with silicate and carbonate as kaolinite and calcium carbonate. These precipitates do not contribute much to B removal. As the temperature raised, the most appropriate pH for B removal decreased. B removal became less efficient as monosulfate precipitated more rapidly as ettringite.

Jan 1, 2015

By E. Ghali, A. D. Bas

There is a lack of electrochemical studies of oxidized gold ores since the majority of previous studies were conducted with sulphidic gold ores. In this study, the influence of agitation and iron oxide minerals, i.e. magnetite, hematite, and maghemite on gold leaching was investigated by means of galvanic and passivation phenomena. Cyclic voltammetry studies of Roasted Gold Ore (RGO) in de-aerated electrolyte have shown one oxidation and one reduction reaction while three oxidation and one reduction peaks were observed with gold electrode. Galvanic coupling results by Zero Resistance Ammeter (ZRA) mode indicated that magnetite showed a negative effect on gold dissolution while maghemite and hematite showed a positive effect, relatively, as a result of higher galvanic corrosion rates. Generally, gold dissolution was found to increase in the initial 15 minutes. Increasing agitation speed from 100 to 400 rpm resulted in higher galvanic corrosion rates for RGO, magnetite, and maghemite electrodes, while 250 rpm was found to be optimum for hematite electrode. Passive products such as silver and iron-oxide were identified by XPS and SEM-EDS analysis, respectively.

Jan 1, 2015

By V. G. Papangelakis, T. Clark, G. Kolliopoulos

Sustainability of the hydrometallurgical industry requires the development of processes for effective water recovery; if process water is recovered and recycled, fresh water intakes will be reduced. Forward osmosis (FO) is an innovative membrane process that promises to recover water from industrial process aqueous streams or seawater with less energy input compared to reverse osmosis (RO) and evaporation; the energy efficiency relies on the spontaneity of the process (no energy input required). The driving force of the process is the osmotic pressure gradient between a dilute feed solution (process water) and a concentrated draw solution. The draw solution is an engineered aqueous solution that contains a highly soluble chemical reagent that is able to osmotically "draw" only water from the dilute stream, through a semi-permeable membrane, leaving behind a small volume of concentrated brine. The draw solute is separated and recovered for reuse, leaving behind water. The main energy requirements of the FO process arise from the separation and the regeneration of the solute chemicals from the diluted draw solution. This work focuses on the evaluation of aqueous carbonated trimethylamine (TMAH:HCO3) as the draw solution and reports recent findings on the separation efficiency of TMA and CO2 from the solution.

Jan 1, 2015

By Jamie N. Burdeski, Susan E. Hartfield-Wünsch

Aluminum sheet use has been steadily increasing in the automotive industry to achieve mass reduction and improve fuel economy. One significant manufacturing challenge for aluminum sheet implementation is the reduced formability compared to the steel alloys it replaces. This paper includes friction results from the draw bead simulator (DBS), twist compression (TCT) and strip draw (SDT) tests, for two oil based lubricants and four hot melt lubricants. Formability testing was done with the same lubricants and materials, testing in pure stretch with a hemispherical punch, and in draw with a breadpan shaped die.

Jan 1, 2015

By S. Usui, Y. Shinohara, C. Tokoro, K. Horiuchi, S. Owada

Process optimization of heating and physical separation for Cobalt (Co) recycling from spent lithium ion battery (LIB) was investigated. LiCoO2 in spent LIB was transformed to LixCoO2 which was more easily decomposed than LiCoO2 by heating. Coexisting materials of aluminum and carbon, and sealed atmosphere of the LIB promoted LixCoO2 decomposition. In an atmosphere of Argon, 95 % of LixCoO2 in the spent LIB was decomposed to 76 % of Co oxide and 19 % of Co metal in 10 min at 823 K; a lower temperature than the theoretical value for LiCoO2. The Co oxide and Co metal exhibited magnetic properties and could be recovered by wet magnetic separation. Furthermore, slow heating was effective for grain growth of Co oxide and Co metal. At 2 K/min rate of heating, average grain size of Co oxide and Co metal were 239 µm and 28 µm respectively, whereas at 30 K/min they were 190 µm and 15 µm respectively. Therefore, separation efficiency for Co recovery by wet magnetic separation was increased when spent LIB was slowly heated at 2 K/min.

Jan 1, 2015