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By G. M. Ritcey, S. H. Lucas

"On the north shore of the St. Lawrence River, in Quebec, are located orebodies of low-grade titaniferous magnetite. The Quebec Mining Exploration Company (SOQUEM), who have an interest in the deposits, believed that beneficiation of the could generate sufficient revenue to defray the mining costs and the costs of transporting the ore to a steel production facility. A joint research project of SOQUEM and CANMET investigated alkaline roasting of a magnetic concentrate, followed by leaching of the calcine and separation and recovery of Cr and V by solvent extraction. Aluminum was recovered by precipitation.The present paper describes the roast-leach bench-scale and pilot-plant work leading to the development of the optimum conditions f or the integrated process.A plant flowsheet was developed for the treatment of 5 x 106 tons of magnetic concentrate per annum. Estimates of capital and operating costs were made.Based on a recovery of approximately 90% V, 85% Cr and 75% AI, the total hydrometallurgical plant fixed capital costs, including mining, concentration and shipping, are estimated at $1.021 x 109; the operating costs are estimated at $131.92/ton concentrate. Annual revenue from the Na2CrO4.H2O, V2O5 and A12O3 produced is calculated to be $421 x 106.IntroductionThe Quebec Mining Exploration Company (SOQUEM) acquired in 1968 an interest in four titaniferous magnetite orebodies located in Eastern Quebec. 85 miles north of Mingan on the north shore of the St. Lawrence River. The Mingan deposit, with an estimated tonnage of one billion tons, has a reported average grade of 43% Fe, 6.3% Ti , 1.60% Cr, 0.19% V and 6.1% Al with minor amounts of nickel. SOQUEM, on the basis of previous bench-scale data, believed that the recovery of chromium, vanadium and alumina by alkaline roasting would generate sufficient revenue to defray the mining costs and the costs of transporting the ore to a steel production facility on the coast. One of the approaches selected by SOQUEM for beneficiation of the ore consisted of a combination of magnetic concentration followed by alkaline roasting of the calcine."

Jan 1, 1980

By J. Béland, C. Giguère

"The auriferous mineralization at the Sigma-2 gold mine occurs in quartz-carbonate-tourmaline veins emplaced in a fractured granaphyre layer in the upper part of a differentiated gabbro-diorite sill. Kinematic indicators show that fracture planes were active as strike slip, dip-slip (reverse) and tensional faults.Measurements of attitudes of fractures and movement vectors indicate eight different sets that can be grouped into three systems: (I) an east-west oriented system includes a subvertical set and two other sets dipping north and south respectively; (2) a subhorizontal system of two conjugate sets bisected by a third tensional set; and (3)a system of sub vertical conjugate northeast and north-northwest trending sets.Kinematic analysis indicates that the subvertical set of the east west system was subjected to dextral strike-slip movement activated by a northwest-southeast compressive stress whereas the bulk deformation resulting from the remaining and subsequent seven sets can be explained by a protracted subhorizontal north-south compressive stress.The valuable gold mineralization is found principally in the fracture-filling veins of the subhorizontal system and subordinately in the other sets; among these other sets, the NE trending subvertical one is slightly more favourable.The over-all tectonic picture is that of an early mild dextral strike slip faulting in a ductile-brittle medium followed by a general flattening involving, first, a vertical and, later, a lateral extension by fracturing in a medium that had become brittle.The structural features are such that the differentiated sill could not be the source of the auriferous hydrothermal solutions."

Jan 1, 1990

By M. H. Moys, J. A. Engelbrecht

"Large-diameter flotation columns are subject to severe axial mixing which has reduced column recovery and has generally limited it to cleaner applications. It has been assumed that columns with diameter greater than 1 m should be baffled to reduce axial mixing, but little work has been reported quantifying the effectiveness of baffling. Tests were done on a 0.2 m by 2 m column fitted with baffles of different geometry. It was generally found that the inclusion of baffles in the column worsened rather than improved mixing conditions in the column. This is explained in terms of a model for the effect of poor gas distribution on the behaviour of the column; this showed that under typical conditions a 16% excess of gas flux in the one compartment of a two-compartment column could result in one of the compartments being ""dead"" (i.e. with no net flow of slurry through it), resulting in a substantial loss of performance. The quality of mixing in the laboratory column was only reliably improved when the baffle was raised so that its top was positioned above the froth-slurry interface level. It should be possible to increase column recovery substantially with this configuration. The improved residence time distribution also means that columns can be used more effectively in roughing and scavenging applications. IntroductionFlotation columns have generally been used in cleaner applications, starting with their dramatic success at Mines Gaspe(1). Their lack of applications as roughers and scavengers is probably due to their poor residence time distribution (RID) when compared to the conventional cells they would replace. Espinosa-Gomez et al,(2) recently used them in rougher applications but installed three columns in series, presumably to cope with this disadvantage.Dobby and Finch in their seminal papersl(3,4) on the scale-up of flotation columns were the first to quantify the impact of axial mixing on the performance of industrial flotation columns. Laplante et al.(5) collected further data from the literature for column diameter D, ranging between 5 cm and 183 cm, gas superficial velocity Jg ranging between 0.7 cm/s and 2.8 cm/s and per cent solids in the feed S ranging between 3% and 52%. These data were analyzed with reference to the axial mixing model using the boundary conditions for closed vessels (the latter are more appropriate for flotation columns but the model is more difficult to use because analytical solutions for the RID are not available). The data were correlated by:"

Jan 1, 1993

By P. R. A. Andrews

"A sample of flotation feed from Bakertalc Inc., High water, Quebec was subjected to flotation evaluation to improve the recovery of talc. A number of alternative frother/collectors and depressants as well as flotation parameters including pH, conditioning time, frother/collector concentration and pulp density were assessed. In addition, the possibility of using a size coarser than that currently employed for flotation (95% minus 50 um) was investigated.As far as possible, a laboratory duplication of the present circuit arrangement was folio wed so as to minimize the cost of any changes. The best results obtained were a concentrate analyzing 95.96% acid insol for a recovery of 65.98% after four stages of cleaning. With recirculation of cleaner tailings, the recovery would be higher.The possibility of using an alternative method, based on the natural ability of talc to float unaided by a frother/collector, was briefly explored with encouraging results.IntroductionBakertalc lnc ., located in the eastern townships at Highwater, Quebec, Is approximately 140 km east of Montreal near the Vermont, U.S. border. Originally called Baker Mining and Milling Co. Ltd., it has produced pulverized talc products since 1938(1 ), although records show that talc was mined in the area as early as 1871(2). Feed to the mill originally was obtained from local deposits, but since 1952 the van Reet mine near south Bolton, approximately 25 km from Highwater, has been the source of ore .In 1957 a Raymond high -side roller mill was installed which enabled production of a greater range of talc products and, in 1960, new crushing equipment and a dryer were added. Other additions to the mill were the introduction of wet magnetic separation, although this was later discontinued, and flotation to produce high-grade talc concentrates."

Jan 1, 1985

By W. H. Mathews

"The Hardie group of cinnabar claims is in the interior of British Columbia; 25 miles northwest of the city of Kamloops. It is one of a number of mercury; properties scattered along a north trending belt 20 miles long and up to 5; miles wide. In all but one of these properties cinnabar is associated with; dolomite veinlets in zones of carbonate alteration in bedded rocks of Triassic; and Cretaceous (?) age; or in intrusives cutting these bedded rocks. No dolomite alteration or cinnabar mineralization is known in the undoubted Tertiary rocks adjacent to the mercury belt.The mercury showings of the Hardie group lie for the most part in a granitic stock cutting Cretaceous (?) volcanics. The rock in this intrusive shows marked variations in texture and has been described in earlier reports as granite and granodiorice, granite porphyry, and trachyte or dacite porphyry. At Hardie mountain the cinnabar mineralization, unlike that of the other properties, is associated with a fine-grained, almost chalcedoni c, quartz; carbonates, though present, are of minor importance. Some of the most interesting showings are found in an adit in the southeastern part of the property where cinnabar mineralization shows a very distinct structural but not a genetic relationship to a brown porphyry dyke 2 to 8 feet wide cutting a phase of the stock that may best be described as aplitic"

Jan 1, 1954

By Robert B. Parsons

"During hard times, the focus on tax issues makes a slight change in direction. Mining companies contemplate the tax treatment of transactions and circumstances which are the product of a difficult financial environment. Some of these issues are discussed in this month's edition of Tax Notes.Every industrial sector in Canada is undergoing a major restructuring of some form, and the mining industry is not an exception. The longest recession since the Great Depression continues to affect the economy. Mining firms seek to bring their debt/equity ratios into line, and try to replenish depleted retained earnings by selling assets. This month, Tax Notes briefly examines some of the tax issues which are generally encountered during the course of such a restructuring process.Debt SettlementOne question which commonly arises during hard times concerns the tax treatment of a "" gain "" realized by a debtor on the settlement of a debt. Consider, for example, a simple situation where a creditor wants to protect itself from further losses, and makes a deal with the mining company to accept a cash payment of $8 million in full settlement of a $10 million loan. In financial terms, the debtor has made a $2 million gain on the settlement of the debt. What is the tax treatment of that gain?The Income Tax Act (the Act) contains provisions in section 80 of the Act and in section 5400 of the Income Tax Regulations which deal specifically with this question. First of all, it is noted that the $2 million gain is not brought directly into income for tax purposes. However, as indicated below, the gain could affect the debtor's income indirectly to the extent that certain of the debtor's tax pools must be reduced by the amount of the gain."

Jan 1, 1993

By S. K. Paul

"This paper briefly describes the underground crushing and conveying system at Sherritt Gordon Mines' Ruttan Mine. A series of three steel-cord belted conveyors, with a total length of 2J55 metres and a total vertical lift of 407 metres, convey the muck from the underground crushing station to the mill at the surface. The maximum size of the crushed rock is 6 in. All the conveyors are provided with numerous safety and fire suppression devices. IntroductionThe Ruttan Mine of Sherritt Gordon Mines Limited is located 20 km east of the town of Leaf Rapids, 760 km north of Winnipeg. The orebody is multilensed, with lens width varying from 6 to 45 m. Ore production started in 1973 with the opening of a 10,000-tpd open-pit mine. Initial development of the underground mine was started in 1972 with the driving of parallel conveyor and access declines at minus-2507o gradient to the I 220-m level, and then the access ramp was further extended to the 1160-m level. Exploration drifting was done on the 1280-m and 1160-m levels from the access ramp. The final development plan for the underground project was approved in January 1977, and full-scale development and constructionwere resumed.At present, Ruttan Mine is in a period of transition from open-pit to underground mining. Ore production is now coming from both operations. By mid-1980, open-pit production will cease and all production will come from the undergroundmine.The underground mining method at the Ruttan Mine is sublevel open stoping with delayed backfilling. The orebody is divided along strike into a series of 27-m-long stopes and 15-m pillars, both 60 m high."

Jan 1, 1980

By D. W. Smith, J. J. Koskinen, T. A. Enwald, M. E. Ball

"A full-scale demonstration unit of Tampella's LIFAC desulphurization process was tested at SaskPower's Poplar River Power Station Unit No. I. The test program included a series of parametric tests, followed by a 1500 hour operational evaluation. This paper summarizes the results of the test program, and SaskPower's economic evaluation which led to selection of the LlFAC process for SaskPower's 300 MW Shand power station. IntroductionOne of the major influences on the coal mining industry today is public and legislative response to acid rain. When sulphur-bearing fuels such as coal are burned, the sulphur oxidizes to sulphur dioxid e (S00 which, if uncontrolled, enters the atmosphere as one of the by-products of combustion. S02 then combines with water in the air to form an acid and acid rain results. Combustion also produces nitrogen oxides (N0J which can combine with water in the air forming nitrogen based acid , also contributing to acid rain.Acid rain has become a significant international concern. Newspapers have reported on dying forests, dead lakes and crumbling statues. Papers also include articles professing that the physical results of acid rain are vastly overstated. In the United States, a IO-year, Y2-billion dollar study called the National Acid Precipitation Assessment Program (NAPAP) was commissioned to evaluate the effects of acid rain. Even this extensive scientific study did not resolve the controversy. Despite disagreement over the quantitative effects of acid rain, there is no doubt that public concern over the issue is widespread and deeply felt.In response to this concern, legislators throughout the world have reacted with programs that restrict the emission s o f SO, and NO,. To industries involved in the supply and use of coal, the impact of these legislative programs has been extensive. United States power plants will be spending 10 billion dollars in the next decade for flue gas clean-up equipment. Even all this new equipment will not stem the tide of change to low sulphur coals and to “clean “natural gas. The following summarizes legislative actions taken for Canada and the United States."

Jan 1, 1993

By M. R. Shadnam

This contribution provides an assessment of research and development efforts to optimize SOx, NOx and mercury capture in flue gas. Coa, characteristics and combustion conditions in a power plant have an impact on the types and concentration of flue gas pollutants. These factors can also affect the amount of pollutant removed. This contribution would also provide a comparative study of the technologies that holistically aim remova, of SOx, NOx and mercury altogether in coal-fired power plants. A portion of this contribution provides background information on regulatory drivers.

Jan 1, 2010

By Makhlouf Boubahziz

The HNIA field is part of the Tinrhert project which consists of developing 17 fields containing essentially gas with a few small rings of oil. It is considered as one of the main fields in this project in terms of its area and the number of geological structures that has formed it. It is a wide anticline of Cambro-Ordovician age, orientated NNE-SSW and located in the South-eastern part of Illizi basin. This structure extends from Alrar-center in the North, to the North of In Amenas in the South. The area is 1350 km2. The main reservoirs forming HNIA field are the Devonian (F2, F3 and F4), Siluro-Devonian (F6) and Cambro-Ordovician. These latest are formed by 4 sandy units alternated by layers of shale and shaly silt termed from the base to the top as follow: Unit II, Unit III-3U, Unit IV-2L and Unit IV3; these units are the subject of this study. The HNIA field is essentially gas, up to day this field is at the stage of appraisal and evaluation in order to establish a development plan; therefore the main target of this study is to contribute to this frame work. The following objectives are: ?To build a structural model of the study area. ?To integrate all the sedimentological, structural and petrophysical data in order to build a 3D geological model

Aug 1, 2013

By F. R. Ploeger, J. H. Crocket

"IntroductionRocks in the Kirkland Lake district form part of the Timiskaming Group, a south-facing homoclinal sequence of wackes, conglomerate, trachytic flows and pyroclastic rocks and syenitic intrusive rocks. Hewitt (1963) indicates that the thickest section, about 5 km, of the Timiskaming Group rocks is attained in Lebel Township. Several writers (Thomson, 1948; Hewitt, 1963; Hyde, 1978; Jensen, 1978; and Downes, 1979) have observed that the Timiskaming Group unconformably overlies the Keewatin volcanics, particularly along the northern contact. Recent work by Downes (1979) in McGarry and McVittie townships to the east of Kirkland Lake has shown that much of what had formerly been classified as Timiskaming actually belongs to an older group of rocks, the Larder Lake Group (Jensen 1978).General GeologyA series of fluviatile, braided-stream sedimentary rocks (Hyde, 1978) form the oldest of the three major rock suites at Kirkland Lake. Conglomerates constitute a large proportion of these sedimentary rocks and typically contain a large percentage of a variety of locally derived alkalic rock clasts as well as the distinctive red jasper iron-formation pebbles (Fig. 1a). The associated wacke units can be massive to finely bedded and are interbedded with the conglomerate. They also contain a large alkalic tuffaceous component.Interbedded with these sedimentary rocks are alkalic extrusive rocks, including tuffs, agglomerates, breccias and flows, which represent episodes of fissure and explosive crater eruption (Cooke and Moorhouse, 1969). The tuffs, although dominantly alkalic in composition, are commonly reworked and contain sedimentary features such as graded bedding, scouring and crossbedding (Fig. 1 b). The trachytic flows are massive to porphyritic and outcrop mainly east of Kirkland Lake in the adjoining townships. Altered leucitic porphyritic flows, locally referred to as red and green spotted trachytes, commonly occur."

Jan 1, 1982

By P. J. Urso

"This paper discusses the mining problems encountered at the Fording River coal mine to date, and how they have been solved. All of the production now comes from surface mining, but underground hydraulic mining is planned and briefly described. Other facets of the operation, including markets, equipment and personnel, are covered. IntroductionFording Coal Limited was formed in 1968 to mine and market metallurgical coal resources held by the company in the East Kootenay region of southeastern British Columbia. The company, at its Fording River operations, holds approximately 48,000 acres of coal lands, having an estimated 2.0 to 3.0 billion long tons of metallurgical coal in place. (Although not a point for further discuss ion in this paper, the company also holds approximately 1.0 million acres of mineral rights. These consist primarily of coal in Alberta, potash and coal in Saskatchewan, and minor industrial mineral holdings of limestone, salt and bentonite in the three western provinces.)Fording Coal is owned 60% by Canadian Pacific Investments Ltd. and 40% by Cominco Ltd. Inasmuch as Cominco itself is owned approximately 54% by CPI, it is seen that the effective CPI ownership of Fording is about 82%. The company, originally staffed and managed by Cominco, has been independent since January, 1978, with its own board of directors, management, staff and employees.The company's head office is in Calgary, Alberta. The Fording River operations are located approximately 45 miles north of the Crowsnest Pass, near the Alberta/British Columbia boundary, only 95 air miles and 200 road miles from Calgary.A contract was signed in 1969 with the Japanese steel mills to provide 45 million long tons of metallurgical coal over IS years, commencing in 1972 at an annual rate of 3 million long tons per year. Despite some start- up difficulties, the mine and plant facilities achieved their rated capacities in 1975, producing and shipping at the 3-million-Iong-ton level. The coal specifications are shown in Table I."

Jan 1, 1980

By A. Sacit Saydam

"Induced polarization/resistivity and magnetometer surveys have been carried out over the Casmo molybdenite deposit in mountainous terrain of northern British Columbia. Molybdenite occurs in quartz-bearing fractures with or without pyrite along a zone of hydrothermal alteration and intense fracturing, believed to be a northerly dipping fault zone, within medium-grained equigranular and porphyritic quartz monzonite.The molybdenite-bearing zone is characterized by a significant resistivity low, a metal factor high and a subtle IP low flanked by highs outside the mineralized area. Magnetic trends, indicated by a magnetometer survey, generally parallel the zone and strike direction of the different intrusive phases, and have been helpful in delineating contacts and faults in the area.IntroductionThe Casmo molybdenite deposit is 6 km southwest of the asbestos mining town of Cassiar in northern British Columbia, at an elevation of 1,550 metres. Molybdenite was first discovered during the early 1950s and the first important exploration work was done in 1964. Between 1964 and 1971, about 25,000 feet of drilling was done by various operators, as a result of which 33.7 million tons of molybdenite ore was drill indicated at a grade of 0.123%. In 1979, Shell Canada Resources entered into an option agreement with the former operator, New Jersey Zinc Corporation. Shell completed 27,000 feet of diamond drilling between 1979 and 1980 and ha s reported 75 million tonnes of drill-indicated ore with an average grade of 0.13% MoS2• This paper is a case history of IP I resistivity and magnetometer surveys done over the Casmo deposit during 1979 and 1980."

Jan 1, 1983

By Robert B. Wickham

"American Barrick has always balanced its aggressive operating approach with a conservative financial strategy. In fact, what enables their mining team to pursue such aggressive plans with confidence is the conservative financial strategy adhered to by the company. These policies are built on a prudent mix of gold linked financings, equity and gold price hedging.This paper outlines these policies and focusses in particular on American Barrick's gold price hedging program.IntroductionThe company's balance sheet at the end of 1990 clearly shows the wisdom of its conservative policies. Total assets have grown to over US$1 billion; cash has grown to US$312 million and shareholders' equity to US$645 million. All amounts included in this paper are quoted in U.S. dollars. Increased gold production and an effective gold price hedging program also combined to produce record income from operations, earnings and cash flow in 1990.The first half of 1991 is also indicative of the benefits of the company's conservative financial policies. Increasing production, together with its comprehensive gold hedging program, has generated increased earnings, even in a period of falling gold prices.All year-over-year numbers for the first six months are up. Gold production was 36% higher; earnings of $40.2 million $ 0.30 per share - were 46% higher than 1990.Barricks revenue continued to increase despite gold prices remaining unchanged during 1990. Barrick's hedging policy protects the company from falling gold prices on the basis that the upside looks after itself. Their hedging program - including various goldlinked fmancings - enabled Barrick to realize an average price of $437 per ounce of gold sold in 1990, compared with the Comex average gold price for the year of $384 per ounce."

Jan 1, 1991

By Peter Harben

"This paper discusses the benefits of industrial minerals, their sources of supply, price and marketing trends, and their increasing use as substitute materials and ""strategic"" minerals. IntroductionKaolin finds have yet to spark the kind of frenzy associated with the 1849 California gold rush; no dolomite deposit has ever gained the notoriety of the Comstock Lode; and few industrial minerals are counted among the currently fashionable list of "" strategic mineral s"". Nevertheless, the glamorous zhine associated with metals may be somewhat superficial; further digging provides perhaps the real foundation of modern society - industrial minerals.They are often tagged as common, everyday materials that are simply dug out of the ground, crushed and hauled to a local point of consumption. Although this description is accurate in the case of road aggregates, sand and gravel, and the like, there are many exceptions to this rule. The term industrial minerals is rather nebulous, covering as it does the mundane and esoteric, the chemically active and the refractory, the $2 and the $10m-a-ton product. All of these minerals influence every facet of modern life from fertilizers to fire retardants, ceramics to cars, construction to clothes, and toothpaste to tennis courts. Their usefulness is well illustrated by the variety of industries they serve; the main ones are listed in Table 1. It is now time to dismiss the notion of non-metallics as the ""third world"" of natural resources business after the metallic and energy products by dispelling some of the myths regarding abundance, variety and value of the group's sixty-plus products."

Jan 1, 1982

By D. Lauzon, H. de Ruiter

"In 1988a decision was taken to design and install a computerized mine monitoring and control system. This system had to monitor and control all pumping and ventilation underground. The operation of the mine air heating, using waste heat from the mine water and compressors, was to be part of the system. It ultimately also had to interface with the four existing Canadian General Electric Series 3 PLC's which controlled the No .3 shaft loading pockets. Beside operational control and trouble shooting, the system is a valuable tool in energy management and ultimate savings are estimated at $50,000 per year.The final equipment selection was a General Electric Series Six PLC on surface with a total of 17 Series One Plus and Juniors PLC located underground. Data is transferred through a two-pair shielded cable using modems. Both analog and digital functions are being utilized.The basic monitoring and control system was commissioned during 1989and, due to a higher level of technology today, further improvements have been planned for the future. The system was designed by Walter Dow together with Gordon Champion of D.G. Champion Engineering Ltd. of Toronto. Advice for the ventilation part of the project was obtained from Maurice White, Independent Ventilation Consultant.The Ministry of Energy, Mines and Resources and the Ministry of Energy of Ontario approved this project together with the waste heat recovery project to qualify for a grant of$135,000 under the Enerdemo-Canada program.IntroductionThe Macassa mine is a narrow vein gold mine situated about 2 km west of the town of Kirkland Lake in northeast Ontario. The mine has been in continuous operation since 1933 and a total of about 3.0 million ounces have been recovered out of 6.6 million tons of ore ."

Jan 1, 1991

By M. A. Mahtab, A. S. Burgess, R. G. Charlwood, P. O. Sandstrom, J. L. Ratigan

"Addressing a current operating and environmental concern, this paper first presents an overview of the design program for an underground radioactive waste storage vault. It then reviews the construction, operational and thermal-mechanical aspects of such a project. The relevant experience from major underground construction projects is reviewed and the paper concludes with brief comments on the design-oriented research and development requirements . 1. IntroductionA program to develop techniques for the ultimate disposal of high-level radioactive waste into geologic formations was announced by AECL in 1975 (Tamrnernagi, 1976), and is discussed more fully in a later document (Boulton, 1978). Our paper summarizes the studies caried out, as part of the AECL waste management program, by the authors and associates on the development of design concepts for a vault situated in crystalline rocks of the type present in the Canadian Shield.The design studies have been carried out in three phases, the elements of which are described in Section 2.1 (also see Fig. 1). The general vault designs are presented in Section 2.2. These provide for emplacement of either immobilized fuel or solidified reprocessing wastes in a room-and-pillar facility at a depth of 1,000 m.Section 3 reviews the principal design considerations from the construction, operation and thermal-mechanical response aspects. The concepts have been studied in both temporal and spatial domains, and the requirements and responses assessed in each as appropriate.Section 4 briefly reviews the availability of relevant experience from previous major underground construction projects. Finally, in Section 5, brief comments are given regarding design-oriented research and development requirements."

Jan 1, 1980

By K. Enns, J. J. Byerley

"While thiocyanate (SCN-) is used in a number of industrial processes (production of polyacrylonitrile filaments, synthesis of agricultural chemicals and certain metallurgical solvent extraction and flotation circuits) it is recognized more as an undesirable by-product associated with ' the metallurgical industry. Thiocyanate is present at low concentrations in some waste streams from the iron and steel industry. Of particular significance is the formation of thiocyanate during cyanidation of gold and silver ores, concentrates, tailing s and residues. The thiocyanate levels present in the resulting effluents may range from a few mg/I to several thousand mg/I.At present, thiocyanate does not appear to be as hazardous in the environment as cyanide (CN-) at the same concentration although its interaction with other species and resulting decomposition of products may be unacceptable. Of course the presence of thiocyanate in the leaching circuit and ultimately in the effluent streams may add considerably to the oxidative requirments of any non-selective treatment process for cyanidation wastes.With respect to the thiocyanate as it relates to the cyanidation process, two aspects are evident. Thiocyanate forms and persists in the cyanidation circuit resulting in a ""fouling"" condition with subsequent loss of leaching activity. In order to reduce or control this problem, it is common practice for some mills to discharge daily as much as 20% of the barren leach liquor. Besides contributing to fouling of the leach liquor the formation of thiocyanate represents an irreversible loss of reagent cyanide. It is noteworthy that in some present or proposed mill practice reagent cyanide loss through thiocyanate formation may reach 50%(1). The purpose of this paper is to discus s the application of controlled electrooxidation of thiocyanate with the view of suggesting a process for regenerating cyanide from waste thiocyanate(2). The paper describes the important theoretical aspects and presents experimental data obtained for thiocyanate electrooxidation using both small and large scale electrochemical reactors. Some economic conclusions are presented."

Jan 1, 1984

"Eastern Canadian thermal coal mined at Minto, New Brunswick, and in western Cape Breton at St. Rose, Inverness County, Nova Scotia, contains 6-8 per cent sulphur. Both coals are high volatile bituminous. types. The Minto coal averages 18 per cent ash, 7 per cent sulphur and has a Btu rating of 11,900 per lb. Pyritic sulphur accounts for 75 per cent of the total sulphur and the remainder is largely organic; the amount of sulphate sulphur is negligible. This means that in a 7 per cent sulphur coal, 2 per cent is organic and 5 per cent pyritic sulphur. Pit-head St. Rose coal contains approximately 10 per cent ash, 7 per cent sulphur and 11 ,800 Btu/lb. The distribution of sulphur is different to that of Minto coal because about 12 per cent sulphate sulphur is present. Thus, a 7 per cent sulphur coal would contain 4 per cent pyritic, 2 per cent organic and 1 per cent sulphate sulphur.The iron sulphides, pyrite and, to a lesser extent, marcassite occur over a wide size range from large sulphur balls to crack fillings, lenses, and individual crystals and framboids. Coarse-grained pyrite and sulphur balls are easily separated during washing. It is the fine grain sizes, intimately mixed with the coal constituents, that are difficult to separate. Quantimet analyses of the fine grains in coal from both localities showed that about 50 per cent were smaller than 30 micron(1).No efforts have been made to wash the Inverness coal of Nova Scotia and in 1980 washing ceased in New Brunswick. Previously, the Minto coal was processed in an antiquated jig circuit which reduced ash from the strip operation run-of-mine value of more than 20 per cent to less than 18. More effective removal of ash and sulphur could clearly be obtained. Laboratory tests on both Minto and St. Rose coal have shown that ash rejection rates of 40 to 50 per cent at yields of 70-80 per cent were possible(2), Little information on sulphur removal was available."

Jan 1, 1981

By Robert M. Hopkins, Craig C. Monahan

A corrosion survey was performed on ten selected H-piles which support a reinforced concrete wharf located at Trepassey, Newfoundland. Approximately 900 thickness measurements were taken at twelve different locations in each off our zones on the steel piles: the splash (atmospheric) zone, the intertidal zone, the low tide zone and the submerged zone. Results show that over the 2o-year life of the wharf, corrosion has been most severe in the splash, low tide and submerged zones with average corrosion rates for the flanges of 6.95, 9.45 and 6.86 mils per year (mpy}, respectively, and average corrosion rates for the webs of 5.13, 4.12 and 3.45 mpy, respectively. Minimal attack was found in the intertidal zone where the average corrosion rate was only 1.66 mpy on the flanges and 1.37 mpy on the webs. Such a pattern of attack is frequently observed f or steel piles partly submerged in seawater. The abnormally low corrosion rate associated with the intertidal zone is generally explained as being due to cathodic protection induced by the high corrosion rate in the adjacent low tide zone. Analysis of the corrosion data obtained for the Trepassey wharf would suggest that this explanation might be incorrect. An alternate hypothesis has been brought forward which better accounts for the extremely low corrosion rate observed in the intertidal zones of these piles.

Jan 1, 1990