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By T. R. Madhavan

The development of contact angles on highly polished ?uraninite surfaces, using sodium oleate and dodecyl ammonium acetate as collectors, has been studied at different collector and hydrogen ion concentrations. It was found that sodium oleate in acidic media (up to a neutral: PH) and dodecyl ammonium acetate in neutral and alkaline media give good contact angles. It appears that the combined forms of these collectors, viz., oleic acid and free amine, are more important in effecting contact. W ITH the emergence of uranium as a strategic metal in the last fifteen years, considerable effort has been directed toward the commercial recovery of uranium from its ores. This has resulted in the development of a uranium technology. It is only in recent years, However, that fundamental data regarding the floatability and surface properties of uraninite and ?pitchblende have been elucidated by different methods. Contact-angle measurement is one of the important tools for tl1e evaluation of the conditions of floatability

Jan 1, 1964

By W. J. Blackstock

Introduction To The great majority of people, the term 'strip coal' has little or no meaning, or if it has any significance it is thought to refer to a poor grade of coal that had to be accepted during the war because no other fuel was available. Few people in the Province of Alberta realize the magnitude of our coal stripping industry, and fewer realize that strip coal has been available to domestic consumers for at least forty years. Among the first in the field of strip coal mining in Alberta were the Tofield Coal Company, Ltd., and Sterling Collieries Company Ltd. It was not until the advent of World War II, with its huge drain on industrial and domestic coal sup? plies produced by the underground mines, that some other source of coal was seriously sought. The tremendous shortage of manpower du ring this period of National emergency made it imperative that any increase in the coal production must be procured on a high tonnage per man-hour basis. It was therefore natural that the highly mechanized strip mine should be eagerly encouraged and subsidized by the Governmental agency - the Emergency Coal Production Board - under the very able direction of Mr. G. A. Vissac.

Jan 1, 1949

By M. S. Moats, C. M. Campbell

Samples of a high impurity (90.05 wt. % Cu, 4076 ppm Pb, 1939 ppm As and 635 ppm Bi) commercial copper anode were characterized and then electrorefined in a laboratory scale cell. Anode inclusions were examined using backscatter mode scanning electron microscopy and energy dispersive spectroscopy. Hundreds of inclusions were measured for size, morphology and composition. Commonly found inclusions were copper oxide (Cu2O), complex oxides (Cu-Pb-Bi-As-O) and copper selenides/tellurides. The weight percent of lead and arsenic increased with increasing inclusion size up to 4- 5 microns. During electrorefining, starter sheet ductility was negatively impacted by thiourea addition. The importance of arsenic (V) concentration on the electrolyte concentration of bismuth was observed. INTRODUCTION Copper electrorefining is a commercial process used to produce the majority of the world’s refined copper. During this process, impure copper anodes are dissolved electrolytically, and high purity copper is deposited on cathodes. As the anodes dissolve, the impurities either accumulate in the electrolyte or report to solids that form on anodes surfaces or at the bottom of the refining cell. These solids are called slimes. Slimes contain precious metals and are collected for further processing. Slimes are also an important outlet for problem impurities such as lead, antimony and bismuth. The electrorefining process is operated in such a way to encourage the deportment of these elements to the slimes. Impurities in copper anodes have been studied extensively by Chen and Dutrizac (1990, 1993 and 2005). The most common impurities found in modern copper anodes include: Ag, As, Au, Bi, Fe, Ni, O, Pb, Sb, Se, Sn and Te. Impure copper anodes are produced by pyrometallurgical methods and have purities ranging from 97.7–99.7% Cu (Moats et al., 2019). The composition ranges of commercial copper anodes from the 2019 worldwide tankhouse survey are given in Table 1. The concentrations of anode impurities vary widely dependent on the source material and prior processing steps. Based on the work of Chen and Dutrizac, both gold and silver are predominantly found in solid solution within the copper grains while a minor amount of Ag can be found in Cu2(Se/Te) inclusions. Nickel is entirely soluble within the copper grains up to anode compositions of 2500–3000 ppm Ni; above which NiO and kupferglimmer phases are formed (Chen & Dutrizac, 1990). As, Bi, Pb and Sb are found in solid solution within copper and within oxide inclusions typically found along grain boundaries. Oxides are formed due to the presence of 0.13-0.18 wt. % O (Chen & Dutrizac, 1990). This is because during solidification of the cast anodes, impurities are enriched in the liquid phase as the copper grains nucleate and grow. The inclusions form from the last liquid to freeze, which is typically along grain boundaries (Wenzl & Filzwieser, 2007; Wenzl, Filzwieser, Mori & Pesl, 2008).

Jan 1, 2019

By Andre du Preez

Emergency Fall Arrest System Rio Tinto?s Primary Objective: ?To achieve repeatable controlled safe deceleration rates during emergency fall arrest activation (Ontario OHSA Regulations) ?Must operate effectively on mine specified steel shaft guides.

May 1, 2013

By S. Pauly, U. Kühn, J. Eckert, I. Kaban, G. Wiehl, F. Silze

In the present work, the effect of Ga on the wetting behavior of the Cu-rich braze filler CuGa10 (wt.%) on the steel 304L was investigated. For this, the macroscopic and microscopic effects governing the wetting of pure Ga, pure Cu and CuGa10 alloy (wt.%) on the austenitic steel were analyzed and compared. Contact angle and surface tension measurements were carried out by means of the sessile drop technique and, in addition, the phase formation at the interface was determined. Pure liquid Ga spreads on 304L, which supposedly is related to the formation of intermetallic Fe-Ga phases growing into the liquid Ga. Depending on the annealing time, FeGa3 and Fe14.5Ga12 were identified. In contrast, CuGa10 as well as pure Cu show secondary wetting on the steel surface. Especially, liquid Cu prefers to spread laterally and vertically along the grain boundaries of the steel substrate. In spite of rather similar mechanisms, CuGa10 wets 304L steel at lower rate than pure Cu above the liquidus temperature.

Jan 1, 2014

By V. G. Papangelakis, G. A. Moldoveanu

"One of the major commercially viable secondary sources of rare earths elements (REE) are the ion-adsorption ores, containing 0.05-0.3 wt% rare earth oxides physically adsorbed on the surface of clay minerals formed during weathering of lanthanide-rich rocks. Although ion-adsorption deposits are substantially lower grade than other types of rare earth sources, this is offset by the easier mining and processing costs and the low content of radioactive elements. The conventional extraction route involves ion exchange leaching with monovalent cation solutions (usually ammonium sulphate) under ambient conditions; during the process, the lanthanides are desorbed and transferred into solution, being replaced by the exchange cation. While ammonium ions are known to perform best, there is increased environmental motivation to investigate alternative lixiviants in order to minimize ammonium sulphate impact via reducing its use without considerable loss in rare earth recovery.The objective of the present research was to screen various cations salts (alkaline and alkalineearth metals present as sulphates, chlorides and acetates, respectively) in order to comparatively evaluate lanthanide desorption levels and provide a theoretical base of the observed behaviour. The overall aim is to gain a better understanding of how both cation and anion may affect the overall REE recovery from ores in order to provide alternative processing routes. The distinct exchange capabilities of cations were explained in terms of differences in cation hydration enthalpy within the same group, i.e. Cs+ > NH4 + > K+ > Na+ > Li+ and Ba2+ > Ca2+ > Mg2+. For the same cation, it was determined that REE extraction efficiency follows the order sulphate > acetate > chloride, based on dissimilarities in constants of formation values. Various process implications scenarios will be described based on using mixed cations and anion matrices."

Jan 1, 2016

By E. Fiset, T. Hennebel, F. Verbruggen, A. Prévoteau, K. Rabaey

Arsenic (As), bismuth (Bi) and antimony (Sb) are known to affect the quality of copper deposits in copper electrowinning operations. The codeposition of As was previously believed to occur only at current densities far exceeding the range of typical current densities for copper electrowinning. In this study, we investigate the copper electrodeposition on different pretreated stainless steel (SS) substrates from bleed electrolyte in galvanostatic mode at –45 mA/cm². Scanning electron microscopy (SEM) micrographs illustrate that during the initial phases of copper nucleation and growth, the current density was locally increased due to the pretreatments. It was reasoned that the codepostion of As could possibly occur in normal electrowinning conditions, but the risk can be substantially reduced by good SS substrate handling and maintenance practices. INTRODUCTION The presence of As, Bi and Sb is known to have a deleterious effect on the copper cathode quality in copper electrowinnings (Hiskey & Maeda, 2003; Hoffmann, 2004; Xiao, Cao, Shen, & Volinsky, 2012; Xiao, Cao, Mao, Shen, & Ren, 2014; Jafari et al., 2017). They are known to influence both the chemical and physical quality of the copper as they can contaminate the copper (Jafari et al., 2017) and affect the copper deposit structure (Hiskey & Maeda, 2003; Kim, Kim, & Chung, 2009), which contributes to a degraded market value of the copper (Tuddenham, 1984). The incorporation mechanisms of these impurities are believed to occur mainly through slime inclusion (F. Xiao et al, 2012) and electrolyte inclusion (Hiskey & Maeda, 2003). Other studies suggested that codeposition of these impurities is possible by their standard reduction potential being close to the one of copper (Xiao et al, 2014). Hiskey and Maeda (2003) investigated the copper electrodeposition on a copper electrode substrate in Cu electrolytes with a Cu, H2SO4, As, Bi, Sb composition representative for commercial copper tankhouses. The combination of voltammographic techniques and Auger electron spectroscopy showed that As was the first impurity to be electrodeposited from this electrolyte, yet at potentials where the limiting current density of the copper electrodeposition reaction is exceeded. The copper tankhouses usually operate at a current density ratio of 0.3 to the limiting current density in order to achieve tolerable copper quality deposits. The codeposition of As could be considered impossible in this current density condition. However, it is known that during the initial phases of electrodeposition on foreign substrates, a substantial part of the reaction proceeds by growth of individual nuclei where the current density is locally high and diffusion limited (Radisic, Ross, & Searson, 2006). Furthermore, it was observed that copper nucleation on TiO substrates occurred preferentially in the scratched oxide free areas which could serve as parts with high localized current densities (Chang, Choe, & Lee, 2005).

Jan 1, 2019

By R A. Stevenson

The purpose of this paper is to outline a recent development in ground fault protection. The paper deals with the A problems of both grounded and ungrounded systems, with regard to hazards to personnel and equipment, and shows that the increased sensitivity and speed of operation of this new detector results in increased safety to personnel and reduced stresses on equipment, and permits the detection of leakage currents before they become serious faults. The detector can be applied to all distribution systems, either A.C. or D.C., up to 15 kv., and the detector itself can be tested at regular intervals without interrupting line circuits. T HERE is always controversy among engineers as to whether distribution systems should be grounded or ungrounded. There are many experi-enced engineers on both sides of this controversy, and each have valid reasons for their choice

Jan 1, 1964

By K. L. Ford, D. R. Lentz, J. H. Rickard, R. P. Taylor

Abstract - Coupled gamma-ray spectrometric and lithogeochemical studies throughout the Heath Steele Mines area, Bathurst Camp, New Brunswick, indicate that primary and secondary geochemical differences exist between the stratigraphic footwall and hangingwall crystal tuff units which host the massive sulfide deposits. Of particular interest is Th, and to a lesser extent, Zr and Y, which are more concentrated in the hangingwall than the footwall crystal tuffs, whereas the opposite is true for TiO2. This expands on earlier lithogeochemical-chemostratigraphic results concentrated in the eastern part of the Heath Steele belt that led to revision of the local stratigraphy, and necessitated a structural re-interpretation of the area with implications for exploration. Although K depletion (decreased K and K/Th) is typical of chloritized footwall zones of chloritization, these features were not fully apparent here due to the recessive nature of these altered zones. In situ radiometric analysis using a portable gamma-ray spectrometer is a rapid, inexpensive analytical technique for chemostratigraphic characterization of rock units within volcanogenic massive sulfide deposit settings, provided there is a contrast in the distribution of natural radioelements, particularly Th and K.

Jan 1, 1998

Induced microseismicity monitoring is: ?Essential tool in improving the geotechnical understanding about a mine and its inaccessible surrounding rock masses. It helps to determine: -Event timing, location, and magnitude - identification of highly stressed areas -Event source mechanism - the physics of fracturing in its seismic source region -Seismic strain-rate distribution in 5D - identification of stress concentration or migration patterns -Geomechanical interpretation - identification of hidden geological structures or weaknesses in the ground -Strategy for mining e.g. by a block caving method - maximization of mine production and to optimize ground support design -Potential of future seismic hazards -Large event re-entry protocol, to improve mine safety ?The norm as part of mine safety maintenance and long-term mine design practices

Aug 1, 2013

By Frank Condon

?Location ?Background ?Drilling Program ?Mineral Resources ?Geology ?Economic Assessment ?Strategic Partner ?Located in Nunavik, Québec ?160 km northwest of Schefferville ?240 km south of Kuujjuaq ?160 km northeast of Brisay ?Magnetic Anomaly ?Property Boundary ?Diamond Drill Holes

May 1, 2011

By P. Rosario

"Current industry practice for HPGR assessment and sizing relies on conducting a series of tests using pilot-scale machines with roll diameters of 700 mm to 1000 mm. Substantial amounts of sample are required for such pilot test programs, typically 1 to 10 tonnes of the sample is needed depending on the level of study and complexity of the resource. Collection of large quantities of representative samples during the early stage development is challenging and expensive, thus significantly hinders the HPGR technology from being incorporated into early-stage designs. A robust and reliable laboratory test is therefore needed to allow a fair consideration of HPGR for early stage projects. With support from the Canadian Mineral Industry Research Organization (CAMIRO), the NBK Institute of Mining Engineering at the University of British Columbia (UBC) developed a suite of Piston Press bench-scale tests that correlated to pilot and full scale HPGR operating information (Davaanyam, 2015; Davaanyam et al, 2015; McClintock, 2018). The Piston Press Tests (PPTs) are capable of assessing the HPGR technology at the scoping, pre-economic analysis (PEA), and pre-feasibility (PFS) stages of project development. This paper will briefly describe the theory on which the PPTs are based, and then presents a case study conducted for a copper deposit to show how the PPTs are being used for scoping and pre-feasibility level studies. Specifically, the PPTs are being used to provide information for preliminary sizing and selection of an HPGR and to assess the effect of ore variability on HPGR performance. The results are also applied to developing HPGR circuit designs and can be incorporated in simulation so that optimum design parameters can be selected.INTRODUCTION It is widely accepted that high pressure grinding rolls (HPGRs) offer a viable energy-efficient solution for the modern comminution flowsheet design. Table 1 summarizes selected examples of HPGR applications in the hard rock mining industry. The main benefits of HPGRs are energy savings which leads to lower operating costs, and its stable operating characteristics that can better cope with variations in ore hardness when compared to the conventional SAG mill-based comminution circuits."

Jan 1, 2019

By Helen Shang, Jianjun He

In nickel and copper production, sulfur dioxide (SO2) is generated during mineral smelting. Emission of sulfur dioxide into the atmosphere causes serious health and environment issues. Sulfuric acid plants, which convert the harmful SO2 gas to commercially useful sulfuric acid product, ensures safe and environmentally sound smelter operations. The sulfuric acid plant is mainly composed of a SO2 to SO3 converter, a series of heat exchangers and SO3 absorption towers. The SO2 converter is crucial for minimizing SO2 emission in a smelter. In this paper, steady state and dynamic modelling are carried out for the converter using mole and energy conservations. Simulations are performed to investigate the effect of feed conditions on SO2 conversion. The developed model represents an important component for modelling the acid plant in a smelter and is expected to provide a fundamental tool for the future optimization and control development.

Jan 1, 2014

In-Situ Leaching (ISL) process plants are low cost producers for uranium deposits where the geology is suitable. In the 1970s, a three-year pilot ISL program occurred on gold ore from the Ajax Mine, Cripple Creek District, Colorado, using a chloride and iodide solution [1]. The test was halted due to poor results. With gold and silver the international ISL progress has been slow; however the potential for low capital expenditure (CAPEX) and operating expenditure (OPEX) with large low grade deposits is real. Unless the metallurgy has been demonstrated there are significant risks which could be fatal flaws to an ISL gold or silver project. The metallurgy of gold ISL projects is far from simple and it is early days with project development.

Jan 1, 2011

By D. Neely

As Saskatchewan potash mines grow in age and size, mining reaches greater depths.  The stress-relief design principals which were empirically derived at shallower depths are beginning to show fault.  Nutrien Vanscoy Potash has began to encounter new ground support and panel design challenges which were previously had negligible effect.  While the initial reaction was to reduce extraction and implement distance buffers between operating machines, it eventually became clear that these would only provide short term relief and that in order to continue safely and efficiently mining broad areas, a fundamental change in the mine design would provide the long-term protection required.  Presented is a case study with an overview of the challenges encountered at Vanscoy Potash in areas of greater depth along with an account of the design changes considered, implemented and recommended for future success. 

May 4, 2025

By Rodrigo Craig Cerello

The Brazilian economy has always presented a strong correlation with the mineral activity. Since colonization days, due to the territorial expansion caused by the explorers search for gold, mining in Brazil became a basic sector of national economy. Currently, the Brazilian mineral sector¹ estimates a 550% production increment (Figure 1A) in the last 10 years, reaching the US$ 50 billion value, reflecting the increased global demand for raw materials from mineral origin. According to the Brazilian Constitution², mineral resources belong to the Federal State and, consequently, their exploitation must be authorized, under penalty of engendering federal crime. Furthermore, activities of this nature are prone to cause environmental degradation such as, but not limited to, deforestation, pollution, soil deterioration and water contamination. The GPEMA represents the forensics group of the Brazilian Federal Police responsible for the technical analysis of traces related to crimes against the environment and consequently, illegal mining cases.

Aug 1, 2013

By M. I. Kalashnikova, Y. M. Shneerson, M. V. Keskinova

Interaction between mattes having various compositions and solutions with a wide range of free acid and non-ferrous metals concentration have been studied in terms of chemistry, mechanism and kinetics. The solution acidity and oxidizers to reducers ratio in the matte-solution-gas phase system have been demonstrated to be the major factors determining the process behaviour. It was found that the types of copper and nickel secondary sulphides resulted from nonferrous metals precipitation from solution, depend on of the solution and initial matte composition. Based on these studies, technologies of matte leaching and nonferrous metal precipitation in the form of rich sulphide concentrates are developed.

Jan 1, 2004

By Mariam Melashvili, Chris Fleming, Rene Jackman

"A study was undertaken to develop a flowsheet for treating a high grade silver/gold ore body by cyanidation, CCD and Merrill Crowe precipitation, with tailings detoxification to meet stringent limits for cyanide and thiocyanate concentrations in the final discharge. In one of the flowsheets examined, free cyanide in the final leach liquor was recycled to the mill where it was hoped that it might react beneficially with fresh ore to reduce the cyanide makeup by an equivalent amount. However, laboratory results suggested that most of the cyanide recycled to the mill reacted with iron forming a soluble ferrocyanide complex. This would have had a negative impact on cost, not only because the cyanide recycled to the mill could not be claimed as a credit, but also because the presence of ferrocyanide in the final tailings meant copper sulphate had to be added to the SO2/air cyanide detoxification process to precipitate the iron cyanide. In an alternative flowsheet that was examined, recycling of cyanide to the mill was abandoned, and this allowed the milled slurry to be pre-aerated in a single mixing tank before cyanidation. During alkaline pre-aeration, any ferrous ions that are generated in the mill are oxidized to ferric ions, which, unlike ferrous ions, are inert in cyanide solution. This significantly reduced cyanide consumption and lowered costs in the detoxification of the tailings. In this paper, the cost implication of these two circuits is compared.INTRODUCTIONMost of the gold that is produced by hydrometallurgical processes is recovered by cyanide leaching. The reason for that lies in the superior thermodynamic stability of the gold cyanide complex and the favorable economics this confers on the process (Fleming, 2014). However, the gold in most of the gold-bearing ores processed is a very minor component, and therefore, the leaching response is often dominated by that of the host minerals.Many gold ores treated by the cyanidation process contain iron minerals. Cyanide reacts readily with some iron minerals forming ferrocyanide as one of the compounds. Ferrocyanide is stable when solutions are exposed to air and does not retard the dissolution of gold. In fact, it has been claimed that potassium ferrocyanide in the presence of oxygen is a weak solvent for gold (Hedley & Tabachnick, 1958). The main problem with the formation of this compound is the consumption of cyanide. Ferrocyanide contains six molecules of cyanide for each atom of iron {Fe(CN)64-} so the wasteful consumption of cyanide is greatly increased by its presence. Thiocyanate is also often produced during the reaction of certain iron sulphide minerals with cyanide, and contributes to the wasteful consumption of cyanide. In addition, environmental regulations in certain countries demand that thiocyanate be removed from the tailings, and this adds significantly to the cost of tailings treatment."

Jan 1, 2016

By M. Turner-Jones, N. Steenekamp

"The Lonmin Base Metal Refinery treats converter matte from the Lonmin Smelter to produce nickel sulphate crystals, copper cathode as well as a concentrate containing the platinum group (PGM) metals. The original process employed a Sherritt design and utilizes atmospheric and pressure leaches for the dissolution of base metals. This paper describes the original flow sheet and the improvements made to enhance PGM recoveries, product quality and to increase capacity. Changes include the introduction of flash recycle cooling on the autoclave, batch leaches to improve the quality of the PGM concentrate and the implementation of solid-liquid separation with centrifuges. INTRODUCTIONThe Lonmin Base Metal Refinery (BMR) is about 100 km north-west of Johannesburg and treats converter matte from the Lonmin Smelter to produce nickel sulphate crystals, copper cathode and a concentrate containing the PGMs. The plant was commissioned in 1985 based on a Sherritt design to treat 12 tonnes converter matte per day. The original flow sheet consists of a milling circuit, an atmospheric leach and a pressure leach to produce a PGM concentrate which is despatched by helicopter to the Lonmin Platinum refinery in Brakpan, about 40 km east of Johannesburg. The liquor from the atmospheric leach is treated by crystallization to produce a nickel sulphate hexa-hydrate crystal. The leach liquor from the pressure leach is treated by a selenium removal step followed by electro-winning to produce copper cathode. The spent solution from the copper electro-winning is recycled to both the atmospheric and pressure leach steps to provide sulphuric acid for the leaching reactions.Modifications were made to the original circuit to increase the plant capacity, to improve the PGM recoveries and to improve the quality of the PGM concentrate. Capacity increases included all the unit operations, new mill, new first stage, additional autoclaves, additional nickel sulphate crystallizers, new copper electro-winning and new batch leach reactors for upgrading the PGM concentrate. The current circuit is described in this paper and not the detailed history of each plant change."

Jan 1, 2012

By G. A. Brown

"Mining executives are becoming increasingly involved with decisions of the ""What would happen if ... "" variety. Potential changes in government policy, such as tax incentives, E.G.M.A. allowances, etc. affect the economic future of present and proposed mining ventures.This paper will discuss various measures of effectiveness normally used in assessing this future, such as discounted cash flow, etc., and will describe means of introducing uncertainty into the computations. As the recognition of risk and attitudes toward accepting it are very important in the life of a mine executive, there will be a brief discussion of utility theory and its application to risk analysis.Risk models are usually of a size to warrant the use of an electronic computer. Therefore, to demonstrate the simple interaction necessary between a financial analyst and such a model, data will be read into a remote computer from a time-sharing terminal in the meeting room. It will be shown that changes may be rapidly made and alternative policies investigated ""on line"" to a computer."

Jan 1, 1970