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By Edwards A. B

The occurrence of gold so finely divided as to be invisible under the microscope, even at magnificatioIl; of 1,200 to 2,000 diameters, is rare, but not unknow;n.. Burg (1930) has described an occurrence of such "invisible gold" from the 25/37 vein of the Bradisor mine at Brad in the Siebengeburgen district of Rumania (Transylvania), in which the pyrite contained up to 150 grams of gold per ton (approx. 5 oz. gold per ton). Hoffman (1931) has described an epithermal silver gold ore from the Titiribi district of Columbia (South America), in which "invisible gold" to the extent of 150 grams per ton occurred in the pyrite, arsenopyrite and zincblende; and Haycock (1937) has recorded it in pyrite from the Surf Point mine (Canada), which contained no visible gold, but yielded positive testsfor gold whenever samples drilled from polished surfaces of apparently homogeneous pyrite were tested spectrographically.The examination of a cyanided pyritic concentrate, together with a sample of the ore from which it' was prepared, from the Dolphin East lode at Vatukoula, Fiji, carried out as part of the programme of the Mineragraphic Section of the Council for Scientific and Industrial Research, Australia, has established a further occurrence of "invisible gold" in pyrite and arsenopyrite. The Dolphin pyrite contains about 25 oz. gold per ton, and the arsenopyrite contains more than 33 oz. per ton.The concentrate has been prepared for the Mill Superintendent of the Emperor Gold Mining Co. by L. Mayger...

Jan 1, 1946

By S K. Michelic, N Preisser

For certain applications, steels have to feature a very distinct and well-defined level of cleanness in terms of the number and composition of non-metallic inclusions. Therefore, one crucial aspect of steelmaking is removing and controlling said non-metallic inclusions during the process. Particle removal during ladle refining comprises three stages, namely: 1. Flotation 2. Transport through the steel/slag interface 3. Dissolution of the particle in the slag. Only if all three stages are completed the particle can be considered as fully removed from the steel melt which, in turn, leads to the slag being one of the most influential parameters for inclusion removal and control. Depending on the composition of the particles and the slag, the dissolution can be controlled by different mechanisms. This study focuses on the diffusion-controlled dissolution of solid oxidic particles in slags. For this, a model of particle dissolution has been developed. For modelling diffusion, either the differential equation following Fick’s second law can be solved, or an analytical solution to this equation valid for stationary interfaces can be used. Both approaches allow for calculations of concentration profiles of the dissolving species in surrounding slag. From this, the mass flux can be derived, which finally leads to calculating the boundary layer velocity due to considerations of mass balance. In this work, both methods as well as results of dissolution experiments using High Temperature Confocal Scanning Laser Microscopy are compared. This research aims to provide a framework for diffusion-based dissolution modelling in further expanding the understanding of particle dissolution in secondary metallurgy.

Aug 21, 2024

Deep hydrothermal fluids adjacent to the Alpine Fault move through the brittle-ductile transition to mix with convecting fluids from near surface environments. These tectonically driven fluids evolve mainly from prograde metamorphism at mid crustal depth (ten kilometres) within the ductile regime which has been elevated due to advection and drag on the fault plane. Through the onset of brittle failure and cataclasis within Alpine Fault mylonites, fluid overpressuring results in hydrofracturing and localized implosion. Along the length of the Alpine Fault, hydrothermal alteration varies on most levels (Table 1). There is an observable increase in Fe-Mg carbonate between the Waitaha and Taramakau Rivers (between Ross and Aurthur's Pass, respectively). Field studies concentrate to the north east of the Arahura River, noted for historical mineral wealth. Late meteoric fluids move through cataclasite, brecciated mylonite, and other open fractures. Chloritisation is the major retrogressive phase. Dolomitic hydrofracture veins (Figure 1) within coherent mylonites contain iron and copper sulphides. Notably, the enrichment in Fe-Mg carbonate towards the Alpine-Hope Fault intersection seems to represent a region of enhanced permeability possibly related to shallow seismicity, increased regional faulting, footwall variation, strike-slip dip-slip distribution, and/or topographical anomalies (ie saddles). Isotope studies identifying an 'Inboard Fault Gouge Calcite Zone' correlate to values from the Main Divide region at the headwaters of the Arahura River (Browning Pass-Wilberforce Valley) (Becker et aI, 2000). These correlations are supported by rare arsenic anomalies (avg l06 ppm n = 5, Figure 2) found in both regions which suggest that fluids may be interconnected at depth.

Jan 1, 2001

By C J. Noack, P B. Ganza

The concept of large trucks underground has been around for some time. While the road train concept is gaining momentum, there are underground mining applications where these trucks have not been suitable. Unfortunately few of the ægreenfieldsÆ projects that are most suited to the road train concept have come æon lineÆ since the underground road train was first introduced to Australia in 2001 so that the trucks have generally been adapted to existing operations. As at December 2004, there were 17 road trains operating underground in Australia, one being rebuilt and one under construction. This paper addresses the necessity for the mining industry to have an integrated ore transport system that starts at the underground load haul dump unit (LHD) in the stope production area and finishes at the crusher feed at the processing plant. Chute and orepass designs are investigated, as well as feeders to determine the best load and haul system for large-scale trucking. The paper also discusses potential developments in the large truck scene. The paper highlights the cost and productivity gains by introducing large trucks and associated integrated ore transport systems underground. While 400 vertical metres was seen as the limit of vertical hauling in the 1970s, one kilometre is a common discussion point for trucking limits today. In real terms the cost of underground trucking (including ownership costs) has decreased from $1.50 - $2.00/t.km in the mid-1990s to $1.00 - $1.20/t.km at present.

Jan 1, 2005

This paper describes the oil engihe plant owned and operated by Gold Mines .of Kalgoorlie Limited, and gives some details of installation, operational, and maintenance experiences which have arisen during the years of service, the last 5 years of which have been under the writer's control. Nos. 1, 2, 3 and 4 alternator units have run 50,276, 48,006, 49,677 and 25,930 hours respectively, and much knowledge has been obtained of their performances and faults. During the war years, it has not been easy to obtain spare parts; this, coupled with the loss of No. 4: alternator unit to the Commonwealth Government, made operation and maintenance a very difficult problem.All engines are of the enclosed vertical, single acting, 4-stroke cycle, airless injection type.The electrical power plant originally consisted of four 6-cylinder Belliss & Morcom heavy oil engines, direct coupled to Bruce Peebles alternators, running at 375 r.p.m., and generating 3-phase electric power at 3,300 volts, 50 cycles.No. 1 unit, installed in 1936, is a 6-cylinder 450 b.h.p. standard 12A Belliss & Morcom heavy oil engine, direct coupled to 280 kw. 0.8 p.f. alternator. The remaining three units are 6-cylinder, 660 b.h.p., lSA oil cooled piston type Belliss & Morcom heavy oil engines, direct coupled to 410 kw. 0.8 p.f. alternators, making a total capacity of 1,510 kw.No. 4"alternator. unit, an 18A Bellis.& Morcom set, was taken over by the Commonwealth Government in June 1943.

Jan 1, 1945

Christmas Island "C"-grade phosphate consists essentially of the minerals crandallite and millisite. Although containing over 25% P205, this material is not suitable for the manufacture of water-soluble phosphate fertilizers by conventional processes, because of its high iron and aluminium content Cover 25% total R203). In order to produce a water-soluble fertilizer from such material it is necessary to separate the iron and aluminium from the phosphate, which must report in a product acceptable as a fertilizer. Several processes were studied in detail. The first used ion exchange for dissolution and separation and yielded diammonium phosphate; processing costs were high compared with conven- tional processes based on apatite. The latter processes have basically simple flowsheets and cost of processing is low when compared with the costs of the raw materials. The need to separate iron and aluminium from the phosphate introduces additional complexity into the treatment of the C-grade material. The higher processing costs might be justified, however, if alumina could be produced as a byproduct. Two proposed processes have been developed in which: 1. hydrochloric acid is used for dissolution, and solvent extrac- tion for the separation of ferric chloride from phosphoric acid. Aluminium chloride is precipitated and hydrolysed to recover alumina and hydrochloric acid. 2. sulphuric acid is used for dissolution and aluminium is crystallized as ammonium alum. The phosphate is produced as an ammonium phosphate-sulphate fertilizer. High purity alumina can be obtained by treatment of the recrystallized alum. The technology of these processes is described, and their broad economics discussed briefly.\

Jan 1, 1971

The Archean Gossan Hill Group at Golden Grove, Western Australia, hosts two potentially economic volcanogenic massive sulphide deposits. The volcanic-sedimentary succession hosting this mineralisation is composed of a facies association which includes the products of rhyodacitic to,andesitic effusive volcanism, mass-flow sedimentation and concentrated hydrothermal fluid discharge, in a deep subaqueous setting. The Tertiary Kuroko deposits of Japan are widely compared to Archean volcanogenic massive sulphide deposits and a comparison of the facies associations hosting this style of mineralisation, in these two successions separated widely in time, allows a refinement of facies models suitable for exploration in ancient successions. The required deep subaqueous environment for the formation of volcanogenic massive sulphide deposits places constraints on the physical processes that can operate during accumulation of the host stratigraphy. Limitations on the operation of physical processes is reflected by the resultant facies association which can be used to characterize suitable volcanic-sedimentary successions in which volcanogenic massive sulphide mineralisation may be present. The facies association includes: (1) proximal effusive volcanic products - lavas and associated autoclastic breccias (2) distal volcanic products - mass-flow resedimented pyroclastic debris (3) background sedimentation - reworked volcanogenic and terrigenous mass-flow sediments and (4) chemical sediments - exhalites including cherts, sulphides and oxides, with perhaps various carbonates and sulphates. Primary pyroclastic deposits are not expected to be present, other than distal water-lain air-fall deposits, derived from shallow to emergent basin margin explosive volcanic centres, which also provide a source for the resedimented pyroclastic debris.

Jan 1, 1987

By Y A. Stepanyants, J Crawford

A practical field method for determining the maximum value of the intrinsic oxidation rate, Smax , of sulfidic materials in waste rock dumps is proposed. Knowledge of the intrinsic oxidation rate of sulfidic materials distributed in a dump is necessary for predictive modelling of oxidation and pollutant generation over time. The suggested method uses the fact that drilling waste rock dumps to install probes for monitoring temperature and oxygen concentration causes large volumes of air to be injected into a dump by the drill rig. By measuring the rate of decrease of oxygen concentration along the length of a borehole immediately after installation, it is proposed that Smax can be calculated at different depths. The aims of this work were: to derive a simple, practical formula for the estimation of Smax from the oxygen concentrations measured over time, based on some simplifying assumptions; to use a two-dimensional numerical model that incorporates all the necessary physical processes to model the behaviour of an aerated dump over time for a reasonable range of dump and material parameters; and to compare the results of the two approaches to assess the validity of the simple formula as a method for estimating Smax. It has been found that the technique can provide reliable estimates of Smax when the value is of the order of 10-7 kg(O2) m-3 s-1 or greater. At the lower end of the range however the radius of the zone aerated during drilling becomes an important parameter and further work has been recommended to investigate this aspect of the method.

Jan 1, 2003

By C V. Putnis, T Geisler, A Putnis

In nature, ilmenite (FeTiO3) undergoes weathering through oxidation and removal of Fe to form an apparently continuous series of compositions from ilmenite to pseudorutile (ideally Fe2Ti3O9), and with further weathering, to leucoxene. To determine the mechanism of acid-leaching of ilmenite to ultimately form rutile, we have carried out an experimental study of ilmenite alteration in autoclaves at 150¦C in HCl solutions. Resulting products were studied by X-ray diffraction, scanning electron microscopy, electron microprobe and Raman spectroscopy. In some experiments the solution was initially enriched in 18O and the distribution of the isotope in the alteration products mapped from the peak shift in the Raman spectra. The results indicate that the alteration may proceed in two stages, each with a sharp interface between the parent phase and the product. The alteration begins at the original ilmenite crystal surface and along cracks through which the fluid can migrate. The first alteration product is pseudorutile û no phases intermediate between ilmenite and pseudorutile were detected. The textural relationship between ilmenite and pseudorutile suggests a coupled dissolution-reprecipitation mechanism rather than a solid state continuous oxidation and Fe diffusion mechanism. The second stage involves a further dissolution-reprecipitation step to form rutile. Raman spectroscopy shows that the 18O is incorporated in the rutile during the recrystallisation. Throughout the alteration process the original morphology of the ilmenite is preserved although the product is highly porous. The rutile inherits crystallographic information from the parent ilmenite, resulting in a triply-twinned rutile microstructure.

Jan 1, 2008

By C Tukel

Copper sulfate is traditionally used to activate various types of sulfide minerals. The list of users includes Falconbridge Sudbury operations, where copper sulfate solution is added to the pyrrhotite/pentlandite middlings at the scavenging stage. Results from some batch tests reported in the literature suggested that copper activation is helpful for the improvement of pentlandite recovery, especially in the difficult to float fine particle range. Any improvement in pentlandite recovery is important since it is the main nickel bearing sulfide mineral. The impact of copper sulfate for this function has been investigated. Since the focus of current investigation was the flotation behaviour of minerals at the scavenger stage, rougher flotation was kept as constant as possible at two different weight recoveries, namely 13.2 per cent and 15.5 per cent that is relevant to industrial practice. Samples taken during batch testing were extracted using DETA and flotation products from selected tests were analysed to determine the recovery by size behaviour in relation to the use of copper sulfate. Results provide significant evidence that the addition of copper sulfate to these middlings does not yield greater nickel recovery, either on an overall or specific particle size basis. It is concluded that copper sulfate is wasted in the process and that self activation behaviour of the ore at a slightly reduced pH is sufficiently significant to maintain the scavenger recovery of pyrrhotite and pentlandite at desirable levels. Results obtained from limited circuit trials have shown supporting evidence for this conclusion.

Jan 1, 2005

By Reilly SY, Green TH, O&apos

Alkali feldspar meggacrysts are commonly found (with aluminous clinopyroxene, kaersutitic amphibole, titanomagnetite, ilmenite and apatite, and more rarely with zircon and corundum) in alkalic basalts and their derivatives as discrete crystals and fragments. They are commonly euhedral or subhedral and may be up to 15 cm in size. Their occurrence has been reported from many localities around the world, e.g., Africa, Antarctica, eastern Australia, eastern China, East Fife (Scotland), Eifel (Germany), Massif Central (France), Mongolia, New Zealand, New Mexico (USA) and Siberia (USSR). These megacrysts are relatively homogeneous and belong to the Na-rich anorthoclase group, although Kutolin and Frolova (1970) called them sanidine due to their monoclinic nature. The majority of megacrysts have a molar orthoclase content (Or%) between 20 and 30 (Fig.1). These anorthoclase megacrysts possess a high degree of disorder, with the structural state belonging to the high albite-high sanidine series (Hoffer and Hoffer, 1973; Chapman, 1976).Published interpretations of the origin of anorthoclase megacrysts fall into the following two categories: either (1) Anorthoclase together with the associated pyroxene and amphibole crystallized from basaltic magmas as phenocrysts (cumulate phases) at high pressure and the present host basaltic rocks are the parent magmas for the anorthoclase megacrysts (Binns,l969; Binns et al. 1970; Kutolin and Frolova, 1970; Hoffer and Hoffer, 1973; Laughlin et al. 1974); or (2) Anorthoclase probably crystallized from a more evolved liquid at relatively lower pressure and was then picked up and carried to the surface by a later

Jan 1, 1990

By Bellairs P, Stewart JC

On 20 December 1983 at 8.40am blast- hole 57 of Blast RN177 prematurely detonated follwed by a violent deflagration of blast- hole 59 at 10.40am. The blastholes were 380mm diameter drilled in black pyritic Mt McRae shale. The blastholes were loaded with ANFO and primed. Blasthole 57 was stemmed and blasthole 59 was not. A poss- ible mechanism which could lead to such a detonation is described. preliminary tests showed the top 5m of a bench had the highest temperature which could not be influenced by a range of treat -ments. Small scale laboratory tests show- ed that zinc oxide (ZnO) and magnesium carbonate (Mg2CO3) inhibited the reaction. A series of tests using AN with and without inhibitors loaded into the collars of blast -holes drilled in the top 6m of the bench and unstemmed is described. An analysis of the time to reaction of the holes loaded with AN against temperature shows that the decomposition of the AN in contact with the black pyritic shale is probably a sulphuric acid catalysed react- ion. All the inhibitors tested can neut- ralise the sulphuric acid in the shale. 10% ZnO appears to be an effective inhibitor of the reaction providing the AN/ZnO (90/10) is kept out of contact with surface material whose temperature can be as high as 60¦C in summer. It is concluded that ANFO/ZnO (90/ 10) should be now tested in stemmed holes.

Jan 1, 1986

By D Wardiman, R Benton, D Sims, T Carr, V Singh

The Kencana underground gold mine comprises two world-class epithermal vein deposits located in the North Maluku province of Indonesia on Halmahera Island. The K1 deposit has a recent extensive mining history, whilst development of the K2 deposit is in progress. Kencana epithermal vein zones have a relatively simple planar geometry dipping 25 to 45¦ towards the East and extend 400 to 600 m along strike and down dip. True width ranges from 1 m to 20 m. Economic gold grades are generally associated with two distinct mineralisation styles: Main Zone û continuous material characterised by classic epithermal vein textures including crustiform/colloform chalky white quartz- adularia sulfide banded and brecciated veining typically grading 10 to 40 g/t Au. Bonanza Zone û semi-continuous identifiable zones within the Main Zone. Characterised by brecciated quartz-adularia sulfide banded vein æginguroÆ material typically grading 80 to 200 g/t Au. Associated with this æBonanzaÆ zone are gold grades averaging around ten times higher than the surrounding Main Zone. At the resource evaluation stage, these deposits are typically drilled on approximately 25 m by 25 m spacing. This drilling density is usually adequate to allow robust estimation of global resources, including the lateral definition of æBonanzaÆ style mineralisation. It appears intuitive at the resource definition stage to separately model the æBonanza ZoneÆ using deterministic methods such as manual interpretation and wireframing. Inevitably, however, such deterministic methods result in a simplified version of reality. Whilst the geologistÆs interpretation of the overall vein volume and lateral extent of æBonanzaÆ mineralisation has proven to be remarkably accurate, close-spaced sampling and mapping of the K1 orebody has shown that this style of mineralisation exhibits extreme short-scale geometric and spatial variability. A consequence of this short-scale geometric and grade variability is the significant uncertainty with reporting these Resources and Reserves at relatively small reporting time periods such as monthly production periods. The mining method employed at Kencana often involves extracting the full width of the mineralised vein with multiple mining passes over several months. In the past it has proven difficult to achieve accurate production budgets and forecasts at Kencana as any given mining schedule based on the resource model is acutely sensitive to the quantity and location of æBonanzaÆ material. Moreover, the degree of uncertainty or risk associated with a mining schedule significantly increases as the reporting time period becomes smaller. A further deficiency of deterministic methods for geometric modelling is the inherent lack of ability to derive confidence intervals for quantifying uncertainty and risk. The use of conditional simulation techniques can help overcome this deficiency. Geostatistical conditional simulation techniques have been applied at Kencana in an attempt to model and quantify geological and grade variability in the upcoming K2 orebody based on the experience to date with mining the K1 orebody. At Kencana, conditional simulation has provided a successful means to quantify uncertainties and risks associated with various data densities and reporting time periods. The results of this project have provided managers and planners with a clearer understanding of the likely variances and risks associated with predicting gold metal production at key reporting time periods based on data at the resource model level of resolution. With corporate requirements to adhere to mining budgets/quarterly schedules, this type of analysis allows a more scientific approach to estimating grade uncertainty in the mining schedule. Until now this has been difficult to quantify due to the extreme gold metal variability. The availability of this type of analysis allows a time-efficient rationalisation on redesigns of the mining shapes and effective communication of the likely uncertainties involved.

Jan 1, 2009

By Horiszt G

his report is going to point to that the effect of the mining dewatering on the area of Transdanubian Mountain Range has reached a phase when the cost of dewatering and providing damages can seriously jeopardize a profitable mining operation. Up to 60s the interest of mining had been dominant only, but since the begining of 80s the conceptions of industrial development and the value of enviroment protection have been changed. The natural karstwater balance of the TMR can be presented (Figure Land 2.) and the present situation of it points to that the descharge has exceeded the reacharge in 50 %. During the past 10 years the decreasing of the stored karstic water resourches was 1.1 km . The decreasing of the spring yields reached 80-82 % of the natural ones. (Figure 3-4.). Conservation of the present discharge may lead up to the totaly drain of the karstwater regime. A computer aid control system had been to develop by the bauxite mining and using of it the yield of dewatering decreased and a moderate rising of the water table has started since 1986. A recunstruction was made at the biggest thermal-medicinal lake its springs have had their source in 40 meter depth inside a spring cave at the bottom of the lake. Earlier the spring yield decreased due to the dewatering activity of mines. As a result of using of the CAC system and the providing works at the thermal sprino,the karstwater balance has got in the state of equilibrum, the first cost was decreased and spring yield was increased and the enviromental limits were adverted from the way of mining.

Jan 1, 1988

By d&apos, Alton AJ, Rigden DT

Modern petroleum refining offers a complexity of environments, each requiring different metals for the satisfactory performance of-the various sections of the refinery, and this paper first outlines the varied enva.x¦on-ments thus met.It follows that the metal types in use will also vary to suit each particular environment, and the paper' consequently covers the use of ferrous-metals, ranging from plan carbon steels to the high alloy types and the non-ferrous metals, particularly copper and its alloys.The failures of some,of these metals and alloys are then illustrated by experiences it Kwinana. These failures are duo to (a) corrosion, (b) erosion, (c) faulty welding, and (d) mechanical defects,' of which the first is by far the most prevalent. The protective measures taken to prevent subsequent failures are then given under one or other of the following headings :(1) alterations in process conditions, (2) the use of alternative ,alloys,(3) suitable heat treatment, (4) redesign of the failed section, (5) cathodic protection, and (6) use of corrosion inhibitors.Reference is then made to the use of specialised metals and alloys.Metals, generally in the form of oxides or salts, are also used as catalysts in refining processes. Activated alumina is used, combined with silica .forScracking' of heavy oils, and as a support -for platinum, cobalt, molybdenum, nickel and similar metals, which catalyse hydro-genation and dehydrogenation-processes. .In the final formulation of petroleum products metallic compounds may be added. Reference is made to the large quantities of lead used by the petroleum industry and to the use of metallic soaps and detergents in the formulation of lubricating oils and greases.

Jan 1, 1962

The Quioma Mine is located along the axis of the Cordillera Oriental, 130 km southeast of Cochabamba, South Central Bolivia. Silver, lead, zinc, antimony, and gold have been intermittently produced from veins in the Quioma area since Colonial times. Mineralization occurs within steeply dipping fissure veins transecting moderately folded Lower Ordovician sediments. Tectonic activity is early to mid-Tertiary and the vein system parallels the fold axis of a major northwest-southeast striking, doubly plunging anticline. Vein sets occur within a 2 km wide band over a strike distance of 13 km along the northeast limb of the anticline. Economic mineralization occupies syntectonic pre-mineral fault zones developed in more competent stratigraphis units of Lower Ordovician clastic sediments. Veins average 55 cm in width, although mineralized structures up to 3 m wide with a known strike length of several hundred meters have been mined. Mineralization consists of siderite, argentifferous galena, sphalerite, and quartz, with minor amounts of chalcopyrite, barite, and bournonite. Pyrite is rare except at the Boston vein where it occurs with stibnite that contains trace amounts of gold. A marked characteristic of veins in the district is evidence of repeated stages of movement during mineralization. Intrusive rocks are rare in the Quioma area. Narrow porphyritic dikes of Andesitic composition averaging 1 m in thickness have been observed. These dikes occasionally show a close spatial relationship to the veins and are often kaolinized and carbonitized. Vein and dike contacts are sharp and alteration does not appear to extend into the wall rock. Mineral zoning is suggested by antimony mineralization observed in peripheral areas of the anticline.

Jan 1, 1987

In south-eastern King Island, sediments and lavas of possible Upper Proterozoic to Lower Cambrian age have been intruded by Lower Carboniferous granitic rocks.Within the contact aureole of the Bold Head adamellite north of Grassy the sediments and lavas have been metamorphosed to hornblende hornfels facies grade. The thermal gradient within the contact aureole was small, as the hornfelses exhibit no mineral zoning over a distance of 700 ft from the adamellite.Skarns occur both within the adamellite near its contact with the country rocks, and within the country rocks as partial replacements of three dolomitic limestone horizons. The latter type, the exoskarns, commonly have an andradite-salite mineralogy and carry economic concentrations of scheelite. These resulted from the replacement of carbonate beds due to both diffusion and infiltration metasomatism. Silica, tungsten, minor sulphides, and water were introduced from the adamellite, while aluminium and iron diffused from the enclosing pelitic sediments. Calcium released during marble replacement countered the loss of iron and aluminium in the pelitic hornfelses transforming them to diopside-rich rocks.Endoskarns within the adamellite are the result of two way diffusion across the contact; calcium, aluminium, and iron diffused from sediment to adamellite as silica, potassium, sodium, and water diffused from adamellite to the sediments. From estimates of the lithostatic pressure and mole fraction of CO2, the mineral assemblages of the hornfelses imply that the temperature of metamorphism lay between 530° and 710°C. This temperature range is in good agreement with minimum temperatures, between 610° and 710°C, for the recrystallization of the marbles of the contact aureole, calculated from the determinations of the solid solution of the magnesite molecule in calcite.

Jan 1, 1971

Models of the genesis of existing ore oodles and targetting of exploration for new mines are greatly enhanced by an-understanding of the plate tectonic environment existing at the time of mineral emplacement. In areas of recent or active tectonism, a study of the present-day crustal and upper mantle structure is an obvious starting point in unravelling the evolution of the accessible upper crust. Bougainville is the northern-most island in the Solomon Islands arc. A 7km deep trench almost 100km off its western coast marks the commencement of subduction of the Solomon Sea plate beneath the Pacific plate. As outlined by the seismicity, the subducted crustal slab under the southern half of Bougainville reaches the axis of the island at about 100km depth, from which point it dips near vertically another 300km into the upper mantle. Large surface blasts at the Bougainville Copper Mine at Panguna, Bougainville, Papua New Guinea were used to derive an unreversed upper crustal profile of the island. The crust appears to be relatively simple, being comprised of a 5km deep layer with a P-wave velocity of 4.5km/sec, overlying a l0km thick layer with a P-wave velocity of 7.2km/sec. Constraints on the 15km mantle depth were provided by the identification of both P to and S to P phase conversions of seismic waves from local shallow earthquakes at the Moho boundary. An upper mantle velocity of 7.95(¦ 0.15) km/sec was measured from travel times of selected shallow earthquakes along the strike of the island arc.

Jan 1, 1987

By Iley J. D

The production of zinc from low grade concentrates, particularly those high in iron, has a poor economic return due to a combination of higher concentrate transport costs, increased processing costs and an increased cost for disposal of iron residues. The production of iron-bearing residues from the electrolytic zinc process is also seen as undesirable for both cost and environmental reasons. This paper details the pilot plant testwork conducted at the Pasminco Research Centre in conjunction with Minproc for the production of zinc oxide fume from a high-iron zinc sulphide concentrate from Colquiri in Bolivia. The concentrate is derived from a tailings retreatment operation and has a high iron content (40 - 45 per cent Zn, 14 - 17 per cent Fe) due to the presence of marmatite. Pilot plant trials were conducted using the slag bath reactor at Pasminco Research Centre at rates up to 500 kg/h of pelletised zinc concentrate, using a natural gas/oxygen-enriched air lance. The fume produced averaged 76 per cent Zn at recoveries up to 96 per cent and was recovered in a baghouse after gas cooling. The iron was oxidised into a fayalitic slag that passed the TCLP test (toxicity characteristic leaching procedure) and the sulphur was oxidised to produce a high SO2 gas which would be suitable for sulphuric acid production. The process produces a zinc oxide fume that can replace calcine as a feed for electrolytic zinc plants. The iron reports to a stable slag for disposal, thus eliminating the need for its disposal as jarosite from the leach plant. Only a simple leaching operation on the fume is required as there is no zinc ferrite present.

Jan 1, 1993

By Takagi T, Seetharam R, Sie SH, Naito K

Tin-polymetallic vein type deposits are one of the major source of metal producers in the Circum Pacific Belt. This type of deposit is of great importance for the modem electronics and medical industries because of their high content of rare metals (especially indium and bismuth). We have studied two representatives, Tosham of India (Cu-In-Bi-Sn-W-Ag-Au), and Mount Pleasant of Canada (Zn-Cu-In-Bi-Sn-W), using proton and electron microprobes in order to delineate the distribution of medical/high-tech rare metals. The electron microprobe study showed that major indium carrier in such type of deposit are roquesite (CulnSZ), sphalerite, stannite and a Cu-Zn-Fe-In-Sn-S mineral; and that indium is incorporated in sulfides by coupled substitution like Cu + In = 2(Zn + Fe). The proton microprobe showed that indium at trace levels is also present in chalcopyrite and pyrite. In addition, zinc, copper, arsenic, antimony, selenium, tin, and bismuth are common in chalcopyrite and pyrite. Arsenopyrite contains nickel, copper, zinc, silver, tin, antimony and bismuth. In chalcopyrite and pyrite, zinc, arsenic, indium, bismuth and lead are higher in Mount Pleasant ore, but silver is higher at Tosham. Also thallium and gold were found only in Tosham pyrite. The Tosham deposit is genetically related to S-type magma, while the Mount Pleasant deposit is related to A-type granite. Tosham ore contains zinc-bearing biotites that coexist with chalcopyrite in ore bodies but Mount Pleasant ore lacks such biotite. We propose that the difference in elemental abundance between the two deposits are caused by the different character of source magma and different mineral associations of the ore body.

Jan 1, 1995