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By Davey P. T, Tsambourakis G

Mineralogical analysis of supergene sulphide ore recovered from areas close to the underground workings at the abandoned Mutooroo (South Australia) mine shows that the original sulphide minerals have undergone substantial alteration. The cause of this alteration is believed to be contact with the highly saline, acidic mine water. The copper is now present as a sulphide that can best be described as a copper- and iron-delicient chalcopyrite, CuxFeyS2, where in most cases x < y. The values of x and y vary from point-to-point within each grain.Leach tests under a variety of conditions show that dissolution of the copper from the supergene sulphide ore can be readily achieved, particularly when compared with the behaviour of Mt Isa chalcopyrite concentrate. For the supergene sulphide ore, an increase in the acidity and the iron(lll) concentration of the leachant re ults in an increase in the rate of copper dissolution.The results are briefly discussed in terms of the experimental in-situ leaching operation at Mutooroo, South Australia.

Jan 1, 1986

Australia is the Western world's largest producer of alumina, supplying one third of total needs. Western Australia's South-West has the greatest concentration of alumina production in the world, with a current annual production rate in the region of 6.8 million tonnes per annum, over 20 per cent of the total supplied to market economies. The value of this production in 1989-90 was 2.34 billion dollars, a very significant contribution to the economy of the State (1). This is despite the fact that the bauxite from the Darling Range is the lowest grade that has ever been commercially exploited, and despite the geographical isolation of the region. It is therefore of great importance to the National and State economies that this industry retain its competitive edge, particularly in the current times of economic downturn. One essential ingredient of this competetiveness is technology and innovation, which can be assured by the committment of the industry to an active program of Research and Development, with support from the public sector as Appropriate.

Jan 1, 1991

By Bisshop J. P W

Maximum recovery of sulphide minerals by flotation is achieved over a limited size range. Valuable particles above and below this range have a smaller probability of being recovered. In the normal grinding-flotation operation, not all valuables are reduced to the optimum size range, and therefore sub- stantial losses occur. A significant improve- ment in the size distribution is not usually possible within the conventional circuit, and a more complex arrangement may be necessary to obtain optimum recovery of the valuable mineral. This problem is considered with refer- ence to the Mt. LyeZl concentrator. The performance of the existing circuit is dis- cussed, and it is shown that losses in recovery occur in both coarse and fine sizes. Laboratory tests indicate that regrinding the coarse particles results in an increase in recovery of up to 4%. Redistribution of plant grinding capacity to reduce initial grinding power by 6% and use this capacity to regrind coarse particles was considered. It is con- cluded that overall plant efficiency would be increased by 2% provided that overloading of the regrind mill could be avoided.

Jan 1, 1977

By West-Sells P, King J. A, Patel C

The Eskay Creek orebody is located in north-central British Columbia (Canada). The ore contains major gold and silver values and minor but economically significant quantities of zinc. The refractory nature of the gold necessitates a pressure oxidation pretreatment prior to cyanidation. After solid-liquid separation the oxidation solution can be treated by oxyhydrolysis for iron removal and cementation with zinc dust for noble element removal. The resulting solution, as obtained in pilot studies, contains 7 - 10 g/L Zn, 0.5 g/L Ca and 2 - 4 g/L Mg. Minor amounts of cadmium, copper and iron may also be present in the solution. Over 90 per cent recovery of zinc from Eskay Creek oxidation solutions could be obtained by four stages of zinc extraction with Cyanex 302 extractant (Cyanamid Canada Inc, Niagara Falls, Canada). Zinc was stripped from the organic with spent zinc electrolyte in two stages. A complete description of the bench scale and miniplant studies of the solvent-extraction electrowinning circuit follows. The behaviour of minor amounts of copper, cadmium and iron in the circuit is also Discussed.

Jan 1, 1993

By Hoffmann CF, White NC, Tedder IJ, Wood DG

Since the discovery of Pajingo in 1984, the northern Drummond Basin has emerged as a significant new gold province, and has become the focus of intense exploration for epithermal gold mineralisation. Prospects in the Conway area are hosted by felsic to intermediate lavas and volcaniclastic rocks near the base of the Drummond Basin sequence. These Drummond Basin rocks appear to represent favourable hosts to mineralisation because they are cut by structures which could have focussed and channelled fluids on a regional scale, and because they constitute a possible source of gold and, perhaps more significantly, sulphur for the transport of gold. Prospects in the Conway area are up to 15 km2 in area, and are of the adularia-sericite type. They illustrate many of the classic features (siliceous sinters, alteration mineralogy, and fluid characteristics) recognised in epithermal deposits. K-Ar dating of sericite alteration in three of the prospects has produced a range of ages from 283 to 334 Ma, suggesting that the systems are the product of multiple hydrothermal events.

Jan 1, 1990

By S M. C Verryn

The amount of raw material used in the production of cement can be reduced by partially supplementing it by pozzolanic waste material without changing its properties negatively. This paper discusses results of an investigation using slag from the Pt industry, from the production of steel using Midrex processes as well as fly ashes from different coal power plants in South Africa. These are blended in a 20 per cent slag or fly ash to 80 per cent cement ratio. The properties of the mixtures depend on the phase composition, chemistry, grain size and the sources of the materials. The results are promising, but show variable behaviour depending on slag and cement composition. Compressive strength tests as well have heat flow curves showing the hydration behaviour, indicating that 20 per cent addition of slag or fly ash to ordinary Portland cement is viable. There is a large potential to use slag in cement mixtures and this study can be used to develop cements that will positively influence CO2 emissions and help to reduce large slag and fly ash stockpiles.

Jan 1, 2008

By Mason D. O, Tuckwell K. D

Whole rock geodhemical analyses from samples of Potosi gneiss within the Willyama Supergroup have been utilised to identify geochemical trends towards Pb/Zn ore positions. Although the analyses come from disparate sources they have been incorporated in the data base only if locational, sampling, analytical, lithological and stratigraphic descriptors were reliable. These data have been statistically analysed using programmes of the GASP software package. A discriminant function has been derived which permits Potosi gneiss associated with the Pb/Zn lode horizons in the Broken Hill domain to be distinguished from Potosi gneiss in a similar stratigraphic position in the Maybell Domain. In the "near ore" position the Potosi gneiss has significantly lower mean Na2O and significantly higher mean MnO. Also mean Rb, CaO and K20 are higher and mean Sr lower. This discriminant function serves to identify areas prospective for Pb/Zn mineralisation. A second discriminant function based on MnO, Si02 and K20/Na20 gives a semi- quantitative indication of proximity to ore.

Jan 1, 1983

The highland region of Papua-New Guinea is relatively rugged terrain where stream gradients are steep. In areas where porphyry copper deposits outcrop the streams commonly expose primary sulphide mineralization in unoxidized rocks. Stream sediment geochemistry combined with float examination and broad geological mapping proved to be an effective tool for detection of outcropping bodies of mineralization. After discovery, detailed stream sediment sampling, soil sampling and rock chip sampling, together with detailed geological mapping proved adequate to delineate drilling targets. Reconnaissance stream sediment sample density was dictated by geology and access and a density of one sample per 25 Km2, or less, was desirable to ensure a high degree of confidence in the programme. Research indicated that the base metals occur in sulphide form in stream sediment and that the -80 mesh size fraction gave the most reliable results. The evaluation of results from any one area relied on the interpretation of the local geology. Basic histogram methods for determining background and threshold values for metals in stream sediments were

Jan 1, 1973

By Kapoor M. L

Emf measurements on SE galvanic cell: SS; Ni-NiO I solid electrolyte/ZrO2 + CaO I [Pb + Bi]liq alloy; (PbO); SS were made in the temperature range 913-1034 K to determine the thermodynamic properties of oxygen dissolution in liquid lead. Bismuth alloys with bismuth in the dilute concentration range of 0 to 3.08 mass per cent and oxygen in the alloy varied by equilibrating the metallic system with a suitable (PbO) slag. Wagner's interaction parameter approach was used to calculate the ternary interaction parameter, eBiO at temperatures of 913, 953 and 993 and 1034 K and to observe the temperature dependence eBiO = 19 200/T - 17.454. Quasichemical fonnulation was employed to yield lnf BiO and reveal the effect of bismuth on oxygen in lead. The results obtained are discussed on the basis of theoretical models and the value of Wagner's energy parameter 'h' estimated to predict the results in a Pb-Bi-O system.

Jan 1, 1995

By Henley R, Harris L

High resolution airborne magnetic and radiometric data have been shown to optimize exploration for epithermal gold deposits in the vicinity of Charters Towers, northeastern Queensland. The radiometric data allow extrapolation of poorly outcropping geology to provide a cost-effective mapping technique, even at exploration scales (eg. 1:25,000). At a regional scale (eg. 1:100,000) the magnetic data reflect the regional tectonics and divide the area into domains for the application of different genetic models. For example: 1. the Ravenswood Batholith is characterized by multiple intrusions dating from Ordovician to Permian age. The polarity of the magnetic anomalies implies an age for the intrusions and indicates a deposit style for exploration. 2. extensional and wrench tectonics along the northern margin of the Drummond Basin are interpreted from the magnetic data and indicate favourable blocks for detailed exploration. Genetic exploration models may be tested in favourable environments by the recognition of geophysical signatures. These signatures reflect structural, lithological and alteration patterns arising from controls on ore deposits and can be applied at regional or detailed scales.

Jan 1, 1989

High pressure (-1.2 GPa) Early Cretaceous granulite facies orthogneisses in Fiordland, New Zealand are in tectonic contact with a cover sequence comprising mid-Palaeozoic amphibolite facies metasediments, subordinate metavolcanic rocks and syntectonic granitic orthogneisses. This cover sequence and the underlying granulites constitute upper and lower crustal plates of a mid-Cretaceous metamorphic core complex whose emplacement was linked to continental rifting and the Late Mesozoic breakup of the Pacific margin of Gondwana. Exhumation of the lower plate granulites occurred in two stages. The first stage was associated with extreme attenuationand tectonic denudation of the cover sequence accompanying emplacement of the core complex, leading to rapid uplift of the granulites but without generating the large volumes of Fiordland-derived sedimentary detritus normally expected if uplift and erosion were the only factors involved in unroofing the granulites. Final uplift and exposure of the granulites at the surface occurred mainly during the last 10 Ma in response to transpression across the mid-Tertiary Alpine Fault and/or the obduction of Fiordland continental crust over oceanic crust of the Tasman Sea.

Jan 1, 1990

Western Mining Corporation (W.M.C.) operates a nickel refinery at Kwinana, 30 km south of Perth. The refinery commenced pro- duction in May 1970, with a rated capacity of 15 000 tpa of nickel metal. A hydrometallurgical route was chosen as the most expedient way to produce nickel metal at a time when world demand for nickel was outstripping the supply. Later events dictated that an increase in production from the refinery be achieved. To this end, matte produced from Kalgoorlie Nickel Smelter, which was commissioned in 1972, was used in varying proportions as a complement to the concentrate initially utilised as input to the refinery. The effect of matte addition was to increase the capacity to 30 000 tonnes of nickel per annum. This was accompanied by other benefits which were 1. reduction in energy consumption per unit of nickel produced, 2. improved metal extraction, 3. improved precious metal recovery, 4. reduced production of ammonium sulphate by-product. Refinery operating results for the years 1970 to 1983 show how matte feed has improved refinery performance in these areas.

Jan 1, 1984

By Avraamides J, Ritchie I. M

Gold Tellurides are important sources of gold at Kalgoorlie, Western Australia, Cripple Creek, Colorado and Vatukoula, Fiji. Unlike free gold, the tellurides of gold are rather refractory and the usual treatment practice has been to oxidize the tellurides, either chemically or by roasting prior to cyanidation of the liberated free gold. There is a large measure of disagree- ment as to the actual cause of the refractory nature of gold tellurides. In order to investigate the leaching chemistry of gold telluride, a study was undertaken on the thermodynamics and kinetics of its dissolution using electrochemical methods. From this study suitable direct leaching condi- tions are suggested. In acidic chloride solutions gold telluride can be leached using iron(III) as the oxidant. At lower acid concentrations the reaction is controlled by the formation of a passivating film of H2TeO3. In alkaline solutions containing cyanide the rate of gold telluride dissolution increases with increasing pH and strength of oxidant. However, this can result in excessive consumption of cyanide in the presence of stronger oxidants.

Jan 1, 1991

By Voermans F. M, Hoyle M. W H

The Archean geological sequence in the West Pilbara region (Fig 1), a deformed greenstone volcano-sedimentary succession regionally intruded by layered mafic/ultramafic lopoliths, batholithic granites, granite stocks and transected by swarms of dolerite dykes, has prompted several companies to search for a variety of base metals and and platinoids (Fig 2). In the first instance, detailed aeromagnetic surveying was completed, producing patterns of marked magnetic anomalism which proved substantially successful in the demarcation of areas warranting geological reconnaissance and detailed follow-up. Revelant to this paper were the obvious magnetic features overlying outcropping and buried mafic/ultramafic bodies which ultimately were proven to be host to Ni-Cu sulphides, pgm, Ti, V, Cr and, more recently, Ag and Au mineralisation. Routine stream sediment, soil sampling and ground geophysical techniques of the day appear, in most cases, to have been adequate in the detection of mineralisation, except in the case of Radio Hill massive sulphides where the Turam E.M. (1972) signal essentially failed to detect the blind conductor (Peters, de Angelis 1987).

Jan 1, 1988

The longwall system with caving is the most common mining system in Polish Collieries and the extraction is carried out simultaneously on several levels and in different seams. The extent and diversity of the methane hazard occurring is strictly connected to the specific geological and gas conditions as well as to the applied mining methods. Taking these factors into consideration the following methane drainage methods are applied as additional means of combatting the methane hazard in Polish gassy coal mines: 1. predrainage by means of boreholes drilled from the surface, 2. predrainage from stone drivages and devel- opment workings, 3. degasification of coal extraction workings, and 4. degasification of sealed-off areas/old goaves. Predrainage gave satisfactory results when holes were drilled from the surface or from underground workings, but only to depths to 300 m. It was necessary to adapt methane drain- age methods to the geological and mining con- ditions as gassiness increased with depth. The results of methane capture, both pre- drainage and post drainage were obtained by investigating several gassy mines.

Jan 1, 1982

By Canning RG, Uusna S, Goodheart BA

The paper outlines the development of"a process for removal of iron oxides from ilmenite, thereby upgrading the TiO2 content of Western Australian ilmenites, from 55 to approximately 90 per cent. In the first stage, the iron oxides are reduced with solid carbon (coal) to metallic iron. Experimental reduc- tions were carried out in crucibles,, a fluidised bed and a small pilot plant rotary kiln. The reduced'ilmenite is,then agitated in aerated water, in the presence of catalysts, so that the iron "rusts" away from the ilmenite'grains and the precipitated iron oxide is easily separable by decantation. The influence of variables on the rates. of reduction and oxidation are discussed, The oxidation rate was exam- ined for both - the' physical oxygen-transfer characteristics and electrochemically by reference to Peurbaix diagrams, which plot redox potential against solution 'PH, The upgraded ilmenite is expected to be an attractive material. for pigment -manufacture,, and the iron oxide has prospects of being a marketable by-product. The process may possibly be. applied, to .other..ores.

Jan 1, 1964

By Koginmo V. I

The concentrator at Bougainville Copper Limited has an annual throughput of 48.2 million tonnes/year producing approximately 175,000 tonnes copper, 16.1 tonnes gold, and 50 tonnes silver. Conventional three stage crushing and screening are used to reduce run of mine ore to an average product d80 size of 6.7mm. The primary objective of the crush- ing plant is to provide a continuous supply of ore to the 12 primary grind- ing mills via an intermediate 300,000 tonnes capacity stockpile. Since ball mill performance improves with decreasing mill feed size, the crushing plant continually strives to produce the finest possible product for mill- ing. This has been achieved by increasing plant availability and total installed power, and improving crusher manganese liner life, screen cloth life, and plant operating practices. A recent innovation was the installa- tion of a 35 million tonnes/year preconcentration screening plant in Janu- ary 1987 to recover high grade fines from low grade run of mine ore types in which the mineralisation occurs preferentially along fracture planes in the parent rock.

Jan 1, 1988

By Liu H, Chen S

Natroalunite is one of colouring minerals in kaolin. In this investigation, natroalunite, on which Ca(II) was adsorbed, was flocculated by HPAM and kaolin was depressed in suspension. The adsorption of Ca(II) on the natroalunite surface was studied by zeta-potential measurement and Auger Electron Spectroscopy analysis. Ca(II) was adsorbed more on the natroalunite surface than on the kaolin surface. The mechanism of Ca(II) adsorption was considered to be chemical adsorption on natroalunite and to be physical adsorption on kaolin. It has been found that Na6P6O18 and Na2Si04 can strongly affect Ca(II) adsorption on the surface of kaolin, but weakly on the surface of natroalunite. The effects of degree of hydrolysis and the molecular weight of HPAM, the effect of pH and the effect of Ca(II) have been studied. The kaolin ore, containing SO3 1.05 per cent has been processed with this method. The products only containing S03 0.36 per cent and the weight ratio of concentrate 52.27 per cent were Obtained.

Jan 1, 1993

By Borgelt B. V, Perry A. J, Wellington H. K

There has been little change in the lead smelting practice at Mount Isa since 1939 when the metallurgy and general practice were outline by Raney and Blott.The purpose of this paper is to descriqe some of the operational details that have influenced the overall production. The slag fall hns been increased by the lowering of the lead content of the concentrate. Further, as it is the practice to include iron on the furnace charge and carry a higher lime content in the slag, both factors have produced notable results in furnace operations.All blast furnace gases are filtered in a baghouse and this unit is. being further extended to take all smelter gases, thus eliminating the existing Cottrell plant handling Dwight-Lloyd gases.The lead smelter was closed down from April 1943, to May 1946, during which time blister copper was produced.The report is subdivided as follows:-1. Filtering and Mixinga. Effect of calcium sulphate on cloth.b. Dwight-Lloyd charge composition.c. Main mixer.d. Return sintel sizing.2. Blast Furnace Operationsa. Introduction.b. Use of orehearth.

Jan 1, 1953

Gravity concentration of tin at Renison Limited uses tables and spirals to treat the various coarser fractions produced from sulphide flotation tailing. An acceptable final tailing cannot be made from one pass over the tables and spirals and therefore the tailing from these separators is reground and combined with the sulphide flotation tailing as the feed to the classification section. The gravity section became increasingly overloaded in the years preceding 1976 due to efforts to maximize tin recovery to the gravity concentrate. In April, 1976, two 2DSV Reichert cone concentrators in series were installed to treat the table and spiral tail- ing stream, prior to regrind, to scavenge a small tonnage of hard, coarse low tin grade material for rejection to final tailing. Gravity section loadings were decreased markedly, allowing operator attention to be directed more to table performance than to spillage collection. An increase in mill throughput of approximately 15% was possible following the commissioning of the Reichert cones. The cones are currently operated to make the minimum tonnage of tailing consistent with reasonable- gravity section loadings.

Jan 1, 1978