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By N. J. Tannyan

Laboratory bath smelting tests were conducted to determine the feasibility of smelting nickel- copper concentrate directly to a low iron matte in one step. Concentrate, air/oxygen and a silica flux were fed to a matte-slag bath kept in MgO crucibles at I 300°C. Various oxygen enrichments and smelting rates were used to maintain 0.5 to 2 wt% iron in the product matte. The slag losses are comparable to those obtained under similar industrial conditions. Due to the highly oxidizing conditions required to produce mattes with low iron contents, it is not recommended to target iron contents below about 2% in the matte. The specific bath smelting rates were equal to or higher than those in various industrial bath smelting processes.

Jan 1, 2003

By G. A. Brooks

Increasing interfacial area through gas injection is one of the main methods for accelerating reaction between slag, metals, and gases in modern pyrometallurgical reactors. In slag-metal reactors, the generation of a large number of metal droplets into the slag phase through high gas velocity has a much larger effect on the overall kinetics compared to the enhanced mass transfer through mixing. Top blowing technology generates large interfacial areas (>300 m2/tonne) through high impingement gas velocity at short distances between the exit of the injection lance and the metal-slag interface. Phase separation may become a limit at the case of very high interfacial areas, though there is still only limited understanding of the trajectories of metal droplets in slag-metal-gas emulsions.

Jan 1, 2003

By N. J. Tannyan

Laboratory bath smelting tests were conducted to determine the feasibility of smelting nickel- copper concentrate directly to a low iron matte in one step. Concentrate, air/oxygen and a silica flux were fed to a matte-slag bath kept in MgO crucibles at 1300°C. Various oxygen enrichments and smelting rates were used to maintain 0.5 to 2 wt"10 iron in the product matte. The slag losses are comparable to those obtained under similar industrial conditions. Due to the highly oxidizing conditions required to produce mattes with low iron contents, it is not recommended to target iron contents below about 2% in the matte. The specific bath smelting rates were equal to or higher than those in various industrial bath smelting processes.

Jan 1, 2003

By W. Riekehof

The paper explains required practice and equipment for capturing airborne fumes and particulates in hot-dip zinc galvanizing plants. An economic and technical comparison of enclosure and tank rim suction options is presented. The paper also compares the performance of various filter media in filtering fumes, to determine the effect of changes in flux as well as changes in filter finishlcoating methods. This includes a recommendation for how to achieve the best result with respect to pressure loss and cleaning behavior of the filter.

Jan 1, 1992

By J. G. Reid

Nickel is second only to aluminium, of all non-ferrous metals, in energy required to convert the ore to metal. Nickel Laterite ores, which constitute the feed source for approximately 40% of world nickel production, are at a particular disadvantage because of the absence of sulphur, as an energy source, in the ore and because lateritic ores general 1 y are not amenable to beneficiation. The dramatic escalation of oil prices which commenced in 1973 and continued for a decade meant that Nickel Laterite refineries using oil as a primary energy source were placed at a distinct disadvantage relative to refineries utilizing nickel sulphide concentrate feeds. By the late 1970's the continuing large difference in oil and coal prices caused Greenvale to consider converting certain high oil consuming areas of the refinery to coal. These investigations confirmed that the areas of ore drying and power generation, which together consumed 50% of total Plant oil requirements, could be economically converted from oil to coal firing. Construction of the coal conversion facilities commenced in October 1980 and the first ore drying air heater came on line in August 1981. Construction was completed with the commissioning of the coal fired boiler in June 1982. This paper outlines the additions required to receive and utilize coal in ore drying and power generation and how the changeover was completed with minimal process disruption.

Jan 1, 1988

By Donald R. Sadoway

The viability of treating certain forms of hazardous waste by direct electrolysis in molten oxides is under investigation. Secondary residue or waste mud produced in the course of chromate chemical production is the focus of attention in this study. The goal is to reduce the water soluble hexavalent chromium either to insoluble trivalent chromium or to chromium metal. Electrolysis tests have been conducted in a high temperature cell containing chromate sludge dissolved in an electrolyte composed of Al2O3, SiO2, CaO, and MgO. Oxygen production on a carbon-free anode has been confirmed.

Jan 1, 1992

By Ramasamy Santhanam

"India’s present annual marine fish catch is 2.9 million tonnes and its low value fishes such as sardines, sciaenids, goat fishes and leiognathids amount to 60%. The fish meal obtained from these resources is mainly used presently as an ingredient in live stock and aquaculture feeds. These fishes offer vast scope in the production of pet foods. Pet foods prepared with leiognathid fish meal (60%), maize flour (10%), wheat flour (5%), vitamin and mineral mixture (5%) and water (20%) and experimented with 50 cats and 50 dogs were found to be ideal. Depending on protein level, feeds are being formulated for experimenting with more number of pet animals. Training programmes are also planned for unemployed people to popularize pet foods for commercial purposes.IntroductionIndia’s present annual marine fish catch is 2.9 million tonnes and low-value fishes sucha s sardines (Sardinella albella, s. gibbosa, S. fimbriata and S. melanura); sciaenids (Otolithus spp. and Jhonius dussumieri); engraulids (Stolephorus indicus); and leiognathids Leiognathus bindus, L. equilus and Gazza achlamys) constitute 60% (Figure 1)[1]. The fish meal obtained from these resources is now mainly used as an ingredient in livestock, poultry and aquaculture feeds. Considering the rich nutritional status of these low-value fishes, it is felt that these resources could be converted into value-added products viz. pet foods."

Jan 1, 2008

By Gordon A. Irons, Diancai Guo

"Uneven movement of scrap during melting in an Electric Arc Furnace causes operation problems: cave-ins interrupt electric power input. The movement also influences the radiation heat loss to water-cooled side panels and roof. An apparatus has been built to simulate the flow of scrap that may be interlocked. It has been observed that flow starts at the point where the suspended length of the pile bottom reaches the average scrap size, and proceeds in the form of cave-ins, but scrap pieces slide with each other as ordinary granules. After a cave-in, the pile angle usually remains much larger than the normally observed angle of repose. The force balance of a partially suspended scrap pile has been analyzed, and the equivalent cohesion due to interlocking estimated. A numerical model has been developed to simulate the scrap flow. Simulated results agree reasonably with observed phenomena.IntroductionWhen one considers the melting of steel scrap in an electric arc furnace (EAF), it is helpful to understand the movement of the material during meltdown. As industrial experience demonstrates, scrap movement greatly affects EAF operation. In a typical operation, scrap is dropped into the furnace from scrap buckets. The roof and electrodes are swung into position, and power is applied to the electrodes situated over the scrap. The electrodes ""bore"" into the scrap by melting into the steel in the immediate vicinity of the electrodes as they are lowered. If solid scrap pieces gradually slide towards the arc area, the electric power supply can be maintained at a high level, with few interruptions or drastic electrode adjustments. This results in a high production rate and low power consumption per tonne of steel produced. On the other hand, if the charge moves down unevenly, i.e. in large surges, usually called cave-ins, the electrodes must be drastically raised, and power supply frequently interrupted. This is also accompanied by a high level of harmonics induced in the power network, deteriorating the quality of electricity supplied to other users.In addition, the movement of scrap in an EAF also influences the furnace heat efficiency, as the scrap pile is much closer to the electric arcs compared to the furnace wall and roof, and absorbs more radiated heat. Early exposure of the wall and roof to the arcs will increase the heat loss due to radiation, and reduce the service life of the furnace."

Jan 1, 2004

By Gerhard Meyer

A new instrument for the determination of iron., zinc, calcium, and other metals independently directly in the fumes emitted from steelmaking processes is described. Based on the well- accepted method of X-ray fluorescence, the instrument can detect numerous metals simultaneously in the fume as well as report their concentration on a mass per unit time basis real time to a control room computer. The instrument mounts on the wall of the fume duct and can., via a small opening, directly view the hot exhaust plum inside the duct. The concentration of metal in the fume over time has been shown to change dramatically depending on process variables. Variables such as oxygen flow rate, lance height and nozzle configuration., slag condition., and episodic scrap addition can affect the presence of metal particles and fume in the exhaust. An analysis response time of 6 seconds enables better control of the steelmaking process thereby conserving primary resources and reducing environmental impact.

Jan 1, 2001

By Steven Wright

The extent and the rate of reduction of slags produced from the smelting of recycled lead batteries were investigated under laboratory conditions using graphite as reductant. Simultaneous reduction of PbO, Fe2O3, Sb2O3 and As2O3 occurred at temperatures of 1180 and 1200°C, with Sb and As reporting to the metal phase while the PbO content of the slag was above 2 wt%. Fuming of As from the metal occurred at lower concentrations of lead in the slag. Discard slags with low levels of As, Pb and Sb were produced. Arsenic levels were reduced to less than accurately measurable by ICP analysis, and Sb levels in the final slags were in the range of 0.1 to 0.2 wt%. The kinetic data obtained were analysed and compared with other measurements on lead oxide containing slags. The results showing a dependence of the reduction rate on the oxidation state and the basicity are consistent with other studies on well characterised industrial and. synthetic lead slags. These results indicate that when carbonaceous reductants are used, the rate of interfacial reactions play an important role in enabling the production of environmentally acceptable discard slags.

Jan 1, 1994

By Patrick R. Taylor

A novel method for Chemical Vapor Infiltration (CVI) using plasma technology is proposed, Plasma Enhanced CVI (PE-CVI). Due to the low rates at which CVI is currently performed, the use of plasma as a source of heat may be considered to be a faster and less expensive production method. Precursors fed in the hot region of the plasma gas are completely vaporized and forced by the same flow through a porous preform where it condenses as a new material. In this research, silica and methane where used as precursors to form SiC/on a / graphite felt (preform). To enhance the infiltration process, vacuum was used to increase the flow through the preform. Characterization of infiltrated graphite was perfontied using Scanning Electron Microscopy (SEM) and X-Ray Diffraction (XRD). A uniform distribution of Sic was observed along the felt with only twenty minutes of infiltration process, yielding a 178% increment in weight.

Jan 1, 1997

By Gary A. Wickham

In the zinc industry, this past decade has seen both prosperity and depression. Significant changes have occurred throughout the world in mining, smelting, refining, and marketing. This paper will review many of the industrywide changes of recent years and the potential impact for 1990s. In addition to an historical review of supply and demand are discussion of technology considerations for zinc and zinc based products, effects of geographical shifting of markets, and projections for the 1990s.

Jan 1, 1990

By R. Togashi, T. Aichi, T. Yamada

"A new automatic material- handling system for cathode transportation has been developed. The first system went into service in August 1994 and the remains will be operational subsequently.Because of the complex cell-layout and the number of cells in each row, the critical part of this work was achieving a planned cycle time. This cycle time is determined by the power costs.The central monitoring system for machine operation was started in June 1996, using original application software based on MICROSOFT EXCEL ® on WINDOWS 95® .As a result, only one person is now required to operate both a crane and a stripping machine for one row of about 50 cells.INTRODUCTIONMainly due to the strong yen and the relatively low price of metal, the zinc refineries in Japan are being forced to reduce production costs again and again.The trend of lijima's production costs is shown in Figure 1.[1] The ratio of labor costs becomes gradually higher. Therefore it is effective to reduce the labor costs in order to reduce the production costs. In Japan, electricity cost during day time is too high to produce zinc at a reasonable cost, that is why the actual production is far from the capacity of production at a cell house. That means a plant in Japan has the disadvantage of relatively low productivity for cell house operation.Saving labor costsSome automatic cranes have been applied to save labor costs for cell house operation in the world. In consideration of the mentioned low productivity, the installation of an Automatic Cathode Transfer (ACn system for transportation of cathodes was planned without changing the present cell house and stripping machines to lower the investment costs. The ACT system must keep up with the stripping machine which is able to strip deposit zinc from a cathode sheet at the rate of 6 seconds.The fifth ACT system of seven was installed in August 1996 and the last one will be operational subsequently."

Jan 1, 1997

By Peter A. Spencer

The metallurgical parameters necessary for the design of a carmercial scale bio-oxidation plant have been determined for the treatment of a refractory arsenopyrite concentrate using a moderately thermophilic bacterial culture. The parameters considered were bio-oxidation rate, culture growth rate, nutrients, solids density, level of bio-oxidation, particle size distribution and oxygen uptake rate. The approach for obtaining the optimum values for these parameters is discussed and values based on results fran batch and continuous testing are given. Estimates of the capital and operating costs for a plant treating the carmercial arsenopyrite concentrate have been calculated fran the test data.

Jan 1, 1990

By Toshihiro Tanaka

The information on viscosity and surface tension of molten slag is indispensable to design new refining procedures in ferrous and non-ferrous processes. For example, the authors have tried to develop "Capillary Refining" to remove impurities in liquid metals by applying capillary absorption of molten slag with those impurities into solid fluxes which have a lot of small capillary tubes. It is necessary to adjust the above physico-chemical properties to adequate conditions on the capillary penetration. In the present paper, we discuss our recent trial to predict surface tension and viscosity of molten slag in multi-component systems. We have derived a thermodynamic model to predict the surface tension of molten slag by using ionic size, molar volume and surface tension of pure components. In addition, we have applied neural network computation to evaluate the viscosity of molten slag. We found good agreement of the calculated results with experimental values of the surface tension as well as the viscosity in various slag systems.

Jan 1, 2006

By W. Persson

The first installation at a copper smelter of a Semtech OPC System for continuous, on-line production control of copper converting in PS converters took place in 1994. At present OPC systems are installed at 19 PS converters. The technology presents to the operator real-time information on the progress of the process he is controlling in the form of optical process parameters, thus facilitating dynamic process control. The optical process parameters are based on time- and wavelength resolved registrations of the light emitted by the off-gas flames and identification of correlation between these parameters and characteristic metallurgical process data. The present paper provides a description of the technology as seen by the furnace operators and a summary of operating experiences made during five years of full-scale, operation at various smelters, reviews influences from the technology on smelter operational practises and comments on recent developments as regards new applications of the technology.

Jan 1, 1999

By C. L. Lin

Multiphase, irregularly-shaped randomly-oriented PARGEN particles were grown to determine the breakage/liberation characteristics of such locked particles. The simulated locked particles were randomly broken to establish the liberation characteristics of the broken fragments. The progeny size distributions are consistent with Gilvarry's volume and surface flaw model for single particle breakage. The extent of liberation of both continuous and dispersed phases can be described from the conservation of interfacial area. In this regard the data can be normalized and liberation described for a wide range of dispersed phase grades and dispersion densities.

Jan 1, 1988

By Zhang Yongzhu

The metallogeneticy and mineralogy of three types of Chinese refractory gold deposits (Au-As; Au-As-MeS; Au-As-C) which are somewhat different from those abroad are discussed. The modes of occurrence, the distribution of grain size, and the morphological features of gold in minerals and their influences on gold recovery by direct cyanidation are also discussed. According to the mineralogy of gold and minerals, bacterial leaching, pressure leaching and roasting technology are suitable for the pretreatment of arsenopyrite-Au, pyrite-Au and carbonaceous-clay-Au refractory gold ores prior to cyanidation, respectively. The most important sulfide pyrite bearing much gold is difficult to be oxidized, its crystalline structure, conduct-types , and minor elements in different mineralizing stages are also discussed. The pyrite aggregates in different deposits are very complicated and much different. Gold grade of arsenopyrite is much higher than that of pyrite for some deposits which have a high correlation coefficient of Au vs As.

Jan 1, 1992

By J. M. D. Wilson

An analytical program using a combination of SEM-based image analysis techniques is developed for automated modal analysis of ores containing silicate and other gangue minerals. Previous knowledge, gathered by means of either optical microscopy, X-ray diffraction, SEM, or electron microprobe analysis is used to establish discrimination criteria in the image analysis program. The program initially discriminates minerals on the basis of their relative grey values in a backscattered electron image. For those minerals which have overlapping grey levels the minerals are identified by the program using energy dispersive X-ray spectrometry with X-ray counting for twelve or more elements. This technique is useful to quantify ores in which the gangue minerals are numerous. Two cases of application are presented.

Jan 1, 1999

By David Seymour

Newmont Gold Company (NGC) located in Northeastern Nevada has been processing carbonaceous and sulfide refractory gold ores through a chlorination circuit prior to cyanidation. A "Flash Chlorination" pilot plant was installed in 1987 in an effort to obtain higher chlorine utilization efficiency and increase gold extraction. The Flash Chlorination process oxidizes organic carbon and sulfide sulfur. It also deactivates preg-robbing carbon, making the ore amenable to cyanidation. Significant recovery improvements were observed using this new process. This scheme has also been instrumental in the processing of higher than normal grade ores at economic chlorine levels. The Flash Chlorination pilot plant has been successfully treating carbonaceous ore on a production scale since April 1988. This paper summarizes laboratory and pilot plant optimization test work, using conventional and statistical methods.

Jan 1, 1989