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By Hirokazu Narita

Keywords: solvent extraction, precious metals, thiodiglycolamide, rapid separation, hydrochloric acid The solvent extraction of some precious metals (Pd(II), Pt(IV), Rh(III) and Au(III)) and base metals (Fe(III), Cu(II) and Zn(II)) in a hydrochloric acid solution was carried out using N,N'-dimethyl-N,N'-dioctyl-thiodiglycolamide (MOTDA) dissolved in the mixed solution of 80 vol-% dodecane and 20 vol-% 2-ethylhexanol. The extraction percentages of Pd(II) and Au(III) in the 0.01 M MOTDA-1.0 M HCl solution system are 99.6% and 71.8%, respectively. In contrast, the other metal ions are hardly extracted under the studied conditions. The Au(III) and Pd(II) extracted in the organic phase are easily back-extracted with a 1.0 M thiourea/1.0 M HCl solution. A comparison with the conventional extractant for the Pd(II) separation, di-n-hexyl sulfide (DHS), revealed that the extraction rate of Pd(II) with MOTDA is much greater than that with DHS. The extraction percentage reached over 99% in less than a 2 min contact time. However, in the DHS-Pd(II) system, it takes about 240 min to achieve the extraction equilibrium. Furthermore, MOTDA can quantitatively extract Pd(II) up to half the molar amount of MOTDA. Therefore, MOTDA is a promising extractant for Pd(II) from the HCl solution after the removal of Au(III).

Jan 1, 2005

By Emmanuel N. Zevgolis Ismene-Polyxeni Kostika

Keywords: reduction, kinetics, laterites, rotary kiln, dust In this work, the reduction kinetics of dust from nickeliferous Greek laterites is investigated. The dust is a by-product from laterite treatment in rotary kilns and it comes from washing towers, electrostatic filters and polycyclones. Laboratory made pellets from this dust were also examined. Reducibility was studied in the temperature range of 700°C to 850°C in a laboratory tube furnace. Kinetic analysis of the results showed that at lower temperature values the mixed kinetic model verifies the experimental results of dust and pellet samples. At higher temperatures (800° and 850°C) diffusion becomes the rate controlling mechanism. The calculated activation energy values verify also the above mentioned results.

Jan 1, 2005

By Elli Nurminen

Keywords: Thermal conductivity of sulphates, flash smelting, heat recovery boiler, flue dust Accretions and build-ups in metallurgical heat recovery boilers decrease the efficiency of the heat transfer and may cause process shut downs. Transient plane source method (Hot Disk) has been applied to measure the thermal conductivities of the Copper Flash Smelting flue dusts. Thermal conductivities of copper, iron and zinc sulphates, and process flue dusts were measured. The results indicate that all the components are effective thermal insulators, having a thermal conductivity of less than 1 W/mK. Decreasing dust layer porosity has an increasing effect on thermal conductivity. Insulating layers on the boiler walls decrease greatly the heat transfer efficiency of the boiler. The gathered information will be used in CFD-modelling of the process, and in the process control.

Jan 1, 2005

By Alexander Burns

Electrolytic salt splitting is a technology where acid and/or base is regenerated from a neutral salt using membrane electrolysis. Recent advances in the understanding of brine treatment, membrane stability, and cell design have made electrolytic salt splitting feasible on certain hydrometallurgical solutions. Meanwhile, environmental regulations have made the bulk disposal of salt solutions more difficult. In this paper, sodium sulfate salt splitting is examined from a cost perspective, compared to purchasing the reagents directly. Relative costs are estimated for several regions based on published electricity and reagent prices. The results show that salt splitting is economically favourable in some regions, and can be made more favourable by applying modifications to the traditional three-compartment desig

By Wen-Ming Chien

Keywords: AN-KN Phase Transition, Lattice Parameters of AN-KN, X-ray Diffraction The lattice parameters of the low and high temperature phase of KNO3-rich (in NH4NO3) solid solutions have been determined by the X-ray diffraction method. The low temperature single KNO3 phase (KN II) are from 92%-100% KNO3 in NH4NO3 composition range and from room temperature to 393 K showing in X-ray diffraction patterns. The high temperature KNO3 phase (KN I) showed very broad composition range between 20% to 100% KNO3. The lattice parameters of KNO3-rich (KN II and KN I) solid solutions have been calculated at different temperature range. The volumes of orthorhombic KN II phase decrease from 0.3208(3) to 0.3195(3) nm³ at the room temperature as the compositions increase from 95% to 100% KNO3. The lattice constants of the hexagonal KN I phase show that there is no significant change in a-direction when the temperature increases. Details X-ray results and lattice expansion equations during heating will be presented.

Jan 1, 2005

By Pinai Mungsantisuk

Keywords: Pd-Ni alloys, Pd-Fe alloys, Pd-Co alloys, Magnetostriction, Magnetic Properties The presence of congruent melting minima, the occurrence of ferromagnetic transition over a large composition range, and FCC type crystal structure make Pd-Ni, Pd-Co, and Pd-Fe based systems attractive candidates in our search for materials with no rare-earths, large low-field magnetostriction, and good mechanical properties. The presence of paramagnetic-ferromagnetic transition over a broad range of composition also provides opportunity for fundamental studies. In this work, we have examined the magnetic and magnetostrictive behavior of Pd-Ni, Pd-Co, and Pd-Fe alloys over the entire composition range. Alloy sample rods were prepared by arc melting and casting. X-ray diffractometer was used to obtain lattice parameter data. Magnetostriction was measured along the rod axis using strain gages. Magnetic properties were measured using a vibrating sample magnetometer.

Jan 1, 2005

By E. Oshima

In May 1991, a New Mitsubishi Continuous Copper Smelter Line started operation at Naoshima. Recently, it has been continuing steady operation and one and a half year campaign life has been achieved. In 1996, new records of on line time, the amount of copper concentrate treated and copper anode production were achieved. 1t proves the superiority of the process with respect to pollution control, energy efficiency, flexibility and easiness of the operation and over all economy including off gas handling cost. Furthermore, .plans are underway to prolong the campaign life for two years and to improve the process efficiency. This paper describes recent operation, improvements, and a future capability study.

Jan 1, 1998

By Mark C. L. Patterson

Hydrothermal brines are extracted from significant depths below the surface of the earth and arrive at the surface at elevated pressure and temperature. The exact chemistry and conditions of these brines depends upon the rock formations through which the water travels, but many of the brines are rich in dissolved minerals especially silica which is often saturated in the brine. At pressure and temperature the minerals remain in solution but in order to extract heat from the brines, they need to be cooled and during which many of the minerals precipitate causing problems. Where precipitation is a problem in the downstream processing, the brines are maintained at a high enough temperature and pressure so as to avoid precipitation and injected back into the geothermal formation. This results in a significant loss in potential energy that could be recovered from the geothermal brines. If left to precipitate in an uncontrolled manner, many of the minerals will precipitate as gels, in a high surface area form which is difficult to extract from the liquor and which can causes problems. Precipitation in this manner often builds up on the inside of pipes, reducing the pipe cross-section available for fluid flow and reducing the overall efficiency of the plant. If the brines are seeded at the appropriate time or the precipitation conditions are changed, mineral particles can be grown and separated more easily from the brine. During this precipitation and growth phase the chemistry of the local environment can also be altered to grow more valuable particulates. Some of the specific chemistries will be discussed with reference to known geothermal brines and what needs to be done to precipitate value added products. A theoretical approach to the complete extraction of minerals from geothermal brines is also discussed with the goal of extracting more heat from the brine prior to reinjection into the well.

Jan 1, 2006

By Egil Aukrust

"An American Iron and Steel Institute Task Force evaluated developing direct steelmaking technology worldwide to seek a replacement for the coke-oven, blast-furnace, basic-oxygen process technology now in use. To remain internationally competitive it is essential to move away from the traditional series of batch processes towards continuous processing and the associated energy savings which are possible with high technology process control systems. The group identified in-bath smelting of iron ore pellets or fines with coal as the process most sui table for domestic raw materials (including abundant scrap) and called for research to study operation with varying degrees of preheat and prereduction of the ore by the gases generated from the coal and various degrees of combustion of these gases above the melt.A coordinated, 3-year, $27 million, direct steelmaking research program is proposed. Concurrent projects include design, construction, and experimental operation of an in-bath smelting pilot plant; modeling, simulations, and laboratory-scale experiments at universities on slag-phase and metallicphase reactions and interactions; and large-scale heat transfer and reaction rate trials. Also included are modeling studies and pilot plant trials of on-stream decarbonization and desulfurization; application of circulating fluid bed technology to fine ore reduction and hot gas cleanup; and specific heat transfer and fluid flow research projects.IntroductionThe American Iron and Steel Institute (AISI), based on the Task Force studying direct steelmaking, believes strongly that a coordinated program of research on the reduction of domestic raw materials to liquid steel should be undertaken as part of the Steel Initiative program. To specify the steelmaking process for development best suited to the American steel industry and domestic raw materials, it was important to determine the state-of-the-art of direct steelmaking worldwide, both as practiced and under development, and then, by expert analysis of the processes and their potentials, to choose the process most likely to provide a domestic competitive edge."

Jan 1, 1988

By J. C. Huyhua

The effect or various oxidants on gold and silver dissolution in thiourea solutions (0.05 M in H2SO4) was studied using the rotating disc technique, a.t 2s c and 600 rpm. These studies were carried out at constant (4:1) initial molar ratio or thiourea to oxidant concentrations, to produce 50 % thiourea. oxidation. The initial dissolution rate of gold was approximately four times higher in the presence. of ferric sulfate (5.37 x 10-3mg cm-2 s-1) than in the presence of hydrogen peroxide (H2O2), potassium persultate (K2S2O3), or monopersulfa.te (KHS06). The dissolution rates for silver were considerably lower than gold for the same oxidants. Oxidation of thiourea in the presence of peroxygen and persulta.te compounds is a. fast reaction and it is completed in less than ten minutes. On the other hand, the oxidation or thiourea with? ferric.sulfate is slow, yielding a second-order reaction rate constant k = 6.09 I mol-1 h-1. Sulfur formation in the ferric thiourea system begins when ferric ion reduction approaches to completion. With hydrogen peroxide, sulfur is observed at lower thiourea concentration than ferric. Suifate. The presence of a large excess or free thiourea i.e., s to 20 % thiourea oxidation) retards sulfur formation and maintains favorable dissolution rates. Finally, carbon-in-leach experiments indicate that thiourea solutions a.re stable for several days, with ferric sulfate or hydrogen peroxide. The dissolution rates of gold and silver doubles in the presence or activated carbon when hydrogen peroxide is used as oxidant.

Jan 1, 1989

By Xuemei Zheng, Aiyuan Ma, Chao Liu, Guojiang Li, Chenyu Sun, Jinhui Peng, Libo Zhang, Yongguang Luo

In this paper, the removal of fluorides and chlorides from blast furnace dusts by water vapor enhanced microwave roasting was investigated, combined with the advantages of microwave selective heating and based on a thermodynamic analysis of zinc and lead halides. According to proposed reactions in the process, detailed experiments were systematically conducted to study the effect of roasting temperature, holding time, air flow, water vapor flow rates, and stirring speed on the efficiency of the removal of F and Cl. The results show that 97.26% of F and 64.23% of Cl could be separated when the condition of the roasting temperature of 650°C, stirring speed of 80 rpm, holding time at 60 min, air flow of 350 L/h and water vapor flow rate of 8 mL/min was optimized.

Jan 1, 2016

By Etsuro Shibata

The saturated solubility of chromium oxide and the valence of chromium in the slag are important matters when considering how to effectively utilize chromium-containing slags. The experimental data of various types of slags cited in the literature were arranged according to the optical basicity in order to evaluate the effects of the oxygen potential and the slag composition. The saturated solubility of chromium oxide and the Cr2+/ Cr3+ ratio tend to decrease with the increase of the optical basicity of the slag at an oxygen potential below 10.5 atm. However, at an oxygen potential of 0.21 atm, the saturated solubility and the Cr6+/Cr3+ ratio tend to increase with an increase of the optical basicity. A practical approach was suggested to reduce chromium in the stainless steel slag and simultaneously recover it as a ferroalloy by the direct smelting reduction of chromium oxide in the molten slag using some reductant in a small furnace.

Jan 1, 2003

By Toshiyuki Kawai

Copper concentrate smelting directly in P-S converters was started at Onahama Smelter in 1983. Thereafter, the tonnage of concentrate smelted through the P-S converters increased, such that by 2002, it equaled the tonnage smelted through the reverberatory furnaces. In 2003, 56% of the total copper concentrates treated at Onahama Smelter were processed directly through the P-S converters. Technical improvements are reviewed and advantages of direct smelting in P-S converters are reported.

Jan 1, 2005

By C. Díaz

Roast-reduction smelting (RRS) of nickel concentrate, combined with flash smelting of copper concentrate, was one of the process options that Inco considered as a means of meeting its 1994 sulfur dioxide abatement target at its Copper Cliff operations. RRS involves deep roasting the nickel concentrate in fluid bed roasters. The roaster off-gas is heated in a sulfuric acid plant, and the low sulfur calcine is reduction smelted with coke in an electric furnace to yield a sulfur-deficient matte. The latter material is converted to Bessemer matte in Peirce-Smith converters, with minimal evolution of sulfur dioxide, and the converter slag is reverted to the electric furnace. Excellent nickel and cobalt recoveries are obtained. This paper discusses the development of RRS, including extensive commercial scale testing at Inco's Thompson Smelter, and its key operating parameters.

Jan 1, 1993

By H. Y. Sohn

The considerable progress made in the sulfide smelting technology since the first International Sulfide Symposium of 1983 is discussed. The new developments and innovations have largely been driven by the recognition of environmental concern as well as the need for increased productivity. The smelting technologies for various nonferrous metals are reviewed, with an emphasis on the industry trend towards larger plants and continuous processes. The tremendous advances made in process modeling and computer simulation to describe the complex smelting processes are also reviewed. The goal of these mathematical models is the quantitative description of the processes and the reactors that will provide a means for the control and optimization of smelting operations as well as the optimal design of the operating conditions and the reactors. Environmental issues remain a key consideration in the smelting industry. One of the most remarkable improvements made in the last fifteen years since the 1983 Sulfide Smelting Symposium is the rapid increase in the sulfur capture by nonferrous smelters. This and other related issues are briefly discussed. Finally, the challenges that the smelting industry faces as the new millenium approaches are discussed. The industry continues to face technical challenges to improve productivity and efficiency, while being responsive to ever-increasing public pressure for environmental protection. It also faces external challenges from factors that may cause the reduction of metal uses as a result of substitutions by other materials. Another serious challenge and dire consequence that the primary metals industry is expected to face is the serious diminution of university-educated manpower as well as basic-research output. To remain competitive and healthy, the industry should take up the void left by the complete disappearance, at least in the U.S., and the reduction in other nations, of the governmental support of higher education and basic research in the field of primary metals production.

Jan 1, 1998

By Kim Fagerlund

Boliden Harjavalta Oy operates a copper smelter in Finland, which is based on flash smelting together with Peirce-Smith converting of copper matte. This paper reviews a case study when a high arsenic feed mixture was successfully eliminated in order to guarantee the anode quality. Based on theoretical and practical knowledge in slag chemistry at Outokumpu Research, the CaO-fluxing practice was introduced. Description of a thermodynamic simulation using MTDATA and implementation of the results into converting practice is given. Results showed that the impurity fluctuations in raw materials could be effectively controlled by efficient utilization of different slag chemistry.

Jan 1, 2005

By D. H. Magoon

The zinc smelter of Cominco Ltd. at Trail, B.C. Is the largest In the western world. A total of 550.000 tonnes of concentrate are proceed at the smelter annually. Approximately 80% of the zinc concentrate is roasted and the remainder Is treated by aqueous oxidation preaaure leaching. The zinc concentrate roasting and sulphur dioxide gas processing plants have undergone many changes over the years. This paper describes the processes and equipment currently used for concentrate roasting, S02 gas cooling and cleaning, mercury removal, sulphuric acid production liquid S02 production, and tall gas S02 scrubbing. The recent Installation of an advanced process control system for the operation of these Integrated processes Is also described.

Jan 1, 1990

By Ji-He Wei

Keywords: stainless steel, AOD refining, side and top combined blowing, mixing characteristics, water modeling The fluid mixing characteristics in the bath during the side and top combined blowing AOD (argon-oxygen decarburization) refining process of stainless steel have preliminarily been investigated on a water model unit of a 120 t AOD converter. The geometric similarity ratio between the model and its prototype (including the side tuyeres and the top lances) was 1:4. On the basis of the theoretical calculations for the parameters of the gas streams in the side tuyeres and the top lances, the gas blowing rates used for the model have more reasonably been determined. The influence of the tuyere number and position arrangement, and the gas flow rates for side and top blowing on the characteristics has been examined. The results demonstrated that the liquid in the bath underwent vigorous circulatory motion during gas blowing, without obvious dead zone in the bath, resulting in a well mixing effectiveness. The gas flow rate of the main tuyere had a governing role on the characteristics, a suitable increase in the gas flow rate of the subtuyere could improve mixing efficiency, and the gas jet from top lance could make the mixing time prolong. Corresponding to the oxygen top blowing rate specified by the technology, a roughly equivalent and good mixing effectiveness could be reached by using six side tuyeres with an angle of 27 degrees between each tuyere, and five side tuyeres with an angular separation of 22.5 or 27 degrees between each tuyere. The relationships of the mixing time with the gas blowing rates of main-tuyeres and sub-tuyeres and top lance, the angle between each tuyere, and the tuyere number have been obtained.

Jan 1, 2005

By Ryan Walton

The Flash Converting Furnace at Kennecott Utah Copper converted over 465kmt of high-grade matte in 2002 but was restricted due to low matte production to 395kmt in 2003. This paper presents updated operational performance data and describes improvements implemented since the mid 2001 rebuild. Matte burner feed distribution, silica and arsenic impacts on settler lime-based slag operability, blister laundering, uptake/boiler accretion control, and dust sulfation will be discussed, as well as current development requirements dictated by operational imperatives and furnace modification plans.

Jan 1, 2005

By J. R. Donald

For processing copper, continuous converting has been successfully employed in a variety of locations, but for nickel, there has yet to be a successful commercial implementation of continuous converting technology. At Inco?s Copper Cliff smelter, there are specific requirements for the production of Bessemer matte relating to downstream processing that makes continuous converting for nickel mattes even more challenging. The nickel carbonyl refineries require very low iron levels in the matte, and the sulphur deficiency must be carefully controlled such that the appropriate quantity of PGM-rich metallics are produced from matte separation. The present paper outlines continuous converter technologies that have been implemented in copper, and evaluates their potential for nickel converting. The challenges of producing a Bessemer matte to the required specifications are discussed. The economic and environmental driving forces, and the challenges of justifying a novel technology in place of productive existing equipment, are discussed.

Jan 1, 2005