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By Frank Robertson Van Horn

In June, 1911, the writer spent a few days in studying the economic geology of the vicinity of Park City. During this rather hurried visit a number of specimens of ore were collected, which have since been examind. The results of these investigations show that bournonite (PbCu-SbSa) is present in the ores in greater or less quantity. This fact has never before been reported, as far as can be learned. The failure to recognize this mineral is due to its similarity to tetrahedrite, with which it has probably been confused during a long period of years. Jamesonite (Pb2sb2s6) has been reported from the region in a rather doubtful manner, but the writer has seen it in notable amounts from several mines, and can offer the first analysis of this mineral from the district. Calamine (HzZn2SiO5) was found at one mine and has never been ecognized and reported from the district. Geogbaphy and Geology Park City, Utah, is located at an elevation of about 7,000 ft. above sea level on the eastern slope of the Wasatch mountains. It is situated approximately 25 miles southeast of Salt Lake City. ' The geology and ore deposits have been described in detail by Bout well and Woolsey.' The mines visited are situated south-southeast from the town. The Silver King Coalition mine is located in Woodside gulch about 1 mile southeast of Park City, at an altitude of about 8,100 ft. The other mines visited were the Daly West and Quincy, which are in Empire canyon about 2 miles sontheast of the town, at elevations of 8,300 to 8,500 ft. respectively. The Daly Judge tunnel goes into the mountain from Empire canyon about 1 mile south of the city, at an altitude of 7,700ft.

Jan 1, 1915

By G. Sachs, G. Espey

Simple methods can be used for the determination of the residual stresses in thin walled tubing if the stresses consist of high tensile stresses at the one surface and high compressive stresses at the other surface. Such a stress distribution is approximated in sunk tubing and in deep-drawn shells. It is possible to cut sections from such articles in such a manner that a major part of the residual stress is relieved by a bending of the Part that is separated from the adjacent metal. The circumferential stress is evaluated from the change in diameter D, occurring on splitting a length of tubing (Fig. Ib) or from deflection resulting from the cutting out of a circumferential tongue (Fig. Ia) .6 The bending moment M released by such a flexure is. M - EI (I-I) = EI R1-R0 I - u2(R0-R1) I -V2 R0XR1 where E = modulus of elasticity, v = Poisson's ratio, I = moment of inertia of the section, R0 =. mean radius before splitting, R1 = mean radius after splitting. The release of this bending moment corresponds to the release of stresses, which, in a thin section, vary linearly from one surface to the other, and have the following value in a particular fiber a certain distance (x) from the surface: S = c d I - V2 x c x d 2 2 RI - R0____E (d ) R1 - R0 X R0 X R1 ~ i - u2 (2 x) Ro X R1 where C is the section modulus and d is the thickness of the section, the ratio M:C being d: 2 for a rectallgular section.* The maximum stress values at the surfaces are. Smax = +E X d X R1-R0 I — u2- 2 R0 X R1 For most purposes the simpler equations: EXd AD1 = ± I - u2 x dm2 and will be satisfactory, where D,, is the aver. age of the mean diameters of the tubing

Jan 1, 1942

By G. Sachs, G. Espey

Simple methods can be used for the determination of the residual stresses in thin walled tubing if the stresses consist of high tensile stresses at the one surface and high compressive stresses at the other surface. Such a stress distribution is approximated in sunk tubing and in deep-drawn shells. It is possible to cut sections from such articles in such a manner that a major part of the residual stress is relieved by a bending of the Part that is separated from the adjacent metal. The circumferential stress is evaluated from the change in diameter D, occurring on splitting a length of tubing (Fig. Ib) or from deflection resulting from the cutting out of a circumferential tongue (Fig. Ia) .6 The bending moment M released by such a flexure is. M - EI (I-I) = EI R1-R0 I - u2(R0-R1) I -V2 R0XR1 where E = modulus of elasticity, v = Poisson's ratio, I = moment of inertia of the section, R0 =. mean radius before splitting, R1 = mean radius after splitting. The release of this bending moment corresponds to the release of stresses, which, in a thin section, vary linearly from one surface to the other, and have the following value in a particular fiber a certain distance (x) from the surface: S = c d I - V2 x c x d 2 2 RI - R0____E (d ) R1 - R0 X R0 X R1 ~ i - u2 (2 x) Ro X R1 where C is the section modulus and d is the thickness of the section, the ratio M:C being d: 2 for a rectallgular section.* The maximum stress values at the surfaces are. Smax = +E X d X R1-R0 I — u2- 2 R0 X R1 For most purposes the simpler equations: EXd AD1 = ± I - u2 x dm2 and will be satisfactory, where D,, is the aver. age of the mean diameters of the tubing

Jan 1, 1942

By B. A. Cheadle, C. E. Ells

The ovienlalion of hexagonal a-zirconium crystals in cold-drawn Zircaloy-2 tubes and in both as-extruded and heat-treated Zr-2.5 wt pcl ND tubes has been rrleasured using the inverse Pole - figure technique. Uniaxial tensile tests hare shown the Zil-caloy-2 lubes to hare highly anisotropic delovmation behavior whereas heat-treated Zr-2.5 wt pet Nb tubes are nearly isotropic. The differences in deformation behavior are esbloilred from the observed textures of the tubes and the deformation systems known to oberate in Zircnloy,-3. Tlze vcsults lead to an explanation of the high effective strain observed fov the Zircaloy-2 tubes as colrzpared to heat-treated Zr-2.5 wt pet Nb tubes in restrained end burst tests at 280° to 300°C. THE Zr-2.5 wt pct Nb alloy. when heat-treated by quenching from temperatures slightly below the (a + p)/P phase boundary and subsequently aged at 500°C, has tensile strengths about 50 pct greater than those of 20 pct cold-worked Zircaloy-2.1 There is. therefore, considerable economic incentive to replace Zircaloy-2 with the heat-treated alloy in some in-reactor applications. notably for pressure tubes, where strength is a prime consideration. However, when tubes of Zr-2.5 wt pct Nb fabricated by extrusion and drawing prior to heat treatment were subjected to restrained end-burst tests at 300 °C. the circumferential expansion at failure1 was only 10 pct that of cold-drawn Zircaloy-2 tubes in similar tests,2 Table I. This result was not predicted from uniaxial tensile tests in which the ductilities of the two materials were quite similar.' The detailed requirement for ductility in pressure vessels has not yet been worked out. and comparison of the relative merits of cold-worked Zircaloy-2 and heat-treated Zr-2.5 wt pct Nb is further complicated by the irradiation-induced loss of ductility and hydrogen pickup each will undergo from reactor operation.1,2 Nevertheless. the lower circumferential expansion of the Zr-2.5 wt pct Nb tubes raised serious doubts on the advisability of their use as pressure vessels. For this reason, an investigation to determine the cause for different ductilities of the two types of tubes was initiated. From a study of uniaxial tensile properties and crystallographic orientation it has been found that the fracture ductilities observed in the burst tests can be related directly to the crystallographic ori-

Jan 1, 1965

By R. E. Salvoti

IN underground coal mining, the increasing trend towards mechanical methods is ever apparent. Figures for 1939 showed that 28 per cent of the total bituminous coal production was mined mechanically 1940 statistic will reveal an even higher figure. Factors causing this trend are varied, but the important are the following;

Jan 1, 1941

ARTICLE I: NAME AND OBJECTS Section 1: This Division shall be known as the Iron and Steel Division of the American Institute of Mining and Metallurgical Engineers. Section 2: The objects shall be to furnish a medium of cooperation between those interested in the metal-lurgy and industry of iron and steel manufacture and use; to represent the A. I. M. E. in so far as ferrous metallurgy is concerned, within the rights given by A. I. M. E. By-law XVII, Section 3, and not incon-sistent with the Constitution and By-Laws of the A. I. M. E.; to hold meetings for social intercourse and the discussion of ferrous metallurgy; to stimulate the writing, presentation and discussion of papers of high quality on ferrous metallurgy; to reject or accept such apers for publication and distribution by-the A. I. M. E. within the limits of the funds available for such purpose. ARTICLE II: MEMBERS Section 1: Any Member, Associate, or Junior Asso-ciate of the A. I. M. E. in good standing may become a Member, Associate or Junior Associate of this Divi-sion upon registering in writing a desire so to do. Section 2: But no one who has been continuously indebted to the. A. I. M. E. or to this Division for more than three months shall be entitled to vote or to receive publications to which, as a member of the Division, he would be entitled.

Jan 7, 1928

The following is an incomplete list of members and guests who called at Institute headquarters during the period Apr. 10, 1919, to May 10, 1919. Arthur K. Adams, Spencer, Mass. Ensign Floyd D. James, U. S. S. Fulton. W. T. Bates, New York City, N. Y. J. Harry Johns, Thorsden, Woking, A. D. Brokaw, Washington, D. C. England. E. H. Clausen, San Francisco, Calif. W. F. Jones, Rock Springs, Wyo. W. M. Corse, Mansfield, Ohio. E. L. Lasier, Washington, D. C. E. O. Daue, Philadelphia, Pa. John M. Lovejoy, New Rochelle, N. Y. G. D. Dub, Washington,, D. C. 2d Lieut. James F. Magee, Lancaster, S. B. Eaton, Dover, N. J. Pa., Sherman Eaton, Smethport, N. C. Ernest Marquardt, Casper, Wyo. J. A. Endweiss, La Jolla, Calif. Geo. B. Marshall, Abangarez, Costa Edgar W. Engle, North Chicago, Ill. Rica. 2d Lieut. Maxwell E. Erdofy, New York Benj. L. Miller, So. Bethlehem, Pa. City, N. Y. Major Desaix B. Myers, Camp Mills. Chas. A. Fellencer, Allentown, Pa. Edmund Newton, New York City, N. Y. Arthur Feust, Joplin, Mo. Seely B. Patterson, Jr., Allentown, Pa. Ensign Harold P. Ford, U. S. S. Radnor. Wm. R. Pearson, New York City, N. Y. A. D. R. Galloway, Accra, West Africa. Harold C. Price, Langeloth, Pa. R. C. Gosrow, Milwaukee, Wis. T. C. Roberts, East. Orange, N. J. C. A. Grabill, El Paso, Tex. P. H. Royster, Washington, D. C. Hobart A. Hanks, San Francisco, Calif. W. H. Staver, New York City, N. Y. John L. Henning, Lake Charles, La. N. L. Wimmler, Bangkok, Siam. 1st Lieut. J. Parke Hook, Philadelphia, Capt. Jay P. Wood, New York City, Pa. N. Y. An item in the May Bulletin made it appear that Frank W. DeWolf had just become connected with the State Geological Survey of Illinois. This was one of the inadvertences of war. Mr. De Wolf has been Director, or Chief, of the State Geological Survey for approximately ten years. Through the courtesy of the Governor of Illinois, lie was loaned to the Bureau of Mines for about seven months, after which period he resumed his former position.

Jan 6, 1919

By N. F. Mott

Jan 1, 1961

By A. S. Keh, H. A. Wriedt

The Precipitation of nitrides in quenched Fe-N alloys, aged between 25° and 200°C, was studied by transmission electron microscopy. Different dislocation substructures were introduced into the materials by recrystallization, cold working, and by Phase transformation prior to the introduction of nitrogen. It was found that the precipitated nitrides, tentatively identified as Fe16N2, have (100) habit planes. Nucleation takes place Preferentially at dislocations and at subboundaries. It sometimes occurs in the matrix, probably on vacancy clusters, but rarely on high-angle boundaries. The process of nucleation on dislocations and subboundaries is very temperature dependent. At room temperature there is no particular orientation relationship between the dislocations involved and the (100) planes on which the nitride Particles formed. With increasing temperature, the nucleation sites tend to become restricted to those dislocation segments lying in (100) planes. The change of yield stress of the 0.022 and 0.043 pet N alloys during quench aging can be correlated semiquantitatively with the change in particle distribution. Strain aging in quenched alloys can be separated into two stages. The early stage is attributed to nitrogen segregation to dislocations and the later stage is associated with precipitation. When previously quench-aged specimens were strained and aged, no additional Precipitates could be seen, although a considerable amount of strain aging occurred. DURING the past two decades, the precipitation of nitrides from a iron has been extensively studied by various techniques. It has been established that two types of nitride exist. The stable nitride, Fe4N, forms at temperatures above 250oC and Fe16N2, the

Jan 1, 1962

By Henderson, Robert

A GOOD idea of the magnitude of the underground operations at Climax can be gained from the following figures. A little more than 43,000,000 tons has been drawn from the mine and of this amount, 40,500,000 tons has been drawn in the past ten years and 12,000,000 tons was drawn in two of the war years. The maximum daily average output over a period of one month was slightly more than 20,000 tons but during this period, production on certain days was 24,000 tons, and 9000 tons was produced in a single eight-hour shift. This production came chiefly from 260 draw points although all of them were never in operation at one time. The haulage system for these draw points is made up of 7.5 miles of 36-in.-gauge track, and 131,000 ft. of subsidiary drifts and 44,000 ft. of raises have been driven to develop the necessary broken ore reserves for this high production. Power consumption is often considered an index of operating efficiency. In 1943, the year of maximum production, the mine power consumption was 19,223,000 kw.-hr. or 3 kw.-hr. per ton; in 1945 it was 3.5 kw.-hr. per ton. To handle this amount of power, there are four transformer stations and one switch station in the mine. Mr. Garrabrant, the chief electrician, describes the electrical installation in this issue.

Jan 1, 1946

By R. F. Mehl

Jan 1, 1961

By Casper A. Nelson, Wendell M. Whitecotton

A WIDE variety of lead ore is treated by the Midvale Smelter, for it is a custom plant not only treating Company lead concentrate and direct-smelting ores but also custom ores and concentrates, principally from Utah, Idaho, and Nevada, with lesser amounts from Arizona, California, Colorado, Montana, Oregon, and Washington. The principal operating departments of the plant are weighing and sampling, Wedge roaster, D&L sintering, blast furnace and drossing, and baghouse. The lead bullion produced is shipped to a subsidiary, the U.S.S. Lead Refinery, Inc., at East Chicago, while the by-products, such as matte and speiss, are shipped to other smelters or re-treated at the plant.

Jan 1, 1948

By Leo H. Glanville

Until 1934, natural ventilation was depended upon in the mine of the Climax Molybdenum Co. at Climax, Colorado. In that year a 7-ft. axial-flow, low-pressure fan was installed as an exhausting unit. In 1936, three more fans of the same kind were installed, all as exhausting units, with a total capacity of 115 000 cu, ft. per min., and since then fans and sprays have been added as required. Atmospheric Conditions Adverse atmospheric conditions at this elevation of 11,500 ft. account in part for difficulty in maintaining adequate ventilation throughout the mine. Barometric pressures range from 18.99 to 20.01 in. of mercury; the norma1 average being 19.70 in. Air weight is 0.051 lb. per cu. ft., and humidity is low—about a 30 per cent yearly average. This makes the use of mechanical humidity aids mandatory the Year around to prevent excessive dryness of the mine workings and the resultant dust hazard. The yearly temperature range is from minus 24" to 75°F.; typically, in February 1942 the mean low was minus 3.25°F. and the mean high, 21.3°F. In August the mean low was 34.8°F.; the mean high, 64.26°F. Even during the summer month air filtration through the openings of the cave area is 32°F., owing to accumulation of snow in the glory hole and in Part to glacial ice, which, combined with a rock temperature of 39°F. on the upper levels (elevation 11,945 ft.) and 42°F. on the main haulage level (elevation 11,470 ft.], makes it difficult to maintain a comfortable working temperature. The one advantage in ventilation of mine workings at the altitude of the Climax mine is that the power required to circulate a given air volume is 32 per cent less than would be required at sea level. Problems since 1936 the mine management has studied intensively plans for providing adequate ventilation for the entire mine for its expected life. As the ore breaks into large pieces, much secondary blasting is necessary, therefore there is a considerable amount of smoke, gas and dust, which requires circulation of a large amount of air to remove the contamination, It is undesirable to use haulage drifts and manways as air passages because some would be passageways for contaminated air also, and there would be undesirable high velocities in some drifts. High velocities and large volumes of subfreezing air dry out the passageways through which they pass, and thus increase the amount of dust. Regulating doors in haulage drifts are difficult of upkeep and interfere with production. It was decided as a general principle to distribute fresh air to each working place at low velocities and low pressures and to remove contaminated air as soon as possible with a minimum of travel through working places.

Jan 1, 1943

By Leo H. Glanville

Until 1934, natural ventilation was depended upon in the mine of the Climax Molybdenum Co. at Climax, Colorado. In that year a 7-ft. axial-flow, low-pressure fan was installed as an exhausting unit. In 1936, three more fans of the same kind were installed, all as exhausting units, with a total capacity of 115 000 cu, ft. per min., and since then fans and sprays have been added as required. Atmospheric Conditions Adverse atmospheric conditions at this elevation of 11,500 ft. account in part for difficulty in maintaining adequate ventilation throughout the mine. Barometric pressures range from 18.99 to 20.01 in. of mercury; the norma1 average being 19.70 in. Air weight is 0.051 lb. per cu. ft., and humidity is low—about a 30 per cent yearly average. This makes the use of mechanical humidity aids mandatory the Year around to prevent excessive dryness of the mine workings and the resultant dust hazard. The yearly temperature range is from minus 24" to 75°F.; typically, in February 1942 the mean low was minus 3.25°F. and the mean high, 21.3°F. In August the mean low was 34.8°F.; the mean high, 64.26°F. Even during the summer month air filtration through the openings of the cave area is 32°F., owing to accumulation of snow in the glory hole and in Part to glacial ice, which, combined with a rock temperature of 39°F. on the upper levels (elevation 11,945 ft.) and 42°F. on the main haulage level (elevation 11,470 ft.], makes it difficult to maintain a comfortable working temperature. The one advantage in ventilation of mine workings at the altitude of the Climax mine is that the power required to circulate a given air volume is 32 per cent less than would be required at sea level. Problems since 1936 the mine management has studied intensively plans for providing adequate ventilation for the entire mine for its expected life. As the ore breaks into large pieces, much secondary blasting is necessary, therefore there is a considerable amount of smoke, gas and dust, which requires circulation of a large amount of air to remove the contamination, It is undesirable to use haulage drifts and manways as air passages because some would be passageways for contaminated air also, and there would be undesirable high velocities in some drifts. High velocities and large volumes of subfreezing air dry out the passageways through which they pass, and thus increase the amount of dust. Regulating doors in haulage drifts are difficult of upkeep and interfere with production. It was decided as a general principle to distribute fresh air to each working place at low velocities and low pressures and to remove contaminated air as soon as possible with a minimum of travel through working places.

Jan 1, 1943

By C. V. Millikan

THE year 1930 in the petroleum industry has been characterized by the establishment of large potential production of crude oil. This has resulted in closer cooperation between companies by proration and unit operation agreements in order to afford an equitable outlet to all, and to prevent a flood of oil being forced on the market with attendant tremendous material and economic waste. Drilling wells in proved areas and wildcat wells are fewer than in the past several years. Restricted production and low prices have caused greater effort to increase producing and recovery efficiencies. Increased refinery efficiencies have amplified the effect of overproduction. Pipe line departments have been especially busy. New oil lines have reached more refineries by new and shorter routes. Establishing greater gas reserves by new fields has justified new gas lines to industrial centers, and has brought this fuel to thousands of new domestic consumers. Two long gasoline lines, a new venture in pipe lines, are being built to obtain a lower cost of transportation and less loss between the refineries and their distribution centers. The chairmen of the various divisions have discussed the developments of their respective branches more fully in the following reviews.

Jan 1, 1931

The Arizona Committee, consisting of GERALD F. G. SHERMAN, Chairman, ARTHUR NOTMAN, Secretary, NORMAN CARMICHAEL, B. BRITTON GOTTSBERGER, W. L. CLARK, J. C. GREENWAY, W. G. MCBRIDE, FOREST RUTHERFORD, has arranged the following program for the Arizona Meeting, which has been approved by the President of the Institute and by the Executive Committee. It is printed herewith for the information of members, and probably will not be changed in any material respect. Sunday, September 17, 1916.-Arrive at El Paso, Texas, 2.40 P.M., leave 10.20 P.M. Monday, September 18, 1916.-Arrive at Deming, N. Mex., .12:47 A.M. Arrive at Santa Rita, N. Mex., 4.00 A.M., where luncheon will be served, after which there will be a visit to the Chino mines. From there the train will proceed to Hurley, N. Mex., where a visit will be made to the mill of the Chino Copper Co.

Jan 7, 1916

By Leo H. Glanville

UNTIL 1934, natural ventilation was depended upon in the mine of the Climax Molybdenum Co. at Climax, Colorado. In that year a 7-ft. axial-flow, low-pressure fan was installed as an exhausting unit. In 1936, three more fans of the same kind were installed, all as exhausting units, with a total capacity of 115,000 cu. ft. per min., and since then fans and sprays have been added as required. ATMOSPHERIC CONDITIONS Adverse atmospheric conditions at this elevation of 11,500 ft. account in part for difficulty in maintaining adequate ventilation throughout the mine. Barometric pressures range from 18.99 to 20.01 in. of mercury; the normal average being 19.70 in. Air weight is 0.051 lb. per cu. ft., and humidity is low-about a 30 per cent yearly average. This makes the use of mechanical humidity aids mandatory the year around to prevent excessive dryness of the mine workings and the resultant dust hazard. The yearly temperature range is from minus 24° to 95°F.; typically, in February 1942 the mean low was minus 3.25°F. and the mean high, 21.3°F. In August the mean low was 34.8°F.; the mean high, 64.26°F. Even during the summer month air filtration through the openings of the cave area is 32°F., owing to accumulation of snow in the glory hole and in part to glacial ice, which, combined with a rock temperature of 39°F. on the upper levels (elevation 11,945 ft.) and 42°F. on the main haulage level (elevation 11,490 ft.), makes it difficult to maintain a comfortable working temperature. The one advantage in ventilation of mine workings at the altitude of the Climax mine is that the power required to circulate a given air volume is 32 per cent less than would be required at sea level. PROBLEMS Since 1936 the mine management has studied intensively plans for providing adequate ventilation for the entire mine for its expected life. As the ore breaks into large pieces, much secondary blasting is necessary, therefore there is a considerable amount of smoke, gas and dust, which requires circulation of a large amount of air to remove the contamination. It is undesirable to use haulage drifts and manways as air passages because some would be passageways for contaminated air also, and there would be undesirable high velocities in some drifts. High velocities and large volumes of subfreezing air dry out the passageways through which they pass, and thus increase the amount of dust. Regulating doors in haulage drifts are difficult of upkeep and interfere with production. It was decided as a general principle to distribute fresh air to each working place at low velocities and low pressures and to remove contaminated air as soon as possible with a minimum of travel through working places.

Jan 1, 1943

By Robert T. DeGavre

INTRODUCTION The $645 million financing for Inco Ltd's Soroako nickel project in Indonesia not only represents a significant human achievement but also there are certain important lessons that can be derived from Inco's experience in financing the project. The paper will not present a technical assessment of the project since Inco Ltd. submitted a series of papers on this subject at the international Laterite Symposium as part of the 108th Annual Meeting of the AIME in February 1979. BRIEF HISTORY OF THE SOROAKO PROJECT Table 1 summarizes the milestones achieved in the Soroako project and its financing. Exploration Phase A contract of Work was signed on July 27, 1968 by the Republic of Indonesia and F.T. International Nickel Indonesia (P.T. Inco) covering an extensive area of over 25,000 square miles on the two southeastern arms of the island of Sulawesi. The Contract provides that P.T. Inco has the sole responsibility for financing the project and determining the terms on which the financing should be obtained, that P.T. Inco has the right to receive and hold outside of Indonesia foreign exchange revenues and to freely dispose of such revenues, and that Indonesians have the right to purchase up to 20% of the equity of P.T. Inco over a period following start of production. P.T. Inco began field investigations in the Contract Area in August 1968. Preliminary reconnaissance sampling with portable drills broadly outlined areas of favorable laterite terrain which were then systematically sampled on surveyed grids. By early 1971 sufficient exploration work had been completed to indicate that the laterite deposits near Soroako could sustain a major nickel-producing plant (figure 1). Pilot plant studies in 1970 and 1971 at Inco's research station in Port Colborne, Ontario, using two bulk samples of Soroako ore material, also confirmed that the ore could be upgraded and treated for the recovery of its metal values. Feasibility Phase Encouraged by the results of its exploration program and pilot-plant work, Inco Ltd. commissioned Toyo Engineering Company of Japan in August 1971 to prepare a capital cost estimate for a relatively small nickel project called "Stage I". Stage I was to be a single-line pyrometallurqical process plant with an annual capacity of approximately 15,000 metric tons of nickel contained in 75% nickel sulphide matte (see Figure 2). Electric power was to be supplied by a thermal power station. It is important to recognize that Inco's strategy was to develop the Soroako ore deposits in several stages: first, construct a small project to gain experience and to reduce the initial capital outlay and then later expand in one or more steps to a much larger project to achieve maximum economies. The strategy reflected both Inco's financial position in 1971 as its sales and earning dropped sharply and the difficulties previously experienced by Inco in trying to launch in the late 1960's very large "greenfield" nickel projects in New Caledonia and Guatemala. Toyo's Project Development Study was completed. in January 1972. Based upon Toyo's cost estimate for physical facilities, Inco estimated the total capital cost of Stage I to be $115 million. For the next several months, Inco ran numerous in-house financial feasibility studies, using as inputs Toyo's cost estimate and the results of its exploration and pilot plant programs. In September 1972, Inco completed a project feasibility study which was based upon a capital cost estimate of $135 million. The feasibility study was immediately made available to potential partners and lenders. Partner Negotiations The Japanese nickel market had from the outset been central to Inco's planning for the Soroako project. That market had been growing dramatically at rates in excess of 20% per annum during the 1950's and 1960's. Japan had established, for rational security and other reasons, a domestic

Jan 1, 1985

By E. P. Abrahamson II

The effect of transition element binary solid-solution additions upon the recrystallization temperature of vanadium has been investigated. Cr, Fe, Co, Ni, Mo, Ru, Rh, Os, and IY lower the recrystallization temperature, while Ti, Mn, Zr, Cb, Pd, Hf, Ta, W, Re, and Pt raise it. The majority of elements have their greatest effect in less than 0.15 at. pet. Both the rate of change of recrystallization temperature with atomic percent solute and the limit of initial linearity are found to Correlate with the free atom grozdnd state outer electron configuration of the sollte element. THE work of Abrahamson and Grant1 and Abraham-son and Blakeney2 has shown that the solute's elec- tron configuration appears to be a prime determinant of both brittle-to-ductile transition and recrystallization temperature in dilute binary alloys. It has also been shown by Abrahamson3 that the limit of linearity, i.e., the limit of initial linear change of recrystallization temperature with atomic percent solute, is also a function of the electron configuration of the solute in iron base alloys. Because of the systematic nature of the solute electron configuration correlation, it is to be expected that some systematic variation might be observed upon changing the solvent. Thus, this study of recrystallization in vanadium base alloys is the first of a series aimed at defining the role played by the electron configuration of solute in determining the recrystallization characteristics of dilute transitional alloys. PROCEDURE All alloys were made using 99.8 pct V containing 0.011 C, 0.024 N, 0.08 0, 0.006 H, 0.035 Ta, and

Jan 1, 1962

By M. C. Lavine, H. C. Gatos, R. S. Mroczkowski

The structure of GaAs-Ge heterojunctions prepared by a back-melting process was studied by X-rav diffraction, melallographic, and electron-micro-analyzer techniques. The boundary region between the GaAs and the germanium was found to consist of a four-layered band. A discontinuity between the two inner bands was brought about by solidification occurring simultaneously from the GaAs and the germanium side. The junction material OH either side of the central discotinuity was found to have grown as a single Crystal with the orientation of the parent substrate. It was found essential to determine the GaAs-Ge phase diagram. This was accomplished by a series of alloys containing 0 to 40 wt pet GaAs. Over this range the diagram is a simple eutectic with the eutectic point at 74 wt pet Ge and 845 C. The limiting- solubility of Coils in germanium was found to bc less than 5 wt pet. The Kossel divergent-beam X-ray technique was used to study orientation relationships across the boundary lager. A great deal of effort has been recently expended on the electrical properties of heterojunctions. Little attention, however, has been given to the metallurgical variables which may be of importance in the formation of the junctions. The present work was undertaken to investigate some of the more pertinent metallurgical aspects of interface-alloyed GaAs-Ge heterojunctions. Such parameters as solidification processes, composition gradients, orientation effects, and the accommodation of crystal structures have been the objects of study in this program. EXPERIMENTAL PROCEDURES Phase Diagram. The phase diagram of the GaAs-Ge pseudobinary system was determined by means of cooling curves. A Bridgeman furnace was employed with the center section maintained at 1200°C and the upper section at 800°C. Melts varying from 0 to 40 at. pct in GaAs content were used. Each charge was incapsulated under a two-thirds atmosphere of argon in a carbon-coated quartz tube. Five min in the furnace hot zone provided rapid melting and homogenization. The capsule was then removed to the cooler portion of the furnace. Cooling times were of the order of 3 min. The resulting homogeneous microstructure indicated that equilibrium conditions were obtained by this procedure. Formation of Heterojunctions. Rectangular parallelepiped single-crystal samples were cut with the large faces of either the (l00), (110), or (111) orientation. The remaining four surfaces were also cut to specific orientations to permit accurate relative orientation of the GaAs-Ge pairs. The

Jan 1, 1965