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A comparison of gold, platinum and sulfide ion selective electrodes was made in this investigation for determination of Eh in solutions containing sulfide ions as a model system. The comparison was made in terms of the accuracy of the measured response, response time, pH dependence, and reproducibility of measurement. In addition, the sensitivity of each electrode towards changes in sulfide ion concentration was measured in terms of the change in measured Eh per decade change in concentration of sulfide ions. On the basis of a detailed investigation of the electrode processes occurring at the surface of gold and platinum electrodes, it was postulated that within the pH range investigated these electrodes respond to changes in the hydrosulfide ion, HS-, concentration in solution. In comparison, the sulfide ion selective electrode is known to respond to changes in the sulfide ion, S-, activity in solution. Although the potentials measured with gold and platinum electrodes were mixed potentials, pretreatment procedures can be used to obtain a signal suitable for process control. For control of sulfide ions in flotation pulps, the use of a gold electrode pretreated at 1.0 V with respect to a standard hydrogen electrode is recommended.

Jan 1, 1990

By James S. Goff, Stephen J. Navin, Wesley W. Moulton

The White River Shale Oil Corporation (WRSOC), as agent for Phillips Petroleum Company, Sohio Shale Oil Company, and Sun Shale Oil Company, is developing a prototype oil shale facility on Federal Lease Tracts Ua and Ub, located in northeastern Utah and known as the White River Shale Project (WRSP). The Ralph M. Parsons Company (Parsons) has been retained as the design engineer/constructor for the project. This paper covers the successful pregrouting of the Bird's Nest Aquifer in conjunction with the sinking of a 9.2-m (30-ft)-diameter shaft and driving of a 3.89-m by 5.64-m (18.5-ft by 12.75-ft) decline. The Bird's Nest Aquifer derives its name from the ellipsidal solution cavities caused by leaching of random-size nacholite nodules. The sodium bicarbonate nodules occur as persistent bands within a matrix of siltstone and marlstone. The team, made up of the owner, engineer/contractor, and subcontractor successfully grouted the shaft down to an inflow of less than 0.06 lps (1 gmp) and the decline down to less than 0.12 lps (2 gpm) by injecting a total of 213.190 kg (470,000 lb) of Celtite Terraseal, 113,400 kg (250,000 lb) of limestone dust, and 41,730 kg (92,000 lb) of cement into the formation.

Jan 1, 1985

By S. Nowosad, O. Langefeld, A. Godge

Pumped storage power plants are one of the options to store the fluctuating production of electric energy from renewable sources in a sustainable manner and is able to provide Europe with the opportunity to overcome the effects of climate change. However, due to the extensive land use required when planning the water reservoirs, several projects have been declined after social conflicts raised, even in Germany. Nonetheless, after the flooding and drought periods in northern Germany, the catastrophic floods of July 2021 in south west Germany, the country’s need to decrease its dependency on import of gas and energy supply, and the energy transition goals set for 2030 and 2050, it has become clear that the implementation for water reservoirs must increase in the coming years, whether above ground or underground. Furthermore, not only Germany is interested in the use of underground cavities for water and energy storage, other European countries as Sweden are currently developing studies and solutions to bring this concept soon to reality in Europe. This article introduces the systematic approach for planning and designing large underground cavities for water reservoirs as a sustainable energy transition approach and a climate change response by showcasing the process of selection and results of the “Energy and Water Storage Harz” (EWAZ) research project. Additionally, the results of the evaluation of the effect of implementing the selected underground and surface infrastructure into the current water management system in the region is presented. Finally, the different possibilities evaluated for the underground cavities within the project and the technical challenges involved are be discussed.

Feb 1, 2023

By J. Hahn

Modern high-performance disc filters such as the BoVac Disc Filter have set new standards in applications where large capacities of solids, liquids and air have to be managed through the filters. These disc filters have an enormous hydraulic capacity. For applications in mineral processing - with a special focus on tailings – which typically have high solids throughputs but low filtrate and air flows, this capacity can be used to expand the filtration area while maintaining the benefits of very good cake discharge even with thin cakes (4-5 mm) and a high filter speed. Research work over the last century has proven that increasing the filter area should be achieved by increasing the disc diameter. Because adding more discs leads to big problems with the cake discharge. However, as the disc diameter increases, the filter segments become longer and heavier. A suitable compromise was therefore found by doing both. The result is the first vacuum disc filter that offers significantly more than 300 m² of filtration area, but has no more than 6 discs.

Feb 1, 2023

By B. J. Arnold

Coal blending inherently means homogenizing a mixture of coals so that, overall, the properties of the blend meet some specifications for maintaining power plant performance and emission requirements. In common practice, however, coal blending is at best coal mixing. If necessary, more sophisticated blending systems can produce a more homogeneous feed by using accurate weighing devices and on-line coal analyzers coupled with sampling systems. Blending can be accomplished at the mine, on stockpiles, and from bins, bunkers, and silos.

Jan 1, 1994

By Yoichi Shimada, Katsuyuki Nishida, Shinichi Takahashi, Yasushi Okada, Yohei Nakamichi, Kazunori Oshiro, Taichi Terui, Sigehiko Sugie

"Temporary retaining walls are ordinarily used for tunnel construction work conducted using the opencut construction method. Retaining walls in such instances are typically installed vertically. However, shoring (such as struts and king posts) is required to ensure the stability of retaining walls in cases of excavation work to depths that exceed approximately 4 m. A new design and construction method that focuses on the effectiveness of retaining walls that are installed on an incline was studied with the aim of improving construction workability by omitting shoring. The inclined braceless excavation support (IBES) method, which was developed for use with the inclined buttress method, requires no shoring, even for deep-open-cut construction work and can be applied to deep excavation work on ground with a high groundwater level. This method has been applied at six work sites in Japan in recent years. This paper introduces the IBES design and construction method and presents verification results based on the design method, a model experiment, finite element analysis, and measurements obtained during construction work.INTRODUCTIONBackgroundIn the past, temporary retaining walls used in open-cut construction work have been installed vertically, and shoring (such as struts and king posts) has typically been used to ensure the stability of these retaining walls when the excavation depth reached 3–4 m. However, shoring interferes with structures built within excavations and requires box-outs and penetration sections in the structures, as well as concrete joints that raise concerns about their impact on the watertightness and long-term durability of structures (Figure 1).Shoring also narrows the space available for conducting construction work and reduces construction work efficiency, and the installation and removal of shoring increases the construction duration and cost. As a result, there has been a demand for ways to reduce or eliminate shoring to improve the quality of structures and construction work efficiency."

Jan 1, 2016

By G. A. Calboreanu

The deterioration rate of any metal or alloy is increased in a erosion-corrosion application because the passivated surface layer is removed by the solid particles contained in the pumping fluid and the material surface becomes corrosion active again. Numerous attempts were made to engineer a stainless steel with higher hardness and unaffected corrosion performance. Alloys of special interest in such an area are the duplex stainless steels particularly the CD4MCu material which has the capability of being hardened due to its ferrite-austenite microstructure. Unfortunately, the CD4MCu with higher hardness comprises different intermetallic compounds which will increase the corrosion rate. The paper is analyzing the erosion-corrosion performance of a new type CD4MCu with 32% higher hardness and superior wear performance. The corrosion performance of this new alloy is better than the corrosion performance of the common CD4MCu material which the industry could supply. The corrosion effectiveness was evaluated with the Huey test, the potentio-dynamic anodic polarization test and the weight loss test whereas the erosion resistance was established with a low stress ball-on-disk type apparatus. The Wilfley hard CD4MCu material had 39% lower weight loss and 32% smaller volume loss than the common CD4MCu alloy The hardness range of the centrifugal pump parts poured and processed with the Wilfley hard CD4MCu is 320-350 HBN versus 250-255 HBN hardness of the common CD4MCu. After approximately 18 months of experimentation and field testing it was clearly established that the life time of the Wilfley hard CD4MCu is higher than the common CD4MCu and consequently centrifugal pumps were supplied to different customers in North and South America. India and more recently Australia. Sincere thanks to all the A.R. Wlifley & Sons Inc. and Western Foundries Inc. employees who supported and help to implement this work. special thanks to George Wilfley. Dave Cobb. Bill Becker Sr. and Wayne Taylor

Jan 1, 1997

By S. Goodfellow, J. C. Ordóñez-Calderón, K. Esmaeili, N. Houshmand

A good understanding of the hardness of ore being handled and processed in a mining operation can significantly improve operational efficiencies by providing valuable data to support decision-making through the mining value chain (drilling, blasting, comminution). This study presents the results from the application of Machine Learning (ML) to predict rock hardness using various geophysical and geochemical features. Core samples from a mine site were logged using a multi-sensor core logging system. Measurements including ultrasonic p-wave and s-wave velocity, elemental concentration via portable XRF, and Leeb Hardness, were measured every 2 cm along the length of the core. The ML model was set up to predict the Leeb Hardness using the elemental concentrations and ultrasonic velocities as predictors. The Leeb Hardness values were grouped into three bins and used as a classification target for the ML models. Various ML models, including linear regression, support vector machines, decision tree, XGBoost, Random Forest, K-Nearest Neighbors, and Naïve Bayes were tested. The model performance demonstrated that the Random Forest and XGBoost models produced the highest accuracy of 74-91%. Random forest and XGBoost were then selected to perform regression models to estimate a Leeb hardness value rather than a hardness class. These models were able to estimate the Leeb hardness value by 4.57-4.87 % error.

Mar 2, 2022

By D. Williamson

In the post war years metals analysts and statisticians have generally tracked the demand for metals in line with changes in OECD industrial production (IP) growth rates because, undoubtedly, the correlation between IP growth and metal demand was reasonable. However the correlation was exaggerated. During times of expanding IP growth metal demand increased at a faster proportional rate than IP growth. This was probably due to industry restocking in anticipation of growing demand at the start of each economic cycle. Conversely, metal demand would slacken at a greater rate than would be suggested by negative IP growth as industry destocked in order to reduce costs. Nonetheless, overall, a reasonable correlation between IP growth, over the longer term, and metal demand could be painted. Yet, although this correlation has stood well since the last world war it has been based on the fact that the bulk of the world's IP growth stemmed from the industrialized countries of the western world, latterly including Japan. The so called "developing world" was of little consequence, whilst countries of the Soviet Union and Communist Bloc were deemed to be closed, self-contained entities which, for each metal, would either be net exporters or importers. These quantities would be used by analysts to calculate the overall supply/demand equation for the western world only and to deduce whether a commodity was in shortage or surplus. It is now believed that this method of projecting total world supply and demand for raw materials is outdated and takes little account of the worldwide political changes which have occurred since the collapse of communism and the revitalization of China, albeit under a notional communist government. It is no longer appropriate to assess global balances for raw materials on the basis of three economic blocs namely, western world, developing world and communist bloc. Rather, global balances need to be projected on a global basis. In this regard, since the collapse of communism and the removal of many other totalitarian regimes, capitalist forces are at work and are attempting to satisfy, with some considerable success, the expectations of the great mass of the world's poorer people. Such people, usually located in Asia, Africa and Latin America have aspired to the same standard of living as people living in western Europe, North America and Japan. Now, with free market forces at work their aspirations will start to be met. Consequently, the demand for metals and other raw materials will now rise at a much faster rate than at any other time in the world's history. Not only will the production of raw materials have to keep pace with rising IP in the developed world but will also have to keep pace with the demands associated with the rising expectations of rapidly increasing populations in the developing world, as well as from within the old communist bloc countries. This paper sets out to argue the case that metal demand could well increase at a rate faster than the world's mining companies, governments and financiers can deliver.

Jan 1, 1997

By G. P. Hand

The purpose of this paper is to bring to your attention the various kinds of high performance graphites available today, their characteristics and possible applications. These materials are products of a proprietary high temperature technology developed by Superior Graphite Company. We feel we have only begun to tap the potential of this technology and the utilization of the resulting products. During the course of the paper, we shall investigate high purity, high performance graphites made from raw materials such as mined natural graphites, synthetic graphites and petroleum derivatives. We shall define their characteristics and resulting benefits to current applications, along with applications currently under development. It is our desire to stimulate speculation and development of current high performance graphites and their applications as well as ideas for new high performance products and applications. First, a little background about the process. The technology was developed through a concentrated R&D effort which culminated in 1976 in the construction of a unique furnace capable of continuously processing tonnage quantities of granular carbons at temperatures in excess of 2,500 degrees C. This process is capable of refining various carbonaceous raw materials, including natural graphites, to levels of purity and consistency that were previously unattainable in commercial quantities. Carbon contents in excess of 99.9% are currently being produced on a continuous flow-through basis. Since beginning operation in 1977, this plant, located in Hopkinsville, KY, has been expanded in stages to its present capacity of producing over 45,000 tons of purified graphites and graphitic carbons per year. In addition to the purification process, the technology used allows the introduction of selected elements into the carbon/graphite structure to provide additional benefits. Elements of interest include boron, silicon, copper, iron and rare earths. The characteristics of and applications for some of these products will be discussed later.

Jan 1, 1990

By E. R. Bauer

The trend in underground room-and-pillar coal mining is to employ remote-control continuous mining machines and extended cuts, 12 m (40 ft) deep or more. This system of coal extraction, adopted by over 435 mines, can create additional worker-safety hazards. To address the ground control and worker-positioning hazards, a combination of statistical analyses and numerical modeling was conducted. Initially, the reported roof-fall incidents and fatalities were reviewed to delineate the ground-control hazards. Then, the application of the Coal Mine Roof Rating (CMRR) for estimating safe extended-cut depths was evaluated. Finally, computer modeling to predict roof displacements during extended-cut mining was completed. The paper describes the results of these studies and their impact on the safety of extended-cut mining.

Jan 1, 1999

By Iga Trisnawati, Fitria Puspita, Himawan Tri Bayu Murti Petrus, Gyan Prameswara, Idi Amin, Andi Nurfaadhilah Ulfah

Laterite ore is a valuable resource due to its high content of metals essential for modern technology, including nickel, iron, and cobalt. However, extracting nickel from laterite ores is challenging due to their complex mineral composition and low nickel concentrations. This study examined the leaching behavior of pre-roasted laterite ore and the effect of roasting on leaching kinetics. The ore was roasted at temperatures of 280°C and 610°C for 3 h, followed by sulfuric acid atmospheric leaching. The results demonstrated that pre-roasting at 610°C significantly enhanced nickel leaching recovery, with up to 93% nickel successfully recovered. The leaching process of pre-roasted laterite ore was found to be controlled by diffusion through the ash layer, with activation energy values of 20.97 and 18.97 kJ/mol for laterite roasted at 280°C and 610°C, respectively. These findings indicate that pre-roasting can improve the leaching performance of laterite ore, potentially leading to more efficient and sustainable nickel extraction processes.

Feb 27, 2024

By R. K. Will

An inactive mining operation in northern California is known to be a source of acid mine drainage and heavy metals which have impacted adjacent creeks. Elevated concentrations of copper and zinc are a concern to aquatic populations, particularly steelhead trout and salmon downstream in the Sacramento River. Previous regional geological surveys of mineralization by the U.S. Geological Survey located and mapped outcrops of massive sulfides and gossan. Recent investigations indicate that a substantial amount of the metals in the local creeks are due to natural causes. The investigations include locating and mapping surface and subsurface minerals, soil and water sampling, and chemical analysis. Groundwater, seeps, and surface water were also sampled and analyzed. A water balance was conducted on a sub-basin level following delineation of surface water drainage and groundwater divides. A chemical mass balance incorporated metal concentrations and water volumes and was then used with other data to determine the contribution of metals from natural versus mining-related causes.

Jan 1, 1998

By D. G. Chedgy

This article presents a novel design, called the Climax High Capacity Processor (HCP), for pre-combustion cleaning of coal. This design is particularly suitable for the plant capacities of 400 -660 TPH. The HCP is different from the conventional designs with an equivalent throughput in three major aspects: 1) the use of one large capacity HM cyclone to separate coarse and intermediate raw coal in a single circuit; 2) the elimination of the conventional secondary magnetics recovery system by use of the high efficiency Climax magnetic separators; 3) the use of "single line" piping with a minimum requirement of ancillary devices. In comparison with conventional designs with similar capacity, the HCP plant costs much less in capital investment, operation and maintenance.

Jan 1, 1997

By William P. Blacutt

This paper examines Bolivia's General Environmental Bill recently passed by Congress: a multi-purpose law with two primary objectives: a) the protection and conservation of the environment, and b) the promotion of sustainable development. In this law, environmental benefits are emphasized by stating general principles, not by attempting to define the means. Regulations are left to the writing of subsequent complementary codes. This paper shows that much of the controversy surrounding the legislation disappears when it is seen as guide rather than an operational part of Bolivia's industrial policy. In essence, the law addresses recent environmental awareness in a region more anxious than ever to speed economic growth.

Jan 1, 1992

By F. Habashi

Chile is at present the largest copper and rhenium producer and was before World War I the largest nitrate producer. She is also an important producer of lithium carbonate and molybdenum oxide. An important event in the history of the country is the Pacific War of 1879-1883 in which she acquired the northern provinces initially belonged to Bolivia and Peru. In 1888 Chile annexed Easter Island. The Chilean mineral and cultural history is briefly reviewed together with the people who contributed to her development. The present report is the result of a number of academic and industrial visits to Chile during the period 1992 to 2009.

Jan 1, 2011

By M. S. Klima

A 25-mm diameter dense-medium cyclone was tested to investigate the effects of geometry and operating conditions on cyclone performance when processing -150 I'm coal. The emphasis was on examining those variables (e.g., flow rate and inlet velocity) which impact the separation kinetics (specifically the number of g's and the mean retention time) and the occurrence of apparent bypass. Apparent bypass, indicated by partition curve "tails", results from the short circuiting of the feed coal to one or both of the product streams and represents a loss and/or contamination of the clean coal. This paper presents the results for this series of tests.

Jan 1, 1993

By G. V. Sullivan

As part of its program to conserve domestic mineral resources through advancing mineral resources technology, the U.S. Department of the Interior, Bureau of Mines, conducted investigations to determine the feasibility of recovering high-grade barite concentrates, suitable for use as well-drilling mud, from current and old waste pond materials and materials bypassed in present mining operations. Flotation studies of waste pond samples from Missouri and Nevada yielded barite concentrates containing over 95 percent BaSO4 with recoveries of 86 percent and 96 percent, respectively, of the barite in the flotation feed. Flotation studies of a hard-rock sample from Georgia, currently bypassed in mining, yielded a barite concentrate containing 97 percent BaSO4 with an attendant recovery of 97 percent of the barite.

Jan 1, 1980

By J. A. Matar

Mineralization features at the Bajo La Alumbrera porphyry copper-gold deposit are discussed as they affect gold leaching and copper flotation behavior. Alteration-mineralization geological blocks are assigned in the zoned body, and each required its own geostatistical model. They extend horizontally outward from potassic to the phyllic-propylitic boundary, vertically from surface down to 300 meters, and include oxide, secondary enriched, and hypogene mineralization. Copper and gold values are calculated geostatistically from assays and all available geologic-mineralogic information. Reserves are classified for each geologic block and for each open-pit bench into leach or float ore according to metal grades, geologic characteristics, and supergene-hypogene relations. Finally ore extraction behaviour is briefly described, grouping gold and copper reserves into metallurgical families.

Jan 1, 1986

By M. D. Monroe

Getting the best match between truck and haul road requires examination of many factors and their effect on the bottom line. Most mines use a bottom line measure based in some way on cost per ton of material moved. This measure focuses on the two components of truck haulage cost per ton: productivity (or performance) and operating cost. Productivity can be measured or predicted for specific tasks using either field measurement or modelling. Individual tasks can be combined to provide a larger scale, longer term net figure for total mine output. True cost is more difficult to capture as they are time and task oriented and can be influenced by a summation of factors over a truck lifetime. For example, "allocated" costs, such as owning (depreciation) and some repair costs, are spread over long periods of time. Other cost, such as fuel and tires can be tied more directly to certain tasks such as fuel and tire cost. This paper focuses on the more direct, task-oriented factors that affect truck productivity and cost.

Jan 1, 1992