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By H. W. Kilau

Thermodynamic calculations indicate that an electrochemical cell might serve as an analytical device for determining the composition of high-purity metals. An equation, readily derived, for the cell voltage, E, is as follows: [E I RT In F NFe unknown sample T of L NFe standard] The cell, however, must come to equilibrium, must be reversible, and must have no thermal effects or complicating side reactions whose magnitude is indeterminable. This Bureau of Mines investigation explores the feasibility of an electrochemical technique for the analysis of high-purity iron. Experiments were conducted using room-temperature aqueous cells and high-temperature molten salt cells. The room-temperature cells proved to be irreversible. The high-temperature cells utilizing FeCl2 and a eutectic mixture of KC1-LiCl were reversible, but did not attain a constant voltage necessary for analytical considerations.

Jan 1, 1963

By R. L. Hopkins

Some typical thiacyclopentanes and thiacyclohexanes were synthesized to provide reference compounds needed for the identification of sulfur compounds in crude oils. Two general methods of synthesis were employed: (1) cleavage of 2-alkyltetrahydropyrans with hydrogen bromide followed by the reaction of the resulting dibromoalkanes with sodium sulfide and (2) the catlyzed reaction of cyclic ethers or 1)4-or 1)5-alkanediols with hydrogen sulfide. Both methods produced mixtures of 2-alkylthiacyclopentanes and 2-alkylthiacyclohexanes with 2-alkyltetrahydropyran as the starting material. The structures of the reaction products were established by analysis for sulfur; desulfurization; gas-liquid chromatography (GLC); mass, infrared, and nuclear magnetic resonance (NMR) spectra; and an alternate synthesis. The synthesis of the cyclic sulfides contributed substantially to the identification of 10 members of this class of sulfur compounds in crude oil.

Jan 1, 1967

By R. E. Head

[Surveys of the manganese situation conducted by the Geological Survey and other agencies have distinctly established the fact that the tonnage of high- grade manganese ore in the United States is relatively small. It is therefore obvious that large-scale production of manganese is possible only through beneficiation of low-grade material. ]

Jan 1, 1941

By L. C. Karrick

The Bureau of Nines has received many inquiries on the subject of assaying oil-shales, both from individuals who desire to wake their own assay while in the field, and also from Commercial assayers and investigators. The present paper describes the assay retort used by the Bureau of Mines. in the research work on oil-shales now in progress at the Intermountain Experiment Station of the Bureau at Salt Lake City, Utah, and at the Colorado cooperative oil-shale laboratory, Boulder, Colorado. This retort, which was developed through experimentation in the bureau's laboratories, has been found to be convenient in use and. capable of yielding reproducible results. M. J. Gavin, Oil-Shale Technologist, gave valuable assistance in preparing the subject matter for publication and made many helpful suggestions during the experiments made by the writer in the course of the development of the assay retort. L. A. Anderson, research "fellow" University of Utah, assisted in the preliminary development of the assay retort.

Jan 1, 1921

By Alla D. Mah

No experimental heat-of-formation value has been reported in the literature for cerium sesquioxide. The heat of formation of bismuth sesquioxide has not been determined in recent years, and the older value was subject to large uncertainty. Accordingly, the heats of combustion of cerium sesquioxide and bismuth metal were measured by the Federal Bureau of Mines. The heats of formation were: ?H°298.15 = -427.01 ± 0.70 kcal. /mole for cerium sesquioxide and ?H°298.15 = -137.16 ± 0.30 kcal./mole for bismuth sesquioxide. The free energy of formation was estimated for cerium sesquioxide and accurately calculated for bismuth sesquioxide. The data were compared with values in the literature.

Jan 1, 1961

By R. E. Head

[Surveys of the manganese situation conducted by the Geological Survey any other agencies have definitely established the, fact that the tonnage of high-grade manganese or in the United States is relatively small. It is therefore obvious that large-scale production of manganese is possible only through beneficiation of low-grade material. Deposits of low-grade manganese ore are being examined by engineers of the Mining Division of the Bureau of Mines to determine their size and possibilities as sources of manganese on a tonnage basis. The Metallurgical Division of the Bureau is developing and perfecting beneficiation processes with the objective of utilizing such low-grade ores. Microscopic study of these ores represents one phase of the research.]

Jan 1, 1941

By Vernon C. Allison

The explosibility of coal dust has long been recognized by competent investigators as constituting one of the dangers of mining coal and in the use of pulverized coal as a fuel in industrial plants. The Bureau of Mines has carried on extensive series of experiments dealing with this subject, and has not only developed methods for the practical prevention of this danger, but in the, course of these experiments has developed a standard method of determining the relative explosibility of coal dusts and other organic dusts.3 Oil shale contains compounds 'of carbon and hydrogen that are either of a petroleum nature and are strongly ,adsorbed upon the incombustible part of the shale, or else are present in the shale as a compound ("kerogen") which has the property of changing into petroleum-like products when acted upon by heat. The oil shales may contain varying amounts of the organic matter, ranging from a trace to more than 66 per cent, depending upon their richness; therefore, it is important to know whether the dusts formed in mining and handling these oil shales are explosive when mixed with air and if so, to indicate remedial measures. This paper gives the results of explosibility tests of several pulverized oil shale's, selected as being typical of those which in the future may be used in commercial shale-oil production test on a sample of typical Colorado oil shale has been., published in an earlier paper.4

Jan 1, 1926

By H. J. Heinen

This report summarizes preliminary research studies by the Bureau of Mines in electrowinning molybdenum directly from pure or impure molybdenum trioxide (MoO3) by fused-bath electrolysis in an open graphite cell without need of a protective inert atmosphere. A formulated electrolyte of the tertiary system containing 41.6 percent sodium pyrophosphate, 16.7 percent sodium tetraborat, 33.3 percent sodium chloride, and 8,4 percent molybdenum trioxide, by weight, electrolyzed at 1,000° C,, gave excellent results. Current density studies were made over a range from 20 to 260 amperes per square decimeter. Current efficiencies of 80 to 90 percent were obtained over the entire range. Yields up to 500 grams of molybdenum per kilowatt-hour were obtained. Higher current densities, however, reduced yields and produced a finer grained metal. The two most important facets in electrowinning molybdenum from MoO3, in an open cell, are temperature and electrode spacing to minimize or eliminate the formation of the suboxide MoO2, the major source of oxygen contamination. At temperatures of 1,000° C. and higher, together with the proper spacing of the electrodes, formation of oxides are practically eliminated. Molybdenum metal electrowon from pure MoO3 was 99.9 percent pure and contained 0,056 percent oxygen and 0,007 percent carbon. This metal, when arc-melted, had a Vickers hardness number of 175 and contained 50 parts per million oxygen and less than 10 parts per million carbon. Molybdenum metal electrowon directly from an impure MoO3 containing 90 percent MoO3 resulted in a metal of 99.8 percent purity.

Jan 1, 1961

By H. D. Baylor

This paper, describing the operations of the Louisville Cement Co. in quarrying limestone for the manufacture of quicklime, is one of a series being prepared for and published by the United States Bureau of Mines on stone quarries throughout the United States. Those papers are designed to disseminate technical information regarding the methods used. The cost tabulations represent operating only and not total costs. It is recognized that publication of total costs might in many instances cause embarrassment to individual operators as well as to the industry as a whole. On the other hand, operating costs are essential to the technical discussion and study of the methods employed. The attention of the reader is specifically called to this differentiation in order that no misunderstanding of the scope of the cost tabulations shall ensue. ACKNOWLEDGMENTS The author acknowledges the assistance of J. H. Lemmon, plant superintendent, Charles Taylor, plant engineer, and F. H. Compton, chief engineer, of the Louisville Cement Co. in the compilation and preparation of this paper.

Jan 1, 1932

By R. V. Ramani, P. M. T. White, D. Sutton

1.1 General The examination and evaluation of a mineral deposit to determine whether or not it can be profitably exploited entails many factors unrelated to the physical nature and intrinsic worth of that deposit. Nevertheless, geology and geologically related factors have great bearing on the economic potential of the deposit. This is only natural because the deposit owes its existence to these factors. This is even more so in underground mines where the whole system is a geologically enclosed one. Geology plays a major role in at least four phases of a mineral venture. Firstly, it acts as an indicator of the existence of parti¬cular minerals. For example, it is inconceivable that a sedimentary coal deposit would exist in a granitic batholith or stock, or that a sandstone would host primary copper or nickel sulphides. Further, the positional relationship of different rock types may be significant in locating deposits such as replacement zinc and copper sulphides in limestones which have been intruded by igneous rocks. Thus, geology is important in the exploration phase of a mineral deposit. Secondly, once potentially valuable minerals have been discovered, knowledge of geology plays a significant role in determining the dis¬tribution, grade and extent of the mineralization. Controls on mineralization include one or all of those related to structure, rock type, sedimentary features, post-depositional redistribution, etc. Con¬sequently, in order to effectively evaluate a deposit in terms of

Jan 1, 1974

By F. S. Crawford

This report deals with the effectiveness and economy of installing mine timbers treated with preservatives in long-life service locations. Early in the present century, when mine timbers and labor were plentiful, it was not general practice to install treated timbers in such places. Because national sources of good mine timber are declining steadily, the mining industry must now conserve timber. Moreover, the cost of installing and replacing mine timbers has been rising. Therefore, even the simplest of treatments can be expected to give some return on the investment when applied to timbers that are to be installed in relatively permanent locations. Better methods of treatment will produce better returns. In a service test of maple timbers treated by the hot-and cold-bath method and installed in main haulageways of the Athens mine of the Cleveland Cliffs Iron Co., Negaunee, Mich., zinc chloride-treated timbers had an average useful life of 13.3 years; borax-treated timbers, 11.2 years; and sodium fluoride-treated timbers, 7.7 years. Untreated timbers used as controls had an average useful life of 3.8 years.

Jan 1, 1950

By John S. Dunning

This is one of a. series of papers being prepared for and published by the United States Bureau of Mines, describing raining and milling methods at crushed-stone plants throughout the United States. These papers are designed to disseminate technical information regarding the methods used. The cost tabulations represent operating expenditures only and not total production costs. It is recognized that publication of total production costs might in man; instances cause embarrassment to individual producers as well as to the industry as a whole. However, operating costs are essential to technical discussion and study of the methods employed. The attention of the reader is specifically called to this differentiation in order that the scope of the cost tabulations shall not be misunderstood. This paper deals with the quarrying and crushing methods used at the Avon Mountain trap-rock quarry of the Atlas Sand, Gravel & Stone Co., in West Hartford, Conn.

Jan 1, 1936

Lower the respirable dust expo-sure of longwall mine workers by reducing the amount of air-borne respirable dust generated during coal extraction. Approach Increase the moisture content of the coal seam through water infusion before the coal is mined. How Water Infusion Works Increasing the moisture content in coal tends to prevent respirable dust from becoming air-borne during mining and transport. The moisture content of the coal seam can be increased by infusing water into the seam. Water under pressure is forced into the cracks (cleats) of the coal seam through sealed bore-holes. The effectiveness of water infusion is a function of the amount of water the coal seam accepts (its infusibility), which depends on the cleat density (cleat spacing) and cleat size (crack diameter). Thus the effect of water infusion on dust control depends mainly on coal seam characteristics. Water infusion techniques are generally used to restrict the flow of methane gas to the working face; however, the technique provides an alternative dust control method in mines with severe dust problems which limit production.

Jan 1, 1987

By L. C. IlsLey, R. A. Kearns

"The electrical section of the Bureau of Mines has obtained copies of all available State safety rules and regulations in order to make a study of those portions of the codes relating to electrical equipment. While it has been found almost impossible to compare the several codes as a whole, comparison of those regulations dealing with a single subject has proved both interesting and instructive.Sixteen states have rules or enactments having reference to telephones and the present paper covers a compilation of these references. It is believed that data of this kind will be of service to commissions or other bodies contemplating the revision of existing codes.The compilation taken from the various codes follows: State Rules and Regulations.California.Sec. 5 (Par. c) Telephone communication shall be maintained between a co-operative station and each mine which it supplies. If the foreman in charge of a station does not reside thereat, his residence also shall be in telephone communication with each mine supplied by his station.Sec. 8 (Par. a) Whenever a fatal accident occurs in or about any mine, notice thereof shall be given promptly by telephone or telegraph if possible, followed by a notice in writing to the chief inspector, by the superintendent or other person having immediate charge of the work at the time of the accident."

Jun 1, 1921

By A. Wahab Khair, Richard D. Begley

"This paper presents results of destructive tests performed on rectangular coal specimen under the influence of two vertical and simultaneous wedge indentation forces. Several wedge designs and spacings were utilized in compression tests. The objective of these experiments was to qualitatively monitor the effect of different wedge designs and spacings on the stress distribution within the coal specimen.Coal samples from the Waynesburg coal seam were cut and trimmed to cubical dimensions of approximately 5 X 10 X 20 cm. These specimen were subjected to parallel compressive forces through two vertically applied wedge indentors. Loading was achieved with a hydraulic hand pump in order to facilitate interferogram construction. The load increments were limited due to the sensitivity of the holographic interferometric technique (holometry) in measuring small displacements; therefore, interferograms were taken only during similar increments in order to allow for a qualitative comparison between different wedge design and spacings. In some cases, interferograms were taken immediately before and after failure of the specimen.Introduction Failure Modes Three distinct modes of failure occur when geologic materials are subjected to wedge indentation forces. As shown in Figure 1, a crushed zone is located immediately adjacent to the indentor while chipping can occur if the fractures initiated in the crushed zone extend upwards to the free surface.. The third failure mode is a zone of intricate frac¬tures located between the crushed zone and the chipping zone. Several experiments have been conducted over the years to better understand crater formation and stress distribution within geologic materials under the influence of an indentor. Generally speaking, crack initiation and propogation observed in these experi¬ments correlate fairly well with wedge indentation theory; however, the nature of the .fractures is greatly influenced by different material properties such as grain size and cleavage planes. In other words, a wide range of behavior has been found in different rocks subjected to wedge penetration. For example, it has been observed that some rocks are merely crushed and indented while others are more prone to cracking and chip formation. Therefore, the development or nondevelopment of chips depends mostly on wedge geometry, rock type and depth of penetration. This work is part of the study associated with opti¬mization of cutting parameters, which is best modeled by using brittle materials and subjecting them to rigid wedge penetration tests."

Jun 1, 1988

By Leonard Obert

This report describes the development of a dynamic strain gage and a companion amplifier and recording camera -an apparatus designed to pick up and record the strain waves produced in rock by a nearby explosion. Also included in the report is a discussion of the relationships connecting the strain with the displacement, velocity, and acceleration for both plane and spherical waves. The proposed tests for which the strain gages were intended required making measurements in solid rock, a factor that necessitated the development of a gage that could be inserted and anchored in a small-diameter diamond-drill hole. The restriction on the diameter of the drill hole is required so that the presence of the hole in the medium will not influence the propagation of the strain wave. The gage should respond with fidelity to the frequencies present in a wave pulse generated by the nearby detonation of a small quantity of high-velocity explosive. Preliminary tests showed that this frequency range extends from 200 to 10,000 c.p.s. or greater. Also, the gage should be capable of measuring strains ranging from a few micro-inches per inch to several thousand micro-inches per inch. Other desirable design specifications included a low gage output impedance to permit the use of long cables, and a low gage cost, particularly in view of the fact that for the final design none of the gages can be recovered from the medium.

Jan 1, 1949

By N. S. Dalal, X. Shi

While it is known that vanadate and related compounds of pentavalent vanadium ( V (V)) exert potent toxic effects on a wide variety of biological systems, the underlying biochemical mechanism is still not fully understood ( 1- 3). One of the pathways is thought to involve the oxidation of NAD ( P) H. Thus, considerable effort has been devoted to finding the mechanism of NAD ( P) H oxidation by Vcvi (1-15). Erdmann et al. (5) first noted that vanadate stimulated the oxidation of NADH by plasma membranes and attributed this effect to a membrane containing NAD(P)H-dependent V(V) reductase. Later studies by Liochev and Fridovich indicated that endogenous superoxide ( 02 ) plays a central role in this reaction ( 4, 12, 13) . They proposed that NAD ( P) H dehydrogenases or oxidases produce 02, which causes VCV ) to stimulate NAD ( P) H oxidation via the following free radical chain mechanism ( 4, 12, 13) :

Mar 1, 1992

By Oliver Bowles

"Introduction.During recent months the Bureau of Mines has conducted a detailed study of the slate industry with special reference to increased efficiency in its production, preparation and utilization. The results of these investigations will be incorporated in a forthcoming bulletin. The purpose of this preliminary paper is three-fold. One object is to bring to the attention of slate producers certain modifications in manufacture and classification which would encourage a wider use of slate. A second purpose is to direct the thought of roofers toward the importance of proper laying of slate, and the third object is to acquaint the general public with its enduring qualities.Origin and character.Without entering into any detailed discussion of the origin and history of slate, a subject to be covered in the bulletin mentioned, it may be of interest to the general reader to know that slate is originally formed from mud or soft clay, carried down by streams and laid down in successive layers in deep water. The pressure of superimposed materials gradually compresses the clay into a firm rock known as shale. In many places this shale was, during the succeeding ages, subjected to intense pressure and folding due to mountain-building forces within the earth. This intense pressure, together with high temperature, changed the clay into other minerals such as mica, chlorite, and silica, which are very resistant to weathering, and also developed a very definite cleavage or splitting direction which characterizes the rock as slate. It is this property which renders slate of value for roofing, for, by using a broad chisel and a wooden mallet, a slate worker can readily split it into thin sheets which are later trimmed into rectangles of various sizes."

Jul 1, 1921

By A. F. Colombo

Laboratory-scale tests were conducted by the Bureau of Mines on an argillaceous Michigan copper ore and mill tailing to determine the feasibility of leaching with acidified ferric sulfate solutions. The ore and tailings, containing 1.24 and 0.24 percent copper, respectively, were from the White Pine Copper Co., Ontonagon County, Mich. The investigation showed that ferric sulfate leaching of the ore and tailings followed a predictable pattern. Thus, with 4 hours of leaching, up to 58 percent of the copper in the ore was extracted, but prolonged leaching (2 to 3 weeks) was required to dissolve more than 90 percent of the copper. Similarly, about 50 percent of the copper in the mill tailings sample was dissolved in a few hours, but 8 days or more were required for extractions of over 90 percent.

Jan 1, 1962

By V. Castranova, K. Van Dyke

"I. INTRODUCTIONA mechanism which is present in leukocytes and capable of releasing histamine from rabbit platelets was first described by Barbaro and Zvaitler in I966. A soluble mediator between rabbit leukocytes and platelets was also detected by Siraganian and Osier in 1971. This factor was isolated and characterized in 1971 by Benveniste et al. and named platelet activating factor i PAF). It was shown to be released from rabbit basophils through an antigen - IgE-dependent mechanism. The presence of PAF in human leukocytes' and its aggregation and releasing effects on human platelets were also demonstrated. Chemical analysis has shown that PAF is a glycerophospholipid with a choline polar head group. an ester-linked acyl chain at the second carbon and a nonester link at the first carbon.' The structure of the mediator was found to be 1-O-alky1-2-acetyl-sn-glyceryl-3-phosphoryl choline and it has been chemically synthesized.""' A variable portion exists in the alkyl group attached to the first carbon which can have a variety of molecular sizes such as C and C (where Cu is more abundant). Recent work by Pinckard et al."" has shown that there are at least five variations of the alkyl group.PAF has been shown to have a broad range of biological effects. Release of PAF from alveolar macrophages may be important in asthma, allergy, and shock states. In a rabbit model of antigen IgE anaphylaxsis. PAF can induce all of the effects of antigen challenge and. therefore is presumed to be a key mediator in production of anaphylaxsis. In addition to aggregating and degranulating platelets it is a potent chemoattractant."" and causes contraction of guinea pig ileum contraction of lung tissue and enhanced capillary permeability PAF has important effects in the kidney and is also known as the renal hypotensive factor proposed by Blank et al. who found the structure of PAF independently of Benveniste et al.' In producing these responses. PAF acts by a receptor-like mechanism. In platelets. PAF selectively desensitizes itself but not thrombin or collagen. In smooth muscle tissues a similar phenomenon occurs with anaphylatoxin or other stimuli.In vivo. PAF probably acts in concert with other agents in producing its various biological effects. It causes platelets to release histamine serotonin and RCS (rabbit-contractile substance formed from prostaglandins PPG2, PGH2 and TXA2) which contracts rabbit aorta. PAF can cause cells to release SRS-A and leukotriene B."

Jan 1, 1989