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By A. J. Kraemer

"Introduction In 1925 the Bureau of Mines published as Technical Paper 346 a discussion of typical crude oils of the Western Hemisphere. That paper was one of a series of surveys of typical crude oils, and was the first of these to deal with properties of crude oils from countries other than the United States. The paper contains comments, tabulated data, and individual analyses of crudes typical of the producing districts of Canada, Mexico, Trinidad, Venezuela, Argentina, Colombia, and Peru; for comparison, it also has analyses of typical crudes from the chief producing districts of the United States.The Bureau of Mines undertook a study of foreign crude oils for two reasons: First, foreign fields are potential sources of supply for the United States; in fact, considerable quantities of some foreign crudes have already been imported. Second, these oils are very similar in physical and chemical properties to oils found in the United States, and a study of these resemblances has scientific value.After the publication of Technical Paper 346, the attention of the Bureau was called to the fact that the two analyses of crude oil from Venezuela which appeared in that paper were not completely representative of the production of that country. Samples of other types of oil were procured through the cooperation of Mr. R. Ogarrio, manager of the Texas Petroleum. Co., Huston, Texas, and officials of the following companies operating in Venezuela; British Controlled Oilfields, Ltd., Venezuelan Oil Concessions, Ltd., Creole Syndicate, and Venezuelan Gulf Oil Co.. Samples were collected and dispatched by Mr. D. 3. Park, representative in Maracaibo, Venezuela, of the Texas Petroleum Co. The value of the interest and cooperation of these agencies in obtaining the samples is gratefully acknowledged."

May 1, 1927

By Harry Freund, Kenneth H. Hammill, Francis C. Bissonnette

"Gallic acid is a sensitive, stable, colorimetric reagent for the determination of tantalum in the range of 2 to 40 µ g.Ta/ml. The method consists of the fusion of tantalum oxide with potassium pyrosulfate and solution of the cooled melt in saturated ammonium oxalate, followed by development of a yellow complex with an ethanolic solution of gallic acid. The tantalum-gallic acid complex absorbs over a broad region in the blue and near ultraviolet. Adverse effects due to interfering ions and solution conditions, such as oxalate concentration and pH, can be minimized by a suitable choice of wave length.by a suitable choice of wave length.A new and sensitive colorimetric method is provided that has been used successfully at the Northwest Electrodevelopment Laboratory of the Federal Bureau of Mines for determining minor amounts of tantalum.INTRODUCTIONThe development of corrosion-resistant alloys at the Northwest Electrodevelopment Laboratory prompted a review of the analytical chemistry of columbium (niobium) and tantahnn. Not only are these elements difficult to determine in small amounts, but tantalum especially lacks both sensitive and characteristic color reactions. Various phenolic compounds have been suggested as colorimetric reagents for tantalum, Quentin and Wagner (10, p. 24B) 1/ recommend the use of tannin. The use of pyrogallol was suggested originally by Krivoshlykov (6, pp. 59-60), whose method recently has been subject to a number of modifications (3, pp. 249-254; 5, pp. 1340-1344; 1, pp. 1803-18oi; 4, pp. 345-350). The yellow coloration produced by pyrocatechol in an oxalate solution containing tantalum may also be used to estimate tantalum ( 11, pp, ll-1-4-148) . The use of hydrogen peroxide has been recommended also (7, pp. 164-165; 9, pp. 926-931).Aside from a lack of specificity and sensitivity, the major failing of phenolic reagents is their susceptibility to air oxidation. The oxidation products are highly colored and absorb in the same spectral region as the tantalum complex. Holding reductants are not completely satisfactory in minimizing this effect. Increasing the acidity, while retarding the oxidation, has an adverse effect on the tantalum sensitivity."

Sep 1, 1956

By Maria I. De Rosa

Coal mine fires pose a constant danger to the safety of miners and to their livelihood. Underground mine fires pose an added hazard because of the confined environment with remote exits. Enactment of safety regulations [30 CFR2 75 and 771 for under- ground coal mines and surface coal operations has greatly improved the safety of miners. However, mine fires and fire injuries remain serious hazards for all coal mining operations. This report analyzes mine fires and fire injuries for all U.S. coal mining categories (underground coal mines, surface of underground coal mines, surface coal mines, and coal preparation plants) during 1990-1999. Fires involving contractors are also included in the analysis. Similar analyses (for underground coal mines only) by the former U.S. Bureau of Mines (USBM) were reported by McDonald and Pornroy [I9801 and Pornroy and Carigiet [I9951 for 1950-1977 and 1978-1992, respectively. For comparison purposes, data for 1978-1 992 are mentioned in the "Underground Coal Mine Fires" section of this report. Detailed analyses of mobile equipment fires for all underground and surface coal and metal/nonmetal mining categories during 1990-1999 have recently been reported by NIOSH [De Rosa 20041. Risk rate values (fire and injury risk rates) for the 10-year period (1990-1999) and for five successive 2-year periods within the 10-year period are derived. Risk rate values for individual states for the 10-year period are also derived. Other variables by state and time period include employees&apos; working hours, lost workdays, and coal production (underground and surface coal mines only). The number of fire fatalities is reported by time period. Variables such as ignition source, method of detection and suppression, equipment involved, location, and burning material are reported by five 2-year periods only. Furthermore, the number of fire injuries per number of fires causing injuries and total fires has been analyzed by year, ignition source, equipment involved, and location. For comparison purposes, the major fire and fire injury findings for all coal mining categories have been reported. The data in this report were derived from "Injury Experience in Coal Mining" [MSHA 1991a, 1992,1993,1994a, 1995a, 1996, 1997, 1998b, 1999c, 20001, "Fire Accident Reports" [MSHA 199 1 b,c; 1994b; 1995b,c; 1998a,c,d,e,f; 1999a,b,d,e], MSHA "Fire Accident Abstracts" internal publications, and verbal communications with mine personnel. Mining companies are required by 30 CFR 50 to report to MSHA all fires that result in injuries and fires that are not extinguished within 30 min of discovery. A small number of fires lasting <30 min without injuries reported in the "Fire Accident Abstracts" have been included in this report. The analysis in this report will provide the National Institute for Occupational Safety and Health (NIOSH), the Mine Safety and Health Administration (MSHA), and the mining industry with a better understanding of the causes and hazards of mine fires and fire injuries. It will also form a basis for developing future fire research programs.

Jan 1, 2004

By F. P. Haver

The purpose of this investigation was to determine the effect of common impurities, that is, oxygen, nitrogen, carbon, and iron, on the Brinell hardness of electrolytic titanium. On a weight basis, nitrogen had the greatest hardening effect, followed by oxygen, carbon, and iron in order. The hardening effects of oxygen and carbon were almost identical up to a concentration of approximately 0.1 percent by weight. Above this concentration, the relative hardening effect of carbon decreased rapidly, possibly because of its limited solid solubility in a-titanium. Hardness vs. composition curves for both oxygen and nitrogen were essentially straight lines over the range of Brinell hardness numbers (B.h.n.) covered in the investigation. The hardness of titanium was also determined as a function of the percentage of impurity atoms. On this basis, iron in concentrations up to 0.17 atomic percent had a greater hardening effect than either oxygen or carbon. INTRODUCTION Determination of the as-cast hardness of arc-melted titanium is a method of quality control widely used in industry. Numerous studies4/ have been made of the effect of impurities on the hardness obtained by this method. However, most of them have been based on the use of either iodide titanium or commercially pure Kroll sponge (B.h.n. >90), as a starting material.

Jan 1, 1959

By N. L. Wimmler

"INRODUCTIONSedimentary deposits of titaniferrous magnetite occur at various localities in the eastern foothills of the Teton Ranse in Deer Lodge County, Mont. The Choteau deposit was examined by a Bureau of Mines engineer in August 1942. An exploration project was recommended.Core drilling exploration was begun in June 1945; it was concluded in August 1945, Seventy-six holes were drilled. This report presents the data obtained by the Bureau of Mines exploration.ACKNOWLEDGMENTIn its program of exploration of mineral, deposits, the Bureau of Mines has as its primary objective, the more effective utilization of our mineral resources to the end that they make the greatest possible contri¬bution to national security and economy. It is the policy of the Bureau to publish the facts developed by each exploratory project as soon as practicable after its conclusion. The Mining Branch, Lowell B. Moon, Chief, conducts preliminary examination, performs the actual exploratory work, and prepares the final, report. The. Metallurgical Branch, R. G. Knickerbocker, Chief, analyzes samples and performs beneficiation tests. Both of these branches are under the supervision of Dr. R. S. Dean, Assistant-Director. The field work was supervised by Earshel W. Newman, engineer in charge of the Helena Field Office. D. B. Hoiekvam was the project engineer; he provided most of the data used in the preparation of this report."

Dec 1, 1946

By A. Livingston

This paper on mining practice at the Fresnillo silver mines is one of a series being prepared by the Bureau of Mines on mining practices, methods, and costs in the various mining districts of North America. Two classes of ore are produced at Fresnillo. A low-grade oxidized silver ore; end a complex-base sulphide are containing gold, silver, lead, zinc, and copper. This paper is confined to a discussion of operations relating to the production of oxidized silver ores. To date, more than 10 Million tons of this ore rave been mined. The present (June, 1931) daily production is 2,000 tons of ore, and approximately 600 men are employed in the mining operations.

Jan 1, 1932

By D. H. Zellers

Since its inception the United States Bureau of Mines has fostered the development of portable mine lamps. Although there is still much to be desired with respect to illumination in coal and metal mines and the replacement of open lights has been slow the Bureau has been given credit for assisting materially in the development and introduction of the safe and efficient portable mine-lighting equipment available today. Much of the work conducted by the electrical section of the Bureau entails approval tests of various types of electrical equipment, including lamps; to be used in atmospheres that may contain methane or coal dust in explosive proportion. If a can lamp meets the requirements-for safety, efficiency, and adequacy, as published in Schedule 6B,4 it is approved and is generally known as a "permissible" lamp. The terms "approved" and &apos;"permissible&apos; often are used interchangeably. The manufacturer must put an approval plate on each approved lamp, showing it has mot the schedule requirements. The approval plate is not a guarantee that the lamp is safe. However, if the lamp, once in service, has not had any parts changed or improperly assembled or if carts that wear out or depreciate have been properly replaced it should still, be safe, efficient, and adequate for the service intended. Virtually all electric cap lamps in service today in the United States and a great many that have been sent to foreign countries bear the approval plate of the United States Bureau of Mines. Although many explosions have been attributed to open lights none has been charged against the permissible cap lamp. Nystagmus, a disease of the eye attributed to working under insufficient illumination, is practically unknown among; American miners, although it is quite prevalent among European miners.

Jan 1, 1935

This Part is concerned with the theoretical study of UHF radio communication in coal mines, with particular reference to the rate of loss of signal strength along a tunnel, and from one tunnel to another around a corner. Of prime interest are the nature of the propagation mechanism and the prediction of the radio frequency which propagates with the smallest loss. Our theoretical results are compared with measurements made by Collins Radio Co. This work was conducted as part of the Pittsburgh Mining and Safety Research Center&apos;s investigation of new ways to reach and extend two-way communications to the key individuals that are highly mobile within the sections and haulage ways of coal mines.

Jan 1, 1974

By Roy S. Nutter

An expert system advisor consultant to assist a coal mine section foreman is described in this report. The system is designed for an underground continuous miner section that is being specifically used for longwall development. The system provides three methods of operation that include normal operational mode for use underground, a training mode for use in training section foremen under controlled classroom conditions, and a demonstration mode that is free running. The Face Decision Support System or FDSS, is designed to interface with section environmental monitoring equipment and section production monitoring equipment that may appear in the future. This provides automated reprioritzation of the section foreman&apos;s job list from the system. The system 1S written in LASER which is written in C and is operated under the UNIX operating system. The objective of the entire FOSS system is to ensure that no job or piece of information important to safety or to production is forgotten because of the immediate problems confronting the section foreman.

Jan 1, 1988

By Joseph A. DeCarlo

According to the annual survey of beehive-coke plants by the Bureau of Mines, United States Department of the Interior, there were 61 plants with 9,549 ovens in the United States on December 31, 1956, This publication in¬cludes only those for which an annual report was filed with the Bureau of Mines. Not all plants listed were active, however, as nearly one-third of those canvassed were idle all year. A compilation of the returns showed that 44 plants with 6,920 ovens were active part or all year and 17 plants with 2,629 ovens were idle throughout the year. The capacity of beehive ovens has fluctuated between 6 and 14 million tons during the past decade. At the end of 1956, the annual coke capacity of beehive ovens on which reports were received amounted to 5.8 million tons. As noted in table 2, however, not all of this capacity was in operating condition, as 2,093 ovens with a capacity of 1.2 million tons were not operable on [ember] 31, 1956.

Jan 1, 1958

Mining officials, as well as members of the Bureau of Mines staff, in their efforts to make mining safer are confronted from time to time pith complicated problems concerning solution of which there is a diversity of opinion. To reduce these differences of opinion as much as possible and to obtain a generally acceptable decision on any mine-safety question, the Director of the U.S. Bureau of Mines established the Mine Safety Board on June 1, 1924- *** to consider questions arising within any divisions of the Bureau that require a definition of tie Bureaus s collective opinion as to safety practices, safety devices, or safety methods for underground operations or open-pit mining. The approved2/decisions shall form the basis of teaching and policy for the Bureau.

Jan 1, 1935

By Ralph B. Adair

The Bureau of Mines conducted laboratory and continuous pilot plant flotation tests to determine the feasibility of recovering commercial-grade mica from an Alabama graphitic-mica schist. Preconcentration of the ground ore on a Humphrey&apos;s spiral was employed to reject the heavy minerals and part of the quartz in a product virtually free of mica. The acid-cationic mica flotation process recovered over 89 percent of the mica in a product containing 98.7 percent mica. Grinding of the mica concentrate in a fluid energy mill produced a product with a bulk density of 12 lb per cubic foot.

Jan 1, 1969

By Andrew M. Leszcykowski

In 1984, personnel from the U.S. Bureau of Mines examined the 9,550-acre Yatahoney Creek Wilderness Study Area (WSA) for mineral resources. This study area, in southwestern Idaho, is underlain by tuffs and basalt of Tertiary age. Owyhee County mining records and U.S. Bureau of Land Management records, and other references were examined prior to the field study. There are no known mines, claims, or prospects in or near the WSA. No evidence of mineral deposits or occurrences was observed. Oil and gas leases or lease applications are in the southern portion and northeast corner of the WSA. Although placer gold exists in the Owyhee River drainage, there are insufficient deposits of gold-bearing gravel in the Yatahoney Creek WSA to enable mining. INTRODUCTION The U.S. Bureau of Mines (USBM) and the U.S. Geological Survey (USGS) conduct mineral surveys of designated wilderness study areas (WSAs) 1/ to ensure mineral values that may be present are considered in wilderness recommendations. The USBM examines known mines, prospects, and mineralized sites, and the USGS performs geologic mapping, and geochemical and geophysical surveys on an areal basis.

Jan 1, 1986

By Wilbur I. Duvall

A linear array of shot and gage holes 30 feet deep in a granite outcrop was used to compare the size and shape of radial strain pulses produced in the rock when short cylindrical charges of cast composition B were detonated axially or at one end. The axially detonated charges produced radial strain pulses that had shorter rise times and larger peak strain than the strain pulses produced by end detonated charges.

Jan 1, 1965

By Nabil A. Bibawy

An improved method for preparing gravimetric standard gas mixtures of helium-4 in nitrogen has been developed by the U.S. Bureau of Mines. A single-pan 12-kg analytical balance that has a sensitivity of 3 mg is used to prepare the mixture. The balance will accommodate a cylinder having a volume of approximately 4 L that weighs approximately 5 kg. The method has been improved to a precision of ±O.04 pct by performing four successive dilutions, by improved handling of gases in the manifold, and by using an improved analytical method to select high-purity gases.

Jan 1, 1990

By C. J. Thompson

Two sulfur compounds--the 2,2,5-trimethyl- and the 2,2,5,5-tetramethyl derivatives of thiacyclopentane--were identified in Wilmington, Calif., crude oil, using microdesulfurization and gas-liquid chromtography techniques.

Jan 1, 1963

By F. W. Wood

The method described may be used to delineate irregularities, inclusions, porosity, or shrink holes in ingots up to 43 inches in length. Rou¬tine testing does not require technical personnel, and the equipment is easily maintained. INTRODUCTION For a number of years, the Northwest Electrodevelopment Laboratory of the Bureau of Mines, Albany, Oreg., under contract with the Atomic Energy Commission and the Naval Reactors Division of the Bureau of Ships, has studied the production of zirconium and has adopted the Kroll magnesium-reduction process3/ as the, most economical means of producing high-purity zirconium sponge in quantities commensurate with demand. Consumable-electrode arc melting4/ provides a practical means of melting the sponge without increasing the impurity content. The ultimate application for which the metal is intended requires that strict specifications be met to insure workability and maintain the nuclear properties and corrosion resistance. The control measures employed to satisfy these specifications include chemical, spectrographic, and metallographic analyses, mechanical and corrosion tests, and ultrasonic inspection of the finished ingot. The primary purpose of ultrasonic inspection is to augment the other control measures by checking the soundness of each ingot leaving the laboratory. An incidental but important function has been the revelation of information leading to better understanding of the arc-melting process. For example, information obtained through ultrasonic inspection relative to the occurrence and distribution of porosity in ingots has resulted in a. modification of melting practices that minimizes the occurrence.

Jan 1, 1955

By T. A. Sullivan

High-purity vanadium metal was prepared by electrorefining commercial vanadium in a molten sodium bromide, potassium bromide, and vanadium dibromide electrolyte. Variables investigated were operating temperature, current densities, electrolyte composition, and condition of the anode. The purity of the refined metal was in the range of 99.95 percent vana-dium. Iron and oxygen in the 50- to 250-ppm range were the only major impurities. Metal with hardness numbers of 50 to 60 in the Rockwell F scale was prepared from feed material with a Rockwell B hardness of 90. The arc-melted metal was highly ductile and could be cold-worked into sheet or foil.

Jan 1, 1965

By Thomas E. Green

A gas volumetric method was developed for determining metallic aluminum at the 0.01-to 0.3-percent level in 100-gram samples of recycled glass. The method is based on the measurement of the change in gas volume produced by the reaction 2 Al + 2 NaOH + 2 H2O ? 2 NaAl02 + 3 H2 using a simple apparatus assembled from readily available glassware. Apart from sampling errors, the precision of the method is within ±5 percent. A minor modification of the apparatus would extend the method to larger samples or samples of higher metallic aluminum content. Metallic iron and metallic zinc do not interfere at the concentrations found in recycled glass recovered from incinerator residues.

Jan 1, 1971

By William H. Pailes, Vincent Castronova, Daniel Lewis, Norman L. Lapp, George Goodman

"INTRODCJCTIONAlveolar macrophages are free lung cells located on the surface of small airways and alveoli. These phagocytes play an important role in the protection of the lung against airborne bacteria and particles.1 However, hyperactivation of pulmonary phagocytes can lead to excessive secretion of enzymes and reactive oxygen species which could result in lung injury, emphysema, or fibrosis.2,3 Analysis of bronchoalveolar lavage effluents for cell types and cellular activity has yielded information concerning the etiology of various pneumoconioses. For example, emphysema associated with inhalation of coal dust or cigarette smoke has been related to enhanced secretion of reactive oxygen species from alveolar macrophages.4-7 In contrast, hypoactivation of alveolar macrophages has been associated with inhalation of diesel particulates"" and has been related to increased susceptibility to pulmonary infection. s Inhalation of cotton dust has been associated with dramatic increases in lavagable polymorphonuclear leukocytes9 while pulmonary sarcoidosis and silicosis have been related with high numbers of lymphocytes in lavage effluentsl0,11The objective of the present study was to obtain lavage effluents from 8 control subjects, 8 healthy power plant workers exposed to fly ash, 1 healthy coal miner, and 1 rock driller with acute silicosis. These effluents were analyzed for total numbers of alveolar macrophages, lymphocytes and neutrophils and for secretory activity of alveolar macrophages. Data were then analyzed to determine what response patterns were characteristic for given dust exposures.METHODSSelection of SubjectsThe 8 control subjectS were all adult males from the area of Morgantown, WV. Two subjects among the controls had smoked cigarettes for approximately three pack-years and had stopped more than ten years ago. The 8 power plant :workers were all healthy adult male employees of a power facility in Hatfield, PA, approximately thirty miles from Morgantown. One of the power plant personnel was a comparable ex-smoker. The remaining subjects were all lifelong non-smokers. The coal miner was a healthy non-smoking male from Morgantown, WV. The rock driller was a patient under treatment with corticosteroids for acute silicosis. He had shown considerable clinical improvement with this treatment but still manifested significant radiologic and pulmonary functional abnonnalities at the time of lavage. The mean age of the 8 control subjects was 36 years (range: 31 to 49 years); the mean age of the remaining subjects studied was 38 years (range: 29 to 53 years)."

Jan 1, 1990